CN1930981A - 一种含唑菌胺酯和代森锰锌的杀菌组合物及其应用 - Google Patents
一种含唑菌胺酯和代森锰锌的杀菌组合物及其应用 Download PDFInfo
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Abstract
本发明公开了一种含唑菌胺酯和代森锰锌的杀菌组合物及其应用。该杀菌组合物含有唑菌胺酯和代森锰锌，其中唑菌胺酯和代森锰锌的重量比为1～30∶5～70。该组合物可应用于防治禾谷类、瓜果或蔬菜作物病害。该组合物适用范围广、成本低、效果好。
Description
技术领域
本发明涉及一种杀菌组合物及其用途，尤其是一种以唑菌胺酯和代森锰锌为主要活性成分的杀菌组合物及其应用。
背景技术
唑菌胺酯(pyraclostrobin)是一种广谱高效杀菌剂，能防治谷物、柑桔、水稻、香蕉、葫芦、葡萄、花生、马铃薯、甜菜、番茄和草皮的多种病害，尤其是防治大豆锈病。但是国内现无原药生产企业，其产品主要是由国外提供，产品价格较高，农民难以接收，在中国大面积推广的能力较差。
代森锰锌(Mancozeb)是一种广谱的保护性杀菌剂。对多种蔬菜、果树病害有效。可防治蔬菜早疫病、灰霉病、霜霉病、瓜类炭疽病。此外还可用于防治果树黑星病、赤星病、炭疽病。代森锰锌是国内比较常用的杀菌剂，尤其在农作物上使用的时间比较长，这使的有些菌对代森锰锌产生了一定的抗性，使防治能力下降。
发明内容
本发明的目的是争对上述技术问题提供一种适用范围广、成本低、效果好的含唑菌胺酯和代森锰锌的植物杀菌组合物。
本发明还有一个目的是提供该杀菌组合物的用途。
本发明的目的是通过下列措施来实现的：
一种杀菌组合物，它含有唑菌胺酯和代森锰锌，其中唑菌胺酯和代森锰锌的重量比为1～30∶5～70。
所述的杀菌组合物，其中唑菌胺酯和代森锰锌的重量比为3～25∶10～65。
所述的杀菌组合物，其中唑菌胺酯和代森锰锌与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。这些已知的助剂、赋型剂有分散剂、扩散剂、消泡剂、湿润剂、崩解剂等。
所述的杀菌组合物，其剂型是粉剂、可湿性粉剂、悬乳剂、乳油或颗粒剂。
所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
本发明的有益效果：
1、本发明所用的唑菌胺酯是酰胺类杀菌剂，代森锰锌是唑类杀菌剂，两者相互混配不会产生抵触，可协同增效，减少用药量，降低成本。
2、本发明组合物适用范围增加，适用于防治禾谷类、各种瓜果、蔬菜的作物病害，特别是防治水稻、小麦、辣椒、香蕉、芒果、菠萝、黄瓜、番茄、烟草等作物病害，如小麦白粉病、水稻稻瘟病、瘟枯病、油菜菌核病、辣椒炭疽病、苦瓜黑星病、柑桔青霉病、黄瓜白粉病、番茄早疫病和晚疫病。
具体实施方式
以下结合实施例对本发明作进一步说明。实施例中剂型的制备方法均为常规方法。
实施例1：
将唑菌胺酯10g、代森锰锌25g、扩散剂NNO(亚甲基双萘磺酸钠)4g、净洗剂LS(对甲氧基脂肪酸胺基苯磺酸钠)2g、白炭黑2g，陶土加至100g，混合物进行气流粉碎，制得可湿性粉剂。
实施例2：
将唑菌胺酯5g、代森锰锌40g、十二烷基硫酸钠3g、壬基酚聚氧乙烯醚2g、扩散剂NNO 2g、黄原胶0.15g、乙二醇5g、水加至100g混合，经湿法研磨，均化，制得水悬浮剂。
实施例3：
将唑菌胺酯10g、代森锰锌45g、净洗剂LS 3g、木质素磺酸钠2g、白炭黑5g，高岭土加至100g，混合物进行气流粉碎，制得可湿性粉剂。
实施例4：
将将唑菌胺酯5g、代森锰锌50g、扩散剂NNO 3g、净洗剂LS 5g、羧甲基纤维素1g、轻质碳酸钙加至100g，混合物经过气流粉碎机粉碎，造粒，制成可分散性粒剂。
应用实施例：
用上述实施例制得的制剂防治黄瓜白粉病试验。试验条件和结果见下表：
1、试验处理：本试验药剂用量根据各个成分的不同分别设三个处理浓度，对照药剂分别是市售农药25％唑菌胺酯乳油(EC)和70％代森锰锌WP及空白清水试验。
2、试验方法 每个小区面积为50m2，重复三次；施药前调查及防治后的检查药效方法为：在试验处理区内随机取样5点，每点5株，检查植株白粉病的发生程度。
3、试验结果见下表：
| 处理(g/亩) | 药前病情指数(％) | 防效(％) | |||
| 药后5天 | 药后10天 | 药后14天 | |||
| 实施例1 | 60 | 45.6 | 72.3ab | 79.2ab | 73.4ab |
| 80 | 49.3 | 86.4a | 90.5a | 81.3a | |
| 100 | 39.2 | 88.3a | 92.4a | 83.2a | |
| 实施例2 | 60 | 48.3 | 69.7ab | 77.4b | 70.5b |
| 80 | 50.1 | 79.6a | 83.2a | 80.4a | |
| 90 | 34.2 | 83.1a | 93.4a | 89.9a | |
| 实施例3 | 60 | 47.9 | 63.2ab | 71.9b | 69.3b |
| 80 | 51.2 | 79.5a | 85.2a | 84.2ab | |
| 100 | 49.9 | 83.3a | 89.4a | 86.9a | |
| 70％代森锰锌WP | 200 | 51.2 | 62.2c | 65.2c | 49.1c |
| 25％唑菌胺酯乳油 | 120 | 38.3 | 63.7c | 65.8c | 59.9c |
| 空白清水对照 | 41.8 | - | - | - | |
注：a表示在α＝0.05水平上显著，b表示在α＝0.05水平上有差异，c表示在α＝0.05水平上不显著。
田间药效结果表明，唑菌胺酯与代森锰锌组合物对黄瓜白粉病具有优良的防治效果，防治效果均好于单剂品种。
Claims (5)
1、一种杀菌组合物，其特征在于含有唑菌胺酯和代森锰锌，其中唑菌胺酯和代森锰锌的重量比为1～30∶5～70。
2、根据权利要求1所述的杀菌组合物，其特征在于唑菌胺酯和代森锰锌的重量比为3～25∶10～65。
3、根据权利要求1或2所述的杀菌组合物，其特征在于唑菌胺酯和代森锰锌与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。
4、根据权利要求3所述的杀菌组合物，其特征在于剂型是粉剂、可湿性粉剂、悬乳剂、乳油或颗粒剂。
5、权利要求1所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
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| CN102302025A (zh) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | 一种含吡唑醚菌酯与硫代氨基甲酸酯类的杀菌组合物 |
| CN103960264A (zh) * | 2014-05-05 | 2014-08-06 | 河北双吉化工有限公司 | 一种含有吡唑醚菌酯、代森锰锌和复硝酚钠的杀菌组合物 |
| CN104126595A (zh) * | 2014-08-21 | 2014-11-05 | 陕西上格之路生物科学有限公司 | 一种含有吡唑醚菌酯的杀菌剂组合物 |
| CN104247712A (zh) * | 2014-03-19 | 2014-12-31 | 陕西上格之路生物科学有限公司 | 一种含吡唑醚菌酯和代森锰锌的可分散油悬浮剂 |
| WO2015079334A1 (en) | 2013-11-26 | 2015-06-04 | Upl Limited | A method for controlling rust |
| CN104247712B (zh) * | 2014-03-19 | 2016-11-30 | 陕西上格之路生物科学有限公司 | 一种含吡唑醚菌酯和代森锰锌的可分散油悬浮剂 |
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| CN115316397A (zh) * | 2022-09-08 | 2022-11-11 | 利民化学有限责任公司 | 一种防治柑橘间座壳菌的杀菌组合物的应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1385070A (zh) * | 2001-05-10 | 2002-12-18 | 沈阳化工研究院 | 含氟吗啉的杀菌剂组合物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302025A (zh) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | 一种含吡唑醚菌酯与硫代氨基甲酸酯类的杀菌组合物 |
| WO2015079334A1 (en) | 2013-11-26 | 2015-06-04 | Upl Limited | A method for controlling rust |
| EP3073826A4 (en) * | 2013-11-26 | 2016-10-19 | Upl Ltd | METHOD FOR REST CONTROL |
| EP3073826B1 (en) | 2013-11-26 | 2019-10-30 | UPL Limited | A method for controlling soybean rust |
| CN104247712A (zh) * | 2014-03-19 | 2014-12-31 | 陕西上格之路生物科学有限公司 | 一种含吡唑醚菌酯和代森锰锌的可分散油悬浮剂 |
| CN104247712B (zh) * | 2014-03-19 | 2016-11-30 | 陕西上格之路生物科学有限公司 | 一种含吡唑醚菌酯和代森锰锌的可分散油悬浮剂 |
| CN103960264A (zh) * | 2014-05-05 | 2014-08-06 | 河北双吉化工有限公司 | 一种含有吡唑醚菌酯、代森锰锌和复硝酚钠的杀菌组合物 |
| CN103960264B (zh) * | 2014-05-05 | 2015-07-01 | 河北双吉化工有限公司 | 一种含有吡唑醚菌酯、代森锰锌和复硝酚钠的杀菌组合物 |
| CN104126595A (zh) * | 2014-08-21 | 2014-11-05 | 陕西上格之路生物科学有限公司 | 一种含有吡唑醚菌酯的杀菌剂组合物 |
| CN104126595B (zh) * | 2014-08-21 | 2016-04-13 | 陕西上格之路生物科学有限公司 | 一种含有吡唑醚菌酯的杀菌剂组合物 |
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