CN1862291A - Rod lens array and method of manufacturing the same - Google Patents
Rod lens array and method of manufacturing the same Download PDFInfo
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- CN1862291A CN1862291A CN 200610079449 CN200610079449A CN1862291A CN 1862291 A CN1862291 A CN 1862291A CN 200610079449 CN200610079449 CN 200610079449 CN 200610079449 A CN200610079449 A CN 200610079449A CN 1862291 A CN1862291 A CN 1862291A
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Images
Abstract
In a rod lens array having a structure in which a plurality of rod lens elements are arranged between two side panels and a resin is filled and cured in spaces between the rod lens elements to be integrally formed, the side panels are made of a glass fiber reinforced epoxy resin and a phenol-based curing agent is used as a curing agent of the epoxy resin. In detail, the curing agent is exemplified by a phenol-based curing agent including a tris-hydroxyphenyl-methane skeleton.
Description
Technical field
The present invention relates to a kind of rod lens array, a plurality of therein rod lens elements are arranged between two side plates and fill and cured resin in the space between this rod lens element, form this rod lens element with integral body, and a kind of method of making this rod lens element.Particularly, the present invention relates to a kind of rod lens array, by using glass reinforced epoxy that is used as side plate and the phenylol hardening agent that is used as epoxy curing agent, also have by using the addition reaction-type organic siliconresin, this organic siliconresin comprises the monodisperse spherical organic filler and its viscosity is adjusted, as the resin that is used to fill this space, this rod lens array improves arrangement, optical property and the against weather of lens element.
Background technology
As known in the art, rod lens array has a kind of structure, a plurality of minutes gradient index (minute gradient index) rod lens arrangement of parts are between two side plates in this structure, and potting resin is to be integral with each other between the gap in this lenticular unit, and this lens arra is the example of the optical element of the big image of the single continuous upright grade of formation.Because this rod lens array has short light path and do not need the inverted image mirror, therefore may realize making this device littler.The characteristics that reduce because of size, rod lens is often used as optical element, not only be used to form the image read system of image, such as fax, image reading apparatus, duplicating machine etc., also be used on photoreceptor, forming the image writing system of sub-image (latent image) according to the picture signal that provides.Recently, high resolving power is accelerated, and has improved to higher accuracy in the sub-image with about the requirement than good quality of the degree of accuracy of the position that forms the image place.
Usually, make this type rod lens array by method described in JP61-55610A.For example, on substrate, provide, and arrange the optical fiber lens element of predetermined quantity, with by using this sept as with reference to the one or more lines that form along substrate surface as the sept of arranging reference.After with this lens element of array format, interim sept is set, not disturbing this arrangement, and with another substrate as lid to push this lens element.In this case, resin is packed into the gap of lens element, to keep shape and to make optical property satisfactory.After this, be cut into predetermined lens length, and grind two cutting edge edges by the integrally formed block of lense of cured resin.
Here, glass optical fiber reinforced plastics (FRP) is used as side plate, and particularly, the glass reinforced epoxy plate is widely used in below the grinding (with reference to JP-A-2001-318208).
(a) essential is that the thermal expansivity of side plate is identical with the thermal expansivity of lens material, so that during heating treatment prevent the undesired structure of lens element behind potting resin.
(b) essential is that the grindability of side plate is identical with the grindability of lens material, because side plate must grind equally with lens element.
(c) material because of lens is a glass, thus can consider to use face glass, but because face glass damages easily, face glass is difficult to processing.
In this case, since after resin is filled and is solidified rod lens array by one by one from the block of lense cutting, so side plate must oil has the made of good thermal resistance.Therefore, in the prior art, use the hardening agent that produces glass fiber-reinforced resin plate to be restricted to anhydrides or thermotolerance amine, so that the glass reinforced epoxy plate stands about 200 ℃ processing.Moreover, if above-mentioned hardening agent is used, then behind resin solidification, implement calcination processing, with the quality of stabilized glass fibre strengthening epoxy resin board.For example, with about 200 ℃ of lasting tens hours enforcement calcination processing, the while is imposed load therein.
Yet, use the glass reinforced epoxy plate to be therein: the foreign matter that forms the water droplet shape in against weather test (moistureproof test) afterwards on the surface at lens element as the problem that the rod lens array of side plate has, and play the effect of lens, therefore, obviously reduced optical property.
In addition, the problem of existence is: the glass cloth of glass reinforced epoxy plate breaks away from from this panel, thereby has increased its surperficial unevenness, causes this lens element to arrange degenerating of degree of accuracy.
In addition, the problem that exists is: make handle in when the amido hardening agent is used as oxygenant the surface of glass reinforced epoxy plate be coated with by the bonding agent (cyanoacrylate) that uses and dye, and then high temperature heating and cleaning removing this bonding agent for a long time, thereby cause lower throughput rate.
Turn to be arranged on interpleural filler, the resin of filling in order to support the optical fiber lens element mutually comprises epoxy resin or organic siliconresin.For this resin, add the inorganic filler of ideal quantity to the there, the cutting performance when cutting to improve.In addition, the viscosity of this resin is than higher, and for example, 2500 to 3000mPas, and by the negative pressure potting resin.
In recent years, in order to form high resolving power and less irregular image, need to reduce lens diameter (for example, 0.6mm or still less).Yet if use the lens that use in the prior art, the problem that exists is that in small diameter lenses, the position of these lens or direction may be irregular (just, arranging performance are lowered).Owing to according to the lenslet diameter and gap smaller is difficult to resin is packed into this gap, limited available time, thickness during filling, thereby increased the viscosity impedance, so top problem may occur.When using epoxy resin,,, optical property is offset thereby being lowered and forming the position of image because the contraction quantity in the curing that increases has been disturbed lens arrangement.
Exist another problem to be, not with the resin complete filling in all parts, thereby cause optical property to descend.These problems may be caused that described poor flow properties is owing to high thixotropic and high viscosity, the gathering of inorganic filler or the obstruction of this resin of epoxy resin by the poor flow properties of resin.
In addition, because the high viscosity of resin, the gap with lens element of minor diameter becomes littler, expend this gap of long-time filling, and then workability is lowered.Since the adhering part of resin be unsuitable for lens element (glass) and substrate (FRP: fiberglass-reinforced plastic), so that the problem that exists is the bonding force of lens arra is not strong, so that the frequent bonding fault of appearance.
Summary of the invention
The purpose of this invention is to provide a kind of rod lens array, it has the arrangement of high productivity, good lens element, super optical property and excellent resistance to weathering.
Another object of the present invention is to make a kind of have good arrangement performance and the high-intensity rod lens array of optical property base satisfactorily.
According to a first aspect of the invention, rod lens array has a kind of structure, and in this structure, a plurality of rod lens elements are arranged between two side plates, and in the gap between this rod lens element filling and cured resin so that its whole formation.In addition, in this rod lens array, side plate is by the glass reinforced epoxy manufacturing, and the phenylol hardening agent is used as curing agent for epoxy resin.
Hardening agent with the phenylol hardening agent that comprises three-hydroxy phenyl methane skeleton as example.Yet as long as hardening agent is the phenylol hardening agent, the available hardening agent of the present invention can not comprise three-hydroxy phenyl-methane skeleton.This hardening agent can be by following hardening agent example: aralkyl modified phenol base hardening agent such as polyphenol base hardening agent, bis-phenol base hardening agent, polyphenol base hardening agent, novolac-type phenylol hardening agent and phenylene/methylene/phenol type hardening agent, the phenylol hardening agent of cyclic aliphatic group modification, alkylidene modified phenol base hardening agent, nitrogenous modified phenol hardening agent such as triazine modified phenol hardening agent, phosphorous modified phenol base hardening agent and contain silicone-modified phenol cured agent.
In addition, the invention provides a kind of image processing system, it looks like to form image by using the rod lens array transitive graph.
Rod lens array of the present invention comprises the glass reinforced epoxy as side plate, and it is made as hardening agent by using the phenylol hardening agent, so the unevenness of surface of side plate is lowered, and the arrangement of lens element is enhanced.In addition, because foreign matter is not attached to lens surface after the against weather test, prevented that this lens performance from being become bad.Moreover the difference in thickness of lens arra is reduced, thereby makes high-quality image processing system.
According to a second aspect of the invention, rod lens array has a kind of structure, and in this structure, a plurality of rod lens elements are arranged between two side plates, and in the gap between this rod lens element filling and cured resin so that its whole formation.The resin that is filled in the gap is the addition reaction-type organic siliconresin, and this organic siliconresin comprises the monodisperse spherical organic filler of the average particulate diameter with 0.1 to 25 μ m of 0.1 to 20 quality %.Aspect this, resinous principle and oil component can be added in the organic siliconresin.
According to a further aspect in the invention, a kind of method of making rod lens array comprises: a plurality of optical fiber lens elements are aligned in substrate and place another substrate thereon with fixing assembling processing; Processing is solidified in the gap filling in the lens element arrangement of assembling and the filling of cured resin; To be cut into the cutting process of predetermined lens length by the integrally formed block of lense of resin that solidifies; And the milled processed of grinding two cutting edge edges.Resin as in the gap that is inhaled into and is filled in filling and curing processing in lens arrangement can use the addition reaction-type organic siliconresin.It is 500 to 1500mPas that this addition reaction-type organic siliconresin comprises the monodisperse spherical filler of the average particulate diameter with 0.1 to 25 μ m of 0.1 to 20 quality % and its viscosity.In addition, the curing inhibitors with 0.01 to 0.5 quality % is added into organic siliconresin, the viscosity variation when filling with control.
In addition, according to another aspect of the invention, provide a kind of image processing system, this device uses according to the rod lens array transmission of above-mentioned aspect and forms image.
In rod lens array according to the present invention, owing to use the addition reaction-type organic siliconresin that comprises the monodisperse spherical organic filler, therefore may not produce gathering, improve the obstruction of this resin, thereby will lack non-filling fault.In addition, according to the method for making rod lens array of the present invention, to have viscosity be that 500 to 1500mPas addition reaction-type liquid silicone resin and monodisperse spherical organic filler are comprised in wherein owing to use, and may remove because the fault of filling is disturbed and not have in the arrangement of cure shrinkage.Therefore, be used to this rod lens element, also can improve and arrange performance and optical property even have the lens element of minor diameter.
Description of drawings
Fig. 1 is the skeleton view according to rod lens array of the present invention.
Fig. 2 A and 2B are the key diagrams that the example of manufacture process is shown.
Fig. 3 A and 3B illustrate this rod lens array are applied in the optical printer example as image processing system.
Fig. 4 illustrates this rod lens array is applied in example in the image-scanning device that is provided in scanner and the fax etc.
Fig. 5 A and 5B explanation is the rod lens array among example 1-1 and the comparison example 1-1 after the against weather test.
Embodiment
Fig. 1 is the skeleton view according to typical rod lens array 1 of the present invention.Assemble two side plates 10, face with each other, between this gap, insert two septs 12 to have a gap.A plurality of rod lens elements 14 are arranged on two lines of 10 of this side plates.Resin 16 is filled in the gap of lens element and is cured as whole assembling.The surface of this rod lens array 1 can be with conventional lenses identical.In the present invention, this side plate is made of glass reinforced epoxy, and the phenylol hardening agent is used as curing agent for epoxy resin.
When being used as curing agent for epoxy resin, the reason that lens performance obviously reduces is as follows at anhydride group hardening agent (for example, phthalic anhydride).Pass through the alkaline components reaction that airborne moisture extracts in the unreacted residue hardening agent that extracts by the moisture of air and the glass lens, thus with the formation compound and on lens surface generation water droplet shape foreign matter.In this, if be used as the hardening agent of glass reinforced epoxy as the disclosed phenylol hardening agent of the present invention, then because the difference of polarity, hardening agent not on the surface of lens the alkaline components in glass form compound.Therefore, the performance of lens does not have variation in against weather is tested for a long time.
In addition, according to bonding agent and glass reinforced epoxy panel bonding with and on the throughput rate that causes of stain (chemical reaction of amine and cyanoacrylate) reduce, this stain is produced by the amido hardening agent as curing agent for epoxy resin, this stain can be avoided by using the phenylol hardening agent, because top reaction does not have to take place because of polarity is different.
In addition, in the situation of using the phenylol hardening agent,, behind curing reaction, needn't implement calcination processing because stability is outstanding.If the evaporation and the transformation of resin then appear in the enforcement calcination processing, and then in the extreme case about this, occur becoming fragile, thereby peel off.Therefore, the volume of resin reduces, and then glass cloth breaks away from this surface, causes the tangible unevenness on this surface and the variation in thickness of increase.For this point, in the present invention owing to needn't implement calcination processing, thus unevenness that should the surface be unconspicuous and do not change, therefore improved the degree of accuracy of the arrangement of lens element.
In the present invention, the resin that is filled in this gap is the addition reaction-type organic siliconresin that comprises the monodispersed inorganic spherical filler of 0.1 to 20 quality %, and this inorganic filler has the average particulate diameter of 0.1 to 25 μ m.
Reaction during according to curing (polymerization), organic siliconresin is divided into condensation reaction type and addition reaction-type.The addition reaction-type of Shi Yonging is by the two keys of opening molecule and the polymeric type that adds another molecule therein in the present invention.Therefore, owing to can reduce the deviation of arrangement, the distortion of rod lens array 1 diminishes, and the deviation that can reduce the position that forms image.More specifically, cure shrinkage can be for 250ppm or still less.
Owing to prepare lens arra 1 by the cutting block of lense, so improved cutting performance by filler is added into resin.If the quantity of the filler of inserting is too little, then be difficult to improve cutting performance.Otherwise if the quantity of the filler of inserting is too big, the become membranaceous and substrate (FRP plate) of picture and the adhesive property of lens of this resin is lowered.As mentioned above, increase the filler of 0.1 to 20 quality % to the there.Inorganic filler has just been gathered and the obstruction of resin just occurs, by use organic filler prevent to stop up with non-filling fault be further possible.Particularly, by single dispersion, obstruction is prevented significantly.The example of single dispersion treatment is that silanization is handled.Possible is by silylating reagent being contacted with the organic granular surface as organo-silicon compound or the organoalkoxysilane (organoalkosysilane) that comprises three silicyls (triorganosilyl), suppressing agglomeration of particles.
Preferably, resinous principle and oily composition are added into organic siliconresin.By adding resinous principle, may improve the hardness and the intensity of resin, thereby the intensity of lens arra 1 becomes stronger.Resinous principle is trifunctional or four functional silicone compounds, and adds its 0.1 to 20 quality % (preferred 0.5 to 10 quality %).
Prepare rod lens array 1 by following process.The example of manufacture process is illustrated among Fig. 2 A and the 2B.The side that sept 22a is installed in one of substrate is along (glass fiber-reinforced resin plate) 20a.Next, substrate 20a is tilted, so that sept 22a is positioned at the bottom, optical fiber lens element 24 closely is arranged on the substrate 20a.For example, arrange lens element with two stages.After the lens element 24 of arranging predetermined quantity, another sept 22b is installed in the another side (with reference to Fig. 2 A) of substrate 20a.Another substrate 20b superposes thereon, with assembling lens component structure 38 (with reference to Fig. 2 B).Resin is filled in the gap of lenticular element arrangement 28 of assembling, so that be cured.The filling of carrying out resin consequently is supplied to liquid resin the end in this gap.Carry out negative pressure of vacuum with this resin is complete and be filled in the gap that lens element is arranged equably at the other end.After this, the resin of filling is cured, and has the resin mass of the resin-bonded of curing to be cut every predetermined lens length.At last, cutting edge is ground along (rod lens edge).
In the present invention, as the resin in the gap that is inhaled into and is filled in the lens element arrangement, use the addition reaction-type organic siliconresin.The addition reaction-type organic siliconresin comprises the monodisperse spherical organic filler of 0.1 to 20 quality %, and this organic filler has the average particulate diameter of 0.1 to 25 μ m and 500 to 1500mPas viscosity.0.01 the curing retarding agent to 0.5 quality % is added into organic siliconresin, the viscosity when filling with control changes.The example that solidifies retarding agent is the potpourri of poly-alkyl chain alkenyl siloxane (polyalkylalkenylsiloxane) and reaction control agent.
Fig. 3 A and 3B illustrate this rod lens array 1 are applied in example in the optical printer 30 as image processing system.
The critical piece of optical printer 30 is by cylindrical photosensitive drum 31 with such as other cell configuration of optical printer head 32 and developing device 33, and this other device is relative with the circumferential surface of photosensitive drum 31.
Shown in Fig. 3 B, optical printer head 32 is provided with the combination of light-emitting element array 34 and rod lens array 1.Light-emitting element array 34, is assembled by rod lens array 1 from the light of this light-emitting element array emission, with the circumferential surface of exposure photosensitive drum 31 by with array format driving LED emission light according to picture signal.The zone of the photosensitive drum 31 that is exposed is recharged, to form sub-image.After this, apply toner by 33 pairs of sub-images that on photosensitive drum 31, form of developing device, with this image that develops.Then the image on the photosensitive drum 31 is transferred to the thin page or leaf S that sends from thin page or leaf box 36 in transfer printing device (transferring device) 35.Therefore, a thin page or leaf S epigraph is fixed on the immobilising device 37, and finishing image configuration, and then a thin page or leaf S is stacked in the piler 38.
Fig. 4 illustrates the example that this rod lens array 1 is applied in the image-scanning device 40 that is arranged in scanner and fax etc.
Image-scanning device 40 comprises file table glass 41, on this document table glass 41, place the file D that is scanned, with the scanning device body 42 below this document table glass 41, linear light sorurce 43, rod lens array 1 and linear imaging sensor 44 are installed in this scanning device body 42, are arranged photo-electric conversion element at these linear imaging sensor 44 neutral lines.Be provided with this linear light sorurce 43, rod lens array 1 and linear imaging sensor 44 with respect to shown in Fig. 4 the part vertical extension.
[example]-(1)
Three glass reinforced epoxies below using produce rod lens array (example 1-1 and comparison example 1-1 and 1-2) as side plate.The optical fiber shape lens material that will have the 0.453mm diameter in two stages is deposited between two glass reinforced epoxies, with assembling lens material arrange body, and absorbs the organic siliconresin that is filled between the lens material.Next, continue enforcement heating in 3 hours and curing at 135 ℃, to produce block of lense.Cut this block of lense with preliminary dimension, wherein part is ground to form rod lens array then.
(example 1-1)
Carbon black is added into epoxy resin with after implementing blackening at the phenylol hardening agent that comprises three-hydroxy phenyl-methane skeleton by use, glass cloth is contaminated therein to produce prepreg.Prepreg is heated to 200 ℃ and be pressed the glass reinforced epoxy plate that has about 0.95mm thickness with generation, and then (349 * 380mm) cut this plate with preliminary dimension.The unevenness on the surface of the glass reinforced epoxy plate that obtains in example 1-1 is enhanced, and is 1.1 μ m so that the surface roughness Ra of center line is 0.3 μ m and maximum height Ry.
Arbitrarily taken out by the rod lens array that uses the glass reinforced epoxy plate to produce, as the result who measures this thickness and precision, this variation in thickness is about 20 μ m.Moreover as the result of the arrangement precision of measuring rod lens array, maximum arrangement deviation is 15 μ m.In the environment that rod lens array is retained in 60 ℃, 90%Rh (relative humidity), continue 1000 hours, be removed then, and estimate outward appearance and optical parametric.Shown in Fig. 5 A, on the surface of lens, do not observe foreign matter (among reference marker and Fig. 1 corresponding).The variation of the MTF (modulation transfer function) that measures as optical property is 1% or still less.In addition, rod lens array and led array are combined with the formation led print head, and make optical printer (image processing system) with the enforcement image print by the use led print head, thereby form the picture rich in detail that does not have linear stain.
(comparison example 1-1)
When in example 1-1, after carbon black is added into epoxy resin, by use maleic anhydride base hardening agent as the anhydride group hardening agent to implement blackening, glass cloth is contaminated therein to produce prepreg.This prepreg be heated to 200 ℃ and the compacting have the thick glass reinforced epoxy plate of about 0.95mm with manufacturing.In addition, with 200 ℃ of lasting 16 hours execution calcination processing, be continuously applied load simultaneously.Next, (349 * 380mm) cut this plate with preliminary dimension.With respect to the unevenness on the surface of the glass reinforced epoxy plate of acquisition in comparison example 1, the surface roughness Ra of this center line is that 4.7 μ m and maximum height Ry are 8.9 μ m.
Arbitrarily taken out by the rod lens array that uses the manufacturing of glass reinforced epoxy plate, and as the result who measures this thickness and precision, this variation in thickness is about 80 μ m.Moreover as the result of the arrangement precision of measuring rod lens array, maximum arrangement deviation is 31 μ m.In the environment that rod lens array is retained in 60 ℃, 90%Rh (relative humidity), continue 1000 hours, be removed then, and estimate outward appearance and optical property.Shown in Fig. 5 B, on the surface of lens, observe drops foreign matter (corresponding among reference marker and Fig. 1, and foreign matter is represented as 18).Compare with the MTF that measured before the against weather test, the MTF that measures as optical property reduces significantly, and rate of change is 9.3%.In addition, by using the optical printer (image processing system) of rod lens array, implement image print, and observe print wire.
(comparison example 1-2)
When in example 1-1, after carbon black was added into epoxy resin, to implement blackening, contaminated to produce prepreg therein by glass cloth as the amido hardening agent for use modification aliphatic cyclic amine hardening agent.This prepreg be heated to 200 ℃ and the compacting have the thick glass reinforced epoxy plate of about 0.95mm with manufacturing.In addition, with 200 ℃ of lasting 16 hours execution calcination processing, be continuously applied load simultaneously.Next, (349 * 380mm) cut this plate with preliminary dimension.With respect to the unevenness on the surface of the glass reinforced epoxy plate of acquisition in comparison example 2, the surface roughness Ra of this center line is that 3.8 μ m and maximum height Ry are 7.2 μ m.
Use the glass reinforced epoxy plate to make rod lens array.Because the cementing agent dyeing that the glass reinforced epoxy plate is used in processing, heating of therefore long-time execution high temperature and cleaning (continuing 8 hours with 200 ℃) are to remove this cementing agent.Rod lens array is arbitrarily taken out, and as the result who measures this thickness and precision, this variation in thickness is about 62 μ m.Moreover as the result of the arrangement precision of measuring rod lens array, maximum arrangement deviation is 28 μ m.Rod lens array is retained in 60 ℃, 90%Rh (relative humidity), continues to be removed then in (or should be for) environment of 1000 hours, and estimates outward appearance and optical parametric.On the surface of lens, observe the drops foreign matter.Compare with the MTF that measured before the against weather test, the MTF that measures as optical property reduces significantly, and rate of change is 6.7%.In addition,, implement image print, and observe print wire by using the optical printer (image processing system) of rod lens array.
The result is illustrated in the table 1.
[table 1]-(1)
Example 1-1 | Comparative Examples 1-1 | Comparative Examples 1-2 | |
The hardening agent type | The phenylol hardening agent | The anhydride group hardening agent | The amido hardening agent |
Surface roughness Ra (μ m) | 0.3 | ?4.7 | ?3.8 |
Maximum height Ry (μ m) | 1.1 | ?8.9 | ?7.2 |
Variation in thickness (μ m) | About 20 | About 80 | About 62 |
Lens arrangement deviation (μ m) | 15 | ?31 | ?28 |
MTF changes (%) | ≤1 | ?9.3 | ?6.7 |
Foreign matter | No | The drops foreign matter occurs | The drops foreign matter occurs |
Print quality | There is not linear stain | Non-homogeneous printing | Non-homogeneous printing |
Use the rod lens array of several resins as shown in table 2 (example 2-1 and 2-2 and comparison example 2-1 and 2-2) to be produced and to test.Have the 0.453mm diameter the optical fiber shape in lens material be laminated between two glass fiber-reinforced resin plates of optical fiber (FRP) in two-stage, arrange (wide: 349mm with the assembling lens material, long: as 400mm), and this resin to be inserted in this lens material.Then, the resin that can be filled continues to be cured in 3 hours with 135 ℃, with the preparation resin mass.This resin mass is cut into preliminary dimension, and its edge is ground to obtain rod lens array.
[table 2]-(2)
Example 2-1 | Example 2-2 | Comparative Examples 2-1 | Comparative Examples 2-2 | |
Resin | Organic siliconresin A | Organic siliconresin B | Epoxy resin E | Organic siliconresin C |
Be right after viscosity (23 ℃), (mPas) after mixed with resin | 1200 | ?1000 | ?1600 | ?2200 |
Mixed back four hours | 1400 | ?1100 | ?4000 | ?3100 |
Thixotropic index | 1.04 | ?1.03 | ?1.61 | ?1.03 |
Cure shrinkage (ppm) | 250 | ?250 | ?3500 | ?310 |
Hardness (JIS) | 52 | ?49 | ?95 | ?42 |
Filling time (minute) | 150 | ?120 | ?170 | >2000 |
(example 2-1)
The organic siliconresin A that uses in example 2-1 is the addition reaction-type organic siliconresin with viscosity of 1200 to 1400mPas, it is added 15 quality % as the vinyltrimethoxy silane of resinous principle in addition, add the average particulate diameter of 10 quality % with 25 μ m monodisperse spherical poly methyl silsesquioxane (polymethylsyl sesquioxane), 4.0 quality % as the carbon black of photomask agent and the curing inhibitors of 0.1 quality %.
(example 2-2)
The organic siliconresin B that uses in example 2-2 is the addition reaction-type organic siliconresin with viscosity of 1000 to 1100mPas, and it is added the vinyltrimethoxy silane of 15 quality % as resinous principle.In addition, add the monodisperse spherical poly methyl silsesquioxane, 4.0 quality % of the average particulate diameter of 10 quality % as the carbon black of photomask agent and the curing inhibitors of 0.1 quality % with 25 μ m.
(comparison example 2-1)
The organic siliconresin E that uses in comparison example 2-1 is the epoxy resin with viscosity of 1600 to 4000mPas.Also have, the monodisperse spherical poly methyl silsesquioxane of the average particulate diameter with 25 μ m of 10 quality % and 4.0 quality % are as the carbon black of photomask agent.
(comparison example 2-2)
The organic siliconresin C that uses in comparison example 2-2 is the liquefaction organic siliconresin with viscosity of 2200 to 3100mPas, and it is added the vinyltrimethoxy silane of 15 quality % as resinous principle.In addition, add the average particulate diameter of 10 quality % with 25 μ m monodisperse spherical poly methyl silsesquioxane, 4.0 quality % as the carbon black of photomask agent and the curing inhibitors of 0.1 quality %.
According to comparison example 2-1 and example 2-1 and 2-2, can prepare lens arra.Yet, in comparison example 2-2, can not use resin to fill the gap that lens material is arranged, thereby be difficult to prepare lens arra.
The result that the rod lens array of preparation is assessed is used in table 3.Evaluation item forms position deviation (μ m) for the ratio (%) that does not have potting resin between the lens element of rod lens array, the distance between optical axes (μ m) that the lens of performance are arranged in expression, the image of representing the 1200dpi resolution of optical property.Carry out the not assessment of filling rate, so that intuitively see the cutting rod lens array, and to having the rod lens array counting of at least one through hole.Carry out the assessment of maximum optical axis distance, so that measure the distance of adjacent lens element at two edges, and then calculate difference wherein.Then, the maximal value in the rod lens array is selected.Execution is to the assessment of maximum position deviation, so that by using first lens element as a reference, the position that n lens element is set in the position of lens diameter * n is a normal place.Then, calculate n lens position when observing and the difference between the normal place, with the maximal value in the selection rod lens array at the convex surfaces place.
[table 3]-(2)
Example 2-1 | Example 2-2 | Comparative Examples 2-1 | Comparative Examples 2-2 | |
Unfilled ratio | 0 | ?0.1 | ?37 | - |
Maximum optical axis distance | 15 | ?15 | ?46 | - |
Maximum image forms | 35 | ?38 | ?120 | - |
[0029]-(2)
In example 2-1 and 2-2, the resin filling time is short, thereby obtains optimal result.Compare with these two examples, example 1 has the effect better than example 2-2, and for example, long filling time, higher hardness and less maximum image form position deviation.In addition, when the diameter of lens element was 0.564mm, 0.900mm and 1.100mm, same result was obtained.On the contrary, in comparison example 2-1, hardness is high, and the filling time is long, and cure shrinkage is big.Therefore, comparison example 2-1 has the assessment result than example 2-1 and 2-2 difference.
Claims (13)
1, a kind of rod lens array comprises:
A plurality of rod lens elements;
Pair of side plates is provided with described rod lens element at this side sheet room; And
The resin of filling in the interelement gap of this rod lens and being cured is so that its whole formation;
Wherein this side plate is by the glass reinforced epoxy manufacturing, and the phenylol hardening agent is used as this curing agent for epoxy resin.
2, according to the rod lens array of claim 1, the phenylol hardening agent that wherein comprises three-hydroxy phenyl methane skeleton is used as described hardening agent.
3, according to the rod lens array of claim 1, wherein glass reinforced epoxy comprises glass cloth.
4, according to the rod lens array of claim 1, the resin that wherein is filled in the gap is an organic siliconresin, and this organic siliconresin comprises the Ball-type packing of the average particulate diameter with 0.1 to 25 μ m of 0.1 to 20 quality %.
5, a kind of by using according to the rod lens array transmission of claim 1 and the image processing system of formation image.
6, a kind of by using image scanning apparatus according to the rod lens array scan image of claim 1.
7, a kind of rod lens array comprises:
A plurality of rod lens elements;
Pair of side plates is provided with described rod lens element at this side sheet room; And
The resin of filling in the interelement gap of this rod lens and being cured is so that its whole formation;
The resin that wherein is filled in the gap is the addition reaction-type organic siliconresin, and this organic siliconresin comprises the monodisperse spherical organic filler of the average particulate diameter with 0.1 to 25 μ m of 0.1 to 20 quality %.
8, according to the rod lens array of claim 7, wherein resinous principle and oil component are added in the organic siliconresin.
9, according to the rod lens array of claim 7, wherein this side plate is by the glass reinforced epoxy manufacturing, and the phenylol hardening agent is used as this curing agent for epoxy resin.
10, a kind of by using according to the rod lens array transmission of claim 7 and the image processing system of formation image.
11, a kind of by using image scanning apparatus according to the rod lens array scan image of claim 7.
12, a kind of method of making rod lens array comprises:
Assembling is handled, and a plurality of optical fiber lens elements is aligned in substrate and places another substrate thereon with fixing;
Filling-curing is handled, and fill and cured resin in the gap during the lens element of assembling is arranged;
Cutting process will be cut into predetermined lens length by the integrally formed block of lense of resin that solidifies; And
Milled processed is ground two cutting edge edges,
Wherein fill and solidify handle in the addition reaction-type organic siliconresin be used to suck and be filled in resin in the gap in the lens arrangement, it is 500 to 1500mPas that this addition reaction-type organic siliconresin comprises the monodisperse spherical filler of the average particulate diameter with 0.1 to 25 μ m of 0.1 to 20 quality % and its viscosity.
13, according to the method for the manufacturing rod lens array of claim 12,
Wherein the curing inhibitors with 0.01 to 0.5 quality % is added into organic siliconresin, the change of the viscosity when filling with control.
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JP2005134343A JP4636541B2 (en) | 2005-05-02 | 2005-05-02 | Rod lens array |
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JP2005134417A JP4632303B2 (en) | 2005-05-02 | 2005-05-02 | Rod lens array and manufacturing method thereof |
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CN104142536A (en) * | 2014-08-26 | 2014-11-12 | 福州百讯光电有限公司 | Double-substrate fixing device and method of free space optical modules |
CN106094069A (en) * | 2016-08-26 | 2016-11-09 | 威海华菱光电股份有限公司 | Compound lens and the imageing sensor including it |
CN106626097A (en) * | 2016-12-13 | 2017-05-10 | 莱特巴斯光学仪器(镇江)有限公司 | Production technology for asymmetric lenses |
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CN115043587B (en) * | 2021-03-09 | 2023-10-24 | 飞秒光电科技(西安)有限公司 | Glass fiber arranging structure and method |
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CN85102289A (en) * | 1985-04-01 | 1986-08-20 | 中国科学院长春应用化学研究所 | A kind of epoxy resin insulation material |
JPH01129201A (en) * | 1987-11-16 | 1989-05-22 | Mitsubishi Rayon Co Ltd | Distributed index lens array |
JP2001296405A (en) * | 2000-04-12 | 2001-10-26 | Nippon Sheet Glass Co Ltd | Rod lens array |
JP4440427B2 (en) * | 2000-05-11 | 2010-03-24 | 日本板硝子株式会社 | Rod lens array |
JP4529268B2 (en) * | 2000-10-05 | 2010-08-25 | 住友ベークライト株式会社 | Epoxy resin composition, prepreg and copper-clad laminate using the same |
JP2003026766A (en) * | 2001-07-13 | 2003-01-29 | New Japan Chem Co Ltd | Epoxy-based reactive diluent and liquid epoxy resin composition containing the same |
JP2005181949A (en) * | 2003-01-29 | 2005-07-07 | Mitsubishi Rayon Co Ltd | Method for manufacturing rod lens array, arraying tool used therefor, original plate cutter and end face cutting device |
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CN104142536A (en) * | 2014-08-26 | 2014-11-12 | 福州百讯光电有限公司 | Double-substrate fixing device and method of free space optical modules |
CN104142536B (en) * | 2014-08-26 | 2017-05-17 | 福州百讯光电有限公司 | Double-substrate fixing device and method of free space optical modules |
CN106094069A (en) * | 2016-08-26 | 2016-11-09 | 威海华菱光电股份有限公司 | Compound lens and the imageing sensor including it |
CN106626097A (en) * | 2016-12-13 | 2017-05-10 | 莱特巴斯光学仪器(镇江)有限公司 | Production technology for asymmetric lenses |
CN106626097B (en) * | 2016-12-13 | 2018-07-27 | 莱特巴斯光学仪器(镇江)有限公司 | A kind of production technology of asymmetric lens |
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JP2006309072A (en) | 2006-11-09 |
CN101592745B (en) | 2011-05-04 |
JP4636541B2 (en) | 2011-02-23 |
CN1862291B (en) | 2010-05-26 |
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