CN1979222A - Reflection-proof film - Google Patents
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- CN1979222A CN1979222A CNA2006101022037A CN200610102203A CN1979222A CN 1979222 A CN1979222 A CN 1979222A CN A2006101022037 A CNA2006101022037 A CN A2006101022037A CN 200610102203 A CN200610102203 A CN 200610102203A CN 1979222 A CN1979222 A CN 1979222A
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Abstract
The invention relates to an antireflection film to solve the problem of antireflection capability and antistatic-electricity. The technology plan is that it includes basal material, anti-dazzle hard coating, high refractive index layer and low refractive index layer, and an antistatic-electricity layer, which is made up from water resin dispersion 4-15 portions, antistatic-electricity 4-15 portions, surface activator 0.2-2 portions, cross linker 2-10 portions, and water 70-100 portions, is set between basal material and anti-dazzle hard coating. The invention has antireflection and antistatic-electricity capability, and could be widely used in PDP and LCD.
Description
Technical field
The present invention relates to a kind of improved antireflective film as display device.
Background technology
Usually, antireflective film is used as for example plasma scope (PDP) of display device, the outermost layer of LCD (LCD), and have following function: reduce reflectivity by the interference of light principle, thereby prevent that the contrast that causes because of external light reflection from reducing and the image direct reflection.
Known this antireflective film contains transparent support, has hard conating, high refractive index layer and low-index layer on support, and also the refractive index of known low-index layer should enough be hanged down to reduce the reflectivity of antireflection film.
The support that antireflective film is commonly used is cellulose triacetate or ethylene glycol terephthalate, and the bulk resistor of these two kinds of materials all than higher, is commonly used for insulating material.When the base material as antireflection film uses, all may be because friction produces static in the process of opening or rolling of base material, a large amount of net charges accumulates on the substrate surface, can cause that antireflection film attaching process produces undesirable disadvantage or trouble when display is produced; Because antireflection film all is the outermost layer as display usually, in use, also may adsorb the dust in the environment simultaneously, cause the stained and display quality decline of display surface.
For eliminating the static that produces in the antireflection film forming process, the most frequently used method is to add antistatic agent to solve in coating.The antistatic agent commonly used such as the multipolymer of polystyrolsulfon acid, styrene sulfonic acid and maleic anhydride etc., rely on and absorb airborne moisture content conduction, its anti-static effect is restricted by ambient humidity, when ambient humidity is lower than 40%, just lost anti-static effect, what is more important, this base polymer, fine solubility is all arranged in water, thereby be easy to when the antireflection film saponification is handled, be left antistatic backing, cause the loss of anti-static effect by water-soluble separating.U.S. Pat 6,884,495 propose to add the static of the method for high refractive index layer into the antireflection film generation with the conducting metal oxide powder, this method need make metal oxide powder reach good dispersion effect, particle size is less than 100nm, the material price costliness, there are certain problem in dispersing technology complexity, suitability for industrialized production.
Summary of the invention
Problem to be solved by this invention provides a kind of antireflective film, and it has enough antireflection properties and antistatic performance.
The technical scheme that addresses the above problem is:
A kind of antireflective film comprises base material, anti-dazzle hard coat, high refractive index layer and low-index layer, and its improvement is between base material and anti-dazzle hard coat one deck antistatic backing is arranged, and the parts by weight component of described antistatic backing is:
4～15 parts of aqueous resin dispersions
4～15 parts of antistatic agents
0.2～2 part in surfactant
2～10 parts of crosslinking chemicals
70～100 parts in water
Above-mentioned antireflective film, described water-soluble polymers are acrylic monomers, acryl resin, polyurethane or cellulose derivative.
Above-mentioned antireflective film, described hard conating has 1.48～1.70 refractive index.
Above-mentioned antireflective film, described low-index layer has 1.35～1.42 refractive index.
The base material that can be used in antireflective film of the present invention is transparent, preferably plastic film.The suitable polymers of making film comprises cellulose esters, for example, Triafol T, cellulose propionate, cellulose butyrate, cellulose diacetate, cellulose acetate propionate or cellulose nitrate etc., polyamide, polycarbonate, polyester (for example polyethylene terephthalate, Polyethylene Naphthalate, polybutylene terephthalate etc.), polystyrene, polyolefins (as, polypropylene, tygon, polymethylpentene etc.), polysulfones, polyethersulfone, polyarylate, polymethylmethacrylate or polyetherketone etc.
For transparent base, has at least 80% transmittance, particularly 86% or higher transmittance, and have and be not less than 2.0% optical haze degree, particularly 1.0% or littler.
The thickness of transparent base is preferably but not limited to the 30-150 micron, more preferably the 70-120 micron.
The anti-dazzle hard conating is formed as key component by the polymkeric substance with cohesive and high rigidity characteristic.Comprise: the acrylate of the acrylate of multi-functional acryl resin, trifunctional, the acrylate of difunctional, simple function group etc.
The anti-dazzle hard conating can be the inorganic layer that mainly comprises silicon dioxide, comprises to have stable hydrocarbon or polyethers as the organic layer of main chain or comprise mineral compound and the mixolimnion of organic compound.By have stable hydrocarbon as the polymkeric substance of main chain make the layer be particularly preferred.Polymkeric substance preferably has cross-linked structure.Having stable hydrocarbon preferably prepares by the polymerization of ethylenically unsaturated monomers as the polymkeric substance of main chain.Monomer with two or more alkene class unsaturated groups preferably is used to provide crosslinked bonding agent polymkeric substance.
In antireflection film of the present invention, a kind of coating composition of preferred for preparation, said composition contains the monomer of above listed ethylenic unsaturated group, optical free radical polymerization initiator, polymer beads.
The preferred photo-cleavage type of optical free radical polymerization initiator, Irgacure184 for example, 907 and 651 (Ciba Geigy Ltd), preferred per 100 parts of amount of monomer are used 0.1～15 weight portion, more preferably 2～8 weight portions.
Prevent dazzle in order to give, preferably using mean grain size is the polymer beads of 1～8 μ m, for example crosslinked poly methyl methacrylate particle and crosslinked granules of polystyrene.Particle can be the sphere of rule, can be used alone or two or more mixing use, and the size of particle can be that even distribution also can be irregular distribution.The consumption of polymer beads is preferably 1～30%, preferred especially 10～15% of anti-dazzle hard conating general assembly (TW).Anti-dazzle hard conating thickness is preferably 2～10 μ m, is preferably 3～6 μ m especially.In the preferred 1.45-2.0 of refractive index, particularly 1.48-1.70 scope.
High refractive index layer is made up of the inorganic filler of polymkeric substance, raising refractive index.Used polymkeric substance of high refractive index layer and hard conating are similar, and the powder that has added metal oxide is to improve refractive index, the oxide of preferred following metal: zirconium, titanium, aluminium, tin.Inorganic filler have less than light wavelength particle diameter, thereby can not cause scattering of light and see through.The consumption of inorganic filler is preferably 15～70 of amount of polymers, is preferably 30～50% especially.The high refractive index layer refractive index is preferably 1.70～2.20.
Low-index layer is made up of fluoropolymer, and refractive index is preferably 1.35～1.42, adds in addition to prevent to wear and tear and prevent the material that fingerprint pollutes.
Aqueous resin dispersion in the antistatic backing can be any can with the polymkeric substance of base material tight adhesion, being fit to aqueous resin dispersion of the present invention can be acryl resin, polyurethane or cellulose derivative etc., as: the polyurethane R-960 of Di Siman (DSM) company, R-941, then acryl resin NEO-232 of Ni Ka company etc.From the elasticity, the hardness that improve coating, base material and follow-up coating adhesion angle are considered, preferentially select urethane resin for use.The cured form of coating can be heat curing or ultraviolet light polymerization, for considering the adhesion of raising and base material, preferably uses the mode of heat curing.
The antistatic agent that uses in the antistatic backing, can be inorganic salts antistatic agent such as potassium nitrate, metal oxide antistatic agent such as indium oxide/tin (ITO) or polymkeric substance antistatic agent, the polymkeric substance antistatic agent of preferred electron conductivity type is as the BAYTRONP of BAYER company production
R, this type of antistatic agent, anti-static effect are not influenced by ambient humidity, can be firm be fixed in the coating, even long-term the use, anti-static effect can not lose yet.
The surfactant that uses in the antistatic backing can be known cationic surfactant, anionic surfactant or amphoteric surfactant, as: cationic surfactant can be the monoalkyl mono-quaternaries, the monoalkyl bi-quaternary ammonium salt; Anionic surfactant can be a lauryl sodium sulfate, the monoalky lether phosphate; Amphoteric surfactant can be the shrink sorbitol monooleate, NPE.
The crosslinking chemical that uses in the antistatic backing can be the crosslinking chemical that contains isocyanate group, epoxy radicals, aziridine group, aldehyde radical or active methylene group, as: the aziridine group crosslinking chemical CX-100 that Avecia company produces, epoxy silane, glutaraldehyde.
The coating of described antireflective film forms by UV-irradiation or heating after being preferably continuous coating.
Preparation contains the coating composition that forms each layer component, the coating fluid that will be used to form antistatic backing by for example methods such as dip coating, airblade coating method, metal thread bar rubbing method, intaglio plate rubbing method is coated on the transparent support, heating is also dry, and coating is solidified.Also the coating fluid that is used to form the anti-dazzle hard conating can be coated on the antistatic backing, heating is also dry, by UV-irradiation coating is solidified then.
Similarly, high refractive index layer and low-index layer also so form.
The preparation method of antireflection film of the present invention, it comprises: the web-like transparent support is launched continuously, be coated with antistatic backing, hard conating and high and low refractive index layer on a surface.
Beneficial effect
The present invention has the good anti-static performance, the influence when it is not changed by ambient humidity, and anti-static effect is lasting, can be widely used on LCD or the plasma display.
Preparation method provided by the invention, technology is simple, and is convenient, is applicable to suitability for industrialized production.
Embodiment
The invention will be further described below in conjunction with specific embodiment, but be not limited thereto.
Embodiment 1
1. antistatic backing preparation
10 parts of urethane resin R-961 (DSM Ltd system)
Antistatic agent BAYTRONP
R(BAYER system) 6 parts
0.2 part of surfactant TX-10 (Rohm Hass system)
2 parts of crosslinking chemical CX-100 (Avecia system)
100 parts in water
In 100 parts of water, add successively: 10 parts of urethane resin R-961,6 parts of antistatic agent BAYTRONP
R, 0.2 part of surfactant TX-10,2 parts of crosslinking chemical CX-100 stir, and obtain coating fluid.The coating fluid that obtains was stirred 20 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 3 minutes by silk rod rubbing method.
2. fat dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 20 grams
DPHA (NIPPON KAYAKU system) 10 grams
PO-NPGDA (proud son of heaven chemistry system) 20 grams
Initiating agent 184 1.5 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 0.5 gram
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 4 μ m, refractive index is 1.51 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 69 gram TiO
2Powder (ISHAHARA system) and 12 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 4 gram light triggers 184 more than 180 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 3 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 1.81 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 4 grams in 100 gram butanone, BYK-307 (BYK system) 0.2 gram is made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.42.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Embodiment 2
1. antistatic backing preparation
15 parts of acryl resin NEO-232 (Buddhist nun blocks corporate system)
Antistatic agent BAYTRONP
R(BAYER system) 10 parts
2 parts of lauryl sodium sulfate
5 parts of crosslinking chemical CX-100 (Avecia system)
90 parts in water
In 90 parts of water, add successively: 15 parts of acryl resin NEO-232 (Buddhist nun blocks corporate system), 10 parts of antistatic agent BAYTRONP
R, 2 parts of surfactant lauryl sodium sulfate, 2 parts of crosslinking chemical CX-100 stir, and obtain coating fluid.The coating fluid that obtains was stirred 50 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 5 minutes by silk rod rubbing method.
2. anti-dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 10 grams
DPHA (NIPPON KAYAKU system) 20 grams
PO-NPGDA (proud son of heaven chemistry system) 10 grams
Initiating agent 184 3 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 2 grams
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 5 μ m, refractive index is 1.48 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 75 gram TiO
2Powder (ISHAHARA system) and 10 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 2 gram light triggers 184 more than 150 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 5 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 1.70 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 2 grams in 100 gram butanone, BYK-307 (BYK system) 0.5 gram is made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.35.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Embodiment 3
1. antistatic backing preparation
4 parts of urethane resin R-960 (DSM Ltd system)
15 parts of indium oxides
1.5 parts of shrink sorbitol monooleates
8 parts of epoxy silanes
70 parts in water
In 70 parts of water, add successively: 4 parts of urethane resin R-960,15 parts of indium oxides, 1.5 parts of surfactant shrink sorbitol monooleates, 8 parts of crosslinking chemical epoxy silanes stir, and obtain coating fluid.The coating fluid that obtains was stirred 30 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 5 minutes by silk rod rubbing method.
2. anti-dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 15 grams
DPHA (NIPPONKAYAKU system) 15 grams
PO-NPGDA (proud son of heaven chemistry system) 8 grams
Initiating agent 184 2 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 1 gram
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 5 μ m, refractive index is 1.70 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 80 gram TiO
2Powder (ISHAHARA system) and 5 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 3 gram light triggers 184 more than 80 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 5 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 2.20 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 3 grams in 100 gram butanone, BYK-307 (BYK system) 1.0 grams are made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.40.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Embodiment 4
1. antistatic backing preparation
7 parts of urethane resin R-961 (DSM Ltd system)
4 parts of antistatic agent AS-05 (Chinese Lekai Film Group Co's system)
1 part of nonyl acid alcohol polyoxyethylene ether
7 parts of crosslinking chemical CX-100 (Avecia system)
85 parts in water
In 85 parts of water, add successively: 7 parts of urethane resin R-961,4 parts of antistatic agent AS-05,1 part of surfactant nonyl acid alcohol polyoxyethylene ether, 7 parts of crosslinking chemical CX-100 stir, and obtain coating fluid.The coating fluid that obtains was stirred 20 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 3 minutes by silk rod rubbing method.
2. anti-dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 20 grams
DPHA (NIPPON KAYAKU system) 10 grams
PO-NPGDA (proud son of heaven chemistry system) 10 grams
Initiating agent 184 2.0 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 0.5 gram
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 4 μ m, refractive index is 1.60 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 50 gram TiO
2Powder (ISHAHARA system) and 15 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 2 gram light triggers 184 more than 150 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 3 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 2.0 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 5 grams in 100 gram butanone, BYK-307 (BYK system) 1 gram is made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.37.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Embodiment 5
1. antistatic backing preparation
13 parts of acryl resin NEO-232 (Buddhist nun blocks corporate system)
10 parts in potassium nitrate
2 parts of surfactant TX-10 (Rohm Hass system)
10 parts of glutaraldehydes
100 parts in water
In 100 parts of water, add successively: 13 parts of acryl resin NEO-232,10 parts of potassium nitrate, 2 parts of surfactant TX-10,10 parts of crosslinking chemical glutaraldehydes stir, and obtain coating fluid.The coating fluid that obtains was stirred 30 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 5 minutes by silk rod rubbing method.
2. anti-dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 15 grams
DPHA (NIPPON KAYAKU system) 15 grams
PO-NPGDA (proud son of heaven chemistry system) 8 grams
Initiating agent 184 2 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 1 gram
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 5 μ m, refractive index is 1.70 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 80 gram TiO
2Powder (ISHAHARA system) and 5 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 3 gram light triggers 184 more than 80 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 5 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 2.20 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 3 grams in 100 gram butanone, BYK-307 (BYK system) 1.0 grams are made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.40.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Embodiment 6
1. antistatic backing preparation
10 parts of urethane resin R-960 (DSMLtd system)
Antistatic agent BAYTRONP
R(BAYER system) 5 parts
1.5 parts of surfactant TX-10 (RohmHass system)
4 parts of crosslinking chemical CX-100 (Avecia system)
80 parts in water
In 80 parts of water, add successively: 10 parts of urethane resin R-960,5 parts of antistatic agent BAYTRONP
R, 1.5 parts of surfactant TX-10,4 parts of crosslinking chemical CX-100 stir, and obtain coating fluid.The coating fluid that obtains was stirred 20 minutes, be coated on the cellulose triacetate base material that thickness is 80 μ m, 80 ℃ of heated-air dryings 3 minutes by silk rod rubbing method.
2. anti-dazzle hard conating preparation
Butanone 50 grams
TMPTA (proud son of heaven chemistry system) 20 grams
DPHA (NIPPONKAYAKU system) 10 grams
PO-NPGDA (proud son of heaven chemistry system) 10 grams
Initiating agent 184 2.0 grams
Polymethylmethacrylate MX-500 (SOKEN CHEMISTRY system) 0.5 gram
Above-mentioned substance is added in the reaction bulb successively, stir, obtain coating fluid.The coating fluid that obtains is coated on the above-mentioned base material that has been coated with antistatic backing with silk rod rubbing method, uses LT-UV102 type ultra-violet curing light irradiation to make coating curing after 3 minutes with 50 ℃ of heated-air dryings, thereby acquisition thickness is 4 μ m, refractive index is 1.60 coating.
3. high refractive index layer preparation
In 100 gram cyclohexanone, add 50 gram TiO
2Powder (ISHAHARA system) and 15 gram spreading agents (BYK system) are packed potpourri in the wet grinding machine into, grind more than 24 hours with the zirconium pearl of particle diameter 0.6mm, can obtain the titanium oxide dispersion of particle size less than 100nm.
In 100 gram DPHA, add titanium oxide dispersion and 2 gram light triggers 184 more than 150 grams, make the high refractive index layer coating fluid.This coating fluid is applied on the hard conating with the intaglio plate rubbing method, thereby to use LT-UV102 type ultra-violet curing light irradiation coating is solidified to obtain thickness after 3 minutes be 0.1 μ m for 50 ℃ of heated-air dryings that refractive index is 2.0 coating.
4. low-index layer preparation
Add fluoropolymer T-2020 (DAKIN system) 5 grams in 100 gram butanone, BYK-307 (BYK system) 1 gram is made the low-index layer coating fluid.This coating fluid is applied to high index of refraction with the intaglio plate rubbing method goes up layer by layer, 50 ℃ of heated-air dryings use LT-UV102 type ultra-violet curing light irradiation that coating is solidified after 3 minutes, be 0.08 μ m thereby obtain thickness, the coating of refractive index 1.37.
Can make antireflection film after finishing above-mentioned coating coating, carry out performance test.Test result sees Table in 1.
Table 1: the sheet resistance value (unit: Ω) of antireflection film
| Embodiment | Relative humidity (40%) | Relative humidity (60%) | Relative humidity (60%) | Before the washing (relative humidity 50%) | Washing back (relative humidity 50%) |
| Sheet resistance value | Sheet resistance value | Sheet resistance value | Sheet resistance value | Sheet resistance value | |
| Embodiment 1 | ?0.7*10 10 | ?0.8*10 10 | ?0.6*10 10 | ?0.6*10 10 | ?0.5*10 10 |
| Embodiment 2 | ?0.3*10 10 | ?0.7*10 10 | ?0.4*10 10 | ?0.9*10 10 | ?0.2*10 10 |
| Embodiment 3 | ?40*10 10 | ?3*10 10 | ?0.3*10 10 | ?0.3*10 10 | ?30*10 10 |
| Embodiment 4 | ?30*10 10 | ?4*10 10 | ?0.3*10 10 | ?0.5*10 10 | ?30*10 10 |
| Embodiment 5 | ?35*10 10 | ?5*10 10 | ?0.5*10 10 | ?0.5*10 10 | ?40*10 10 |
| Embodiment 6 | ?0.5*10 10 | ?0.8*10 10 | ?0.6*10 10 | ?0.6*10 10 | ?0.5*10 10 |
The method of testing of surface resistance: the high Insulation Resistance Tester establishing criteria HG/T3008-1997 (sheet primary surface resistance measurement method) that uses Beijing Rui Pu company to produce tests.
Claims (5)
1. an antireflective film comprises base material, anti-dazzle hard coat, high refractive index layer and low-index layer, it is characterized in that, between base material and anti-dazzle hard coat one deck antistatic backing is arranged, and the component of described antistatic backing and parts by weight thereof are:
4～15 parts of aqueous resin dispersions
4～15 parts of antistatic agents
0.2～2 part in surfactant
2～10 parts of crosslinking chemicals
70～100 parts in water
2. antireflection film according to claim 1 is characterized in that, described water-soluble polymers is acrylic monomers, acryl resin, polyurethane or cellulose derivative.
3. antireflective film according to claim 1 and 2 is characterized in that wherein said hard conating has 1.48～1.70 refractive index.
4. antireflective film according to claim 1 and 2 is characterized in that wherein said high refractive index layer has 1.70～2.20 refractive index.
5. antireflective film according to claim 1 and 2 is characterized in that wherein said low-index layer has 1.35～1.42 refractive index.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101022037A CN100434938C (en) | 2006-11-30 | 2006-11-30 | Reflection-proof film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101022037A CN100434938C (en) | 2006-11-30 | 2006-11-30 | Reflection-proof film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1979222A true CN1979222A (en) | 2007-06-13 |
| CN100434938C CN100434938C (en) | 2008-11-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101022037A Active CN100434938C (en) | 2006-11-30 | 2006-11-30 | Reflection-proof film |
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| CN (1) | CN100434938C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101945526A (en) * | 2010-09-16 | 2011-01-12 | 四川虹欧显示器件有限公司 | Anti-static device and method for repairing PDP module |
| CN109776837A (en) * | 2018-12-18 | 2019-05-21 | 合肥乐凯科技产业有限公司 | A kind of anti-blue light protective film |
| CN113462248A (en) * | 2021-08-16 | 2021-10-01 | 郑州中科新兴产业技术研究院 | High-stability water-based paint suitable for various substrates and preparation method thereof |
| WO2023216021A1 (en) * | 2022-05-07 | 2023-11-16 | 京东方科技集团股份有限公司 | Anti-reflection stack structure, manufacturing method therefor, display panel, and display apparatus |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW415888B (en) * | 1998-02-17 | 2000-12-21 | Nippon Kayaku Kk | Transparent sheet or film |
| US6319594B1 (en) * | 1998-03-17 | 2001-11-20 | Dai Nippon Printing Co., Ltd. | Low reflective antistatic hardcoat film |
| US6299799B1 (en) * | 1999-05-27 | 2001-10-09 | 3M Innovative Properties Company | Ceramer compositions and antistatic abrasion resistant ceramers made therefrom |
| JP2003514977A (en) * | 1999-11-22 | 2003-04-22 | スリーエム イノベイティブ プロパティズ カンパニー | Water-based coating composition |
| US7041365B2 (en) * | 2003-05-12 | 2006-05-09 | 3M Innovative Properties Company | Static dissipative optical construction |
| JP2005114852A (en) * | 2003-10-03 | 2005-04-28 | Jsr Corp | Antireflective film for plasma display front plate and its manufacturing method |
| JP2006231316A (en) * | 2004-11-15 | 2006-09-07 | Jsr Corp | Manufacturing method of laminate |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101945526A (en) * | 2010-09-16 | 2011-01-12 | 四川虹欧显示器件有限公司 | Anti-static device and method for repairing PDP module |
| CN101945526B (en) * | 2010-09-16 | 2013-04-10 | 四川虹欧显示器件有限公司 | Anti-static device and method for repairing PDP module |
| CN109776837A (en) * | 2018-12-18 | 2019-05-21 | 合肥乐凯科技产业有限公司 | A kind of anti-blue light protective film |
| CN109776837B (en) * | 2018-12-18 | 2021-07-06 | 合肥乐凯科技产业有限公司 | Prevent blue light protection film |
| CN113462248A (en) * | 2021-08-16 | 2021-10-01 | 郑州中科新兴产业技术研究院 | High-stability water-based paint suitable for various substrates and preparation method thereof |
| WO2023216021A1 (en) * | 2022-05-07 | 2023-11-16 | 京东方科技集团股份有限公司 | Anti-reflection stack structure, manufacturing method therefor, display panel, and display apparatus |
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| Publication number | Publication date |
|---|---|
| CN100434938C (en) | 2008-11-19 |
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