CN1984945A - Method for treating inner peripheral face of fluororesin tubular film, fluororesin tubular film, apparatus for treating inner peripheral face of fluororesin tubular film, method for treating inner per - Google Patents
Method for treating inner peripheral face of fluororesin tubular film, fluororesin tubular film, apparatus for treating inner peripheral face of fluororesin tubular film, method for treating inner per Download PDFInfo
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- CN1984945A CN1984945A CNA2005800235044A CN200580023504A CN1984945A CN 1984945 A CN1984945 A CN 1984945A CN A2005800235044 A CNA2005800235044 A CN A2005800235044A CN 200580023504 A CN200580023504 A CN 200580023504A CN 1984945 A CN1984945 A CN 1984945A
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- Prior art keywords
- shape film
- inner peripheral
- pfa
- tubulation shape
- peripheral surface
- Prior art date
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- 230000002093 peripheral effect Effects 0.000 title claims abstract description 127
- 238000000034 method Methods 0.000 title claims abstract description 55
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 229920001971 elastomer Polymers 0.000 claims abstract description 24
- 239000005060 rubber Substances 0.000 claims abstract description 24
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 120
- 239000007789 gas Substances 0.000 claims description 109
- 229910052786 argon Inorganic materials 0.000 claims description 60
- 239000001307 helium Substances 0.000 claims description 60
- 229910052734 helium Inorganic materials 0.000 claims description 60
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 60
- 229920005989 resin Polymers 0.000 claims description 55
- 239000011347 resin Substances 0.000 claims description 55
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 42
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 42
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 42
- 238000004381 surface treatment Methods 0.000 claims description 34
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 229910021529 ammonia Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 229910052757 nitrogen Inorganic materials 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 229920001296 polysiloxane Polymers 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- 235000011089 carbon dioxide Nutrition 0.000 claims description 16
- 230000008676 import Effects 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000003780 insertion Methods 0.000 claims description 2
- 230000037431 insertion Effects 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 abstract description 63
- 239000004945 silicone rubber Substances 0.000 abstract description 59
- 239000003795 chemical substances by application Substances 0.000 description 31
- 239000003595 mist Substances 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000007864 aqueous solution Substances 0.000 description 9
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- 150000002923 oximes Chemical class 0.000 description 7
- 229960004424 carbon dioxide Drugs 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 208000034189 Sclerosis Diseases 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 235000014347 soups Nutrition 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000004944 Liquid Silicone Rubber Substances 0.000 description 3
- -1 PFA ester Chemical class 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- YROGWJLGNLJNOK-UHFFFAOYSA-N 1-chloro-1-methoxypropane Chemical compound CCC(Cl)OC YROGWJLGNLJNOK-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229920013649 Paracril Polymers 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000001153 fluoro group Chemical class F* 0.000 description 1
- 125000004005 formimidoyl group Chemical group [H]\N=C(/[H])* 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- WALYXZANOBBHCI-UHFFFAOYSA-K magnesium sodium trichloride hydrate Chemical compound O.[Cl-].[Na+].[Mg+2].[Cl-].[Cl-] WALYXZANOBBHCI-UHFFFAOYSA-K 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- NLCVKZQQNSCDFU-UHFFFAOYSA-L potassium;sodium;dibromide Chemical compound [Na+].[K+].[Br-].[Br-] NLCVKZQQNSCDFU-UHFFFAOYSA-L 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Abstract
A method for treating an inner peripheral face (2) in a fluororesin tubular film (1) such as a PFA tubular film to be covered on the outer peripheral face of an elastic layer formed of rubber such as silicone rubber in a roller. This method comprises the steps of inserting an electrode into a space (4) surrounded by an inner peripheral face (2) of a fluororesin tubular film (1), introducing gas into the space (4), immersing at least a part of the fluororesin tubular film (1) in an electrically conductive liquid while avoiding the entry of the liquid into the space (4), and generating plasma of gas in the space (4). There are also provided a fluororesin tubular film (1) produced by this method, a roller using the fluororesin tubular film (1), and an apparatus for treating the inner peripheral face of a fluororesin tubular film (1).
Description
Technical field
The fluoro-resin tubulation shape film that the present invention relates to the inner peripheral surface treatment process of fluoro-resin tubulation shape film, obtains by this method, the cylinder of this fluoro-resin tubulation shape film, the inner peripheral surface treatment unit of fluoro-resin tubulation shape film have been used.
In addition, the present invention relates to the inner peripheral surface treatment process of PFA tubulation shape film, the PFA tubulation shape film that obtains by this method, used the cylinder of this PFA tubulation shape film, the inner peripheral surface treatment unit of PFA tubulation shape film.
Background technology
At present, in duplicating machine, printer or facsimile recorder etc., for its with paper on fusing toner, and use the elastic layer that on metal-cored periphery order lining is made of silicone rubber and the cylinder of PFA tubulation shape film.Because the binding property of PFA tubulation shape film and toning agent is low, so can prevent that toner adhesion is to the periphery of cylinder.Again because the thermotolerance and the wear resistant of PFA tubulation shape film is good, thus can be under with metal-cored heating condition long-time head roll.
Used the cylinder of this PFA tubulation shape film, for example can form with the following method: at the fixing PFA tubulation shape film of the inner face of cylindrical metal mould, the spatial interpolation that surrounds with this PFA tubulation shape film go into metal-cored after, again PFA tubulation shape film and metal-cored between inject silicone rubber, silicone rubber heating with injecting makes its sclerosis.
At this, because the binding property of PFA tubulation shape film and silicone rubber is relatively poor, so, the binding property with silicone rubber is improved by the inner peripheral surface of PFA tubulation shape film is handled.
Patent Document 1: the spy opens the 2003-122164 communique
Patent Document 2: the spy opens the 5-86222 communique
Patent Document 3: the spy opens communique No. 3431079
Patent Document 4: the spy opens the 9-208727 communique
Method as handling PFA tubulation shape film inner peripheral surface for example has the method (for example with reference to Patent Document 1) of using soup.Yet, in the method, owing to be, so exist in the problem that forms folding line on the PFA tubulation shape film after the processing by the soup that reinjects after an end of PFA tubulation shape film pressurization clamping is sealed.When on the cylinder that toner fixing is used, using this formation PFA tubulation creasy shape film, take place sometimes because the concavo-convex existence around the folding line causes the bad phenomenon of toner fixing.In addition, in this case, must be with stronger line pressure with toning agent photographic fixing on paper, owing to be difficult to break away from from cylinder with paper behind the toner fixing, so must on the periphery of PFA tubulation shape film, apply an amount of silicone oil.
In addition, do not form folding line, have periphery with PFA tubulation shape film and in chemical liquid groove, carry out continuously after soup handles, the method (for example with reference to Patent Document 2) of PFA tubulation shape film upset in order to make on the PFA tubulation shape film.But, in the method, after soup is handled, need and therefore the upset of PFA tubulation shape film, will be existed the low problem of processing efficiency.
In addition, as other method of the inner peripheral surface of handling PFA tubulation shape film, the method that the light that sends with ultraviolet laser shines (for example with reference to Patent Document 3) is arranged behind the pretreatment liquid of adhesion defined on the inner peripheral surface of PFA tubulation shape film.But in this method, before the inner peripheral surface of handling PFA tubulation shape film, the pretreatment liquid that must will contain ultraviolet-absorbing compound and fluorine class tensio-active agent is coated on the inner peripheral surface of PFA tubulation shape film, therefore, and the problem that exists process number to increase.In addition, this method is owing to be that the light that sends with ultraviolet laser on the inner peripheral surface of PFA tubulation shape film carries out the point-like radiation treatment, so processing efficiency is low, and also have deviation, the problem of the poor adhesion between PFA tubulation shape film and the silicone rubber take place when the processing of PFA tubulation shape film inner peripheral surface.
In addition, above-mentioned such problem during fluoro-resin tubulation shape film beyond using PFA tubulation shape film, also is owing to the relatively poor binding property of fluoro-resin with respect to bonded body causes.And, even under the situation of the rubber beyond bonded body has used silicone rubber,, just can cause the problems referred to above certainly since used fluoro-resin tubulation shape film.
Summary of the invention
The present invention In view of the foregoing constitutes, its purpose is, provides: can obtain the fluoro-resin tubulation shape film, the cylinder that has used this fluoro-resin tubulation shape film and the fluoro-resin tubulation shape film inner peripheral surface treatment unit that obtain with the fluoro-resin tubulation shape film inner peripheral surface treatment process of the good fluoro-resin tubulation shape film of the binding property of rubber, by this method.
Purpose of the present invention is again, provides: can obtain the PFA tubulation shape film, the cylinder that has used this PFA tubulation shape film and the PFA tubulation shape film inner peripheral surface treatment unit that obtain with the PFA tubulation shape film inner peripheral surface treatment process of the good PFA tubulation shape film of the binding property of silicone rubber, by this method.
The invention provides a kind of inner peripheral surface treatment process of fluoro-resin tubulation shape film, fluoro-resin tubulation shape film is overlayed on the periphery of elastic layer of the cylinder that contains elastic layer metal-cored and that be made of the rubber of being located on the metal-cored periphery, wherein, comprising: the spatial interpolation that surrounds at the inner peripheral surface with fluoro-resin tubulation shape film is gone into the operation of electrode; In the space, import the operation of gas; So that the mode that liquid does not enter in the space is immersed in operation in the conductive liquid with at least a portion of fluoro-resin tubulation shape film; In the space, produce the operation of the plasma body phenomenon of gas.
At this, in the inner peripheral surface treatment process of fluoro-resin tubulation shape film of the present invention, above-mentioned gas is preferably as follows mixed gas: the mixed gas of being made up of argon, helium, carbonic acid gas, methane; The mixed gas of forming by argon and ammonia; The mixed gas of forming by helium and ammonia; The mixed gas of forming by argon and helium and ammonia; The mixed gas of forming by argon and nitrogen and hydrogen; The mixed gas of forming by argon and carbonic acid gas and methane; The mixed gas of forming by helium and carbonic acid gas and methane; The mixed gas of forming by helium and nitrogen and hydrogen; The mixed gas of forming by argon and helium and nitrogen and hydrogen; The mixed gas of forming by argon and oxygen; The mixed gas of forming by helium and oxygen; Or the mixed gas of forming by argon, helium and oxygen.
In addition, the invention provides a kind of fluoro-resin tubulation shape film, inner circumferential surface is handled by above-mentioned fluoro-resin tubulation shape film inner peripheral surface treatment process.
At this, preferably on fluoro-resin tubulation shape film of the present invention, do not form folding line.
In addition, the invention provides a kind of cylinder, it contains metal-cored and by the elastic layer that the rubber that is arranged on the metal-cored periphery constitutes, wherein, is coated with the fluoro-resin tubulation shape film of having handled inner peripheral surface by aforesaid method on the periphery of elastic layer.
Have, the invention provides a kind of device that is used for the inner peripheral surface treatment process of above-mentioned fluoro-resin tubulation shape film, wherein, above-mentioned fluoro-resin tubulation shape film comprises: be inserted into the 1st electrode in the space that the inner peripheral surface with fluoro-resin tubulation shape film surrounds; Between fluoro-resin tubulation shape film and the 1st electrode, import the device of gas; The conductive liquid that contacts with the periphery of fluoro-resin tubulation shape film; The 2nd electrode that contacts with conductive liquid; Between the 1st electrode and conductive liquid, form the device of alternating-electric field.
Also have, the invention provides a kind of inner peripheral surface treatment process of PFA tubulation shape film, this PFA tubulation shape film is overlayed on the periphery of elastic layer of the cylinder that contains elastic layer metal-cored and that be made of the silicone rubber of being located on the metal-cored periphery, wherein, this method comprises: the spatial interpolation that surrounds at the inner peripheral surface with PFA tubulation shape film is gone into the operation of electrode; In the space, import the operation of gas; So that the mode that liquid does not enter in the space is immersed in operation in the conductive liquid with at least a portion of PFA tubulation shape film; In the space, produce the operation of the plasma body of gas.
At this, in the inner peripheral surface treatment process of PFA tubulation shape film of the present invention, any mixed gas in the preferred following gas of above-mentioned gas: the mixed gas of forming by argon, helium, carbonic acid gas, methane; The mixed gas of forming by argon and ammonia; The mixed gas of forming by helium and ammonia; The mixed gas of forming by argon and helium and ammonia; The mixed gas of forming by argon and nitrogen and hydrogen; The mixed gas of forming by argon and carbonic acid gas and methane; The mixed gas of forming by helium and carbonic acid gas and methane; The mixed gas of forming by helium and nitrogen and hydrogen; The mixed gas of forming by argon and helium and nitrogen and hydrogen; The mixed gas of forming by argon and oxygen; The mixed gas of forming by helium and oxygen; Or the mixed gas of forming by argon, helium and oxygen.
In addition, the present invention relates to provides a kind of PFA tubulation shape film, and its treatment process by above-mentioned PFA tubulation shape film inner peripheral surface is handled inner circumferential surface.
At this, preferably on PFA tubulation shape film of the present invention, do not form folding line.
In addition, the invention provides a kind of cylinder, it contains metal-cored and by the elastic layer that the rubber that is arranged on the metal-cored periphery constitutes, wherein, is covered on the periphery of elastic layer and has handled the PFA tubulation shape film of inner peripheral surface by aforesaid method.
At this, cylinder of the present invention can form by the inner peripheral surface coating silicone silane coupling agent at PFA tubulation shape film.
Also have, the invention provides a kind of inner peripheral surface treatment unit of PFA tubulation shape film, wherein, comprise: be inserted into the 1st electrode in the space that the inner peripheral surface with PFA tubulation shape film surrounds; Between PFA tubulation shape film and the 1st electrode, import the device of gas; The conductive liquid that contacts with the periphery of PFA tubulation shape film; The 2nd electrode that contacts with conductive liquid; Between the 1st electrode and conductive liquid, form the device of alternating-electric field.
According to the present invention, can provide: can obtain the fluoro-resin tubulation shape film, the cylinder that has used this fluoro-resin tubulation shape film and the fluoro-resin tubulation shape film inner peripheral surface treatment unit that obtain with the fluoro-resin tubulation shape film inner peripheral surface treatment process of the good fluoro-resin tubulation shape film of the binding property of rubber, by this method.
In addition, according to the present invention, can provide: can obtain the PFA tubulation shape film, the cylinder that has used this PFA tubulation shape film and the PFA tubulation shape film inner peripheral surface treatment unit that obtain with the inner peripheral surface treatment process of the PFA tubulation shape film of the good PFA tubulation shape film of the binding property of silicone rubber, by this method.
Description of drawings
Fig. 1 is the pattern stereographic map of a preferred example of PFA tubulation shape film of the present invention;
Fig. 2 is the pattern side elevational view of the partial preferred example of inner peripheral surface treatment unit of PFA tubulation shape film of the present invention;
Fig. 3 is the pattern side elevational view of a preferred example of the inner peripheral surface treatment unit of PFA tubulation shape film of the present invention;
Fig. 4 is the mode sectional drawing of diagram when cylinder of the present invention is used with cylinder as the photographic fixing of toning agent.
Nomenclature
1 PFA tubulation shape film, 2 inner peripheral surfaces, 3 peripherys, 4 spaces, 5 electrodes, 6 dielectric mediums, 7 anchor clamps, 8,11 trapezoidal anchor clamps, 9 O ring, 10 gas discharge outlets, 12 support rod, 13 lower clamp, 14 pedestals, 15a, 15b hole, 16 gas flow paths, 17 gas introduction ports, 18 liquid, 19 containers, 20,23 cylinders, 21 metal-cored, 22 elastic layers, 24 toning agents, 25 are used paper.
Embodiment
Below, embodiments of the present invention are described.In the application's accompanying drawing, identical reference marks is represented identical part or suitable part.
A preferred example of expression PFA tubulation shape film of the present invention in the pattern stereographic map of Fig. 1.At this, PFA tubulation shape film 1 is that the PFA ester moulding that will be made up of the copolymer of tetrafluoroethylene and perfluoroalkyl Vinyl Ether is the tubular film of hollow form.Such PFA tubulation shape film 1 for example can obtain by extrusion molding or injection model moulding.The represented PFA tubulation shape film 1 of Fig. 1 has inner circumferential surface 2, as the periphery 3 at the back side of inner peripheral surface and the space 4 that surrounds with inner peripheral surface 2.
What represent in the pattern side elevational view of Fig. 2 is the partial preferred example of inner peripheral surface treatment unit of PFA tubulation shape film of the present invention.At this, be formed with the support rod 12 that has the ground connection lateral electrode concurrently at pedestal 14, on this support rod 12, anchor clamps 7 are installed.In addition, pedestal 14 is provided with trapezoidal anchor clamps 11.
And the spatial interpolation that surrounds at the inner peripheral surface with PFA tubulation shape film 1 goes into to be provided with the hollow electrode 5 of dielectric medium 6.End at this dielectric medium 6 is provided with lower clamp 13.At this, as electrode 5, for example use the electrode formed by metal monomers such as copper or aluminium, by the electrode of alloy compositions such as stainless steel or brass or the electrode of forming by the compound between the metal.In addition as dielectric medium 6, use the double oxide of metal oxide, barium titanates etc. such as glass, mica, silicon-dioxide, aluminum oxide, zirconium dioxide or titanium dioxide or plastics such as tetrafluoroethylene or polyethylene terephthalate etc.Need to prove, in the present invention, even the generation that dielectric medium 6 also might have plasma body is not set, but preferred the setting.
In addition, on lower clamp 13, be formed with a hole 15a, be formed with four hole 15b of cross direction in the side of lower clamp 13.And, be formed with gas flow path in the inside of lower clamp 13, so that discharge from four hole 15b from the gas of hole 15a importing.
Then, after clamping dielectric medium 6, slide upward, lower clamp 13 is separated with trapezoidal anchor clamps 11 by making anchor clamps 7 with anchor clamps 7.And, an end of PFA tubulation shape film 1 is embedded the trapezoidal anchor clamps 8 of hollow, connect an end of PFA tubulation shape films 1 by O ring 9.Anchor clamps 7 are slided downwards, lower clamp 13 is contacted with trapezoidal anchor clamps 11.Then, the other end of PFA tubulation shape film 1 is embedded trapezoidal anchor clamps 11, connect the other end of PFA tubulation shape films 1 by O ring 9.
Then, gas is imported to the inside of electrode 5 from gas introduction port 17.At this, as representing with arrow among the figure, the interior gas that imports to electrode 5 from gas introduction port 17 is discharged from 15b behind the hole 15a that flows into lower clamp 13, flows to the top through the space between dielectric medium 6 and the PFA tubulation shape film 1.Then, gas flows into the gap between trapezoidal anchor clamps 8 and the dielectric medium 6, and the gas discharge outlet 10 that forms from the side at trapezoidal anchor clamps 8 is discharged to the outside.In addition, as the gas that uses in the present invention,, preferably use any in the following mixed gas: the mixed gas of forming by argon, helium, carbonic acid gas, methane from the inner peripheral surface that improves PFA tubulation shape film 1 and the fusible viewpoint of copper silicon rubber; The mixed gas of forming by argon and ammonia; The mixed gas of forming by helium and ammonia; The mixed gas of forming by argon and helium and ammonia; The mixed gas of forming by argon and nitrogen and hydrogen; The mixed gas of forming by argon and carbonic acid gas and methane; The mixed gas of forming by helium and carbonic acid gas and methane; The mixed gas of forming by helium and nitrogen and hydrogen; The mixed gas of forming by argon and helium and nitrogen and hydrogen; The mixed gas of forming by argon and oxygen; The mixed gas of forming by helium and oxygen; Or the mixed gas of argon, helium and oxygen composition.At this, from the viewpoint of the planarization that improves PFA tubulation shape film 1 inner peripheral surface, the gas beyond argon and the helium is preferably below 2 volume % of whole mixed gas.Argon of Shi Yonging and helium also can replace with other rare gas element such as neon or krypton in the present invention, and preferably use argon and/or helium in the present invention.
And, shown in the pattern side elevational view of Fig. 3, at least a portion of PFA tubulation shape film 1 is impregnated in the conductive liquid 18 that is contained in the container 19 in the mode of not sneaking into liquid in the space that surrounds at inner peripheral surface with PFA tubulation shape film 1.At this, for example make water, hydrochloride aqueous solution, the lithium chloride aqueous solution, sodium chloride aqueous solution, potassium chloride solution, aqueous ammonium chloride solution, Potassium Bromide sodium water solution, sodium iodide aqueous solution, potassium iodide aqueous solution, the saltpetre aqueous solution, potassium bicarbonate aqueous solution, aqueous sodium hydroxide solution, silver nitrate aqueous solution, magnesium chloride brine, calcium chloride water, the strontium chloride aqueous solution, barium chloride solution, aqueous sodium persulfate solution, copper sulfate solution or zinc sulfate solution as conductive liquid 18.
Then, the support rod 12 that will contact with liquid 18 is made as the ground connection lateral electrode, by applying high-frequency voltage on electrode 5, forms alternating-electric field between the lip-deep dielectric medium 6 of electrode 5 and conductive liquid 18, in the scope that forms alternating-electric field, the plasma body phenomenon of gas takes place to import.Thus, carry out the processing of the inner peripheral surface of PFA tubulation shape film 1, thereby can improve the binding property of PFA tubulation shape film and silicone rubber.
Like this, the reason that the binding property of PFA tubulation shape film and silicone rubber is improved think because: constitute the ion of above-mentioned such gaseous plasma that takes place and atom etc., between the surface of the inner peripheral surface of the PFA tubulation shape film that imports with forms such as functional groups and silicone rubber, some magnetism works.
In addition, in the present invention, by using conductive liquid, even under the situation of the PFA tubulation shape film that has used all size and shape, also modifier and corresponding with it not is again because can handle the whole inner peripheral surface of PFA tubulation shape film simultaneously, so processing efficiency is also very high.
In addition, in the present invention, owing to when handling the inner peripheral surface of PFA tubulation shape film, do not form folding line, so can obtain not having the PFA tubulation shape film of folding line.By not having folding line to be used for cylinder with the good PFA tubulation shape film of binding property silicone rubber with this, thereby the photographic fixing that can prevent toning agent is bad.
At this, the treatment process of inner peripheral surface of the present invention is preferably carried out under following state: make the spatial pressure that is surrounded by PFA tubulation shape film 1 give the pressure of PFA tubulation shape film greater than conductive liquid 18.For example the length of PFA tubulation shape film 1 is made 500mm, make water in conductive liquid, the lower end of PFA tubulation shape film 1 is positioned at water level when being position about 550mm, and the pressure that is applied on the PFA tubulation shape film 1 is 5.4 * 10 to the maximum
3Pa (pressing relatively), therefore, preferably the pressure in the space that will be surrounded by the inner peripheral surface of PFA tubulation shape film 1 is made as 5.9 * 10 by relative pressure
3Pa is above, and (in absolute pressure is 1.06 * 10 approximately
5Pa).But, for example in this case, when being made as 1.18 * 10 by relative pressure by the space pressure that PFA tubulation shape film 1 surrounds
4Pa～1.27 * 10
4Pa is above, and (in absolute pressure is 1.13 * 10 approximately
5Pa) time, might make gas spilling from PFA tubulation shape film 1 with O ring installation place, thereby not only destroy the strength relationship of PFA tubulation shape film 1, and make PFA tubulation shape film 1 suffer to destroy, be out of shape, therefore, suitable these the bad impossible degree that is made as of the upper limit of the space pressure that preferably will surround with the inner peripheral surface of PFA tubulation shape film 1.
In addition, being applied to the frequency of the high-frequency voltage on the electrode 5 and voltage can suit respectively to set.
As mentioned above, the PFA tubulation shape film that will carry out the inner peripheral surface processing is fixed to the inner face of cylindrical metal mould, after side face applies present known silicone silane coupling agent within it, the spatial interpolation that surrounds at inner peripheral surface by PFA tubulation shape film go into by aluminium etc. form metal-cored.Then, PFA tubulation shape film and metal-cored between inject liquid silicone rubber, make its sclerosis by the liquid silicone rubber heating that will inject, the elastic layer that the formation order is applied on metal-cored periphery is made up of silicone rubber and the cylinder of PFA tubulation shape film.At this, inner peripheral surface that PFA tubulation shape film carries out according to the present invention is handled, and therefore, can form PFA tubulation shape film and the good cylinder of binding property of the elastic layer be made up of silicone rubber.Need to prove, if the elastic layer of forming by silicone rubber be with silicone rubber as main component, then certainly contain additives such as weighting agent.
Fig. 4 is the mode sectional drawing of diagram when above-mentioned such cylinder that forms is used with cylinder as the photographic fixing of toning agent.That this cylinder contains is metal-cored 21, be made up of the silicone rubber that is arranged on metal-cored 21 the periphery elastic layer 22 and the PFA tubulation shape film 1 after the above-mentioned inner peripheral surface that is covered on the periphery of elastic layer 22 is handled.And, be provided with cylinder 23 in position with these cylinder 20 subtends, between these cylinders, transporting the usefulness paper 25 that adhesion has toning agent 24.Then, by the line pressure between cylinder 20 and the cylinder 23 toning agent 24 photographic fixing are discharged on paper 25.
In addition, as mentioned above, the situation of having used PFA tubulation shape film is described, but also can use PFA tubulation shape film fluoro-resin tubulation shape film in addition in the present invention.As the fluoro-resin tubulation shape film that uses among the present invention, can use beyond PFA (tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin) the tubulation shape film, for example FEP (tetrafluoroethylene-hexafluoro copolymerization of propylene resin) tubulation shape film, ETFE (tetrafluoroethylene-ethylene copolymer resin) tubulation shape resin, PTFE (trifluorochloroethylene resin) tubulation shape film or PVDF (ethylene fluoride fork resin) tubulation shape film etc.
In addition, as mentioned above, the situation of using the elastic layer of being made up of silicone rubber is illustrated, but also can uses the elastic layer of forming by the rubber beyond the silicone rubber in the present invention.As the elastic layer of forming by rubber that uses in the present invention, except that silicone rubber, for example can use paracril, hydrogenated nitrile-butadiene rubber, viton, ethylene propylene rubber, neoprene, acrylic rubber, isobutylene-isoprene copolymer, poly-iminomethyl acid esters rubber, chlorosulfonated polyethylene rubber, chloro methyloxypropane or natural rubber.
Embodiment
(embodiment 1)
In device shown in Figure 2, in the space that the inner peripheral surface with the PFA tubulation shape film 1 that does not have folding line of bore 17.6mm, thickness 50 μ m and length 530mm surrounds, insertion is provided with the electrode 5 of the dielectric medium of being made up of mica 6, after the end with this PFA tubulation shape film 1 embeds trapezoidal anchor clamps 8, connect an end of PFA tubulation shape film 1 with O ring 9.Then, after the other end with PFA tubulation shape film 1 embeds trapezoidal anchor clamps 11, connect the other end of PFA tubulation shape film 1 with O ring 9.At this, the installation length of PFA tubulation shape film 1 is respectively 20mm.Then, from the inside of gas introduction port 17, gas is imported between the inner peripheral surface of dielectric medium 6 and PFA tubulation shape film 1 by electrode 5.At this,, use the mixed gas of forming by argon, helium, carbonic acid gas, methane as the gas that imports.
Then, as shown in Figure 3, the water level in accommodating container 19 is this device of dipping in the water of 600mm.Then, flow into the gas in 15 seconds in the space between the inner peripheral surface of dielectric medium 6 and PFA tubulation shape film 1 after, applying frequency on electrode 5 is that 5kHz, voltage are the high-frequency voltage of 4.0kV, makes it that plasma body phenomenon in 5 seconds take place.At this, the bore of electrode 5 is 12mm, is spaced apart 2.8mm between the inner peripheral surface of dielectric medium 6 and PFA tubulation shape film 1.In addition, the area of the inner peripheral surface of PFA tubulation shape film 1 is about 271cm
2(1.76cm * 3.14 * 49cm 271cm
2), current value is a 60mA (current density: 0.22mA/cm
2), electric power is a 40W (power density: 0.15W/cm
2).In addition, be installed in valve on the gas discharge outlet 10 by adjusting, making space pressure between the inner peripheral surface of dielectric medium 6 when handling and PFA tubulation shape film 1 is that pressure more than the hydraulic pressure is (in relative pressure: 6.9 * 10
3Pa).
Then, stop to apply high-frequency voltage, device is as shown in Figure 2 slowly mentioned from water with certain speed.By carrying out aforesaid operations, utilize the water resistance of the periphery of PFA tubulation shape film 1, can make does not get wet on the periphery of PFA tubulation shape film 1 drips and with its taking-up.Then, use the program opposite, take PFA tubulation shape film 1 from device shown in Figure 2 with above-mentioned installation, then with the static remover remove the PFA tubulation shape film of taking from device shown in Figure 21 the surface with static.
Secondly, the above-mentioned PFA tubulation shape film that obtains is like that cut into the length of 490mm, the silicone of side face coating within it silane coupling agent.On the other hand, prepare that periphery is carried out the aluminium surface passivation and handle, and in be provided with the cylindric stainless steel metal mould of the aluminum of length 490mm, external diameter 46.3mm of heating source metal-cored and length 490mm, internal diameter 50.0mm.By vacuum attraction, above-mentioned PFA tubulation shape film is fixed on the inner face of this stainless steel metal mould then, goes into above-mentioned metal-cored at the spatial interpolation that surrounds with the PFA tubulation shape film inner peripheral surface that fixes.Then, inject liquid silicone rubber in the space of the about 3.7mm between the inner peripheral surface of metal-cored and PFA tubulation shape film, utilize 150 ℃ hot blast baking 30 minutes, form the elastic layer of forming by silicone rubber.At last, above-mentioned stainless steel metal mould is broken away from, obtain cylinder.
Then, make the part of silicone rubber of the periphery of this cylinder form otch,, destroy silicone rubber as elastic layer from its incision stretching PFA tubulation shape film.Thus, the binding property of affirmation PFA tubulation shape film and silicone rubber is good.
(embodiment 2)
Use the PFA tubulation shape film that does not have folding line of bore 40.1mm, thickness 30 μ m and length 450mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 32mm, PFA tubulation shape film be embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 length be respectively 30mm, 40mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 500mm.In addition, the area of the inner peripheral surface of PFA tubulation shape film 1 is about 487cm
2(4.01cm * 3.14 * 38cm 478cm
2), current value is a 140mA (current density: 0.247mA/cm
2), electric power is a 200W (power density: 0.353W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.Thus, the binding property of affirmation PFA tubulation shape film and silicone rubber is good.
(embodiment 3)
Use the PFA tubulation shape film creasy of bore 28.8mm, thickness 50 μ m and length 250mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 as shown in Figure 2 is 22mm, in addition, device shown in Figure 2 is immersed in the water that the degree of depth is 400mm.In addition, the area of the inner peripheral surface of PFA tubulation shape film 1 is about 190cm
2(2.88cm * 3.14 * 25cm 190cm
2), current value is a 70mA (current density: 0.368mA/cm
2), electric power is a 55W (power density: 0.289W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.Thus, the binding property of affirmation PFA tubulation shape film and silicone rubber is good.
(embodiment 4)
Use the FEP tubulation shape film that does not have folding line of bore 30mm, thickness 50 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, FEP tubulation shape film 1 be embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 length be respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350mm.In addition, the area of the inner peripheral surface of FEP tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.Thus, the binding property of affirmation FEP tubulation shape film and silicone rubber is good.
(embodiment 5)
Use the ETFE tubulation shape film that does not have folding line of bore 30mm, thickness 100 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, and the length that ETFE tubulation shape film 1 is embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 is respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350mm.In addition, the area of the inner peripheral surface of ETFE tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.Thus, the binding property of affirmation ETFE tubulation shape film and silicone rubber is good.
(embodiment 6)
Use the PFA tubulation shape film that does not have folding line of bore 30mm, thickness 50 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, PFA tubulation shape film 1 be embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 length be respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350mm.In addition, the area of the inner peripheral surface of PFA tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).In addition, in the present embodiment, uncoated silicone silane coupling agent on the inner peripheral surface of PFA tubulation shape film.Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, cut the part of the PFA tubulation shape film after the above-mentioned processing, with the treated side of the PFA tubulation shape film under cutting as upside, place in the metal vessel, the hot gravity die silicone rubber of two liquid is poured on the treated side of this PFA tubulation shape film, the temperature heating with 150 ℃ in baking oven made its sclerosis in 10 minutes again.
Then, after above-mentioned silicone rubber sclerosis,, estimate its binding property, found that silicone rubber is destroyed by stretching PFA tubulation shape film and silicone rubber.
Need to prove,, use the rubber that fluid rubber (" DY35-109 " of eastern レ ダ ウ コ one ニ Application ダ シ リ コ one Application (strain) society system) and vulcanizing agent are obtained by the mixed of 100: 1 (mass ratio) as the hot gravity die silicone rubber of above-mentioned two liquid.
(embodiment 7)
Use the FEP tubulation shape film that does not have folding line of bore 30mm, thickness 50 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, and the length that FEP tubulation shape film 1 is embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 is respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350mm.In addition, the area of the inner peripheral surface of FEP tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.
(embodiment 8)
Use the ETFE tubulation shape film that does not have folding line of bore 30mm, thickness 100 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, and the length that ETFE tubulation shape film 1 is embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 is respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350mm.In addition, the area of the inner peripheral surface of ETFE tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.
(embodiment 9)
Use the PFA tubulation shape film that does not have folding line of bore 30mm, thickness 50 μ m and length 300mm, carry out the processing of the inner peripheral surface identical with embodiment 1.
At this, the bore of electrode 5 shown in Figure 2 is 22mm, and the length that FEP tubulation shape film 1 is embedded into trapezoidal anchor clamps 8 and trapezoidal anchor clamps 11 is respectively 30mm, 30mm.In addition, device shown in Figure 2 is impregnated in the water that the degree of depth is 350 mm.In addition, the area of the inner peripheral surface of PFA tubulation shape film 1 is about 226cm
2(3cm * 3.14 * 24cm 226cm
2), current value is a 130mA (current density: 0.459mA/cm
2), electric power is a 250W (power density: 0.883W/cm
2).Except that above-mentioned condition, use the condition identical to carry out the processing of inner peripheral surface with embodiment 1.
Then, a part that cuts the PFA tubulation shape film after the above-mentioned processing is as sample, after being coated to silicone tackiness agent (" the silicone KE45 of SHIN-ETSU HANTOTAI takes off oxime type RTV rubber " of SHIN-ETSU HANTOTAI's chemical industry (strain) system) on the thin slice of forming by silicone rubber, the above-mentioned treated side of this sample being close to tackiness agent adhering.Under this state, carry out 10 hours drying with 50 ℃ temperature, this tackiness agent becomes silicone rubber.Then, this sample that stretches destroys the thin slice of being made up of silicone rubber.
This disclosed embodiment and embodiment should think illustrative comprehensively, hard-core.Scope of the present invention is not above-mentioned explanation, and passes through the scope illustration of claim, is to comprise the meaning identical with the scope of claim and all changes in the scope on the intention.
Utilizability on the industry
According to the present invention, for example following gas is imported to the inner peripheral surface of fluororesin tubulation shape film, that is: The mist that is formed by argon, helium, carbon dioxide, methane; The mist that is formed by argon and ammonia; The mist that is formed by helium and ammonia; The mist that is formed by argon and helium and ammonia; By helium and nitrogen and hydrogen The mist that forms; The mist that is formed by argon and carbon dioxide and methane; By helium and titanium dioxide The mist that carbon and methane form; The mist that is formed by argon and nitrogen and hydrogen; By argon and helium and nitrogen And the mist of hydrogen composition; The mist that is formed by argon and oxygen; The mixing that is formed by helium and oxygen Gas; Or by the mist that argon, helium and oxygen form, make conductive liquid contact fluororesin tubulation shape The outer peripheral face of film by making above-mentioned mist generation plasma state phenomenon, is processed the fluororesin tubulation The inner peripheral surface of shape film, thus the elastic layer that is formed by silicone rubber that has improved with cylinder can be made Fusible fluororesin tubulation shape film.
Have again, according to the present invention, for example following gas imported to the inner peripheral surface of PFA tubulation shape film, That is: the mist that is formed by argon, helium, carbon dioxide, methane; The gaseous mixture that is formed by argon and ammonia Body; The mist that is formed by helium and ammonia; The mist that is formed by argon and helium and ammonia; By helium and nitrogen Mist with the hydrogen composition; The mist that is formed by argon and carbon dioxide and methane; By helium and two The mist that carbonoxide and methane form; The mist that is formed by argon and nitrogen and hydrogen; By argon and helium Mist with nitrogen and hydrogen composition; The mist that is formed by argon and oxygen; Formed by helium and oxygen Mist; Or by the mist that argon, helium and oxygen form, make conductive liquid contact PFA tubulation The outer peripheral face of shape film by making above-mentioned mist generation plasma state phenomenon, is processed the PFA tubulation The inner peripheral surface of shape film, thus the elastic layer that is formed by silicone rubber that has improved with cylinder can be made Fusible PFA tubulation shape film.
In addition, when carrying out this processing, because at fluororesin tubulation shape film and PFA tubulation shape film On be not formed with folding line, do not have irregular smooth cylinder so can form at outer peripheral face.
Claims (13)
1, the inner peripheral surface treatment process of a kind of fluoro-resin tubulation shape film (1), it is the method for handling the inner peripheral surface (2) of the fluoro-resin tubulation shape film (1) that on the periphery of the described elastic layer (22) of the cylinder (20) of the elastic layer (22) that the rubber on the periphery that contains metal-cored (21) and metal-cored by being located at (21) constitutes, has been covered, wherein, this method comprises: the operation of inserting electrode (5) in the space (4) that the inner peripheral surface (2) with described fluoro-resin tubulation shape film (1) surrounds; In described space (4), import the operation of gas; So that the mode that liquid does not enter in the described space (4) is impregnated into operation in the conductive liquid (18) with at least a portion of described fluoro-resin tubulation shape film (1); In described space (4), produce the operation of the plasma body of gas.
2, the inner peripheral surface treatment process of fluoro-resin tubulation shape film as claimed in claim 1 (1), wherein, described gas is any mixed gas in the following gas: the mixed gas of being made up of argon, helium, carbonic acid gas, methane; The mixed gas of forming by argon and ammonia; The mixed gas of forming by helium and ammonia; The mixed gas of forming by argon and helium and ammonia; The mixed gas of forming by argon and nitrogen and hydrogen; The mixed gas of forming by argon and carbonic acid gas and methane; The mixed gas of forming by helium and carbonic acid gas and methane; The mixed gas of forming by helium and nitrogen and hydrogen; The mixed gas of forming by argon and helium and nitrogen and hydrogen; The mixed gas of forming by argon and oxygen; The mixed gas of forming by helium and oxygen; The mixed gas of forming by argon, helium and oxygen.
3, a kind of fluoro-resin tubulation shape film (1), its with claim 1 described fluoro-resin tubulation shape film (1) the inner peripheral surface disposal methods inner peripheral surface (2).
4, fluoro-resin tubulation shape film as claimed in claim 3 (1) wherein, is not formed with folding line.
5, a kind of cylinder (20), the elastic layer (22) that it contains metal-cored (21) and is made of the rubber that is provided with on the periphery of metal-cored (21), wherein, on the periphery of described elastic layer (22), be coated with the fluoro-resin tubulation shape film (1) that inner peripheral surface (2) has been carried out processing with the described method of claim 1.
6, the inner peripheral surface treatment unit of a kind of fluoro-resin tubulation shape film (1), it is the device that is used in the fluoro-resin tubulation shape film inner peripheral surface treatment process described in the claim 1, wherein, this device comprises: be inserted into the 1st electrode (5) in the space (4) that the inner peripheral surface (2) with fluoro-resin tubulation shape film (1) surrounds; Between described fluoro-resin tubulation shape film (1) and the 1st electrode (5), import the device of gas; The conductive liquid (18) that contacts with the periphery (3) of described fluoro-resin tubulation shape film (1); The 2nd electrode (12) that contacts with described conductive liquid (18); Between described the 1st electrode (5) and described conductive liquid (18), form the device of alternating-electric field.
7, the inner peripheral surface treatment process of a kind of PFA tubulation shape film (1), it is a method of handling the inner peripheral surface (2) of the PFA tubulation shape film (1) that has been covered on the periphery of the described elastic layer (22) of the cylinder (20) of the elastic layer (22) that contains metal-cored (21) and be made of the rubber that is being provided with on the periphery of metal-cored (21), and this method comprises: the operation of insertion electrode (5) in the space (4) that the inner peripheral surface (2) with described PFA tubulation shape film (1) surrounds; In described space (4), import the operation of gas; So that the mode that liquid does not enter in the space (4) is immersed in operation in the conductive liquid (18) with at least a portion of described PFA tubulation shape film (1); In described space (4), produce the operation of the plasma body of gas.
8, the inner peripheral surface treatment process of PFA tubulation shape film as claimed in claim 7 (1), wherein, described gas is any mixed gas in the following gas: the mixed gas of being made up of argon, helium, carbonic acid gas, methane; The mixed gas of forming by argon and ammonia; The mixed gas of forming by helium and ammonia; The mixed gas of forming by argon and helium and ammonia; The mixed gas of forming by argon and nitrogen and hydrogen; The mixed gas of forming by argon and carbonic acid gas and methane; The mixed gas of forming by helium and carbonic acid gas and methane; The mixed gas of forming by helium and nitrogen and hydrogen; The mixed gas of forming by argon and helium and nitrogen and hydrogen; The mixed gas of forming by argon and oxygen; The mixed gas of forming by helium and oxygen; The mixed gas of forming by argon, helium and oxygen.
9, a kind of PFA tubulation shape film (1), be with claim 7 described PFA tubulation shape film (1) the inner peripheral surface disposal methods inner peripheral surface (2).
10, PFA tubulation shape film as claimed in claim 9 (1) wherein, is not formed with folding line.
11, a kind of cylinder (20), the elastic layer (22) that it contains metal-cored (21) and is made of the rubber that is provided with on the periphery of metal-cored (21), wherein, on the periphery of described elastic layer (22), be coated with the PFA tubulation shape film (1) of handling inner peripheral surface (2) by the described method of claim 7.
12, cylinder as claimed in claim 11 (20), it is formed at the inner peripheral surface coating silicone undercoat of described PFA tubulation shape film (1).
13, the inner peripheral surface treatment unit of a kind of PFA tubulation shape film (1), it is the device that is used for the PFA tubulation shape film inner peripheral surface treatment process described in the claim 7, wherein, described device comprises: be inserted into the 1st electrode (5) in the space (4) that the inner peripheral surface (2) with PFA tubulation shape film (1) surrounds; Between described PFA tubulation shape film (1) and the 1st electrode (5), import the device of gas; The conductive liquid (18) that contacts with the periphery (3) of described PFA tubulation shape film (1); The 2nd electrode (12) that contacts with conductive liquid (18); Between the 1st electrode (5) and conductive liquid (18), form the device of alternating-electric field.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP261139/2004 | 2004-09-08 | ||
| JP2004261139 | 2004-09-08 |
Publications (2)
| Publication Number | Publication Date |
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| CN1984945A true CN1984945A (en) | 2007-06-20 |
| CN100577716C CN100577716C (en) | 2010-01-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580023504A Expired - Fee Related CN100577716C (en) | 2004-09-08 | 2005-09-02 | Method for treating inner peripheral face of fluororesin tubular film, fluororesin tubular film, apparatus for treating inner peripheral face of fluororesin tubular film, method for treating inner per |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4986624B2 (en) |
| CN (1) | CN100577716C (en) |
| WO (1) | WO2006028016A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108699398A (en) * | 2016-02-17 | 2018-10-23 | 德莎欧洲股份公司 | Silicone adhesive substance is set to be anchored on fluoro-containing copolymer film using sided corona treatment |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4594768B2 (en) * | 2005-03-17 | 2010-12-08 | エア・ウォーター株式会社 | Tubular film inner peripheral surface processing apparatus and tube-shaped film inner peripheral surface processing method |
| JP5229886B2 (en) * | 2008-07-24 | 2013-07-03 | エア・ウォーター株式会社 | Tubular film inner peripheral surface processing apparatus and tube-shaped film inner peripheral surface processing method |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0289079A (en) * | 1988-09-27 | 1990-03-29 | Hokushin Ind Inc | Production of heat fixing roll |
| JP3280994B2 (en) * | 1990-12-28 | 2002-05-13 | 科学技術振興事業団 | Atmospheric pressure glow plasma reaction method in tube |
| JP2803017B2 (en) * | 1993-06-07 | 1998-09-24 | 工業技術院長 | Antithrombotic medical material and medical device, and their manufacturing method, manufacturing apparatus, and plasma processing apparatus |
| JP2794546B2 (en) * | 1995-06-26 | 1998-09-10 | 株式会社荒井製作所 | roller |
| JP2735818B2 (en) * | 1995-08-31 | 1998-04-02 | 日本バルカー工業株式会社 | Fluororesin-based molded article, roll, and method for producing these |
| JPH09208727A (en) * | 1996-02-06 | 1997-08-12 | Sekisui Chem Co Ltd | Surface treatment utilizing plasma |
| JP3594884B2 (en) * | 1999-07-09 | 2004-12-02 | エア・ウォーター株式会社 | Method for producing composite material and composite material obtained thereby |
-
2005
- 2005-09-02 JP JP2006535722A patent/JP4986624B2/en active Active
- 2005-09-02 CN CN200580023504A patent/CN100577716C/en not_active Expired - Fee Related
- 2005-09-02 WO PCT/JP2005/016118 patent/WO2006028016A1/en active Application Filing
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108699398A (en) * | 2016-02-17 | 2018-10-23 | 德莎欧洲股份公司 | Silicone adhesive substance is set to be anchored on fluoro-containing copolymer film using sided corona treatment |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2006028016A1 (en) | 2008-05-08 |
| WO2006028016A1 (en) | 2006-03-16 |
| JP4986624B2 (en) | 2012-07-25 |
| CN100577716C (en) | 2010-01-06 |
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