CN1951862B - 'Baby red' ceramic - Google Patents
'Baby red' ceramic Download PDFInfo
- Publication number
- CN1951862B CN1951862B CN2006100862456A CN200610086245A CN1951862B CN 1951862 B CN1951862 B CN 1951862B CN 2006100862456 A CN2006100862456 A CN 2006100862456A CN 200610086245 A CN200610086245 A CN 200610086245A CN 1951862 B CN1951862 B CN 1951862B
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- CN
- China
- Prior art keywords
- weight part
- red
- oxide
- ceramic
- child
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- 239000000919 ceramic Substances 0.000 title abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 9
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 claims abstract description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims abstract description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001947 lithium oxide Inorganic materials 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- ZXGIFJXRQHZCGJ-UHFFFAOYSA-N erbium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Er+3].[Er+3] ZXGIFJXRQHZCGJ-UHFFFAOYSA-N 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 229960001866 silicon dioxide Drugs 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 238000009377 nuclear transmutation Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract 3
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 abstract 2
- WNJSKZBEWNVKGU-UHFFFAOYSA-N 2,2-dimethoxyethylbenzene Chemical compound COC(OC)CC1=CC=CC=C1 WNJSKZBEWNVKGU-UHFFFAOYSA-N 0.000 abstract 1
- 229910003803 Gold(III) chloride Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 229910001940 europium oxide Inorganic materials 0.000 abstract 1
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 abstract 1
- 229940076131 gold trichloride Drugs 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 abstract 1
- 238000010411 cooking Methods 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 241000272814 Anser sp. Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention discloses a material formula of 'baby red' ceramic, which is characterized by the following: adding erbium oxide and one or composite material of gold trichloride, lithium oxide, viridine, europium oxide and yttrium oxide in the raw material formula of white ceramic; sintering according to normal method, thus obtaining 'baby red' ceramic which displays red-in-white and pink ceramic like pink skin of baby. The material formula of 'baby red' ceramic provided by the present invention changes the current situation that the 'baby red' ceramic can only be obtained by occasional furnace transmutation. According to the material formula, mass production of 'baby red' ceramic can be realized with great historical significance.
Description
Technical field
The present invention relates to a kind of composition of raw materials of pottery, the composition of raw materials of especially a kind of rare porcelain kind-" my child is red " porcelain.
Background technology
Dahua ware is world-famous for to produce ceramic whiteware, its quality is superior be ancient times other kilneye can not compare, its product enjoys common people to like, and is called as " Chinese white " (Blanc de Chine).The Ming Dynasty is another peak period that the Dahua ware ceramic whiteware is produced, and product is a large amount of export trades with the absolute predominance occupying inter-national market of its quality.Because the difference of formula for raw stock makes the quality of Dahua ware ceramic whiteware product also different with glaze color and luster effect.At call among the people and academicly, Ming Dynasty's Dahua ware ceramic whiteware is divided into " milky white ", " ivory white ", " lard white ware ", " the green onion root is white ", " goose down is white " etc., but also have a kind of porcelain kind " my child is red " rarely known by the people in these ceramic whitewares, it is the superfine product in Ming Dynasty's Dahua ware ceramic whiteware.Accumulate redly during " my child is red " glaze colours is white, implements naked eyes under light are looked just as the fair and tender red skin of baby." my child is red " is a kind of transmutation porcelain, is implements differences owing to position in the kiln or temperature when high temperature burns till, a kind of special atmosphere of Chuan Zaoing transmutation of generation down once in a while.Its preciousness is in the stove sometimes in a corner, have only several saggar transmutation successes, uncontrollable on its firing process, and under certain atmosphere, just produce accidentally, it is very few to get the person, handed down from ancient times just still less, thereby " my child is red " is considered as superfine product in the rare treasure by world's ancient pottery and porcelain circle and collection circle.The museum that now has only minority to have long enjoyed a good reputation in the world just collects the superfine product of this Ming Dynasty Dahua ware, as British Museum, Wei A museum, the Ji Mei museum of France, the collection shop, Dresden of Germany and the pottery museum, Dehua County at Dahua ware place etc. of Britain.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can fire " my child the is red " porcelain that forms by common process.
Technical scheme of the present invention is such: " my child is red " porcelain, form by the feedstock production that comprises following component: silicon-dioxide 47.7-51.3 weight part, aluminium sesquioxide 20.8-24.0 weight part, ferric oxide 0.46-1.26 weight part, calcium oxide 3.2-4.8 weight part, magnesium oxide 3.03-3.83 weight part, potassium oxide 3.66-7.66 weight part, sodium oxide 0.26-1.86 weight part, titanium dioxide 0.49-0.69 weight part, barium oxide 4.1-4.9 weight part, strontium oxide 1.76-2.16 weight part, zinc oxide 3.4-4.2 weight part, Erbium trioxide 0.48-0.88 weight part.
Raw material that should " my child is red " porcelain also comprises one or more the mixing in gold perchloride, manganese red, europium sesquioxide, the yttrium oxide, wherein, the consumption of gold perchloride is the 0.06-0.1 weight part, the consumption of manganese red is that the consumption of 0.2-0.8 weight part, europium sesquioxide is the 0.26-0.46 weight part, and the consumption of yttrium oxide is the 0.22-1.02 weight part.
The raw material that is somebody's turn to do " my child is red " porcelain also comprises the Lithium Oxide 98min of 0-0.4 weight part.
After adopting such scheme, " my child is red " of the present invention porcelain method for cooking is routinely fired, and just can burn to accumulate naked eyes under red, the light in white and look just as " my child is red " porcelain of the fair and tender red skin of baby.The present invention has changed the existing present situation that can only obtain " my child is red " porcelain by transmutation once in a while, according to composition of raw materials of the present invention, just can make " my child is red " porcelain by conventional method for cooking, can produce on a large scale " my child is red " porcelain, ceramic industry is had great historic significance.
Embodiment
" my child is red " of the present invention porcelain is formed by the feedstock production that comprises following component: silicon-dioxide (SiO
2) 49.5 weight parts, aluminium sesquioxide (Al
2O
3) 22.4 weight parts, ferric oxide (Fe
2O
3) 0.86 weight part, calcium oxide (CaO) 4 weight parts, magnesium oxide (MgO) 3.43 weight parts, potassium oxide (K
2O) 5.66 weight parts, sodium oxide (Na
2O) 1.06 weight parts, titanium dioxide (TiO
2) 0.59 weight part, barium oxide (BaO) 4.5 weight parts, strontium oxide (SvO) 1.96 weight parts, zinc oxide (ZnO) 3.8 weight parts, gold perchloride (Aucl
3) 0.08 weight part, Lithium Oxide 98min (LiO
2) 0.2 weight part, manganese red 0.36 weight part, europium sesquioxide (Eu
2O
3) 0.36 weight part, Erbium trioxide (Er
2O
3) 0.48 weight part, yttrium oxide (Y
2O
3) 0.62 weight part.
" my child is red " of the present invention porcelain method for cooking is routinely fired, and just can burn to accumulate naked eyes under red, the light in white and look just as " my child is red " porcelain of the fair and tender red skin of baby.The present invention has changed the existing present situation that can only obtain by transmutation once in a while, according to composition of raw materials of the present invention, just can make " my child is red " porcelain by conventional method for cooking, can produce on a large scale, ceramic industry is had great historic significance " my child is red " porcelain.
Claims (3)
1. " my child is red " porcelain, it is characterized in that: form: silicon-dioxide 47.7-51.3 weight part by the feedstock production that comprises following component, aluminium sesquioxide 20.8-24.0 weight part, ferric oxide 0.46-1.26 weight part, calcium oxide 3.2-4.8 weight part, magnesium oxide 3.03-3.83 weight part, potassium oxide 3.66-7.66 weight part, sodium oxide 0.26-1.86 weight part, titanium dioxide 0.49-0.69 weight part, barium oxide 4.1-4.9 weight part, strontium oxide 1.76-2.16 weight part, zinc oxide 3.4-4.2 weight part, Erbium trioxide 0.48-0.88 weight part.
2. " my child is red " according to claim 1 porcelain, it is characterized in that: its raw material also comprises one or more the mixing in gold perchloride, manganese red, europium sesquioxide, the yttrium oxide, wherein, the consumption of gold perchloride is the 0.06-0.1 weight part, the consumption of manganese red is the 0.2-0.8 weight part, the consumption of europium sesquioxide is the 0.26-0.46 weight part, and the consumption of yttrium oxide is the 0.22-1.02 weight part.
3. " my child is red " according to claim 1 and 2 porcelain, it is characterized in that: its raw material also comprises the Lithium Oxide 98min of 0-0.4 weight part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100862456A CN1951862B (en) | 2006-08-23 | 2006-08-23 | 'Baby red' ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100862456A CN1951862B (en) | 2006-08-23 | 2006-08-23 | 'Baby red' ceramic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1951862A CN1951862A (en) | 2007-04-25 |
| CN1951862B true CN1951862B (en) | 2011-11-30 |
Family
ID=38058445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100862456A Expired - Fee Related CN1951862B (en) | 2006-08-23 | 2006-08-23 | 'Baby red' ceramic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1951862B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250093A (en) * | 2013-06-28 | 2014-12-31 | 李建水 | Raw materials formula of lard white ware |
| CN107572786A (en) * | 2016-07-04 | 2018-01-12 | 李建水 | The formula of energy ceramic glaze |
| CN106278337B (en) * | 2016-08-11 | 2019-07-05 | 德化县毅术陶瓷研究所 | Glutinous rice tire high density mercerising jade porcelain and its manufacture craft |
| CN109293348A (en) * | 2017-07-25 | 2019-02-01 | 李建水 | A kind of composition of raw materials of lard ceramic whiteware |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119172A (en) * | 1994-09-19 | 1996-03-27 | 四川省轻工业研究设计院 | Method of manufacturing bright red glaze for ceramics |
| CN1686952A (en) * | 2005-05-06 | 2005-10-26 | 湖南省天博瓷业有限公司 | Method for preparing glaze in bright red for ceramics at intermediate temperature |
-
2006
- 2006-08-23 CN CN2006100862456A patent/CN1951862B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119172A (en) * | 1994-09-19 | 1996-03-27 | 四川省轻工业研究设计院 | Method of manufacturing bright red glaze for ceramics |
| CN1686952A (en) * | 2005-05-06 | 2005-10-26 | 湖南省天博瓷业有限公司 | Method for preparing glaze in bright red for ceramics at intermediate temperature |
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| Publication number | Publication date |
|---|---|
| CN1951862A (en) | 2007-04-25 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C14 | Grant of patent or utility model | ||
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Granted publication date: 20111130 |