CN1944563A - Formaldehyde-free adhesive and preparation method thereof - Google Patents
Formaldehyde-free adhesive and preparation method thereof Download PDFInfo
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- CN1944563A CN1944563A CN 200610114100 CN200610114100A CN1944563A CN 1944563 A CN1944563 A CN 1944563A CN 200610114100 CN200610114100 CN 200610114100 CN 200610114100 A CN200610114100 A CN 200610114100A CN 1944563 A CN1944563 A CN 1944563A
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- tackiness agent
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- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000000853 adhesive Substances 0.000 title abstract description 5
- 230000001070 adhesive effect Effects 0.000 title abstract description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 14
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 14
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 14
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 14
- 239000000230 xanthan gum Substances 0.000 claims abstract description 14
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 14
- 108010082495 Dietary Plant Proteins Proteins 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 75
- 238000001816 cooling Methods 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 27
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 14
- 229920002472 Starch Polymers 0.000 claims description 13
- 229960002989 glutamic acid Drugs 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 12
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 11
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 11
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 239000008107 starch Substances 0.000 claims description 7
- 108010064851 Plant Proteins Proteins 0.000 claims description 4
- 235000021118 plant-derived protein Nutrition 0.000 claims description 4
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 6
- 239000007769 metal material Substances 0.000 abstract description 4
- 239000002023 wood Substances 0.000 abstract description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000881 Modified starch Polymers 0.000 abstract 1
- 239000004368 Modified starch Substances 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 235000013922 glutamic acid Nutrition 0.000 abstract 1
- 239000004220 glutamic acid Substances 0.000 abstract 1
- 235000019426 modified starch Nutrition 0.000 abstract 1
- 229910052755 nonmetal Inorganic materials 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 238000005034 decoration Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 description 1
- 240000008669 Hedera helix Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a formaldehyde-free adhesive and a preparation method thereof. The invention comprises the following components in percentage by weight: 75-99% of the component A and 1-25% of the component B; wherein the component A comprises the following components in percentage by weight: 1-15% of polyvinyl alcohol, 1-10% of xanthan gum, 1-5% of modified starch, 1-5% of vegetable protein powder, 0.1-2% of glutamic acid, 90.1-0.5% of AEO-0.5%, 0.1-2% of defoaming agent, 0.005-0.02% of sodium benzoate, 1-15% of talcum powder and 45.5-74.5% of water; wherein the component B comprises the following components in percentage by weight: 1-25% of MDI, 5-25% of TDI, 5-25% of HDI, 1-25% of DBP and 1-25% of DOP. The preparation method of the invention comprises the following steps of respectively preparing a component A and a component B: respectively sealing and packaging; before use, the required component A and the component B are mixed uniformly. The invention does not contain formaldehyde, has no peculiar smell, and is nontoxic and pollution-free; the price is low, and the adhesive can be widely used for processing semi-finished wood and bonding metal materials, non-metal materials and the like; high adhesion strength and high water resistance. Is suitable for various production line requirements without changing production conditions.
Description
Technical field
The present invention relates to a kind of chemical materials, relate in particular to a kind of tackiness agent that does not contain formaldehyde, also relate to its preparation method.
Background technology
The various wood furnitures of new production both at home and abroad and office furniture are owing to be extensive use of urea-formaldehyde resin adhesive at present, and 100% has formaldehyde to pollute; The car of producing, passenger vehicle, lorry compartment interior 100% have the pollution of formaldehyde and triphen.There are 1,000,000 leukaemics in the whole nation, annual newly-increased 40,000 patients, and wherein 20,000 is child patients about 7 years old, wherein 90% ill reason is relevant with house decoration for this.
The U.S., Britain, Germany, Japan and other countries have research to formaldehyde-free aqueous isocyanate wood adhesive in the world at present, mainly contain Japanese firm of a few family as what products production was used.But because the market sale price is higher, 16000-23000 unit/ton, domestic manufacturer uses seldom, uses also few in the world.Though domestic also have some manufacturer production similar products like, but because price is higher, product is more single, has promptly accomplished formaldehydeless (as core-board) at a kind of product, but other products in house decoration (as furniture etc.) formaldehyde is still arranged, cause or exist formaldehyde to pollute.Therefore, do not have fairly large application basically, can't fundamentally eliminate formaldehyde pollution.
Summary of the invention:
The purpose of this invention is to provide a kind of tackiness agent that does not contain formaldehyde and preparation method thereof.The present invention does not contain the tackiness agent of formaldehyde, owing to do not contain formaldehyde, does not have peculiar smell, Nonpoisonous, non-environmental-pollution, and the formaldehyde of tackiness agent commonly used does not pollute; With the article of its bonding various operations, bonding strength height, water-tolerant; Its price is lower, and suitable multiple material is extensive use of, thereby has overcome the deficiency of the tackiness agent existence of present use.
Component and weight percent thereof that the present invention does not contain the tackiness agent of formaldehyde consist of:
Component A 75%-99%,
B component 1%-25%;
Wherein the component of component A and weight percent thereof consist of:
Polyvinyl alcohol 1%-15%,
Xanthan gum 1%-10%,
Treated starch 1%-5%,
Plant protein powder 1%-5%,
L-glutamic acid 0.1%-2%,
AEO-9 (fatty alcohol-polyoxyethylene ether) 0.1%-0.5%,
Defoamer 0.1%-2%,
Sodium Benzoate 0.005%-0.02%,
Talcum powder 1%-15%,
Water 45.5%-90%;
Wherein the component of B component and weight percent thereof consist of:
MDI (ditan-4,4 '-vulcabond) 1%-25%,
TDI (tolylene diisocyanate) 5%-25%,
HDI (hexamethylene diisocyanate) 5%-25%,
DBP (phthalic acid dibutyl ester) 1%-25%,
DOP (dioctyl phthalate) 1%-25%.
The component and the preferred weight percent thereof of tackiness agent of the present invention consist of:
Component A 80%-95%,
B component 5%-20%.
Wherein the component of component A and preferred weight percent thereof consist of:
Polyvinyl alcohol 3%-15%,
Xanthan gum 1%-7%,
Treated starch 2%-5%,
Plant protein powder 1%-4%,
L-glutamic acid 0.1%-1%,
AEO-9 0.2％-0.5％、
Defoamer 0.8%-2%,
Sodium Benzoate 0.005%-0.01%,
Talcum powder 4%-15%,
Water 52-74.5%.
Preparation method's the step of tackiness agent that the present invention does not contain formaldehyde is as follows:
1) preparation component A: in reactor, add required water, more required polyvinyl alcohol, xanthan gum, L-glutamic acid, AEO-9, defoamer, Sodium Benzoate, talcum powder are added in the reactor successively, be heated to 100 ℃, stir half an hour; After the cooling, add required treated starch and vegetable-protein again, stir half an hour, cooling: pack;
2) preparation B component: earlier required DBP, DOP are put into reactor, mixture is even; And then add MDI successively, and TDI, HDI is heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling; Pack;
3) before the use, required component A, B component are mixed, do not contained the tackiness agent of formaldehyde.
Preparation the present invention does not contain the tackiness agent of formaldehyde, need carry out in Glass Containers or plastic containers.
The tackiness agent that the present invention does not contain formaldehyde can be used for the processing of work in-process timber, comprising: core-board, glued board, facing plate, bentwood furniture, three layers or multi-layer solid wood composite floor, density board and shaving board; Also can be used as bonding, textiles bonding of bonding, the non-metallic material (as plastics etc.) of various metallic substance.
The present invention does not contain the article of the bonding various operations of tackiness agent of formaldehyde, the bonding strength height, and water-tolerant does not have peculiar smell, Nonpoisonous, non-environmental-pollution, the formaldehyde of tackiness agent commonly used does not pollute.Be fit to the requirement of various production lines, need not change working condition.
Raw material required for the present invention, equipment all have commercially available.
Embodiment
Embodiment 1
1) preparation component A: in reactor, add 45.5 kilograms of entry; Again 15 kilograms of required polyvinyl alcohol, 10 kilograms of xanthan gum, 2 kilograms in L-glutamic acid, 0.495 kilogram of AEO-9,2 kilograms of defoamers, 0.005 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 15 kilograms successively, be heated to 100 ℃, stir half an hour; After the cooling, add 5 kilograms of 5 kilograms of required treated starches and vegetable-proteins again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 25 kilograms of mixtures of 25 kilograms of DBP, DOP are even, put into reactor then, add 1 kilogram of MDI more successively, 24 kilograms of TDI, 25 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 75 kilograms of component A jin, 25 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Embodiment 2
1) preparation component A: in reactor, add 74.5 kilograms of entry; Again 11.19 kilograms of required polyvinyl alcohol, 7 kilograms of xanthan gum, 0.1 kilogram in L-glutamic acid, 0.1 kilogram of AEO-9,0.1 kilogram of defoamer, 0.01 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 1 kilogram successively, be heated to 100 ℃, stir half an hour; After the cooling, add 4 kilograms of 2 kilograms of required treated starches and vegetable-proteins again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 20 kilograms of mixtures of 25 kilograms of DBP, DOP are even, put into reactor then, add 5 kilograms of MD more successively, 25 kilograms of TDI, 25 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 99 kilograms of component A jin, 1 kilogram of B component mixes, and is not contained the tackiness agent of formaldehyde.
Embodiment 3
1) preparation component A: in reactor, add 70.985 kilograms of entry; Again 13 kilograms of required polyvinyl alcohol, 8 kilograms of xanthan gum, 1 kilogram in L-glutamic acid, 0.2 kilogram of AEO-9,0.8 kilogram of defoamer, 0.005 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 4 kilograms successively, be heated to 100 ℃, stir half an hour; After the cooling, add 1 kilogram of 1 kilogram of required treated starch and vegetable-protein again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 25 kilograms of mixtures of 23 kilograms of DBP, DOP are even, put into reactor then, add 22 kilograms of MDI more successively, 5 kilograms of TDI, 25 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 80 kilograms of component A jin, 20 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Embodiment 4
1) preparation component A: in reactor, add 90 kilograms of entry; Again 3 kilograms of required polyvinyl alcohol, 1 kilogram of xanthan gum, 1 kilogram in L-glutamic acid, 0.1 kilogram of AEO-9,0.1 kilogram of defoamer, 0.02 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 1 kilogram successively, be heated to 100 ℃, stir half an hour; After the cooling, add 1 kilogram of 2.78 kilograms of required treated starches and vegetable-protein again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 24 kilograms of mixtures of 24 kilograms of DBP, DOP are even, put into reactor then, add 23 kilograms of MDI more successively, 24 kilograms of TDI, 5 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 95 kilograms of component A, 5 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Embodiment 5
1) preparation component A: in reactor, add 67.492 kilograms of entry; Again 1 kilogram of required polyvinyl alcohol, 6 kilograms of xanthan gum, 2 kilograms in L-glutamic acid, 0.5 kilogram of AEO-9,2 kilograms of defoamers, 0.008 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 13 kilograms successively, be heated to 100 ℃, stir half an hour; After the cooling, add 4 kilograms of 4 kilograms of required treated starches and vegetable-proteins again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 25 kilograms of mixtures of 1 kilogram of DBP, DOP are even, put into reactor then, add 25 kilograms of MDI more successively, 24 kilograms of TDI, 25 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 85 kilograms of component A jin, 15 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Embodiment 6
1) preparation component A: in reactor, add 52 kilograms of entry; Add in the reactor successively 14 kilograms of required polyvinyl alcohol, 9.482 kilograms of xanthan gum, 1.8 kilograms in L-glutamic acid, 0.4 kilogram of AEO-9,1.3 kilograms of defoamers, 0.018 kilogram of Sodium Benzoate, talcum powder for 14 kilograms again, be heated to 100 ℃, stir half an hour; After the cooling, add 4 kilograms of 3 kilograms of required treated starches and vegetable-proteins again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 1 kilogram of mixture of 25 kilograms of DBP, DOP is even, put into reactor then, add 25 kilograms of MDI more successively, 25 kilograms of TDI, 24 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 88 kilograms of component A jin, 12 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Embodiment 7
1) preparation component A: in reactor, add 70.79 kilograms of entry; Again 10 kilograms of required polyvinyl alcohol, 2 kilograms of xanthan gum, 0.1 kilogram in L-glutamic acid, 0.1 kilogram of AEO-9,1 kilogram of defoamer, 0.01 kilogram of Sodium Benzoate, talcum powder are added in the reactor for 10 kilograms successively, be heated to 100 ℃, stir half an hour; After the cooling, add 1 kilogram of 5 kilograms of required treated starches and vegetable-protein again, stir half an hour, cooling, stand-by:
2) preparation B component: earlier that 20 kilograms of mixtures of 25 kilograms of DBP, DOP are even, put into reactor then, add 20 kilograms of MDI more successively, 25 kilograms of TDI, 10 kilograms of HDI are heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling, stand-by;
3) component A, the B component with above-mentioned preparation packs respectively, before the use, gets 84 kilograms of component A jin, 16 kilograms of B component mix, and are not contained the tackiness agent of formaldehyde.
Claims (4)
1. a component and a weight percent thereof that does not contain the tackiness agent of formaldehyde consists of:
Component A 75%-99%,
B component 1%-25%;
Wherein the component of component A and weight percent thereof consist of:
Polyvinyl alcohol 1%-15%,
Xanthan gum 1%-10%,
Treated starch 1%-5%,
Plant protein powder 1%-5%,
L-glutamic acid 0.1%-2%,
Fatty alcohol-polyoxyethylene ether 0.1%-0.5%,
Defoamer 0.1%-2%,
Sodium Benzoate 0.05%-0.02%,
Talcum powder 1%-15%,
Water 45.5%-74.5%;
Wherein the component of B component and weight percent thereof consist of:
Ditan-4,4 '-vulcabond 1%-25%,
Tolylene diisocyanate 5%-25%,
Hexamethylene diisocyanate 5%-25%,
Phthalic acid dibutyl ester 1%-25%,
Dioctyl phthalate 1%-25%.
2. do not contain the tackiness agent of formaldehyde according to claim 1, it is characterized in that, component and weight percent thereof consist of: component A 80-95%, B component 5-20%.
3. as not containing the tackiness agent of formaldehyde as described in the claim 2, it is characterized in that wherein the component of component A and weight percent thereof consist of:
Polyvinyl alcohol 3%-15%,
Xanthan gum 1%-7%,
Treated starch 2%-5%,
Plant protein powder 1%-4%,
L-glutamic acid 0.1%-1%,
Fatty alcohol-polyoxyethylene ether 0.2%-0.5%,
Defoamer 0.8%-2%,
Sodium Benzoate 0.005%-0.01%,
Talcum powder 4%-15%,
Water 52%-74.5%.
4. the preparation method who does not contain the tackiness agent of formaldehyde as claimed in claim 1 or 2, step is as follows:
1) preparation component A: in reactor, add required water, more required polyvinyl alcohol, xanthan gum, L-glutamic acid, AEO-9, defoamer, Sodium Benzoate, talcum powder are added in the reactor successively, be heated to 100 ℃, stir half an hour; After the cooling, add required treated starch and vegetable-protein again, stir half an hour, cooling: pack;
2) preparation B component: earlier required DBP, DOP are put into reactor, mixture is even; And then add MDI successively, and TDI, HDI is heated to 80 ℃ under the nitrogen protection atmospheric condition, stir half an hour, cooling: pack;
3) before the use, required component A, B component are mixed, do not contained the tackiness agent of formaldehyde.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101141002A CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101141002A CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1944563A true CN1944563A (en) | 2007-04-11 |
| CN100432175C CN100432175C (en) | 2008-11-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101141002A Expired - Fee Related CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100432175C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102146273A (en) * | 2011-02-12 | 2011-08-10 | 东营正化环保科技有限公司 | Formaldehyde-free phenol-free adhesive and preparation method thereof |
| CN101323767B (en) * | 2007-06-13 | 2012-07-04 | 广东风华高新科技股份有限公司 | Environment protective adhesive |
| CN102676097A (en) * | 2012-06-01 | 2012-09-19 | 湖南福星林业股份有限公司 | Novel non-formaldehyde environment-friendly adhesive and preparation method thereof |
| CN103709990A (en) * | 2013-12-10 | 2014-04-09 | 福建农林大学 | Bio-enzyme modified plant protein base timber adhesive and preparation method thereof |
| CN104927265A (en) * | 2015-06-02 | 2015-09-23 | 铜陵方正塑业科技有限公司 | Oil-proof pea protein powder-based full-degradable plastic film and preparation method thereof |
| CN107286893A (en) * | 2016-03-30 | 2017-10-24 | 王钱生 | A kind of waterborne polymeric isocyanate wood adhesive and preparation method thereof |
| CN108504320A (en) * | 2018-03-16 | 2018-09-07 | 广东始兴县华洲木业有限公司 | A kind of preparation method and applications of aldehyde-free cement |
| CN109929488A (en) * | 2019-01-23 | 2019-06-25 | 福建省泰森源新材料科技有限公司 | Zero aldehyde crystal adhesive of one kind and preparation method thereof |
| CN110561885A (en) * | 2019-08-30 | 2019-12-13 | 李魁 | Preparation method of high-barrier flexible aluminized film |
| CN116787560A (en) * | 2023-06-21 | 2023-09-22 | 广东始兴县华洲木业有限公司 | Composite heavy bamboo board and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5130577B2 (en) * | 1972-08-05 | 1976-09-01 |
-
2006
- 2006-10-27 CN CNB2006101141002A patent/CN100432175C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323767B (en) * | 2007-06-13 | 2012-07-04 | 广东风华高新科技股份有限公司 | Environment protective adhesive |
| CN102146273A (en) * | 2011-02-12 | 2011-08-10 | 东营正化环保科技有限公司 | Formaldehyde-free phenol-free adhesive and preparation method thereof |
| CN102676097A (en) * | 2012-06-01 | 2012-09-19 | 湖南福星林业股份有限公司 | Novel non-formaldehyde environment-friendly adhesive and preparation method thereof |
| CN103709990A (en) * | 2013-12-10 | 2014-04-09 | 福建农林大学 | Bio-enzyme modified plant protein base timber adhesive and preparation method thereof |
| CN103709990B (en) * | 2013-12-10 | 2016-01-20 | 福建农林大学 | Vegetable-protein base based Wood Adhesives of a kind of enzyme modified and preparation method thereof |
| CN104927265A (en) * | 2015-06-02 | 2015-09-23 | 铜陵方正塑业科技有限公司 | Oil-proof pea protein powder-based full-degradable plastic film and preparation method thereof |
| CN107286893A (en) * | 2016-03-30 | 2017-10-24 | 王钱生 | A kind of waterborne polymeric isocyanate wood adhesive and preparation method thereof |
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