CN1939870A - Non-silicon sludge curing treatment of thickened-oil sewage - Google Patents

Non-silicon sludge curing treatment of thickened-oil sewage Download PDF

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Publication number
CN1939870A
CN1939870A CNA2005101058087A CN200510105808A CN1939870A CN 1939870 A CN1939870 A CN 1939870A CN A2005101058087 A CNA2005101058087 A CN A2005101058087A CN 200510105808 A CN200510105808 A CN 200510105808A CN 1939870 A CN1939870 A CN 1939870A
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CN
China
Prior art keywords
silicon sludge
thickened
cement
oil sewage
curing treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2005101058087A
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Chinese (zh)
Inventor
张宁生
屈撑囤
王新强
吴新民
杨志刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China National Petroleum Corp
Xian Shiyou University
Original Assignee
China National Petroleum Corp
Xian Shiyou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China National Petroleum Corp, Xian Shiyou University filed Critical China National Petroleum Corp
Priority to CNA2005101058087A priority Critical patent/CN1939870A/en
Publication of CN1939870A publication Critical patent/CN1939870A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Road Paving Structures (AREA)

Abstract

Treatment for curing silicon-free sludge and condensed oil sewage is carried out by adding cement 30-70wt%, sand 10-30wt%, reinforcer 1-5wt% and water into agitator, adding into silicon-free sludge 10-40wt%, agitating in agitator, forming in mould, curing for 3-7daysm de-moulding, maintaining for 7-15days and curing. It's simple, convenient and cheap and has no secondary pollution.

Description

A kind of non-silicon sludge curing treatment of thickened-oil sewage
Technical field:
The present invention relates to a kind of solidification processing method of removing silicon from thick oil sewage mud.Specifically by with removing silicon from thick oil sewage mud with after cement, sand, toughener mix, solidify, can make cured block with higher-strength, the cured block of gained can be used as ornamental slab for paving the floor, curb etc., can make the silica removal recycling sludge, elimination is to the pollution of environment.
Background technology:
What at present, removing silicon from thick oil sewage produced is more unmanageable problem except that silicon sludge in a large number.For sludge treatment, Chinese patent CN1382652A discloses a kind of quick, economic sludge treatment technique.It is to burn after mud granulizing, the oven dry, can handle continuously the mud that sewage work produces.This processing mode is suitable for the processing of various organic sludges but long flow path, and processing cost is higher.Chinese patent CN1105689C, CN1178777A reclaim the part oil product in the oily sludge by with oily sludge stripping, distillation.This processing mode is suitable for petrochemical complex and the scum silica frost of sewage from oil refinery treating processes generation and the technology of oily sludge.CN1579969A then by add hot water, stirring in oily sludge, realizes the separation of profit.It is suitable for the oil field and lands the processing of oil, jar bed mud and refinery greasy filth.Big and inorganic content is high removes silicon sludge and use aforesaid method and can't handle for generation.
Generally speaking, all there is following problem in aforesaid method:
1, treatment scheme is long, and cost is higher;
2, the suitable object of handling is that height contains organism and oily sludge;
3, processing is thorough inadequately, has the secondary pollution phenomenon.
Summary of the invention:
The present invention aims to provide a kind of non-silicon sludge curing treatment of thickened-oil sewage, is a kind of solidification processing method of removing silicon from thick oil sewage mud of simple, efficient, environmental protection.
For achieving the above object, the present invention take technical scheme be: in agitator, add cement, sand, remove silicon sludge, toughener and water, additional proportion is: the consumption of cement is 30%~70% of a gross weight, is preferably 40%, and the particle of sand is 1~3mm, dosage is 10%~30% of a gross weight, being preferably 20%, removing silicon sludge is 10%~40% of gross weight, is preferably 25%, and the toughener dosage is 1~5%, be preferably 3%, under agitation add the water of surplus then.After in agitator, mixing,, after the demoulding maintenance, its curing is got final product in die for molding.
Cement used in the invention can be 325 #Cement, 425 #Cement, superfine cement, its dosage is 30%~70% of a gross weight, is preferably 40%; Used sand is quartz sand, crushed-gravel, and the particle of sand is 1~3mm, and dosage is 10%~30% of a gross weight, is preferably 20%.Used toughener is cyanamide resin, Resins, epoxy or urea-formaldehyde resin.Its dosage is 1~5% of a gross weight, is preferably 3%.Used remove silicon sludge moisture to be 20~70%, to be preferably 30%~40%, dosage be gross weight 10%~40%, be preferably 25%.Used mould is: ornamental slab for paving the floor mould or curb mould.
Compared with prior art, the present invention has following useful effect:
1, treatment process is simple, and is easy to operate;
2, processing cost is low, and Pollutant Treatment is thorough;
3, big to the treatment capacity of removing silicon sludge, do not produce secondary pollution after handling;
4, remove silicon sludge through after the solidification treatment, can realize removing the resource utilization of silicon sludge.
Embodiment:
Embodiment 1: in agitator, add cement (325 #), (particle diameter is 1~3mm), removes silicon sludge and water (surplus) river sand, and the demoulding after 3 days is solidified constantly placing ornamental slab for paving the floor mould (entire die is full of) under the vibrations in the back that stirs, and uses water curing 7 days, can make ornamental slab for paving the floor.The intensity test that removes the ornamental slab for paving the floor that silicon sludge (water ratio is 70%) makes with domestic certain oil field the results are shown in Table shown in 1:
Table 1 intensity test result
Cement: mud: sand: water (weight ratio) Ultimate compression strength (Mpa)
1∶0.1∶0.5∶0.3 19.2
1∶0.5∶0.5∶0.3 13.8
1∶0.75∶0.5∶0.2 10.4
Embodiment 2: in agitator, add cement (325 #), (particle diameter is 1~3mm), removes silicon sludge, cyanamide resin and water (surplus) river sand, and the demoulding after 5 days is solidified constantly placing ornamental slab for paving the floor mould (entire die is full of) under the vibrations in the back that stirs, and uses water curing 10 days, can make ornamental slab for paving the floor.The intensity test that removes the ornamental slab for paving the floor that silicon sludge (water ratio is 70%) makes with domestic certain oil field the results are shown in Table shown in 2:
Table 2 intensity test result
Cement: mud: sand: cyanamide portions of resin water (weight ratio) Ultimate compression strength (Mpa)
1∶0.1∶1.0∶0.05∶0.3 12.9
1∶0.5∶1.0∶0.05∶0.3 7.8
1∶0.75∶1.0∶0.05∶0.3 6.4
Embodiment 3: in agitator, add cement (425 #), (particle diameter is 1~3mm), removes silicon sludge, urea-formaldehyde resin and water (surplus) river sand, and the demoulding after 7 days is solidified constantly placing ornamental slab for paving the floor mould (entire die is full of) under the vibrations in the back that stirs, and uses water curing 15 days, can make ornamental slab for paving the floor.The intensity test that removes the ornamental slab for paving the floor that silicon sludge (water ratio is 40%) makes with domestic certain oil field the results are shown in Table shown in 3:
Table 3 intensity test result
Cement: mud: sand: urea-formaldehyde resin: water (weight ratio) Ultimate compression strength (Mpa)
1∶0.1∶0.75∶0.05∶0.3 16.3
1∶0.5∶0.75∶0.05∶0.3 12.6
1∶0.75∶0.75∶0.05∶0.3 10.8

Claims (6)

1, a kind of non-silicon sludge curing treatment of thickened-oil sewage is characterized in that: add cement, sand, toughener and water in agitator after, add and remove silicon sludge, after in agitator, mixing,, solidify the demoulding after 3~7 days in die for molding, with water curing 7~15 days, its curing is got final product; Its additional proportion is: the consumption of cement is 30%~70% of a gross weight, and the particle of sand is 1~3mm, and dosage is 10%~30% of a gross weight, and removing silicon sludge is 10%~40% of gross weight, and the toughener dosage is 1~5%.
2, require described a kind of non-silicon sludge curing treatment of thickened-oil sewage according to right 1, it is characterized in that: used cement is 325 #Cement, 425 #Cement or superfine cement.
3, require described a kind of non-silicon sludge curing treatment of thickened-oil sewage according to right 1, it is characterized in that: used sand is quartz sand, or crushed-gravel.
4, require described a kind of non-silicon sludge curing treatment of thickened-oil sewage according to right 1, it is characterized in that: used toughener is cyanamide resin, Resins, epoxy, urea-formaldehyde resin.
5, require described a kind of non-silicon sludge curing treatment of thickened-oil sewage according to right 1, it is characterized in that: removing silicon sludge moisture is 20~70%.
6, require described a kind of non-silicon sludge curing treatment of thickened-oil sewage according to right 1, it is characterized in that: used mould is: ornamental slab for paving the floor mould, curb mould.
CNA2005101058087A 2005-09-29 2005-09-29 Non-silicon sludge curing treatment of thickened-oil sewage Pending CN1939870A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2005101058087A CN1939870A (en) 2005-09-29 2005-09-29 Non-silicon sludge curing treatment of thickened-oil sewage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2005101058087A CN1939870A (en) 2005-09-29 2005-09-29 Non-silicon sludge curing treatment of thickened-oil sewage

Publications (1)

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CN1939870A true CN1939870A (en) 2007-04-04

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CNA2005101058087A Pending CN1939870A (en) 2005-09-29 2005-09-29 Non-silicon sludge curing treatment of thickened-oil sewage

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CN (1) CN1939870A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390915A (en) * 2011-10-11 2012-03-28 中国石油天然气集团公司 Process for curing and dehydrating scum bottom sludge
CN103130390A (en) * 2013-03-25 2013-06-05 陕西延长石油(集团)有限责任公司研究院 Oil-containing sludge treatment method and process flow
CN108706911A (en) * 2018-04-28 2018-10-26 山东源根化学技术研发有限公司 A method of producing Footpath brick with resin and papermaking black mud
CN108752686A (en) * 2018-04-28 2018-11-06 山东源根化学技术研发有限公司 A method of producing Footpath brick with resin and paper white sludge

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390915A (en) * 2011-10-11 2012-03-28 中国石油天然气集团公司 Process for curing and dehydrating scum bottom sludge
CN102390915B (en) * 2011-10-11 2013-04-24 中国石油天然气集团公司 Process for curing and dehydrating scum bottom sludge
CN103130390A (en) * 2013-03-25 2013-06-05 陕西延长石油(集团)有限责任公司研究院 Oil-containing sludge treatment method and process flow
CN108706911A (en) * 2018-04-28 2018-10-26 山东源根化学技术研发有限公司 A method of producing Footpath brick with resin and papermaking black mud
CN108752686A (en) * 2018-04-28 2018-11-06 山东源根化学技术研发有限公司 A method of producing Footpath brick with resin and paper white sludge

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