CN1943353A - Pest killing composition with synergistic function containing fipronil and abamectin - Google Patents

Pest killing composition with synergistic function containing fipronil and abamectin Download PDF

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Publication number
CN1943353A
CN1943353A CN 200610147125 CN200610147125A CN1943353A CN 1943353 A CN1943353 A CN 1943353A CN 200610147125 CN200610147125 CN 200610147125 CN 200610147125 A CN200610147125 A CN 200610147125A CN 1943353 A CN1943353 A CN 1943353A
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China
Prior art keywords
avermectin
worm nitrile
fluorine worm
abamectin
composition
Prior art date
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Pending
Application number
CN 200610147125
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Chinese (zh)
Inventor
罗才宏
朱卫锋
郑艳
朱丽萍
王昝畅
孔健
王新军
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Shenzhen Noposion Agrochemicals Co Ltd
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Shenzhen Noposion Agrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Shenzhen Noposion Agrochemicals Co Ltd filed Critical Shenzhen Noposion Agrochemicals Co Ltd
Priority to CN 200610147125 priority Critical patent/CN1943353A/en
Publication of CN1943353A publication Critical patent/CN1943353A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a pesticide composition; it comprises fipronil and abamectin, and is used in preventing and controlling agricultural pests. It is especially suitable for preventing and controlling cabbage moth, which have resistance.

Description

The Pesticidal combination that contains fluorine worm nitrile and Avermectin with synergistic function
Technical field
The composition pesticide that this invention relates to is to be active ingredient with fluorine worm nitrile and Avermectin, prevents and treats the insect on the agricultural.Be particularly useful for preventing and treating the diamond-back moth that produces resistance special efficacy is arranged.
Technical background
Fluorine worm nitrile is a kind of Phenylpyrazole insecticides, and the desinsection wide spectrum based on stomach toxicity, has certain tagging and systemic action to insect concurrently.To aphid, leafhopper, diamond-back moth, plant hopper, flea beetle has excellent insecticidal activity.
Avermectin is a kind of common environment amenable insecticidal/acaricidal agent.Being a kind of macrolide antibiotics, is actinomycetic extract, has 16 kinds of isomer.The active component that is used as insecticidal/acaricidal agent mainly is Avermectin Bla and Avermectin Blb wherein, and the former is even more important again.On agricultural, Avermectin is control evil mite such as Tetranychus urticae, Tetranychus cinnabarinus etc. and the important kind of insect such as diamond-back moth, liriomyza bryoniae.
Diamond-back moth is a kind of common insect, and the main harm brassicaceous vegetable is often caused crushing disaster.Especially in the zone, south, diamond-back moth is annual takes place.In some serious zone, conventional pesticide composition such as pyrethroid, organic phosphates, carbamates etc., control efficiency is very poor separately.
Go up the insect that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
The composition of different cultivars carries out composite, is control resistant insect or the very common way of evil mite.Heterogeneity is carried out composite, according to the effect of practical application, judge certain composite be synergy, add and or antagonism.Compound synergic is well filled a prescription, owing to obviously improved actual control efficiency, reduced the usage amount of agricultural chemicals, thereby delayed the generation of pest resistance to insecticide greatly, and be the important means of integrated control insect.Still nobody reported in the composite and application of fluorine worm nitrile and Avermectin at present.
Summary of the invention
Go up the diamond-back moth that produces resistance in order to prevent and treat agricultural, we have carried out mutual composite synergy research with compositions such as fluorine worm nitrile, Avermectin.It is tested object that the diamond-back moth in field is adopted in test, and compares with the sensitive strain of indoor feeding, and concrete grammar is:
Test medicine provides former medicine for producer, is mixed with the preparation that needs by research department of the general letter of promise company.The examination worm is the pickles chrysalis of picking up from the field, after sprouting wings, select the diamond-back moth ovum of uniformity, the culture dish that the diameter of access storing cabbage leaf (black leaf Chinese cabbage, outermost layer blade) is 9 centimetres, every ware connects 30, every processing connects three wares, spray under 50PSI pressure with the POTT spray tower, spray a ware at every turn, 3 milliliters of every ware spraying liquids.General each processing is provided with 6-7 concentration gradient.The culture dish of handling is put into 25 ℃, raises in the 12H/12H illumination box to 1 instar larvae phase, checks the survival borer population, calculates the insect population rate that goes down.Blank spray equivalent clear water.Calculate virulence equation and lethal concentration of 50 LC50 with method of least squares, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC value) according to the abundant method of Sun Yun, CTC value greater than 100 be synergistic effect, equaling 100 is addition, is antagonism less than 100.R represents resistance examination worm, and S represents responsive examination worm.Result of the test sees Table 1
Table 1 different disposal is to the Toxicity Determination result of non-resistance (S) and resistance (R) diamond-back moth
As seen from Table 1, Avermectin and Firponil compounded is 1: 1-1; In the scope of 100 (by quality), diamond-back moth there is very high synergistic effect.The examination worm synergistic effect that Avermectin is produced resistance is more obvious.
Handle LC50(PPM) Resistance index Co-toxicity coefficient
Avermectin 1+ fluorine worm nitrile 5 (S) 1.42 275.42
Avermectin 1+ fluorine worm nitrile 10 (S) 1.45 316.66
Avermectin 1+ fluorine worm nitrile 20 (S) 1.48 344.29
Avermectin 1+ fluorine worm nitrile 30 (S) 1.27 416.57
Avermectin 1+ fluorine worm nitrile 40 (S) 1.36 398.15
Avermectin 1+ fluorine worm nitrile 50 (S) 1.43 384.61
Avermectin 1+ fluorine worm nitrile 60 (S) 1.51 366.06
Avermectin 1+ fluorine worm nitrile 70 (S) 1.61 345.81
Avermectin 1+ fluorine worm nitrile 80 (S) 1.68 333.31
Avermectin 1+ fluorine worm nitrile 90 (S) 2.07 270.98
Avermectin 1+ fluorine worm nitrile 100 (S) 2.32 242.62
Avermectin 1+ fluorine worm nitrile 5 (R) 1.12 646.96
Avermectin 1+ fluorine worm nitrile 10 (R) 0.94 728.27
Avermectin 1+ fluorine worm nitrile 20 (R) 0.60 1105.7
Avermectin 1+ fluorine worm nitrile 30 (R) 0.65 995.64
Avermectin 1+ fluorine worm nitrile 40 (R) 0.71 904.34
Avermectin 1+ fluorine worm nitrile 50 (R) 0.72 893.77
Avermectin 1+ fluorine worm nitrile 60 (R) 0.78 825.65
Avermectin 1+ fluorine worm nitrile 70 (R) 0.80 805.00
Avermectin 1+ fluorine worm nitrile 80 (R) 0.90 711.17
Avermectin 1+ fluorine worm nitrile 90 (R) 1.06 604.26
Avermectin 1+ fluorine worm nitrile 100 (R) 1.44 443.64
Avermectin (S) 1.48
Fluorine worm nitrile (S) 5.80
Avermectin (R) 27.53 18.60
Fluorine worm nitrile (R) 6.34 1.09
Embodiment
Application example one: control diamond-back moth
By Avermectin 0.5%, fluorine worm nitrile 10%, emulsifier 1,601 8%, emulsifier 500#6%, surplus is toluene and tricresyl phosphate, is mixed with missible oil.This prescription is by 2000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 95.6%, 1.8% abamectin emulsifiable concentrate and 15% fluorine worm nitrile missible oil according to using with quadrat method, 72 hours preventive effects are respectively 56.3% and 77.0% behind the medicine.
Application example two: control diamond-back moth
By Avermectin 03%, fluorine worm nitrile 10%, emulsifier 1,601 8%, emulsifier 500#6%, surplus is toluene and tricresyl phosphate, is mixed with missible oil.This prescription is by 2000 times of dilution sprayings, behind the medicine 72 hours control efficiency be 95%, 1.8% abamectin emulsifiable concentrate and 15% fluorine worm nitrile missible oil according to using with quadrat method, 72 hours preventive effects are respectively 54.3% and 76.0% behind the medicine.

Claims (3)

1, a kind of composition pesticide is made up of fluorine worm nitrile and Avermectin, and the ratio of fluorine worm nitrile and Avermectin (by quality) is 1: 1-1: between 100.
2, the composition of mentioning in the claim 1 is made different application forms during practical application, comprise missible oil, micro emulsion, water and milk, suspending agent, wetting powder.
3, the composition of mentioning in the claim 1, the mass percentage content of fluorine worm nitrile and the two accumulation of Avermectin is between 1%-40%.
CN 200610147125 2006-11-07 2006-11-07 Pest killing composition with synergistic function containing fipronil and abamectin Pending CN1943353A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200610147125 CN1943353A (en) 2006-11-07 2006-11-07 Pest killing composition with synergistic function containing fipronil and abamectin

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Application Number Priority Date Filing Date Title
CN 200610147125 CN1943353A (en) 2006-11-07 2006-11-07 Pest killing composition with synergistic function containing fipronil and abamectin

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CN1943353A true CN1943353A (en) 2007-04-11

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010020510A3 (en) * 2008-08-18 2011-01-27 Syngenta Participations Ag Insecticidal combinations comprising abamectin and cyflumetofen
US20110319263A1 (en) * 2009-02-11 2011-12-29 Basf Se Pesticidal mixtures
CN104522006A (en) * 2014-12-19 2015-04-22 湖南化工研究院有限公司 Composition for preventing and controlling lepidoptera and homopteran pests
CN105941436A (en) * 2016-06-27 2016-09-21 青岛润生农化有限公司 Abamectin and acetoprole-containing insecticidal combination
CN106804602A (en) * 2015-11-27 2017-06-09 陕西韦尔奇作物保护有限公司 A kind of Pesticidal combination of the nitrile of worm containing acetyl and AVM

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010020510A3 (en) * 2008-08-18 2011-01-27 Syngenta Participations Ag Insecticidal combinations comprising abamectin and cyflumetofen
EA017524B1 (en) * 2008-08-18 2013-01-30 Зингента Партисипейшнс Аг Insecticidal combinations
US8598130B2 (en) 2008-08-18 2013-12-03 Syngenta Crop Protection Llc Insecticidal combinations
US20110319263A1 (en) * 2009-02-11 2011-12-29 Basf Se Pesticidal mixtures
CN102307478A (en) * 2009-02-11 2012-01-04 巴斯夫欧洲公司 Pesticidal mixtures
US20140194285A1 (en) * 2009-02-11 2014-07-10 Dirk Voeste Pesticidal Mixtures
CN104522006A (en) * 2014-12-19 2015-04-22 湖南化工研究院有限公司 Composition for preventing and controlling lepidoptera and homopteran pests
CN106804602A (en) * 2015-11-27 2017-06-09 陕西韦尔奇作物保护有限公司 A kind of Pesticidal combination of the nitrile of worm containing acetyl and AVM
CN105941436A (en) * 2016-06-27 2016-09-21 青岛润生农化有限公司 Abamectin and acetoprole-containing insecticidal combination

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Open date: 20070411