CN1994519A - Filter core with molecular sieve structure and method for preparing same - Google Patents

Filter core with molecular sieve structure and method for preparing same Download PDF

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Publication number
CN1994519A
CN1994519A CN 200610170662 CN200610170662A CN1994519A CN 1994519 A CN1994519 A CN 1994519A CN 200610170662 CN200610170662 CN 200610170662 CN 200610170662 A CN200610170662 A CN 200610170662A CN 1994519 A CN1994519 A CN 1994519A
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Prior art keywords
molecular sieve
filter core
powder
order
structure according
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CN100464818C (en
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苟全伦
栾云堂
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Beijing Zhongke Green Hydrogen Technology Co ltd
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BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd
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Abstract

The invention relates to a filter element at molecule screen structure and relative production, wherein its production comprises that: preparing materials via formula, mixing and putting into mould; sintering at high temperature, drying to normal temperature, removing mould, to obtain the porous filter element. The invention is made for natural mineral material, with micro filter, molecule wide adsorption and static adsorption characters. The invention can effectively remove virus, harmful heavy metals, etc.

Description

A kind of filter core with molecular sieve structure and preparation method thereof
Technical field
The present invention relates to a kind of filter core, particularly relate to a kind of filter core with molecular sieve structure and preparation method thereof.
Background technology
At present, along with developing rapidly of industry and agricultural, cause China's water resource to be seriously damaged.Increasing industrial wastewater discharge has destroyed our ecological environment in rivers, lake.The discharging wantonly of the extensive application of agricultural chemicals, pesticide and house refuse causes the quality of groundwater variation, and causes producing in the water a lot of harmful materials.Water pollutes more and more becomes the severe problem that influences people's life.
Present stage, along with growth in the living standard, people's health care consciousness is also more and more stronger.Only can not satisfy people through the water source of waterworks sterilization normally drinks and other service condition.Drink the water quality of health, safety, become most of residents' primary demand.The water-purifying device miscellaneous and the filtering technique that occur on the market arise at the historic moment under this condition.
At present, the material for core that is used for purifying drinking water mainly contains PP cotton, active carbon, ion exchange resin, RO reverse osmosis membrane etc.The PP cotton is used for absorption more and removes suspended impurity, particle, mud or the like in the water, is applicable to preposition filtration.Active carbon is an abutment surface cellular tissue absorption chemical pollutant, can improve the heterochromatic peculiar smell in the water and remove some organic pollutions, but effect is not fine, and some heavy metals and salts substances in the water are not had tangible removal effect, is not suitable for being used in the relatively poor area of water quality.Ion exchange resin generally is used for calcium, magnesium ion softening or removal water, and the reduction hardness of water is used for industrial preparation demineralized water more or family's soft water needs, and is not suitable for human body and directly drinks.The RO counter-infiltration is one of effective water treatment mode in the existing science and technology, it can handle salt in the water (as hardness impurity such as calcium, magnesium), heavy metal, chemical residual material effectively, but the water that this filter membrane comes out is pure water, be used for industrial pure water needs such as seawater desalination system, electric ultrapure water rectification systems, biochemical pharmacy more, wash kidney, Cosmetic Manufacture manufacturing, beverage, packing water etc., this water does not contain human body and needs mineral matter, thereby is not suitable for human body and directly drinks.
Summary of the invention
The present invention provides a kind of filter core that is used for purifying drinking water in order to address the above problem, especially a kind of filter core with molecular sieve structure made from molecular screen material.This filter core with molecular sieve structure can effectively improve the water quality of drinking water, goes out water security, health, meets national drinking water standard fully, is fit to very much the demand of drinking.
An object of the present invention is to provide a kind of filter core with molecular sieve structure.
Another object of the present invention provides the preparation method of described filter core with molecular sieve structure.
The objective of the invention is to be achieved through the following technical solutions:
A kind of filter core with molecular sieve structure, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-300 of activated carbon powder 10-200 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 5-20 5A molecular sieve powder 5-20g
Gas generation agent 10-200
Preferably, a kind of filter core with molecular sieve structure, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 180-250 of activated carbon powder 80-150 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 10-20 5A molecular sieve powder 10-20g
Gas generation agent 50-150
More preferably, a kind of filter core with molecular sieve structure, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 200g of activated carbon powder 90g 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 10g 5A molecular sieve powder 10g
Gas generation agent 50g
Activated carbon powder described in the present invention is the medicinal active powdered carbon, has huge specific area, can efficiently adsorb chemical fertilizer, residues of pesticides, heterochromatic peculiar smell, chlorine and each heavy metal species, and its order number is the 40-200 order.
Polyethylene powder described in the present invention has the effect of powerful static dynamic absorption, can capture trickle, superfine particle that microfiltration can not filtration resistance, and its order number is the 20-160 order, and molecular weight is 1,500,000-7,000,000, and preferred, molecular weight is 2,500,000-4,000,000.
4A molecular sieve powder described in the present invention, 5A molecular sieve powder also can adsorb peculiar smell, foreign odor, industrial solvent etc. in a large number, and its order number is the 40-200 order.
Gas generation agent described in the present invention is food-grade carbonic hydroammonium, Celogen Az, oxalic acid, can play pore-creating and make the effect in chamber, and its order number is the 150-250 order, and is preferred, food-grade carbonic hydroammonium.
The preparation method of a kind of filter core with molecular sieve structure of the present invention, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 20-40 minute, insert in the mould again, at high temperature through the sintering aftershaping, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness, height of porous.In use, this naked filter core liner two-layer nonwoven, the outsourcing two-layer nonwoven wraps polypropylene porous net at skin again, and bonding the going up in filter core two ends connects end cap, is positioned over stainless steel or plastic casing, gets final product.
Sintering temperature is at 200-300 ℃ among the preparation method of a kind of filter core with molecular sieve structure of the present invention, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
A kind of filter core with molecular sieve structure of the present invention, utilize the newest fruits of nonmetallic mineral research field, employing has refining the forming of natural mineral raw of specific physical chemical property, has submicron microfiltration, the absorption of molecular sieve wide spectrum and static dynamic absorption three big technical characterstics.(1) submicron microfiltration structure, this is that an accuracy rating is 0.1 micron, and absolute precision is 0.4 micron a microfiltration layer, and it is the harmful bacteria in the filtering water all.(2) molecular sieve wide spectrum absorbing structure, it can efficiently adsorb various chemical pollutants, heavy metal and chlorine such as Insecticides (tech) ﹠ Herbicides (tech), industrial solvent peculiar smell and the foreign odor at interior various materials.(3) static dynamic absorption structure can capture the molecule that microfiltration can not filtration resistance, and the harmful particle of various ultra micros.After testing, filter core with molecular sieve structure of the present invention is the malignant bacteria in the filtering drinking water, harmful heavy metal, toxic organics, odor smell etc. fully, and the water after guaranteeing to filter becomes the drinking water of safety and Health.
The specific embodiment
Following examples are in order further to describe the present invention for example, rather than limit the present invention by any way.
Embodiment 1
Polyethylene powder (100 order) 200g of medicinal active powdered carbon (160 order) 90g 4,000,000 molecular weight
4A molecular sieve powder (80 order) 10g 5A molecular sieve powder (100 order) 10g
Food-grade carbonic hydroammonium (180 order) 50g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 30 minutes, insert again in the tubular die, at 250 ℃ of following sintering after 150 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 2
Polyethylene powder (50 order) 280g of medicinal active powdered carbon (60 order) 25g 3,000,000 molecular weight
4A molecular sieve powder (150 order) 5g 5A molecular sieve powder (60 order) 15g
Celogen Az (160 order) 30g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 25 minutes, insert again in the tubular die, at 260 ℃ of following sintering after 130 minutes, the demoulding after 45 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 3
Polyethylene powder (150 order) 100g of medicinal active powdered carbon (200 order) 110g 2,500,000 molecular weight
4A molecular sieve powder (70 order) 15g 5A molecular sieve powder (180 order) 20g
Oxalic acid (250 order) 150g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 40 minutes, insert again in the tubular die, at 230 ℃ of following sintering after 160 minutes, the demoulding after 50 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 4
Polyethylene powder (80 order) 130g of medicinal active powdered carbon (100 order) 190g 4,500,000 molecular weight
4A molecular sieve powder (200 order) 18g 5A molecular sieve powder (160 order) 8g
Food-grade carbonic hydroammonium (150 order) 15g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 35 minutes, insert again in the tubular die, at 220 ℃ of following sintering after 120 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Below the effect of filter core with molecular sieve structure by the survey report explanation embodiment of the invention 1;
Institute for Environment Hygiene and Health Related Product Safety, China CDC
Survey report
Sample is accepted numbering: the 2005KF0890 date: on December 9th, 2005
The sample title The filter core of the embodiment of the invention 1Kind of inspection Entrust
Interventions Requested The filter element filtering performance testDate of manufacture In September, 2005
Be subjected to the sample date On November 28th, 2005Inspected the date On December 9th, 2005
Assay:
According to " U.S.'s 2001 drinking water standards ", " European Union's 1998 drinking water standards ", U.S. EPA 524.2 methods " stripping capture-gas phase look/mass spectrometric determination volatile organic matter method ", the filter core with molecular sieve structure of inspecting by ready samples is carried out filtration test.At specified aquifer yield 0m 3The time, through this filter core, filter core sees Table 1 to the clearance of test compound to running water with flow 0.19L/min.
The filter core with molecular sieve structure water examination result of table one embodiment of the invention 1
Sequence number The mensuration project Mark-on influent density (μ g/L) Filter back water concentration (μ g/L) Clearance (%)
1 2 3 4 5 Tribute selenium beryllium barium chromium 8.7 9.3 9.2 14 19 <0.2 <1 0.5 7 8 98.9 94.6 94.6 50.0 57.9
6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Cadmium antimony chloroform bromofom chlorodibromomethane 1,1,1-trichloroethanes 1,1,2-trichloroethanes 1,2-dichloropropane 1,1,1,2-tetrachloroethanes 1,2-Bromofume vinyl chloride cis-1,2-dichloroethylene anti-form-1,2-dichloroethylene 1,1-dichloroethylene trichloro-ethylene tetrachloro-ethylene benzene toluene ethylbenzene chlorobenzene butachlor butylate Niran heptachlor Bravo 4,4 '-drip to drip her 4,4 '-DDT a-BHC 9.0 9.6 9.63 10.3 11.2 8.17 11.3 9.28 9.09 11.0 9.61 8.17 8.70 8.20 9.04 9.90 8.85 9.27 10.0 12.1 5.10 2.28 1.36 1.68 3.00 0.75 0.66 8.93 0.4 <0.5 <0.05 <0.18 <0.06 <0.08 <0.14 0.103 <0.11 <0.10 <0.19 <0.08 <0.08 <0.35 <0.09 <0.07 <0.03 <0.03 <0.04 <0.05 <0.02 <0.008 <0.01 <0.01 <0.02 <0.003 <0.006 <0.01 95.6 97.4 99.7 99.1 99.7 99.5 99.4 99.4 99.4 99.5 99.0 99.5 99.5 97.9 99.5 99.6 99.8 99.8 99.8 99.8 99.8 99.9 99.6 99.7 99.7 99.8 99.5 99.7

Claims (9)

1. filter core with molecular sieve structure, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-300 of activated carbon powder 10-200 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 5-20 5A molecular sieve powder 5-20g
Gas generation agent 10-200
2. a kind of filter core with molecular sieve structure according to claim 1, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 180-250 of activated carbon powder 80-150 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 10-20 5A molecular sieve powder 10-20g
Gas generation agent 50-150
3. a kind of filter core with molecular sieve structure according to claim 2, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 200g of activated carbon powder 90g 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 10g 5A molecular sieve powder 10g
Gas generation agent 50g
4. a kind of filter core with molecular sieve structure according to claim 1, wherein said activated carbon powder are the medicinal active powdered carbons, and its order number is the 40-200 order.
5. a kind of filter core with molecular sieve structure according to claim 4, the polyethylene powder of wherein said 1,500,000-7,000,000 molecular weight, molecular weight are 2,500,000-4,000,000, its order number is the 20-160 order.
6. a kind of filter core with molecular sieve structure according to claim 5, the order number of wherein said 4A molecular sieve powder and 5A molecular sieve powder is the 40-200 order.
7. a kind of filter core with molecular sieve structure according to claim 6, wherein said gas generation agent are food-grade carbonic hydroammonium or Celogen Az or oxalic acid, and its order number is the 150-250 order.
8. the preparation method of a kind of filter core with molecular sieve structure according to claim 1, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, placed grinding in ball grinder 20-40 minute, insert in the mould again, at high temperature through the sintering aftershaping, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness and height of porous.
9. the preparation method of a kind of filter core with molecular sieve structure according to claim 8, wherein said sintering temperature is at 200-300 ℃, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
CNB2006101706629A 2006-12-27 2006-12-27 Filter core with molecular sieve structure and method for preparing same Active CN100464818C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102350129A (en) * 2011-06-21 2012-02-15 黄光智 Integrated water purifying filter core for removing fluorine and filtering
CN102553352A (en) * 2011-10-20 2012-07-11 常州亚环环保科技有限公司 Structure filter for removing formaldehyde from drinking water and its preparation method
CN102698505A (en) * 2012-05-23 2012-10-03 北京佳康尔水处理技术有限公司 Method for preparing 13x molecular sieve filtering element for purifying drinking water
CN101898117B (en) * 2009-05-25 2013-01-02 奇迪电器集团有限公司 Filter medium, preparation method thereof, filter element, water purifying plant and water dispenser
CN104667889A (en) * 2015-01-29 2015-06-03 佛山市农业总公司 Filtering medium for removing nitrate in drinking water, filter core and preparation method
CN108889938A (en) * 2018-08-28 2018-11-27 佛山市宝粤美科技有限公司 A kind of production method of molecular sieve metal filtration plate
CN110217867A (en) * 2018-03-01 2019-09-10 云南诺能科技有限公司 A kind of Electrostatic Absorption process for purifying water and water purifier based on Internet of Things
CN110291394A (en) * 2017-01-10 2019-09-27 盛思锐股份公司 For detecting the sensor device of permanent gas

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CN1055869C (en) * 1997-12-12 2000-08-30 马昆 Structural filter element for purifying water and preparing process thereof
US20060000763A1 (en) * 2004-06-30 2006-01-05 Rinker Edward B Gravity flow carbon block filter
CN1329114C (en) * 2004-12-24 2007-08-01 上海化工研究院 Formulation of dry filter core for refrigerating system

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101898117B (en) * 2009-05-25 2013-01-02 奇迪电器集团有限公司 Filter medium, preparation method thereof, filter element, water purifying plant and water dispenser
CN102350129A (en) * 2011-06-21 2012-02-15 黄光智 Integrated water purifying filter core for removing fluorine and filtering
CN102553352A (en) * 2011-10-20 2012-07-11 常州亚环环保科技有限公司 Structure filter for removing formaldehyde from drinking water and its preparation method
CN102698505A (en) * 2012-05-23 2012-10-03 北京佳康尔水处理技术有限公司 Method for preparing 13x molecular sieve filtering element for purifying drinking water
CN102698505B (en) * 2012-05-23 2015-08-26 北京佳康尔水处理技术有限公司 A kind of preparation method of 13x molecular sieve filter element of purifying drinking water
CN104667889A (en) * 2015-01-29 2015-06-03 佛山市农业总公司 Filtering medium for removing nitrate in drinking water, filter core and preparation method
CN110291394A (en) * 2017-01-10 2019-09-27 盛思锐股份公司 For detecting the sensor device of permanent gas
US11506646B2 (en) 2017-01-10 2022-11-22 Sensirion Ag Sensor device for detecting a permanent gas
CN110217867A (en) * 2018-03-01 2019-09-10 云南诺能科技有限公司 A kind of Electrostatic Absorption process for purifying water and water purifier based on Internet of Things
CN108889938A (en) * 2018-08-28 2018-11-27 佛山市宝粤美科技有限公司 A kind of production method of molecular sieve metal filtration plate

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Address after: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

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