CN1913864B - Transparent solid composition and transparent solid cosmetic preparation containing the same as base - Google Patents

Transparent solid composition and transparent solid cosmetic preparation containing the same as base Download PDF

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Publication number
CN1913864B
CN1913864B CN2005800033381A CN200580003338A CN1913864B CN 1913864 B CN1913864 B CN 1913864B CN 2005800033381 A CN2005800033381 A CN 2005800033381A CN 200580003338 A CN200580003338 A CN 200580003338A CN 1913864 B CN1913864 B CN 1913864B
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acid
transparent solid
ester
oil
transparent
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CN1913864A (en
Inventor
金子胜之
仓桥琢磨
长谷川克行
三浦由将
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Abstract

A transparent solid composition characterized by comprising (a) 1 to 20 mass% dextrin fatty acid ester, (b) 10 to 40 mass% volatile oily matter having a boiling point of 250 DEG C or lower at ordinary pressure, (c) 10 to 40 mass% oily matter having a refractive index of 1.4 to 1.6, and (d) 15 to 60 mass% spherical particles having a refractive index of 1.3 to 1.6 and an average particle diameter of 3 to 30 m. Also provided is a transparent solid cosmetic preparation which gives an excellent transparent feeling, has the effect of smoothing surface irregularities of the skin and the effect of making the pores inconspicuous, and gives an excellent use feeling.

Description

Transparent solid-state composition and contain its transparent solid, cosmetic as basic material
Technical field
The present invention relates to a kind of transparent solid-state composition and contain its transparent solid, cosmetic as basic material.
Background technology
Because oil-based cosmetic preparation has apparent attractive in appearance, coating and the time has advantages such as transparent feel, has has now researched and developed various transparent basic materials.Wherein, carried out big quantity research for the basic material that cooperates the 12-hydroxy stearic acid especially.
For example, in patent documentation 1, the transparent dressing product that contain 12-hydroxy stearic acid and rosiny polyol ester and polyhydric alcohol branched fatty acid partial ester or polyhydric alcohol unsaturated fatty acids acid partial esters are disclosed.
In addition, the cosmetics that use the transparent basic material of the refractive index 1.45～1.54 that contains 12-hydroxy stearic acid and oil content are disclosed in patent documentation 2.
In addition, in patent documentation 3, disclose the transparent solid, cosmetic that contains 12-hydroxy stearic acid, heavy liquid paraffin and liquid oiliness composition, disclose in the patent documentation 4 and contained 12-hydroxy stearic acid and hydroxyl valency transparent solid, cosmetic at transparent liquid oiliness composition below 120 and methyl phenyl silicone.
And as the transparent dressing product that cooperate the fatty acid dextrin ester, the glossiness when also disclosing from the improvement coating in patent documentation 5 is considered, is used the transparent solid, cosmetic of fatty acid dextrin ester, heavy liquid paraffin and liquid oiliness composition.
In patent documentation 6, disclose and contained the fatty acid dextrin ester 0.2～40% that defines ad hoc structure that obtains by specific manufacture method and the transparent dressing product of fluid oil, disclose the cosmetics of cosmetic hair (embodiment 1,2), suntan oil gel (embodiment 3,4), oiliness foundation cream (embodiment 5,6), w/o type foundation cream (embodiment 7～9), cleansing cream various dosage forms such as (embodiment 10) in the embodiment.
In patent documentation 7, disclose the transparent dressing product of gel combination, it is characterized by in containing the transparent dressing product of 12-hydroxy stearic acid and oil content, define ad hoc structure the fatty acid dextrin ester, and the refractive index of oil content be 1.44～1.54.
In patent documentation 8, disclose a kind of contain amorphous fine-particle silicic acid anhydride that fatty acid dextrin ester and particle diameter are 0.001～0.05 μ m, and particle diameter be the transparent solid cosmetics of the spherical silicic acid anhydride of 0.1～30 μ m.
On the other hand, disclose the cosmetics that a kind of conduct has the polychrome type in the patent documentation 9, it is characterized by the porous matter that contains microgranule spherical or globular PMMA powder of micropartical and silicone oil, its outward appearance by oil-base gel agent stabilisation has pleochroism.
Patent documentation 1: the spy opens clear 63-119405 communique
Patent documentation 2: the spy opens flat 1-163111 communique
Patent documentation 3: the spy opens flat 2-264707 communique
Patent documentation 4: the spy opens flat 4-91010 communique
Patent documentation 5: the spy opens flat 9-235210 communique
Patent documentation 6: the spy opens flat 2001-39817 communique
Patent documentation 7: the spy opens the 2001-39817 communique
Patent documentation 8: the spy opens flat 11-255616 communique
Patent documentation 9: the spy opens the 2000-212039 communique
Summary of the invention
But as mentioned above, the transparent dressing product that are used 12-hydroxy stearic acid or fatty acid dextrin ester are widely adopted, but that putting on the skin when there is coating in this type of transparent dressing product smeared is smooth, the adhesion sense of oil residues and do not have problems such as salubrious sense, ageing stability difference.These problems are considered to derive from the insoluble in essence problem of the prescription system of the 12-hydroxy stearic acid that cooperates transparent composition and fatty acid dextrin ester.In addition, cooperate in the transparent dressing product of fatty acid dextrin ester, the formability when particularly bar-shaped is insufficient, exists to be used for it is remedied and the problem of transparency reduction when adding firming agent such as paraffin.
On the other hand, at the worry of facial skin, the applicant is that object is investigated with 180 women of 20 years old age bracket～50 years old age bracket, in 20 years old age bracket and 30 years old age bracket, pore is evident as the most serious, is the 2nd serious situation for 40 years old age bracket.Therefore, for the impression of giving the skin of nature by transparent basic material, and the expectation that can eliminate the tangible foundation cream of pore, cosmetic base material increase day by day.
But in existing technology, it obviously is very difficult making the transparent dressing product have the concavo-convex repair efficiency of skin and eliminating pore.
The purpose of this invention is to provide a kind of compositions, it is to have concave-convex effect, the elimination pore of repairing skin obviously to give the transparent dressing product of nature skin sense, and do not have the adhesion sense of oil, have have good stability novel of salubrious usability, compositions and effectively.
The inventor is in view of above-mentioned viewpoint, further investigate addressing the above problem and develop better transparent solid, cosmetic, found that to be characterized as and contain: (a) fatty acid dextrin ester 1～20 quality %, (b) boiling point under the normal pressure is volatility oil content 10～40 quality % below 250 ℃, (c) refractive index is 1.4～1.6 oil content 10～40 quality %, (d) refractive index is the specific transparent solid-state composition of globular powder 15～60 quality % of 1.3～1.6 mean diameter 3～30 μ m, can lead to provides transparent feel good, can bring into play the concavo-convex repair efficiency of skin, has the pore of elimination obvious effects, and can give the transparent solid, cosmetic of good use sense of touch, thereby finished the present invention.
Promptly, the invention provides a kind of transparent solid-state composition, it is characterized by and contain: (a) boiling point under fatty acid dextrin ester 1～20 quality %, (b) normal pressure is that volatility oil content 10～40 quality %, (c) refractive index below 250 ℃ are that oil content 10～40 quality %, (d) refractive index of 1.4～1.6 are globular powder 15～60 quality % of 1.3～1.6 mean diameter 3～30 μ m.
In addition, the present invention also provides above-mentioned transparent solid-state composition, and the globular powder that it is characterized by above-mentioned (d) refractive index and be 1.3～1.6 mean diameter 3～30 μ m is one or more the powder that is selected from silicic acid anhydride, polyurethane, the polyethylene.
The present invention also provides above-mentioned transparent solid-state composition, it is characterized by to contain (e) and be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether one or more.
The present invention also provides above-mentioned transparent solid-state composition, and it is characterized by one or more the content that (e) be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether is 1～10 quality %.
In addition, the present invention is also for containing the transparent solid, cosmetic of above-mentioned transparent solid-state composition as basic material.
Transparent solid, cosmetic of the present invention has the good transparency and stable.It is a kind of by being coated on the skin that this transparent solid cosmetic compositions can provide, and can bring into play the transparent solid, cosmetic of surprising elimination pore positive effect.In addition, its usability is also extremely good.
Description of drawings
[Fig. 1] is the figure of the intensity of expression light diffusion.
The specific embodiment
Below, invention is described in detail.
(a) fatty acid dextrin ester
The fatty acid dextrin ester that agent plays a role as transparent cured among the present invention is the ester of the fatty acid of dextrin and the alkyl (carbon number is preferably 3～30) with straight or branched, can obtain by using pyridine as base catalyst dextrin and fat acyl chloride to be reacted.
Preferred myristic acid, Palmic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid and have side chain or substituent above-mentioned fatty acid such as hydroxyl or phenyl and dextrin bonding.
Preferred especially Dextrin palmitate ester.
The use level of fatty acid dextrin ester is 1～20 quality % with respect to total composition (be with respect to the cosmetics total amount during for cosmetics, below identical), is preferably 7～14 quality %.
(b) boiling point is a volatility oil content below 250 ℃ under normal pressure
Can enumerate for example isoparaffin (about 225 ℃), octamethylcy-clotetrasiloxane (175 ℃), decamethylcyclopentaandoxane (210 ℃), ten dimethyl D5s cyclohexyl methyl siloxanes such as (245 ℃), boiling point and be low-molecular-weight dimethyl siloxane below 250 ℃, and their derivant etc.Be preferably the cyclohexyl methyl siloxanes.
Need to prove that (b) boiling point under normal pressure is that the refractive index of the volatility oil content below 250 ℃ is at 1.4～1.6 o'clock, calculate the content of (b) composition.
Boiling point under the normal pressure is that the use level of the volatility oil content below 250 ℃ is 10～40 quality % with respect to total composition, is preferably 10～25 quality %.
(c) refractive index is 1.4～1.6 oil content
For example can enumerate dimethyl polysiloxane (about 1.40), polyoxyalkylene gathers alkylsiloxane (alkene=ethylene: about 1.42), three-2 ethyl hexanoic acid glyceride (about 1.44), 2 ethyl hexanoic acid cetyl ester (about 1.44), three sad trihydroxymethyl propanes (about 1.45), squalane (about 1.45), alpha-olefin low polymers (about 1.46), two glyceryl isostearates (about 1.46), malic acid two iso stearyl esters (about 1.46), three isostearic acid polyglycerin ester (about 1.47), macadimia nut oil (about 1.47), liquid paraffin (about 1.47), methyl phenyl silicone (about 1.4～1.6) etc.
Can preferably use the シ リ コ one Application KF56 that produces as the Shin-Etsu Chemial Co., Ltd of methyl phenyl silicone (refractive index: about 1.5, viscosity 10～20mm 2/ s).
Refractive index is that the use level of 1.4～1.6 oil content is 10～40 quality % with respect to total composition, (b) boiling point under normal pressure be below 250 ℃ the volatility oil content, and (c) refractive index be the ratio of components of 1.4～1.6 oil content, because of combination, the use level of oil content, powder different, therefore can't unify regulation, for example in (b) decamethylcyclopentaandoxane, and (c) during the combination of methyl phenyl silicone, mass ratio is preferably (b): (c)=1: 4～4: 1, be preferably 2: 3～3: 2 especially.
(d) refractive index is that 1.3～1.6 mean diameter is the globular powder of 3～30 μ m
Use for example globular powder of polystyrene (about 1.59), PET (about 1.58), nylon (about 1.53), polyethylene (about 1.51), polyurethane (about 1.50), silicic acid anhydride (about 1.45～1.50), moisture silicic acid (about 1.40～1.50), politef mean diameter 3～30 μ m such as (about 1.35～1.38), be preferably silicic acid anhydride, polyurethane, poly globular powder. the numeral refractive index in above-mentioned (). need to prove that the PMMA powder is not suitable as the powder of (d) of the present invention composition.
Above-mentioned powder preferably carries out surface treatments such as hydrophobization processing and cooperates by conventional method.
The use level of globular powder is 15～60 quality % with respect to total composition, is preferably 25～50 quality %.The height cooperation ratio of globular powder is a feature of the present invention.
Among the present invention, refractive index is for oil content, by digital index meter (ATAGO society system model: the value of Ce Dinging RX5000 α), but about powder reference literature value.
The present invention is the transparent solid, cosmetic of basic material for transparent solid-state composition or with it.
The transparency of the present invention can be passed through the described transparent algoscopy in back, following object is estimated: it is thick to reach 5mm in the transparent resin container that sample is packed into, 25 ℃ of visibility and vividnesses of estimating the literal of the Times New Roman that is imprinted on the font 88 on the container down.
The present invention when further cooperating (e) to be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether one or more, can obtain not having the compositions of oiliness floating thing etc. and excellent in stability except above-mentioned essential composition.The applicable work of said composition is with the various basic materials headed by foundation cream or the cosmetic base material.
Higher alcohols is the higher alcohols with alkyl of carbon number 6～20, is preferably caproyl alcohol, capryl alcohol, lauryl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, arachidic alcohol.Alkyl can have side chain, also substituent groups such as unsaturated bond, hydroxyl, carboxyl, phenyl can be arranged.
Higher fatty acids is the fatty acid with alkyl of carbon number 9～30, preferred capric acid, lauric acid, myristic acid, Palmic acid, stearic acid, arachidic acid, mountain Yu acid, melissic acid.Alkyl can have side chain, or has substituent groups such as unsaturated bond, hydroxyl, carboxyl, phenyl.Unsaturated acids such as for example preferred palmitoleic acid oleic acid, linoleic acid, linolenic acid, petroselic acid, elaidic acid, ricinoleic acid, linolelaidic acid (acid of リ ノ エ ラ イ ジ Application), arachidonic acid; Branched chain fatty acids such as isostearic acid; Hydroxy carboxylic acid such as 12-hydroxy stearic acid etc.
The POEPOP dimethyl ether can use the spy to open the alkylene oxide hydrocarbon derivative that the 2003-113023 communique is put down in writing.
The use level of above-mentioned substance can be suitable decision, be 1～10 quality % for total composition usually, be preferably 2～7 quality %.
The dosage form of transparent solid, cosmetic is gel combination or solid-state composition, and its goods form is not particularly limited.For example can enumerate hair cosmetic compositions such as cosmetic cosmetics such as foundation cream, lipstick, transparent high light lip pomade, lip pomade, eye shadow, cosmetic base material, skin protection cosmetics, hair jelly (ヘ ア ス テ イ Star Network), pomade etc.Can the container filling or bar-shaped transparent solid, cosmetic use.
In the scope of not damaging effect of the present invention, can cooperate any composition in the transparent solid, cosmetic compositions of the present invention.Usually, can in cosmetics, add the composition that is used, and make any transparent solid, cosmetic according to common method.
In the cooperation scope of not damaging the transparency, powder, fat-soluble medicament, vegetable oil, UV absorbent etc. are arranged as other composition that preferably is used.
Powder for example can be enumerated inorganic powder (Talcum for example, Kaolin, Muscovitum, sericite (zeolite)), white mica, phlogopite, synthetic mica, rubellan, biotite, Vermiculitum, magnesium carbonate, calcium carbonate, aluminium silicate, barium silicate, calcium silicates, magnesium silicate, strontium silicate, the wolframic acid slaine, magnesium, silicon oxide, zeolite, barium sulfate, calcined calcium sulfate hemihydrate (calcined gypsum), calcium phosphate, fluor-apatite, hydroxyapatite, ceramic powders, metallic soap (Grillocin P 176 for example, calcium palmitate, aluminium stearate), boron nitride etc.; Inorganic Chinese white (for example titanium dioxide, zinc oxide etc.); Inorganic red class pigment (for example ferrum oxide (iron oxide red), iron titanate etc.); Inorganic brown class pigment (for example gamma-iron oxide etc.); Inorganic yellow class pigment (for example yellow ferric oxide, loess etc.); Inorganic black class pigment (for example Black Rouge, low order titanium oxide (low order acidify チ タ Application) etc.); Inorganic purple class pigment (for example manganese violet, cobalt violet etc.); Inorganic green class pigment (for example chromium oxide, chromic oxide gel, cobalt titanate etc.); Inorganic cyan class pigment (for example ultramarine, Prussian blue etc.); Pearlescent pigment (for example titanium oxide coated mica, titanium oxide coat bismuth oxychloride, titanium oxide coats Talcum, painted titanium oxide coated mica, bismuth oxychloride, argentine (guanin) etc.); Metallic powdery pigment (for example aluminium powder, copper powders may etc.); Zirconium, organic pigments such as barium or aluminum color lake (for example red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, yellow No. 205, yellow No. 401, reach cyan and wait organic pigment No. 404, red No. 3, red No. 104, red No. 106, red No. 227, red No. 230, red No. 401, red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3 and blue No. 1 etc.); Natural pigment (for example chlorophyll, beta-carotene) etc.
Liquid fat can be enumerated for example American Avocado Tree oil, Camellia oil, turtle oil, macadimia nut oil, Semen Maydis oil, mink oil, olive oil, Oleum Brassicae campestris, egg oil, Oleum sesami, Apricot kernel oil, Semen Tritici aestivi germ oil, Flos Camelliae Japonicae caul-fat, Semen Ricini oil, Semen Lini oil, Oleum Helianthi, cotton seed oil, perilla oil, soybean oil, Oleum Arachidis hypogaeae semen, Oleum Camelliae, Oleum Cocois, Testa oryzae oil, Chinese wood oil (シ Na ギ リ oil), Japanese tung oil, ホ ホ バ oil, germ oil, triglycerin etc.
Solid grease can be enumerated for example cocoa butter, Oleum Cocois, sclerosis Oleum Cocois, Petiolus Trachycarpi oil, palm kernel oil, wood wax oil, fixed oil, haze tallow, hardened castor oil etc.
Waxiness can be enumerated for example Apis cerana Fabricius, candelilla wax, cotton wax, Brazil wax, Fructus Lauri nobilis wax, insect wax, spermaceti, montan wax, bran wax, lanoline, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, the lanolin fatty acid isopropyl esters, lauric acid hexyl ester, the reduction lanoline, ホ ホ バ wax, the hard lanoline, shellac wax, POE lanoline alcohol ether, POE lanolin alcohol acetas, POE cholesterol ether, the lanolin fatty acid Polyethylene Glycol, POE hydrogenation lanoline alcohol ether, ceresin, microwax etc.
Hydrocarbon-type oil can be enumerated for example liquid paraffin, ceresine, squalane, pristane, paraffin, Squalene, vaseline etc.
Esters oil can be enumerated for example isopropyl myristate, sad cetyl ester, myristic acid octyl group dodecyl ester, isopropyl palmitate, butyl stearate, lauric acid hexyl ester, myristyl myristate, decyl oleate, the sad hexyl of dimethyl ester in the last of the ten Heavenly stems, the lactic acid cetyl ester, Tetradecyl lactate, lanolin acetate, stearic acid isocetyl ester, isostearic acid isocetyl ester, 12-hydroxy stearic acid cholesterol ester, two-2 ethyl hexanoic acid glycol ester, the dipentaerythritol fatty acid ester, single isostearic acid N-alkyl diol ester, two capric acid DOPCP, malic acid two iso stearyl esters, two-2-heptyl hendecanoic acid glyceride, three-2 ethyl hexanoic acid trihydroxymethyl propane ester, three isostearic acid trihydroxymethyl propane esters, four-2 ethyl hexanoic acid pentaerythritol ester, three-2 ethyl hexanoic acid glyceride, tricaprylin, three different tripalmitins, three isostearic acid trihydroxymethyl propane esters, cetyl-2-ethylhexanoate, 2-ethylhexyl cetylate, myristin, three-2-heptyl hendecanoic acid glyceride, the Castor Oil Fatty Acid methyl ester, Cetiol, acetoglyceride, Palmic acid-2-heptyl undecyl ester, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyl group dodecyl ester, adipic acid 2-hexyl undecyl ester, ethyl laurate, Diisooctyl Sebacate, myristic acid 2-hexyl ester in the last of the ten Heavenly stems, Palmic acid 2-hexyl ester in the last of the ten Heavenly stems, adipic acid 2-hexyl ester in the last of the ten Heavenly stems, Dermol DIPS, succinic acid 2-Octyl Nitrite, triethyl citrate etc.
Silicone oil can be enumerated for example chain polysiloxanes (for example dimethyl polysiloxane, methyl phenyl silicone, diphenyl polysiloxanes etc.); Cyclic polysiloxanes (for example octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes etc.), the silicones that forms tridimensional network, silicone rubber, various modified polyorganosiloxane (amino-acid modified polysiloxanes, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, fluorine modified polyorganosiloxane etc.) etc.
The lipophile non-ionic surface active agent can be enumerated for example sorbitan fatty ester class (for example dehydrating sorbitol monooleate, anhydrosorbitol list isostearate, sorbitan monolaurate, sorbitan-monopalmityl ester, anhydrosorbitol monostearate, sorbitan sesquioleate, anhydrosorbitol trioleate, five-2 ethyl hexanoic acid, two glycerol sorbitan esters, four-2 ethyl hexanoic acid, two glycerol sorbitan esters etc.); Glycerol polyglyceryl fatty acid ester class (for example single cottonseed oil fatty acid glyceride, single glycerol sinapate, sesquialter olein, glyceryl monostearate, α, α '-oleic acid pyroglutamic acid glyceride, glycerol monostearate malic acid etc.); Methyl glycol fatty acid ester class (for example propylene glycolmonostearate etc.); The hardened castor oil derivant; Glycerol alkyl ether etc.
Hydrophilic non-ionic surfactant can be enumerated for example POE-sorbitan fatty ester class (for example POE-dehydrating sorbitol monooleate, POE-sorbitan stearate, POE-dehydrating sorbitol monooleate, POE-anhydrosorbitol four oleates etc.); POE-Span class (for example POE-sorbitan monolaurate, POE-sorbitol monooleate, POE-sorbitol five oleates, POE-sorbitol monostearate etc.); POE-glycerine fatty acid esters (for example POE-monoleates such as POE-glyceryl monostearate, POE-glycerol list isostearate, POE-glycerol three isostearates etc.); POE-fatty acid ester (for example POE-distearate, the single dioleate of POE-, diglycol stearate etc.); POE-alkyl ether (for example POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-Shan Yu base ether, POE-2-octyl group lauryl ether, POE-cholesterol ether etc.); POEPOP-alkyl ether etc. (for example POEPOP-cetyl ether, POEPOP-2-decyl four decyl ethers, POEPOP-single-butyl ether, POEPOP-hydrogenated lanolin, POEPOP-glycerin ether etc.); POE-Oleum Ricini hardened castor oil derivant (for example POE-Oleum Ricini, POE-hardened castor oil, POE-hardened castor oil list isostearate, POE-hardened castor oil three isostearates, POE-hardened castor oil list pyroglutamic acid list isostearic acid diester, POE-hardened castor oil maleate etc.); POE-Apis cerana Fabricius lanolin derivative (for example POE-sorbitol Apis cerana Fabricius etc.); Alkanolamide (for example cocoanut fatty acid diethanolamide, lauric monoethanolamide, fatty acid isopropanol amide etc.); The POE-methyl glycol fatty acid ester; The POE-alkanamine; The POE-fatty acid amide; The Saccharum Sinensis Roxb. fatty acid ester; Trioleyl phosphate etc.
Wetting agent can be enumerated for example Polyethylene Glycol, propylene glycol, glycerol, 1,3 butylene glycol, xylitol, sorbitol, maltose alcohol, chondroitin sulfate, hyaluronic acid, mucoitin sulfuric acid, the acid of カ ロ ニ Application, ア テ ロ コ ラ one ゲ Application, cholesterol-12-hydroxy stearic acid ester, sodium lactate, bile salt, the dl-pyrrolidone carboxylic acid salt, short chain soluble collagen matter, two glycerol (EO) PO addition product, イ ザ ヨ イ バ ラ extract, achillea millefolium (セ イ ヨ ウ ノ コ ギ リ ソ ウ) extract, Herba Meliloti officinalis (メ リ ロ one ト) extract, trehalose, erithritol, POEPOP random copolymer methyl ether etc.
UV absorbent can be enumerated following chemical compound.
(1) benzoic acids UV absorbent
For example para-amino benzoic acid (being designated hereinafter simply as PABA), PABA monoglyceride, N, N-propoxyl group PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethoxy PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester etc.
(2) anthranilic acid UV absorbent
For example high menthyl (ホ モ メ Application チ Le)-N-acetic acid o-aminobenzoa etc.
(3) salicylic acid UV absorbent
For example amyl salicylate, salicylic acid menthyl ester, high menthyl salicylate, ethylhexyl salicylate, salicylic acid phenylester, salicylic acid benzyl ester, salicylic acid are to isopropyl alcohol phenylester etc.
(4) meat silicic acid class UV absorbent
Meat silicic acid monooctyl ester for example; ethyl-4-second propyl group meat esters of silicon acis; methyl-2; 5-diisopropyl meat esters of silicon acis; ethyl-2; 4-diisopropyl meat esters of silicon acis; methyl-2,4-diisopropyl meat esters of silicon acis; propyl group-right-methoxyl group meat esters of silicon acis; isopropyl-right-methoxyl group meat esters of silicon acis; isopentyl-right-methoxyl group meat esters of silicon acis; octyl group-right-methoxyl group meat esters of silicon acis (2-ethylhexyl-right-methoxyl group meat esters of silicon acis); 2-ethoxyethyl group-right-methoxyl group meat esters of silicon acis; cyclohexyl-right-methoxyl group meat esters of silicon acis; ethyl-alpha-cyano-beta-phenyl meat esters of silicon acis; 2-ethylhexyl-alpha-cyano-beta-phenyl meat esters of silicon acis; glyceryl list-2-ethyl hexanoyl base-di-p-methoxy meat esters of silicon acis etc.
(5) triazines UV absorbent
For example, two resorcinol triazines.
Two { [4-(2-ethyl hexyl oxy)-2-hydroxyl] phenyl }-6-(4-anisyl) 1,3,5-triazines, 2,4 are arranged more specifically, 6-three 4-[2-ethyl hexyl oxy carbonyl] anilino-) 1,3,5-triazines etc.
(6) other UV absorbent
3-(4 '-methyl benzal)-d for example; l-Camphora, 3-benzal-d; l-Camphora, 2-phenyl-5-Jia base benzoxazole, 2; 2 '-hydroxy-5-methyl base phenyl benzotriazole, 2-(2 '-hydroxyl-5 '-uncle's octyl phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole, two anisoyl methane, 4-methoxyl group-4 '-tert-butyl group dibenzoyl methane, 5-(3, the inferior norborny (ノ Le ボ Le ニ リ デ Application) of 3-dimethyl-2-)-3-pentane-2-ketone.Pyridyl derivatives such as dimorpholino tetrahydro pyridazine ketone.
Can enumerate for example 1-hydroxyl ethane-1 as the blocking metal agent, 1-di 2 ethylhexyl phosphonic acid, 1-hydroxyl ethane-1,1-tetra-na diphosphate salt, disodiumedetate, sodium versenate, tetrasodium ethylenediamine tetraacetate, sodium citrate, sodium polyphosphate, Polymeric sodium metaphosphate., gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, ethylenediaminetetraacetic acid, ethylenediamine hydroxyethyl three acetic acid trisodiums etc.
Vitamin can be enumerated for example vitamin A, B1, B2, B6, C, E and derivant thereof, pantothenic acid and derivant, biotin etc.
Antioxidant can be enumerated for example tocopherol, dibenzylatiooluene, butylhydroxy anisoyl ester, gallate ester etc.
The antioxidation adjuvant can be enumerated for example phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, ヘ キ サ メ タ Off オ ス Off エ イ ト, phytic acid, ethylenediaminetetraacetic acid etc.
Other gradation composition can be enumerated for example antiseptic (methyl parahydroxybenzoate, ethylparaben, butyl p-hydroxybenzoate, phenyl phenol etc.); Antiinflammatory (for example glycyrrhizin derivative, Enoxolone derivative, thiolaurine, hypotaurine, order cypress alcohol, zinc oxide, allantoin etc.); Whitening agent (for example Herba Saxifragae (ユ キ ノ シ タ) extract, arbutin, tranamic acid, L-ascorbic acid, L-magnesium L-ascorbyl-2-phosphate salt, L-ascorbic acid glucoside, 4-methoxyl group potassium salicylate etc.); Various extracts (Cortex Phellodendri for example, Rhizoma Coptidis, Rhizoma Seu Herba Bergeniae, Radix Paeoniae, as medicine (セ Application Block リ), betula alleghaniensis (バ one チ), salvia (セ one ジ), Folium Eriobotryae, Radix Dauci Sativae, Aloe, Radix Malvae sylvestris (ゼ ニ ア オ イ), Rhizoma Iridis Tectori (ア イ リ ス), Fructus Vitis viniferae, Semen Coicis (ヨ Network イ ニ Application), Fructus Luffae (ヘ チ マ), Bulbus Lilii, Stigma Croci (サ Off ラ Application), Rhizoma Chuanxiong, シ ヨ ウ キ ユ ウ, Herba Hyperici Erecti (オ ト ギ リ ソ ウ), オ ノ ニ ス, Bulbus Allii, Fructus Capsici, Pericarpium Citri Reticulatae, Radix Angelicae Sinensis, Sargassum etc.), activator (Lac regis apis, the sensitization element, cholesterin derivative etc.); Blood circulation accelerant etc.
Embodiment
Enumerating embodiment below is described more specifically the present invention.The present invention is not subjected to the qualification of following embodiment.Use level is quality % if no special instructions.And embodiment and comparative example are all made by usual method.
Need to prove, among the following embodiment and comparative example the methyl phenyl silicone of (c) composition if no special instructions, all use Shin-Etsu Chemial Co., Ltd シ リ コ one Application KF56 (refractive index: 1.405～1.595, viscosity: 10～20mm 2/ s).
[transparency]
Sensory evaluation: it is thick to reach 5mm in the transparent resin container that sample is packed into, by the professional visibility and the vividness of the literal of the Times New Roman that is imprinted on the font 88 on the container under 25 ℃ estimated.Transparent solid-state composition of the present invention has the good transparency.
5: literal is very high-visible, and vividness is very high.
4: literal is high-visible, the vividness height.
3: literal as seen, vividness is low a little.
2: closely see literal as seen, but vividness is poor.
1: can't read literal, opaque.
[usability]
For the salubrious sense after the oily residual sense after the coating, the coating, in the coating process the continuing of dry feeling, dry feeling, put project such as smear light/sliding on the skin, carry out sensory evaluation through 20 professionals.5 mark sections with very good (5 minutes), good (4 minutes), common (3 minutes), some poor (2 minutes), poor (1 minute) are estimated, and the meansigma methods of the score of 20 evaluations is rounded up try to achieve parameter.Transparent solid-state composition of the present invention has good usability.
[stability]
Behind each sample of filling, in each temperature chamber of-5 ℃/room temperature/37 ℃, left standstill 1 month respectively, outward appearance is estimated every 1 week.Transparent solid-state composition of the present invention has advantages of excellent stability.
5. at each temperature, outward appearance no change, excellent in stability.
4. under a part of temperature, visible a little oil is floating to wait variation, but and no problem.
3: under a part of temperature, variations such as visible oil float phenomenon.
2: under a part of temperature, violent variations such as visible oil float are outside allowed band.
1: under each temperature, violent variations such as visible oil float are outside allowed band.
[concavo-convex repair efficiency]
In transparent, eliminate the effect of the concave-convex sense of skin, can by the intensity of light diffusion carry out through the time measure and estimate.That is, if the effect height of light scattering just has high evaluation to the concavo-convex repair efficiency of skin.Therefore, this mechanism by the intensity of the light of transparent solid-state composition diffusion is carried out through the time measure and estimate.
Transparent solid, cosmetic of the present invention, after the coating to through the time the intensity of light diffusion when measuring, the time is long more, the diffusion strength of light (relative value of value=1 after the coating immediately) can increase.
This figure represents in " Fig. 1 ".In the figure of Fig. 1, the figure (the present invention) that ethereal oil divide to cooperate be all cooperate essential composition (a) (b) (c) (d) reach the compositions of embodiment 17 (e).In addition, the figure of Pei Heing (comparative example) does not only have (a) (c) (d), cooperates (b) and the compositions of replacing with (c) in its ratio.
From this icon as can be known, transparent solid-state composition of the present invention shows good concavo-convex repair efficiency according to the difference of (b) composition in particular composition of the present invention.
(1) about property (Obscure position, the excellent position property of powder) (effect)
Total composition of gauge table 1 at room temperature disperses until evenly.
Figure G2005800033381D00141
In the disperse system of powder, the refractive index of foreign minister and powder can improve the transparency when consistent to a certain extent. therefore, at the powder (comparative example 2 that disperses to have than the refractive index of foreign minister Geng Gao, 3) transparency the time is poor. in addition, if the use level of volatility oil content is after a little while in the powder of the refractive index that has and be close outward, usability variation (comparative example 1). the result of embodiment 1～4 satisfies these requirements.
(2) effect of volatility oil content
At room temperature total composition of his-and-hers watches 2 measures and heats after 95 ℃, carries out homodisperse, at room temperature solidifies after the degassing.
Table 2
Embodiment 3 Comparative example 2 Comparative example 3 Comparative example 4
Methyl phenyl silicone 44 64 - -
Decamethylcyclopentaandoxane 25 5 0 0
Liquid paraffin - - 69 -
Glyceryl triethyl group alkyl caproate - - - 69
Spherical silicic acid anhydride powder (mean diameter: 4～6 μ m) 30 30 30 30
The Dextrin palmitate ester 1 1 1 1
Add up to 100 100 100 100
Oily residual sense after the coating 4 2 2 2
Salubrious sense after the coating 4 2 2 2
Dry feeling in the coating process 4 2 2 2
Continuing of dry feeling 4 3 2 2
The amount of residual oil content reduces if the use level of volatility oil content increases, and when the residual sense of oil content reduced, salubrious sense, dry feeling were good.
(3) amount of powder
At room temperature total composition of his-and-hers watches 3 measures and heats after 95 ℃, carries out homodisperse, at room temperature solidifies after the degassing.
The usability of powder is according to use level and difference.Can determine, in this basic material, for the dry feeling that shows globular powder must cooperate more than 15%.
(4) higher alcohols/higher fatty acids/POEPOP dimethyl ether
At room temperature total composition of his-and-hers watches 4 measures and heats after 95 ℃, carries out homodisperse, at room temperature solidifies after the degassing.
Figure G2005800033381D00181
By being used of higher alcohols, higher fatty acids, POEPOP dimethyl ether, successfully improved stability with the various basic materials headed by the oil float.
Following transparent solid, cosmetic is by the common method manufacturing.
Table 5
Foundation cream/base material
Embodiment 17 Embodiment 18 Embodiment 19
Spherical silicic acid anhydride powder (mean diameter: 4～6 μ m) 40 40 40
The Dextrin palmitate ester 9 4.5 0
Palmic acid/sad dextrin ester - 4.5 9
Stearyl alcohol 4 4 4
Methyl phenyl silicone 28.4 28.4 28.4
Decamethylcyclopentaandoxane 16.2 16.2 16.2
Methoxyl group meat silicic acid monooctyl ester 2 2 2
EDTA·3Na·2H 2O 0.3 0.3 0.3
Citric acid 0.1 0.1 0.1
Add up to 100 100 100
Table 6
Foundation cream/base material
Embodiment 20
Spherical silicic acid anhydride powder (mean diameter: 4～6 μ m) 40
The Dextrin palmitate ester 9
Stearyl alcohol 4
Methyl phenyl silicone 22
Decamethylcyclopentaandoxane 23
Methoxyl group meat silicic acid monooctyl ester 2
Embodiment 20
Add up to 100
Table 7
Foundation cream/base material
Embodiment 21 Embodiment 22
Spherical silicic acid anhydride powder (mean diameter: 4～6 μ m) 40 40
The Dextrin palmitate ester 10 10
Stearyl alcohol 4 4
Methyl phenyl silicone 18.8 18.8
Decamethylcyclopentaandoxane 23.8 23.8
Methoxyl group meat silicic acid monooctyl ester 2 2
Olive oil 1 -
Squalane - 1
EDTA·3Na·2H 2O 0.3 0.3
Citric acid 0.1 0.1
Add up to 100 100
Table 8
Foundation cream/base material
Embodiment 23
Spherical silicic acid anhydride powder (mean diameter: 4～6 μ m) 35
The Dextrin palmitate ester 10
Stearyl alcohol 0.25
Embodiment 23
Methyl phenyl silicone 21.5
Decamethylcyclopentaandoxane 29.25
Methoxyl group meat silicic acid monooctyl ester 2
アエロジルR972 2
Add up to 100
Table 9
Foundation cream/base material
Embodiment 24
The spherical silicic acid anhydride powder of hydrophobization surface-treated (mean diameter: 15 μ m) 40
The Dextrin palmitate ester 9
Palmic acid/sad dextrin -
Stearyl alcohol 4
Methyl phenyl silicone 28.4
Decamethylcyclopentaandoxane 16.2
Methoxyl group meat silicic acid monooctyl ester 2
EDTA·3Na·2H 2O 0.3
Citric acid 0.1
Add up to 100
Table 10
Eye shadow
Embodiment 25
The spherical silicic acid anhydride powder of hydrophobization surface-treated (mean diameter: 25 μ m) 25
The Dextrin palmitate ester 9
Palmic acid/sad dextrin ester -
Stearyl alcohol 4
Methyl phenyl silicone 28.4
Decamethylcyclopentaandoxane 16.2
Pearling agent 10
ラ メ agent 5
Methoxyl group meat silicic acid monooctyl ester 2
EDTA·3Na·2H 2O 0.3
Citric acid 0.1
Add up to 100
The transparent dressing product of the foregoing description are that the transparent feel of basic material outward appearance good (evaluation of carrying out through above-mentioned transparent test is 5 fens), usability are good and can eliminate the transparent dressing product of the synapse sense of pore.
Industrial applicability
The transparent feel of transparent solid-state composition of the present invention is good, and suitable basic material as transparent solid, cosmetic uses. In addition, in the good transparent feel of performance, also can provide a kind of concavo-convex effect of when transparent feel is good, passing through repair of skin, make the pore of face or the transparent solid, cosmetic that mole is difficult to manifest. And its security and use sense are extremely good.

Claims (6)

1. transparent solid-state composition is characterized by and contains: (a) boiling point under fatty acid dextrin ester 1～20 quality %, (b) normal pressure is that volatility oil content 10～40 quality %, (c) refractive index below 250 ℃ are that oil content 10～40 quality %, (d) refractive index of 1.4～1.6 are globular powder 15～60 quality % of 1.3～1.6 mean diameter 3～30 μ m.
2. transparent solid-state composition as claimed in claim 1, the globular powder that it is characterized by described (d) refractive index and be 1.3～1.6 mean diameter 3～30 μ m are one or more the powder that is selected from silicic acid anhydride, polyurethane, the polyethylene.
3. transparent solid-state composition as claimed in claim 1 or 2, it is characterized by also and contain (e) and be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether one or more, wherein said higher alcohols is the alcohol with alkyl of carbon number 6～20, and described higher fatty acids is the fatty acid with alkyl of carbon number 9～30.
4. transparent solid-state composition as claimed in claim 1 or 2, it is characterized by one or more the content that (e) be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether is 1～10 quality %, wherein said higher alcohols is the alcohol with alkyl of carbon number 6～20, and described higher fatty acids is the fatty acid with alkyl of carbon number 9～30.
5. transparent solid-state composition as claimed in claim 3, it is characterized by one or more the content that (e) be selected from higher alcohols, higher fatty acids, the POEPOP dimethyl ether is 1～10 quality %, wherein said higher alcohols is the alcohol with alkyl of carbon number 6～20, and described higher fatty acids is the fatty acid with alkyl of carbon number 9～30.
6. transparent solid, cosmetic, it contains each described transparent solid-state composition of claim 1～5 as basic material.
CN2005800033381A 2004-01-27 2005-01-21 Transparent solid composition and transparent solid cosmetic preparation containing the same as base Expired - Fee Related CN1913864B (en)

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