CN1947508B - Miticide contg. abamectin and tebrfenpyrad synergistic building effect - Google Patents

Miticide contg. abamectin and tebrfenpyrad synergistic building effect Download PDF

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Publication number
CN1947508B
CN1947508B CN2006101460027A CN200610146002A CN1947508B CN 1947508 B CN1947508 B CN 1947508B CN 2006101460027 A CN2006101460027 A CN 2006101460027A CN 200610146002 A CN200610146002 A CN 200610146002A CN 1947508 B CN1947508 B CN 1947508B
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tebufenpyrad
avermectin
abamectin
miticide
mite
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CN1947508A (en
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罗才宏
朱卫锋
郑艳
朱丽萍
王昝畅
王新军
孔健
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Shenzhen Noposion Agrochemicals Co Ltd
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Shenzhen Noposion Agrochemicals Co Ltd
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Abstract

An agricultural miticide is prepared from tebufenpyrad and abamectin.

Description

The miticide that contains tebufenpyrad and Avermectin with synergistic function
Technical field
The composition pesticide that this invention relates to is to be active ingredient with tebufenpyrad and Avermectin, prevents and treats the harmful mite on the agricultural.
Technical background
Tebufenpyrad is a kind of novel miticide rapidly and efficiently, and full phase of growth of various mite classes and mite is all had immediate effect and efficient, the lasting period is long, toxicity is low, do not have in absorption, but have permeability.
Avermectin also is a kind of common environment amenable insecticidal/acaricidal agent.Being a kind of macrolide antibiotics, is actinomycetic extract, has 16 kinds of isomer.The active component that is used as insecticidal/acaricidal agent mainly is Avermectin B1a and Avermectin B1b wherein, and the former is even more important again.On agricultural, Avermectin is control evil mite such as Tetranychus urticae, Tetranychus cinnabarinus etc. and the important kind of insect such as diamond-back moth, liriomyza bryoniae.
In the real process of agricultural production, the problem that pest control is easy to generate most is the drug-fast generation of insect evil mite.Important harmful mite is because its breeding cycle is short, and breeding amount is big, and mobility is little on the agricultural, and selfing degree height is easy to generate resistance especially.In some mite classes serious zone of causing harm, common miticide such as dicofol reach the mite spirit, and what effect use has not had separately.Avermectin is because large-area application has also caused very serious resistance.
Go up the harmful mite that produces resistance for control agricultural, a kind of way be release new do not have the new component of cross resistance with existing kind.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
The composition of different cultivars carries out composite, is control resistant insect or the very common way of evil mite.Heterogeneity is carried out composite, according to the effect of practical application, judge certain composite be synergy, add and or antagonism.Compound synergic is well filled a prescription, owing to obviously improved actual control efficiency, reduced the usage amount of agricultural chemicals, thereby delayed the generation of pest resistance to insecticide greatly, and be the important means of integrated control insect.Still nobody reported in the composite and application of tebufenpyrad and Avermectin at present.
Summary of the invention
Go up the two spotted spider mite that produces resistance in order to prevent and treat agricultural, we have carried out mutual composite synergy research with compositions such as tebufenpyrad, Avermectin.It is tested object that Tetranychus urticae, the Tetranychus cinnabarinus in field are adopted in test, and compares with the sensitive strain of indoor feeding, and concrete grammar is:
1) the Tetranychus urticae test medicine provides former medicine for producer, is mixed with the preparation that needs by my research department of company.The examination worm is the female one-tenth mite of Tetranychus urticae of picking up from the field, through 6 generations of indoor feeding, select the one-tenth mite of growth uniformity, the culture dish that the diameter of access storing apple blade (red fuji apple, the moulding blade of New Development then) is 9 centimetres, every ware connects 30, every processing connects three wares, spray under 50PSI pressure with the POTT spray tower, spray a ware at every turn, 3 milliliters of every ware spraying liquids.Blank spray equivalent clear water.General each processing is provided with 5 concentration gradients.The culture dish of handling is put into 25 ℃, cultivates in the 12H/12H illumination box, checks the survival borer population in 48 hours, calculates the insect population rate that goes down.Calculate virulence equation and lethal concentration of 50 LC50 with method of least squares, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC value) according to the abundant method of Sun Yun, CTC value greater than 100 be synergistic effect, equaling 100 is addition, is antagonism less than 100.
2) the Tetranychus cinnabarinus test medicine provides former medicine for producer, is mixed with the preparation that needs by my research department of company.The examination worm is the female one-tenth mite of Tetranychus cinnabarinus of picking up from the field, through 6 generations of indoor feeding, select the one-tenth mite of growth uniformity, insert the culture dish of the diameter 9 casket rice of putting cotton leaf, every ware connects 30, and every processing connects three wares, sprays under 50PSI pressure with the POTT spray tower, ware of each spray, 3 milliliters of every ware spraying liquids.Blank spray equivalent clear water.General each processing is provided with 5 concentration gradients.The culture dish of handling is put into 25 ℃, cultivates in the 12H/12H illumination box, checks the survival borer population in 48 hours, calculates the insect population rate that goes down.Statistical method is the same.
3) measurement result of Tetranychus urticae, Tetranychus cinnabarinus see Table 1 respectively, table 2, table 3.Ratio is all by mass ratio
Table 1 different disposal is to the toxicity test result of Tetranychus urticae
Handle LC50(PPM) Co-toxicity coefficient
Tebufenpyrad 5+ Avermectin 1 1.89 532.62
Tebufenpyrad 10+ Avermectin 1 1.50 652.57
Tebufenpyrad 20+ Avermectin 1 1.18 814.88
Tebufenpyrad 40+ Avermectin 1 1.14 834.84
Tebufenpyrad 60+ Avermectin 1 1.23 767.13
Tebufenpyrad 80+ Avermectin 1 1.19 599.10
Tebufenpyrad 100+ Avermectin 1 1.68 340.43
Tebufenpyrad 9.41
Avermectin 4.24
Table 2 different disposal is to the toxicity test result of Tetranychus cinnabarinus
Handle ?LC50(PPM) Co-toxicity coefficient
Tebufenpyrad 5+ Avermectin 1 ?2.03 458.19
Tebufenpyrad 10+ Avermectin 1 ?1.57 573.94
Tebufenpyrad 20+ Avermectin 1 ?1.25 706.41
Tebufenpyrad 40+ Avermectin 1 ?1.22 718.28
Tebufenpyrad 60+ Avermectin 1 ?1.34 654.07
Tebufenpyrad 80+ Avermectin 1 ?1.24 529.09
Tebufenpyrad 100+ Avermectin 1 ?1.68 314.14
Tebufenpyrad ?8.68
Avermectin ?3.39
As seen from Table 1, tebufenpyrad and abamectin compounded is 5: 1-100: in the scope of 1 (by quality), Tetranychus urticae is had very high synergistic effect.
As seen from Table 2, tebufenpyrad and abamectin compounded is 5: 1-100: in the scope of 1 (by quality), Tetranychus cinnabarinus is had very high synergy
Embodiment
Application example one: Tetranychus urticae
By Avermectin 0.2%, tebufenpyrad 10%, emulsifier 16018%, emulsifier 500#6%, surplus is a toluene, is mixed with missible oil.This prescription is by 1000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 98.6%, 0.5% abamectin emulsifiable concentrate and 15% tebufenpyrad missible oil according to using with quadrat method, 72 hours preventive effects are respectively 63.3% and 57.0% behind the medicine.
Application example two: Tetranychus urticae
By Avermectin 0.3%, tebufenpyrad 10%, emulsifier 16018%, emulsifier 500#6%, surplus is a toluene, is mixed with missible oil.This prescription is by 3000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 100%, 1.8% abamectin emulsifiable concentrate and 15% tebufenpyrad missible oil according to using with quadrat method, 72 hours preventive effects are respectively 56.3% and 72.0% behind the medicine.
Application example three: Tetranychus cinnabarinus
By Avermectin 0.2%, tebufenpyrad 10%, emulsifier 16018%, emulsifier 500#6%, surplus is a toluene, is mixed with missible oil.This prescription is by 1000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 99.4%, 0.5% abamectin emulsifiable concentrate and 15% tebufenpyrad missible oil according to using with quadrat method, 72 hours preventive effects are respectively 65.2% and 78.5% behind the medicine.
Application example four: Tetranychus cinnabarinus
By Avermectin 0.3%, tebufenpyrad 10%, emulsifier 16018%, emulsifier 500#6%, surplus is a toluene, is mixed with missible oil.This prescription is by 2000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 100%, 1.8% abamectin emulsifiable concentrate and 15% chlorfenapyr missible oil according to using with quadrat method, 72 hours preventive effects are respectively 63.2% and 74.5% behind the medicine.

Claims (2)

1. composition pesticide, active ingredient is made up of tebufenpyrad and Avermectin, and the ratio of tebufenpyrad and Avermectin (by quality) is 100: 1-5: between 1.
2. the composition of mentioning in the claim 1 is made different application forms during practical application, is respectively missible oil, micro emulsion, water and milk, suspending agent, wetting powder.
CN2006101460027A 2006-11-05 2006-11-05 Miticide contg. abamectin and tebrfenpyrad synergistic building effect Active CN1947508B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101288403B (en) * 2008-06-16 2012-04-25 陕西上格之路生物科学有限公司 Insecticidal composition containing tebufenpyrad and uses thereof
CN104054739B (en) * 2013-03-20 2018-04-27 上海生农生化制品股份有限公司 Tebufenpyrad miticide composition
CN104521999B (en) * 2014-12-25 2018-02-16 广东中迅农科股份有限公司 A kind of Synergistic mite killing composition containing tebufenpyrad and Ivermectin HCL
CN107593716A (en) * 2017-10-31 2018-01-19 南京扬子鸿利源化学品有限责任公司 A kind of Synergistic type tebufenpyrad aqueous emulsion and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
蒋才武等.阿维菌素的生物合成、理化性质及其应用.《广西师院学报(自然科学版)》.1999,(第01期),98-101. *
顾保权等.吡螨胺的合成.《现代农药》.2002,(第06期),9-11,28. *

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