CN100432175C - formaldehyde-free adhesive and preparation method thereof - Google Patents
formaldehyde-free adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN100432175C CN100432175C CNB2006101141002A CN200610114100A CN100432175C CN 100432175 C CN100432175 C CN 100432175C CN B2006101141002 A CNB2006101141002 A CN B2006101141002A CN 200610114100 A CN200610114100 A CN 200610114100A CN 100432175 C CN100432175 C CN 100432175C
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- CN
- China
- Prior art keywords
- component
- kilograms
- formaldehyde
- preparation
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000000853 adhesive Substances 0.000 title abstract description 5
- 230000001070 adhesive effect Effects 0.000 title abstract description 5
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims abstract description 27
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 14
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 14
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 14
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 14
- 239000000230 xanthan gum Substances 0.000 claims abstract description 14
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 14
- 108010082495 Dietary Plant Proteins Proteins 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 72
- 238000001816 cooling Methods 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- 229920002472 Starch Polymers 0.000 claims description 13
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 13
- 229960002989 glutamic acid Drugs 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 12
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 12
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 239000008107 starch Substances 0.000 claims description 7
- 108010064851 Plant Proteins Proteins 0.000 claims description 4
- 235000021118 plant-derived protein Nutrition 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000007769 metal material Substances 0.000 abstract description 4
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002023 wood Substances 0.000 abstract description 4
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000881 Modified starch Polymers 0.000 abstract 1
- 239000004368 Modified starch Substances 0.000 abstract 1
- 235000013922 glutamic acid Nutrition 0.000 abstract 1
- 239000004220 glutamic acid Substances 0.000 abstract 1
- 235000019426 modified starch Nutrition 0.000 abstract 1
- 229910052755 nonmetal Inorganic materials 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 238000005034 decoration Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 description 1
- 240000008669 Hedera helix Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101141002A CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101141002A CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1944563A CN1944563A (en) | 2007-04-11 |
CN100432175C true CN100432175C (en) | 2008-11-12 |
Family
ID=38044221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2006101141002A Expired - Fee Related CN100432175C (en) | 2006-10-27 | 2006-10-27 | formaldehyde-free adhesive and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN100432175C (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101323767B (en) * | 2007-06-13 | 2012-07-04 | 广东风华高新科技股份有限公司 | Environment protective adhesive |
CN102146273B (en) * | 2011-02-12 | 2013-04-10 | 东营正化环保科技有限公司 | Formaldehyde-free phenol-free adhesive and preparation method thereof |
CN102676097B (en) * | 2012-06-01 | 2014-02-12 | 湖南福星林业股份有限公司 | Non-formaldehyde environment-friendly adhesive and preparation method thereof |
CN103709990B (en) * | 2013-12-10 | 2016-01-20 | 福建农林大学 | Vegetable-protein base based Wood Adhesives of a kind of enzyme modified and preparation method thereof |
CN104927265A (en) * | 2015-06-02 | 2015-09-23 | 铜陵方正塑业科技有限公司 | Oil-proof pea protein powder-based full-degradable plastic film and preparation method thereof |
CN107286893B (en) * | 2016-03-30 | 2020-08-18 | 桂林新美环保科技有限公司 | Aqueous polymer isocyanate wood adhesive and preparation method thereof |
CN108504320A (en) * | 2018-03-16 | 2018-09-07 | 广东始兴县华洲木业有限公司 | A kind of preparation method and applications of aldehyde-free cement |
CN109929488A (en) * | 2019-01-23 | 2019-06-25 | 福建省泰森源新材料科技有限公司 | Zero aldehyde crystal adhesive of one kind and preparation method thereof |
CN110561885A (en) * | 2019-08-30 | 2019-12-13 | 李魁 | Preparation method of high-barrier flexible aluminized film |
CN116787560B (en) * | 2023-06-21 | 2024-02-20 | 广东始兴县华洲木业有限公司 | Composite heavy bamboo board and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3931088A (en) * | 1972-08-05 | 1976-01-06 | Kuraray Co., Ltd. | Adhesive composition consisting of polyvinylalcohol solution or polyvinylacetate latex modified with hydrophobic solution of isocyanate compound |
-
2006
- 2006-10-27 CN CNB2006101141002A patent/CN100432175C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3931088A (en) * | 1972-08-05 | 1976-01-06 | Kuraray Co., Ltd. | Adhesive composition consisting of polyvinylalcohol solution or polyvinylacetate latex modified with hydrophobic solution of isocyanate compound |
US3931088B1 (en) * | 1972-08-05 | 1983-03-15 |
Also Published As
Publication number | Publication date |
---|---|
CN1944563A (en) | 2007-04-11 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: BEIJING JINZE SHENGRUI TECHNOLOGY CO., LTD. Free format text: FORMER NAME: HUAYU HONGYE SCIENCE AND TECHNOLOGY DEVELOPMENT CO., LTD., BEIJING |
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CP03 | Change of name, title or address |
Address after: 163400 Daqing hi tech industry zone, Daqing three, Heilongjiang Province Patentee after: Jinze Beijing Sheng Rui Technology Co., Ltd. Address before: 163400, Heilongjiang Daqing hi tech industry zone three Yu ang company Patentee before: Huayu Hongye Science and Technology Development Co., Ltd., Beijing |
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ASS | Succession or assignment of patent right |
Owner name: HEILONGJIANG JINZE SHENGRUI SCIENCE + TECHNOLOGY C Free format text: FORMER OWNER: BEIJING JINZE SHENGRUI TECHNOLOGY CO., LTD. Effective date: 20150114 |
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Free format text: CORRECT: ADDRESS; FROM: 163400 DAQING, HEILONGJIANG PROVINCE TO: 151423 SUIHUA, HEILONGJIANG PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20150114 Address after: 151423 Ren Ren Town, anda, Suihua, Heilongjiang Patentee after: Jinze, Heilongjiang Sheng Rui Polytron Technologies Inc Address before: 163400 Daqing hi tech industry zone, Daqing three, Heilongjiang Province Patentee before: Jinze Beijing Sheng Rui Technology Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081112 Termination date: 20171027 |
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CF01 | Termination of patent right due to non-payment of annual fee |