CN1922276A - Reactive dye compositions and method for dyeing with the same - Google Patents
Reactive dye compositions and method for dyeing with the same Download PDFInfo
- Publication number
- CN1922276A CN1922276A CNA2005800055164A CN200580005516A CN1922276A CN 1922276 A CN1922276 A CN 1922276A CN A2005800055164 A CNA2005800055164 A CN A2005800055164A CN 200580005516 A CN200580005516 A CN 200580005516A CN 1922276 A CN1922276 A CN 1922276A
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- formula
- dye
- free acid
- expression
- dyestuff
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Links
- 0 C*(C(C1)C=NCc2ccccc2)(O)Oc2c1cccc2 Chemical compound C*(C(C1)C=NCc2ccccc2)(O)Oc2c1cccc2 0.000 description 2
- RNVCVTLRINQCPJ-UHFFFAOYSA-N Cc(cccc1)c1N Chemical compound Cc(cccc1)c1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/507—Azo dyes
- C09B62/51—Monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
A red reactive dye composition comprising a red reactive dye whose free acid form is represented by formula (A) and one or more of the red reactive dyes whose free acid forms are represented by formulae (B-1), (B-2), and (B-3) respectively or a reactive dye composition comprising the red reactive dye composition and a specific blue reactive dye and/or a specific yellow reactive dye can dye cellulose fiber or cellulosic fibrous materials with well-balanced affinity and reactivity and excellent reproducibility and leveling to give products excellent in color fastness particularly to perspiration and light.
Description
Technical field
The present invention relates to the painted reactive dye compositions of the filamentary material that is applicable to cellulosic fibre and contains cellulosic fibre and utilize its staining.In more detail, relate to the filamentary material dyeing that can make cellulosic fibre and contain cellulosic fibre, obtain that equalization, dyeing reproducibility etc. are good, the reactive dye compositions of product dyed thereby that the fastness of the fast light fastness of sweat proof etc. is good and utilize its cellulosic fibre and contain the staining of the filamentary material of cellulosic fibre.
Background technology
Reactive dyestuffs are used for the dyeing of cellulosic fibres such as kapok, artificial silk more.As everyone knows, in the dyeing of the cellulosic fibre material of using reactive dyestuffs, it is effective using, cooperate them to carry out painted method with various ratios with dyestuff as three primary colors with yellow, red and blue reactive dyestuffs.
But there is the problem of dyeing reproducibility that aberration takes place in the dyeing way to take place between equalization problem that spot dyes and the dyeing in batches etc. sometimes in the occasion that affinity, reactivity or the dyeing kinetics etc. of each dyestuff that uses with dyestuff as three primary colors have nothing in common with each other.In recent years, along with the automatization of the variation of the kind of fiber raw material and form and dye-works, be used for simple to operateization that dyeing time shortens etc., for equalization and dyeing reproducibility active demand equalization, the better reactive dyestuffs of dyeing reproducibility.In addition, in recent years, owing to be that the painted dress material of center, absorbing sweat causes variable color and the problem of fading when illuminated easily under sunlight, so urgently wish to have the good reactive dyestuffs of the fast light fastness of so-called sweat proof with the Sportswear dress material.In order to solve such problem,, can't obtain satisfied result though carried out various investigations (for example with reference to patent documentation 1).
Patent documentation 1: No. 3168624 communique of patent
Summary of the invention
The objective of the invention is to, address the above problem, exploitation be used to the filamentary material that makes cellulosic fibre or contain cellulosic fibre based on good reproducibility, detergency, equalization well and also the fastness highland carry out painted reactive dye compositions and staining.
In order to solve above-mentioned prior art problems point, what the inventor etc. studied with keen determination found that, contain with the red reactive dye composition of specific red reactive dyes by use as the composition of necessary composition, the reactive dye compositions that perhaps contains this red reactive dye composition and specific blue active dye and/or specific Yellow active dye, constitute the affinity of each dyestuff of their dye composite, dyeing kinetics is consistent, can make the cellulosic fibre equalization, reproducibility dyes well, and the fast light fastness of sweat proof is good, until finishing the present invention.
That is to say, the form that the present invention relates to contain free acid with the form of the red reactive dyes of formula (A) expression and free acid with wantonly a kind or 2 kinds of the red reactive dyes of formula (B-1), formula (B-2) and formula (B-3) expression or the red reactive dye composition more than it.
(in formula (B-1), (B-2) reach (B-3), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2)
In addition, the form that the present invention relates to contain above-mentioned red reactive dye composition and free acid is with the form of the blue active dye of formula (C-1) expression and/or the free acid reactive dye compositions with the blue active dye of formula (C-2) expression.
(in formula (C-1) and (C-2), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2)
In addition, the present invention relates to contain the reactive dye compositions of the form of above-mentioned red reactive dye composition and free acid with the Yellow active dye of formula (D) expression.
(in formula (D), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2)
In addition, the form that the present invention relates to contain above-mentioned red reactive dye composition and free acid with the form of the blue active dye of formula (C-1) expression and/or free acid with the form of the blue active dye of formula (C-2) expression and/or free acid reactive dye compositions with the Yellow active dye of formula (D) expression.
In addition, the present invention relates to cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre, it is characterized in that, use above-mentioned red reactive dye composition or above-mentioned any reactive dye compositions.
In addition, the present invention relates to cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre, it is characterized in that, in the dye bath that contains above-mentioned red reactive dye composition, handle cellulosic fibre or contain the filamentary material of cellulosic fibre.
In addition, the present invention relates to cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre, it is characterized in that processing cellulosic fibre or contain the filamentary material of cellulosic fibre in the dye bath of the Yellow active dye that the form that contains above-mentioned red reactive dye composition and free acid is represented with formula (D) with the form of the blue active dye of formula (C-2) expression and/or free acid with the form of the blue active dye of formula (C-1) expression and/or free acid.
Red reactive dye composition of the application of the invention or reactive dye compositions, the filamentary material that can make cellulosic fibre or contain cellulosic fibre is that reproducibility, dyeing processing that equalization is good are carried out in the basis to have isostatic affinity, reactivity.In addition, can carry out the fastness dyeing that particularly the fast light fastness of sweat proof is good processing.
Embodiment
The form of free acid is to be recorded in known dyestuff in the special table 2003-532569 communique etc. with the red reactive dyes of formula (A) expression, the form of free acid with formula (B-1) and (B-2) expression red reactive dyes be to be recorded in special fair 7-91483 communique respectively, the spy opens known dyestuff in 2000-192374 communique etc., the form of free acid is to be recorded in known dyestuff in No. 3116461 communique of patent etc. with the red reactive dyes of formula (B-3) expression, the form of free acid is to be recorded in known dyestuff in the special fair 3-10669 communique etc. with the blue active dye of formula (C-1) expression, the form of free acid is to be recorded in known dyestuff in the special fair 1-24826 communique etc. with the blue active dye of formula (C-2) expression, the form of free acid is to be recorded in the spy to open known dyestuff in the clear 56-15481 communique etc. with the Yellow active dye of formula (D) expression, can be the benchmark manufacturing with the method for putting down in writing in these communiques or easily obtains from market.
As the red reactive dyes that the form of free acid is represented with formula (B-1), the form of preferred free acid is with formula (1)
(in formula (1), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression orchil, still, this is not limited.
As the red reactive dyes that the form of free acid is represented with formula (B-2), the form of preferred free acid is with formula (2)
(in formula (2), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression orchil, still, this is not limited.
As the red reactive dyes that the form of free acid is represented with formula (B-3), the form of preferred free acid is with formula (3)
(in formula (3), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression orchil, still, this is not limited.
Red reactive dye composition of the present invention contain with the form of free acid with the form of the red reactive dyes of formula (A) expression and free acid with wantonly a kind or 2 kinds of the red reactive dyes of formula (B-1), formula (B-2) and formula (B-3) expression or more than it as necessary composition.Their ratio of components, wantonly a kind or 2 kinds of the red reactive dyes that the form of free acid is represented with formula (B-1), formula (B-2) and formula (B-3) with the form of the red reactive dyes of formula (A) expression and free acid or be respectively 95 weight %～5 weight % and 5 weight %～95 weight % usually more than it, preferred 95 weight %～55 weight % and 5 weight %～45 weight % are more preferably 85 weight %～65 weight % and 15 weight %～35 weight %.The form that contains free acid is 85 weight %～65 weight % with the form of the ratio of components preference of the occasion of wantonly a kind or 2 kinds of the red reactive dyes of formula (B-1), formula (B-2) and formula (B-3) expression such as free acid with the red reactive dyes of formula (A) expression, and the red reactive dyes that the form of free acid is represented with formula (B-1) is that the red reactive dyes that the form of 10 weight %～25 weight % and free acid is represented with formula (B-2) is 5 weight %～10 weight %.
In addition, also can and with the form of free acid with the form of the red reactive dyes of formula (A) expression and free acid red reactive dyes reactive dyestuffs in addition with formula (B-1), formula (B-2) and formula (B-3) expression.And the reactive dyestuffs of the usefulness preferably form of free acid and formula (A), (B-1), (B-2) and (B-3) have the reactive dyestuffs of allovitalism base, but in order to obtain the form and aspect of purpose, also can and with the reactive dyestuffs of the various form and aspect that are used to mix colours of several dyestuffs of mixing with other active group.
The present invention can and the reactive dyestuffs of other form and aspect of usefulness in, the dyestuff that preferably uses as the reactive dyestuffs of blueness is the blue active dye that the form of free acid is represented with above-mentioned formula (C-2) with the form of the blue active dye of formula (C-1) expression and/or free acid.As the form of free acid blue active dye with formula (C-1) expression, the form of preferred free acid be with formula (4) (in formula (4), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression blue dyes, still, this is not limited.
As the blue active dye that the form of free acid is represented with formula (C-2), the form of preferred free acid is with formula (5)
(in formula (5), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression blue active dye, but this is not limited.
As the preferably combination of the blue active dye represented with the blue active dye of formula (C-1) expression with formula (C-2) of the form of free acid of blue active dye.Their ratio of components, the form of free acid is respectively 95 weight %～5 weight % and 5 weight %～95 weight % with the blue active dye of formula (C-1) expression and the blue active dye of representing with formula (C-2) usually, preferred 95 weight %～65 weight % and 5 weight %～35 weight % are more preferably 95 weight %～75 weight % and 5 weight %～25 weight %.In addition, the blue active dye reactive dyestuffs in addition that also can also use formula (C-1) and represent with formula (C-2) with the form of free acid.
Can and other reactive dyestuffs of usefulness in can enumerate the Yellow active dye of the form of free acid as yellow dyes with formula (D) expression.As the form of the free acid Yellow active dye with formula (D) expression, preferably the form of free acid is with formula (6)
(in formula (6), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2) expression Yellow active dye, but this is not limited.
The form of free acid both can exist with the form of free acid with all reactive dyestuffs of formula (A), formula (B-1), formula (B-2), formula (B-3), formula (C-1), formula (C-2), formula (D), formula (1)～(6) expression, perhaps also can exist with the form of its salt.As salt preferably an alkali metal salt or alkali earth metal salt, especially preferably sodium salt, sylvite, lithium salts.
In red reactive dye composition of the present invention or reactive dye compositions, the fitting method of each reactive dyestuffs is not done special restriction.For example, can adopt the method that reactive dyestuffs separately cooperate thereafter of making respectively; The active liquid that contains each reactive dyestuffs that generates during with manufacturing mixes, its after drying is made method for compositions afterwards; Perhaps be dissolved in dyestuff in the dye bath respectively, in dye bath, form the method for the composition identical with each composition.The red reactive dye composition of this moment and the blending ratio of blue active dye and/or Yellow active dye cooperate according to the tone of hope, do not do special restriction.In addition, according to necessity, also can contain known additive in the composition of the present invention, for example consistency adjusting agent, dispersion agent, dye leveller, precipitation prevent that agent, metal ion encapsulant, reduction from preventing agent etc.
Each dye well additive as described above that constitutes red reactive dye composition of the present invention or reactive dye compositions in above-mentioned is directly joined in dye bath, dip-dyeing solution, the printing paste modulation dye bath etc. when carrying out painted occasion, and the dissolving order of each dyestuff, additive can be an order arbitrarily.The usage quantity of each medicament that uses also determines as benchmark aptly with public method.
In the staining of using red reactive dye composition of the present invention or reactive dye compositions, their usage quantity is 0.005～15 weight % with respect to fibre weight usually.
The dyeing that peacekeeping contains its filamentary material for cellulose fiber of red reactive dye composition of the present invention or reactive dye compositions is useful.The filamentary material that contains cellulosic fibre as the cellulose fiber peacekeeping that becomes object for example can enumerate kapok, fiber crops, artificial silk, koplon, copper ammonia fibre リ ヨ セ Le etc. cellulosic fibre separately or their blend fiber each other.Can also enumerate and these fibers or blend fiber beyond fiber, for example with the blending of tynexs such as trevira, acetic ester fiber, polyacrylonitrile fibre, wool, thin,tough silk, nylon etc. or intertexture etc.
In the present invention, staining can be carried out according to itself known for example following method.
As staining, for example, in the dyeing of cellulosic fibres such as kapok, to put into dye bath according to the form and aspect of hope and the red reactive dye composition of the present invention or the reactive dye compositions of concentration, separately or and with known inorganic neutral salt for example yellow soda ash, sodium bicarbonate, sodium hydroxide, sodium phosphate etc. and dye of thenardite, salt etc. and acid binding agent for example.Do not do special restriction for the at this moment used inorganic neutral salt and the usage quantity of acid binding agent yet, but preferably use 1g/L at least.In addition, both inorganic neutral salt and acid binding agent once can be dropped into dye bath, also can the gradation input.In addition, dyeing auxiliary of softening agent, dye leveller etc. is not done special qualification as dyeing auxiliary to it in can bathing by known method and with other yet.Dyeing temperature is 40～90 ℃, preferred 50～70 ℃.Pollutant as bath raio: dye bath normally 1: 5～1: 50.
In the continuous dyeing method, can example illustrate by separately with acid binding agent yellow soda ash for example, sodium bicarbonate, sodium hydroxide etc. separately or and with they 2 kinds or join more than it in dyestuff dip-dyeing solution, after the known method dip-dye, after the drying, xeothermic with known method, decatize is carried out painted one bathing dip method, and by after in dyestuff, contaminating, after the drying, at known inorganic neutral salt thenardite for example, salt etc. and acid binding agent be sodium bicarbonate for example, contaminate in the water glass etc., xeothermic or decatize is carried out painted secondary and is bathed dip method with known method, but as the continuous dyeing method this is not limited.
For dyeing method, undertaken by xeothermic after printing and dyeing in the printing paste of starching, contain acid binding agents such as dyestuff and sodium bicarbonate with sodiun alginate, emulsion paste etc. as stamp substantially with known method, with known method or decatize.
After dyeing process is ended, after washing, the rinsing, bathe and wash with containing soaping of the commercially available soaping agent of 0.1～5g/L, finish dyeing by well-established law.
Red reactive dye composition of the present invention or reactive dye compositions and staining are at cellulosic fibre and contain in its dyeing of filamentary material, can provide very good as equalization and reproducibility, as promoting also good etc. the good and very good product dyed thereby of the fast light fastness of each fastness, particularly sweat proof of various dyeing properties of pile-on properties (build up).
Below, illustrate in greater detail the present invention by embodiment." part " among the embodiment only otherwise record and narrate especially and just represent weight part.
(embodiment 1)
The cooperation of reactive dyestuffs is formed
Table 1 has been recorded and narrated the combination and the usage quantity thereof of reactive dyestuffs.In table 1, C.I.Reactive refers to the Colour Index generic name.
Table 1 cooperates to be formed
Cooperation example 1 of the present invention:
Red reactive dyes
0.11 part of the dyestuff of formula (A)
0.03 part of the dyestuff of formula (1)
0.01 part of the dyestuff of formula (2)
Blue active dye
0.09 part of the dyestuff of formula (4)
0.02 part of the dyestuff of formula (5)
Yellow active dye
0.14 part of the dyestuff of formula (6)
The cooperation example 2 of usefulness relatively:
Red reactive dyes
195 0.08 parts of C.I.Reactive Red
Blue active dye
221 0.11 parts of C.I.Reactive Blue
Yellow active dye
145 0.14 parts of C.I.Reactive Yellow
The cooperation example 3 of usefulness relatively:
Red reactive dyes
271 0.20 parts of C.I.Reactive Red
Blue active dye
235 0.11 parts of C.I.Reactive Blue
Yellow active dye
206 0.12 parts of C.I.Reactive Yellow
The bath raio dependence test
(1) bath raio is 1: 10 dyeing
In the dyestuff of forming respectively cooperating shown in the table 1 and 15 parts of anhydrous sodium sulphate, add entry, the dye bath that the modulation full dose is 490 parts.The kapok knitted fabrics is dropped in this dye bath for 50 parts, in 20 minutes, be warmed up to 60 ℃.After handling 20 minutes under 60 ℃, drop into 10 parts of yellow soda ash, dyeing is 60 minutes under this temperature.Then, after washing, the rinsing, containing commercially available soaping agent (the wide ケ ミ カ Le (strain) in ス コ ア ロ one Le C-1200 north, 1g/L, below same) 1000 parts of aqueous solution in after soaping under 100 ℃ 15 minutes, wash, drying, obtain tawny product dyed thereby respectively.
(2) bath raio is 1: 30 dyeing
In the dyestuff of forming respectively cooperating shown in the table 1 and 45 parts of anhydrous sodium sulphate, add entry, the dye bath that the modulation full dose is 1470 parts.The kapok knitted fabrics is dropped in this dye bath for 50 parts, in 20 minutes, be warmed up to 60 ℃.After handling 20 minutes under 60 ℃, drop into 30 parts of yellow soda ash, dyeing is 60 minutes under this temperature.Then, washing, after the hot water wash is washed after soaping under 100 ℃ 15 minutes in containing 1000 parts of aqueous solution of above-mentioned soaping agent, drying, obtains tawny product dyed thereby respectively.
(3) decision method
With bath raio be the product dyed thereby that obtained in 1: 10 o'clock as benchmark, visual judgement bath raio is the hue difference of the product dyed thereby that obtained in 1: 30 o'clock.Judge that index is as follows.
Zero: hue difference is little *: hue difference is big * *: hue difference is significantly big
Absorption, fixation behavior test
In dyestuff that each shown in the table 1 cooperate to be formed and 30 parts of anhydrous sodium sulphate, add entry, the dye bath that the modulation full dose is 980 parts, each 4 dye baths that amount to 12 of every kind of dyestuff.50 parts of kapok knitted fabrics inputs are divided in other dye bath, for dividing other dye bath to handle, test its absorption, fixation behavior with the method for following (1)～(4).
(1) after handling 10 minutes under 30 ℃, will dye cloth and from dye bath, take out, make its 2 five equilibrium, carry out following (A) or aftertreatment (B).
(A) stubborn dying cloth, dehydration back seasoning (absorption cloth).
(B) washing, behind the hot water wash stained cloth, in containing 1000 parts of aqueous solution of above-mentioned soaping agent, after soaping 15 minutes under 100 ℃, wash, dry (fixation cloth).
(2) then, drop into 20 parts of yellow soda ash (adding up to 1000 parts dye bath), dyeing is after 15 minutes down at 30 ℃, and taking-up is dyed cloth, and makes its 2 five equilibrium, carries out above-mentioned (A) or aftertreatment (B) respectively.
When (3) being warming up to 60 ℃ with 15 minutes again, taking-up is dyed cloth, and makes its 2 five equilibrium, carries out above-mentioned (A) or aftertreatment (B) respectively.
(4) take out last dying cloth in dyeing under 60 ℃ after 40 minutes again, make its 2 five equilibrium, carry out above-mentioned (A) or aftertreatment (B) respectively.
Decision method (a)
In above-mentioned (1)～(4) every, with the processing cloth of (A) hue difference as the processing cloth of the visual judgement of benchmark (B).Judge that index is as follows.
Zero: any hue difference of (1)～(4) is all little
*: the somewhere hue difference of any of (1)～(4) is big
Decision method (b)
Degree for processing cloth visual judgement foxy between (1), (2), (3), (4) of above-mentioned (B).Judge that index is as follows.
Zero: (1)～(4) all are that the form and aspect of same system are (trichromatic solid
Look speed is balanced good)
*: (trichromatic fixation speed is equal greatly for foxy in (1)～(4)
It is bad to weigh)
The fast light fastness test of sweat proof
(1) test portion manufacturing conditions
The dyestuff of cooperate forming with each shown in the table 1 is that benchmark dyes with 1: 10 the dyeing condition of bath raio of above-mentioned bath raio dependence test (1), obtains the stained cloth as tawny test portion.
(2) the fast light fastness test condition of sweat proof
ATTS: fibre product technical study meeting is that benchmark is implemented test with weak method.
Make stained cloth in acidity shown in the table 2 and alkaline synthetic perspiration, after 30 minutes, take out stained cloth at dipping under bath raio 1: 50, the normal temperature respectively, be clipped in and push lightly between the filter paper 2～3 times, make unnecessary sweat take off liquid.The former state of stained cloth with moisture state is contained on the fast light trier (JIS L 0824) immediately, and with respect to JIS L 0842: the fastness of dyeing test method of carbon arc light was as benchmark irradiation 7 hours.
Table 2 synthetic perspiration's modulation
| Acid | Alkalescence | |
| Sodium-chlor SODIUM PHOSPHATE, MONOBASIC 12H 2O lactic acid DL-aspartic acid D-sodium pantothenate glucose L-L-Histidine hydrochloride H 2O acetic acid | 5.0g 5.0g 5.0g 0.5g 5.0g 5.0g 0.5g pH3.5 | 5.0g 5.0g 5.0g 0.5g 5.0g 5.0g 0.5g - |
| The full liquid measure of sodium hydroxide (water) | -1 liter | 1 liter of pH8.0 |
(3) decision method
With JIS L 0804: becoming fades judges with irradiation portion not as the change fading extent of the irradiation portion of benchmark with the grey scale.Judge that index is as follows.
4: quite good
3-4: good
3: moderate
2: poor
1-2: be on duty mutually
Result of determination
Table 3 has been represented cooperation example 1 of the present invention and has relatively been used the comparative result of the bath raio dependency, absorption, fixation behavior and the fast light fastness of sweat proof that cooperate example 2～3.
Table 3 test-results
| Compare dependency | Absorption, fixation behavior | The fast light fastness of sweat proof | |||
| Cooperate example 1 to cooperate example 2 to cooperate example 3 | ○ × ×× | Decision method (a) | Decision method (b) | Acid | Alkalescence |
| ○ × × | ○ ○ × | 4 2 3-4 | 3-4 1-2 3 | ||
Painted occasion is carried out in reactive dyestuffs combination with cooperation example 1 of the present invention, the dyeability of red reactive dyes, blue active dye and Yellow active dye is consistent, even the occasion of change such as the dyeing condition of bath raio etc., color change is also little, absorption rate, dyeing kinetics are almost consistent, dyeing reproducibility, equalization is good, and the fast light fastness of sweat proof is also very good in addition.Carry out painted occasion can the get both dyeability that satisfies dyeing reproducibility, equalization etc. and the result of the fast light fastness of sweat proof with the combination of the reactive dyestuffs of cooperation example 1 of the present invention.
Embodiment 2～12
In the combination of the reactive dyestuffs of the cooperation example 1 that replaces embodiment 1 with the combination of the dyestuff shown in the table 4 and usage quantity (part) and usage quantity, 40 parts of anhydrous sodium sulphate, add entry, modulate the dye bath of 980 parts of full doses respectively.The kapok knitted fabrics is dropped in this dye bath for 50 parts, in 20 minutes, be warmed up to 60 ℃.After handling 20 minutes under 60 ℃, drop into 20 parts of yellow soda ash, dyeing is 60 minutes under this temperature.
Then, washing, after the hot water wash, with 1000 parts of aqueous solution that contain above-mentioned soaping agent after soaping under 100 ℃ 15 minutes, wash, drying, obtain each product dyed thereby.
Table 4: cooperate and form
Embodiment 2:
Red reactive dyes
0.60 part of the dyestuff of formula (A)
0.20 part of the dyestuff of formula (1)
Embodiment 3:
Red reactive dyes
0.60 part of the dyestuff of formula (A)
0.20 part of the dyestuff of formula (2)
Embodiment 4:
Red reactive dyes
0.60 part of the dyestuff of formula (A)
0.20 part of the dyestuff of formula (3)
Embodiment 5:
Red reactive dyes
0.60 part of the dyestuff of formula (A)
0.14 part of the dyestuff of formula (1)
0.06 part of the dyestuff of formula (2)
Embodiment 6:
Red reactive dyes
0.36 part of the dyestuff of formula (A)
0.08 part of the dyestuff of formula (1)
0.04 part of the dyestuff of formula (2)
Blue active dye
0.27 part of the dyestuff of formula (4)
0.05 part of the dyestuff of formula (5)
Embodiment 7:
Red reactive dyes
0.24 part of the dyestuff of formula (A)
0.06 part of the dyestuff of formula (1)
0.02 part of the dyestuff of formula (2)
Yellow active dye
0.48 part of the dyestuff of formula (6)
Embodiment 8:
Red reactive dyes
0.23 part of the dyestuff of formula (A)
0.08 part of the dyestuff of formula (1)
Blue active dye
0.17 part of the dyestuff of formula (4)
0.03 part of the dyestuff of formula (5)
Yellow active dye
0.30 part of the dyestuff of formula (6)
Embodiment 9:
Red reactive dyes
0.23 part of the dyestuff of formula (A)
0.08 part of the dyestuff of formula (2)
Blue active dye
0.17 part of the dyestuff of formula (4)
0.03 part of the dyestuff of formula (5)
Yellow active dye
0.30 part of the dyestuff of formula (6)
Embodiment 10:
Red reactive dyes
0.23 part of the dyestuff of formula (A)
0.08 part of the dyestuff of formula (3)
Blue active dye
0.17 part of the dyestuff of formula (4)
0.03 part of the dyestuff of formula (5)
Yellow active dye
0.30 part of the dyestuff of formula (6)
Embodiment 11:
Red reactive dyes
0.23 part of the dyestuff of formula (A)
0.06 part of the dyestuff of formula (1)
0.02 part of the dyestuff of formula (2)
Blue active dye
0.17 part of the dyestuff of formula (4)
0.03 part of the dyestuff of formula (5)
Yellow active dye
0.30 part of the dyestuff of formula (6)
Embodiment 12:
Red reactive dyes
0.23 part of the dyestuff of formula (A)
0.06 part of the dyestuff of formula (1)
0.02 part of the dyestuff of formula (2)
Blue active dye
0.20 part of the dyestuff of formula (4)
Yellow active dye
0.30 part of the dyestuff of formula (6)
The form and aspect of the product dyed thereby that obtains, embodiment 2～5th, and red, embodiment 6 is purples, and embodiment 7 is orange, and embodiment 8～12nd, and is dark brown.
Even in arbitrary group of reactive dyestuffs combination of embodiment 2～12, very good as equalization and reproducibility, also good etc. the various dyeing properties of pile-on properties are good as promoting, and fast light, sweat proof is fast light, each fastness of anti-chlorine water etc. is also good.What be worth the record in letters of gold especially is that the fast light fastness of sweat proof is outstanding.
Embodiment 13～17
In with the combination of the reactive dyestuffs shown in the embodiment 8～12 and usage quantity (part), 40 parts of anhydrous sodium sulphate, add entry, modulate the dye bath of 980 parts of full doses respectively.50 parts of artificial silk hair muslins are dropped in this dye bath, in 20 minutes, be warmed up to 60 ℃.After handling 20 minutes under 60 ℃, drop into 20 parts of yellow soda ash, dyeing is 60 minutes under this temperature.
Then, washing, after the hot water wash, with 1000 parts of aqueous solution that contain above-mentioned soaping agent after soaping under 100 ℃ 15 minutes, wash, drying, obtain each product dyed thereby.The form and aspect of the product dyed thereby that obtains, embodiment 13～17 all is dark brown.
Even for the dyeing of artificial silk hair muslin, very good as equalization and reproducibility, also good etc. the various dyeing properties of pile-on properties are also good as promoting, and fast light, sweat proof is fast light, each fastness of anti-chlorine water etc. is also good.Particularly the fast light fastness of sweat proof is outstanding.
Embodiment 18
To with the combination of the reactive dyestuffs shown in the embodiment 11, use in its 20 times of amount ratios, 10 parts of m-nitrobenzene sodium sulfonates, 20 parts of sodium bicarbonates, 1 part of sodiun alginate and add entry, make the pad bath of 1000 parts of whole volumes.After kapok is contaminated in this pad bath, with ironer with 60% mangle expression twisting.At 100 ℃ down after 5 minutes dryings of stubborn cloth,, make dye fixing 100 ℃ of following decatizes 5 minutes.Then, washing, after the hot water wash, with 1000 parts of aqueous solution that contain above-mentioned soaping agent after soaping under 100 ℃ 15 minutes, wash, drying, obtain product dyed thereby.The form and aspect of the product dyed thereby that obtains are dark brown.
Even in continuous dyeing, very good as equalization and reproducibility, also good etc. the various dyeing properties of pile-on properties are good as promoting, and fast light, sweat proof is fast light, each fastness of anti-chlorine water etc. is also good.Particularly the fast light fastness of sweat proof is outstanding.
Embodiment 19
To with the combination of the dyestuff shown in the embodiment 11, use in its 20 times of amount ratios, 100 parts of urea, 20 parts of sodium bicarbonates, 10 parts of m-nitrobenzene sodium sulfonates, 25 parts of sodiun alginates and add entry, make the printing and dyeing of 1000 parts of full doses and stick with paste with look.This look is stuck with paste on kapok, printed and dyed,,, make dye fixing 100 ℃ of following decatizes 5 minutes at 100 ℃ down after dry 5 minutes.Then, washing, after the hot water wash, with 1000 parts of aqueous solution that contain commercially available soaping agent after soaping under 100 ℃ 15 minutes, wash, drying, obtain product dyed thereby.
The form and aspect of the product dyed thereby that obtains are dark brown.Even in printing and dyeing, very good as equalization and reproducibility, also good etc. the various dyeing properties of pile-on properties are good as promoting, and fast light, sweat proof is fast light, each fastness of anti-chlorine water etc. is also good.Particularly the fast light fastness of sweat proof is outstanding.
Claims (9)
1. red reactive dye composition, it is characterized in that, the form that contains free acid is with the red reactive dyes of formula (A) expression, and the form of free acid is with wantonly a kind or 2 kinds of the red reactive dyes of formula (B-1), formula (B-2) and formula (B-3) expression or more than it
In formula (B-1), (B-2) reach (B-3), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2
2. a reactive dye compositions is characterized in that, the form that contains described red reactive dye composition of claim 1 and free acid is with the form of the blue active dye of formula (C-1) expression and/or the free acid blue active dye with formula (C-2) expression,
In formula (C-1) and (C-2), substituting group-SO
2CH
2CH
2OSO
3H also can be that it is decomposed to form-SO
2CH=CH
2
3. a reactive dye compositions is characterized in that, contains the Yellow active dye of the form of described red reactive dye composition of claim 1 and free acid with formula (D) expression,
In formula (D), substituting group-SO
2CH
2CH
2OSO3H also can be that it is decomposed to form-SO
2CH=CH
2
4. reactive dye compositions, it is characterized in that, the form that contains described red reactive dye composition of claim 1 and the described free acid of claim 2 with the form of the blue active dye of formula (C-1) expression and/or free acid with the form of the blue active dye of formula (C-2) expression and/or the described free acid of claim 3 Yellow active dye with formula (D) expression.
5. according to each described reactive dye compositions of claim 1～4, it is characterized in that, in the described red reactive dye composition of claim 1, wantonly a kind or 2 kinds or its above 5 weight %～95 weight % of the red reactive dyes of the form red reactive dyes 95 weight %～5 weight % of formula (A) expression that contain free acid, form formula (B-1), formula (B-2) and formula (B-3) expression of free acid.
6. according to claim 2 or the described reactive dye compositions of claim 4, it is characterized in that, the form that contains free acid is with formula (C-1) with these two kinds of dyestuffs of blue active dye of formula (C-2) expression, contains blue active dye 5 weight %～95 weight % that the form of free acid is represented with the blue active dye 95 weight %～5 weight % of formula (C-1) expression, with formula (C-2).
7. a cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre is characterized in that, uses each described reactive dye compositions of claim 1～6.
8. a cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre is characterized in that, handles cellulosic fibre or contain the filamentary material of cellulosic fibre in the dye bath that contains the described red reactive dye composition of claim 1.
9. a cellulosic fibre or contain the staining of the filamentary material of cellulosic fibre, it is characterized in that, the form that contains described red reactive dye composition of claim 1 and free acid with the dye bath of form of the form of the blue active dye of formula (C-1) expression and/or free acid with the Yellow active dye of formula (D) expression with the blue active dye of formula (C-2) expression and/or free acid in, handle cellulosic fibre or contain the filamentary material of cellulosic fibre.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004058935 | 2004-03-03 | ||
| JP058935/2004 | 2004-03-03 |
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|---|---|
| CN1922276A true CN1922276A (en) | 2007-02-28 |
| CN100549104C CN100549104C (en) | 2009-10-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005800055164A Expired - Fee Related CN100549104C (en) | 2004-03-03 | 2005-01-17 | Reactive dye compositions and the staining of utilizing it |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPWO2005085368A1 (en) |
| KR (1) | KR20060124717A (en) |
| CN (1) | CN100549104C (en) |
| TW (1) | TW200530342A (en) |
| WO (1) | WO2005085368A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212275A (en) * | 2011-04-06 | 2011-10-12 | 上虞亿得化工有限公司 | Composite reactive blue dye |
| CN102212276A (en) * | 2011-04-08 | 2011-10-12 | 丽源(湖北)科技有限公司 | Blue reactive dye mixture and preparation and application thereof |
| CN102220030A (en) * | 2011-04-08 | 2011-10-19 | 丽源(湖北)科技有限公司 | Active yellow azo dye and preparation method and application thereof |
| CN102358803A (en) * | 2011-08-25 | 2012-02-22 | 浙江亿得化工有限公司 | Composite black active dye |
| CN103044969A (en) * | 2013-01-22 | 2013-04-17 | 上海雅运纺织化工股份有限公司 | Dye composition for one-bath and one-type based dyeing and dyeing method of dye composition |
| CN104479402A (en) * | 2014-12-11 | 2015-04-01 | 吴江桃源染料有限公司 | Semi-finished product of deep red dye, preparation method and application thereof |
| CN108226439A (en) * | 2017-12-22 | 2018-06-29 | 苏州瑞奇丽新材料有限公司 | A kind of synthetic perspiration and preparation method thereof |
| CN111032790A (en) * | 2017-09-01 | 2020-04-17 | 日本化药株式会社 | Reactive dye composition and dyeing method using same |
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| JP5682947B2 (en) * | 2009-05-28 | 2015-03-11 | 日本化薬株式会社 | Reactive dye composition and dyeing method using the same |
| JP5638908B2 (en) * | 2010-10-08 | 2014-12-10 | 日本化薬株式会社 | Reactive dye composition and dyeing method using the same |
| CN103013174A (en) * | 2012-12-17 | 2013-04-03 | 浙江亿得化工有限公司 | Composite reactive dye composition and use method |
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| CN114292529B (en) * | 2021-12-25 | 2023-09-05 | 苏州科法曼化学有限公司 | Golden yellow dye composition and application thereof |
| CN114561818B (en) * | 2022-04-06 | 2024-02-13 | 浙江亿得新材料股份有限公司 | Compounding method of reactive dye yellow suitable for dyeing composite cellulose fiber, product and application thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5742986A (en) * | 1980-08-29 | 1982-03-10 | Nippon Kayaku Kk | Dyeing of natural or synthetic fiber by using reactive monoazo compound |
| DE19810906A1 (en) * | 1998-03-13 | 1999-09-16 | Basf Ag | New reactive azo dyes useful for dyeing and printing material containing hydroxyl groups or nitrogen |
| JP4218101B2 (en) * | 1998-12-21 | 2009-02-04 | 住友化学株式会社 | Reactive dye mixture and dyeing or printing method using the same |
| JP4538897B2 (en) * | 2000-05-26 | 2010-09-08 | 住友化学株式会社 | Reactive dye mixture and its application |
| JP4614671B2 (en) * | 2003-02-21 | 2011-01-19 | 日本化薬株式会社 | Reactive dye composition and dyeing method using the same |
-
2005
- 2005-01-17 KR KR1020067016997A patent/KR20060124717A/en not_active Application Discontinuation
- 2005-01-17 CN CNB2005800055164A patent/CN100549104C/en not_active Expired - Fee Related
- 2005-01-17 WO PCT/JP2005/000468 patent/WO2005085368A1/en active Application Filing
- 2005-01-17 JP JP2006510617A patent/JPWO2005085368A1/en active Pending
- 2005-01-20 TW TW094101687A patent/TW200530342A/en unknown
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212275A (en) * | 2011-04-06 | 2011-10-12 | 上虞亿得化工有限公司 | Composite reactive blue dye |
| CN102212276A (en) * | 2011-04-08 | 2011-10-12 | 丽源(湖北)科技有限公司 | Blue reactive dye mixture and preparation and application thereof |
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| CN104479402A (en) * | 2014-12-11 | 2015-04-01 | 吴江桃源染料有限公司 | Semi-finished product of deep red dye, preparation method and application thereof |
| CN111032790A (en) * | 2017-09-01 | 2020-04-17 | 日本化药株式会社 | Reactive dye composition and dyeing method using same |
| CN108226439A (en) * | 2017-12-22 | 2018-06-29 | 苏州瑞奇丽新材料有限公司 | A kind of synthetic perspiration and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100549104C (en) | 2009-10-14 |
| WO2005085368A1 (en) | 2005-09-15 |
| TW200530342A (en) | 2005-09-16 |
| JPWO2005085368A1 (en) | 2008-01-24 |
| KR20060124717A (en) | 2006-12-05 |
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