CN1830873B - Bricks made of magnesium slag and the production method therefor - Google Patents

Bricks made of magnesium slag and the production method therefor Download PDF

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Publication number
CN1830873B
CN1830873B CN2006102002685A CN200610200268A CN1830873B CN 1830873 B CN1830873 B CN 1830873B CN 2006102002685 A CN2006102002685 A CN 2006102002685A CN 200610200268 A CN200610200268 A CN 200610200268A CN 1830873 B CN1830873 B CN 1830873B
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CN
China
Prior art keywords
slag
parts
lime
raw material
gypsum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006102002685A
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Chinese (zh)
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CN1830873A (en
Inventor
陈黔
张继强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHIJI TIANYUAN MINING CO Ltd GUIZHOU PROV
Original Assignee
SHIJI TIANYUAN MINING CO Ltd GUIZHOU PROV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHIJI TIANYUAN MINING CO Ltd GUIZHOU PROV filed Critical SHIJI TIANYUAN MINING CO Ltd GUIZHOU PROV
Priority to CN2006102002685A priority Critical patent/CN1830873B/en
Publication of CN1830873A publication Critical patent/CN1830873A/en
Priority to PCT/CN2007/000900 priority patent/WO2007107111A1/en
Priority to US12/229,154 priority patent/US7594964B2/en
Application granted granted Critical
Publication of CN1830873B publication Critical patent/CN1830873B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Processing Of Solid Wastes (AREA)

Abstract

A Mg-slag brick with high strength is prepared proportionally from reduced Mg slags, broken stone, gypsum, lime and water through mixing, adding water, stirring, natural stacking, die pressing, steam curing and natural drying.

Description

A kind of Mg-slag brick and preparation method thereof
Technical field
The present invention relates to a kind of Mg-slag brick and preparation method thereof, belong to building material field.
Background technology
Can produce a large amount of magnesium reduction slags in industry refining magnesium process, what these slags can not be careless topples over, and it destroys the ecotope and the eubiosis, and processing cost is quite big.At present, be in the method for main raw material brickmaking with industrial residue now, be to be main raw material with flyash basically.Though the method for also useful magnesium slag brickmaking, because the defective of making method self, the brickmaking effect is unsatisfactory.
Summary of the invention
The objective of the invention is to: a kind of Mg-slag brick and preparation method thereof is provided.It is main raw material that this method adopts the magnesium reduction slag that produces in the refining magnesium process, makes high-intensity building brick, and its making method will be easy to grasp, and prescription rationally reduces the pollution of industrial waste to environment, helps the utilization again of waste material.
Technical scheme of the present invention: a kind of Mg-slag brick, it is to make with the water of following weight proportion raw material and raw material total amount 10%~40%;
60~80 parts of magnesium reduction slags, 15~25 parts of rubbles,
1~15 part in gypsum, 3~15 parts in lime.
Above-mentioned Mg-slag brick, it is to make with the water of following weight proportion raw material and raw material total amount 10%~40%;
70~80 parts of magnesium reduction slags, 17~23 parts of rubbles,
5~13 parts in gypsum, 5~13 parts in lime.
In the aforesaid Mg-slag brick, rubble is natural rock or the industrial residue that particle diameter is no more than 10mm.
In the aforesaid Mg-slag brick, rubble is Wingdale, blast-furnace slag or the phosphorus slag that particle diameter is no more than 7mm better.
In the aforesaid Mg-slag brick, gypsum is the plaster of paris, phosphogypsum or industry byproduct desulfurated plaster preferably.
In the aforesaid Mg-slag brick, lime is the unslaked lime or the carbide slag that can generate calcium hydroxide.
The preparation method of aforesaid Mg-slag brick makes by following step;
A, water is added in the magnesium reduction slag, mixing is stacked more than 12 hours, again with rubble, gypsum and lime mixing naturally; Or water added in the mixed raw material, mixing is stacked more than 12 hours naturally; Get the A product;
B, the A product are pressed into adobe, after the seasoning finished product.
Among the above-mentioned Mg-slag brick preparation method, its step b is, the A product are pressed into adobe, vapor cure 1-12 hour, after the seasoning finished product.
Compared with prior art, the invention provides a kind of Mg-slag brick and preparation method thereof.The present invention is a main raw material with a large amount of magnesium reduction slags that produce in the refining magnesium process, adds suitably batching, and adopts suitable preparation method, makes building brick, has both alleviated the pollution of industrial residue to environment, has increased novel material for construction work again.The present invention fills a prescription rationally, making method rationally and be easy to grasp, the brick intensity of making very high (can reach more than the 25MPa) reaches the standard of national building brick.Have be easy to produce, with short production cycle, production cost is low, the characteristics of good product effect.
Embodiment
Embodiment 1.Make Mg-slag brick by following step.
A, get the water of 200Kg, add the magnesium reduction slag of 700Kg, mixing, stacking is 2 days naturally, again with the rubble of 200Kg, the gypsum of 100Kg and the lime mixing of 100Kg; Or earlier the magnesium reduction slag of 700Kg, the rubble of 200Kg, the gypsum of 100Kg and the lime of 100Kg are mixed, adding the water of 200Kg again, mixing was stacked 2 days naturally; Get the A product;
The magnesium reduction slag that magnesium reduction slag can obtain with the magnesium reduction slag that produces in the production of magnesium by pidgeonprocess process or other method.Rubble is Wingdale, blast-furnace slag or the phosphorus slag that is no more than 7mm with particle diameter as aggregate better, also available other natural rock or industrial residue.Gypsum can be used phosphogypsum, the plaster of paris or industry byproduct desulfurated plaster.The lime available energy generates the unslaked lime or the carbide slag of calcium hydroxide.
B, the A product are pressed into adobe, after the seasoning finished product.
Embodiment 2.Make Mg-slag brick by following step.
A, get the water of 250Kg, add the magnesium reduction slag of 750Kg, mixing, stacking is 3 days naturally, again with the rubble of 120Kg, phosphogypsum and the 130Kg lime mixing of 120Kg; Or earlier the magnesium reduction slag of 750Kg, the rubble of 120Kg, the phosphogypsum of 120Kg and the lime of 130Kg are mixed, adding the water of 250Kg again, mixing was stacked 3 days naturally; Get the A product;
B, the A product are pressed into adobe, vapor cure 4~6 hours, after the seasoning finished product.
Can suitably improve the intensity of brick and shorten the production time with vapor cure.

Claims (5)

1. Mg-slag brick, it is characterized in that: it is to make with the water of following weight proportion raw material and raw material total amount 10%~40%;
60~80 parts of magnesium reduction slags, 15~25 parts of rubbles,
1~15 part in gypsum, 3~15 parts in lime;
Described rubble is natural rock or the industrial residue that particle diameter is no more than 10mm;
Described gypsum is the plaster of paris, phosphogypsum or industry byproduct desulfurated plaster;
Described lime is the unslaked lime or the carbide slag that can generate calcium hydroxide.
2. Mg-slag brick according to claim 1 is characterized in that: it is to make with the water of following weight proportion raw material and raw material total amount 10%~40%;
70~80 parts of magnesium reduction slags, 17~23 parts of rubbles,
5~13 parts in gypsum, 5~13 parts in lime.
3. Mg-slag brick according to claim 2 is characterized in that: described rubble is Wingdale, blast-furnace slag or the phosphorus slag that particle diameter is no more than 7mm.
4. as the preparation method of the described Mg-slag brick of arbitrary claim in the claim 1 to 3, it is characterized in that: make by following step;
A, water is added in the magnesium reduction slag, mixing is stacked more than 12 hours, again with rubble, gypsum and lime mixing naturally; Or water added in the mixed raw material, mixing is stacked more than 12 hours naturally; Get the A product;
B, the A product are pressed into adobe, after the seasoning finished product.
5. Mg-slag brick preparation method according to claim 4 is characterized in that: described step b is, the A product are pressed into adobe, vapor cure 1-12 hour, after the seasoning finished product.
CN2006102002685A 2006-03-23 2006-03-23 Bricks made of magnesium slag and the production method therefor Expired - Fee Related CN1830873B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2006102002685A CN1830873B (en) 2006-03-23 2006-03-23 Bricks made of magnesium slag and the production method therefor
PCT/CN2007/000900 WO2007107111A1 (en) 2006-03-23 2007-03-20 Mg-slag brick with high strength and method for preparing the same
US12/229,154 US7594964B2 (en) 2006-03-23 2008-08-19 High strength magnesium slag brick and method of producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2006102002685A CN1830873B (en) 2006-03-23 2006-03-23 Bricks made of magnesium slag and the production method therefor

Publications (2)

Publication Number Publication Date
CN1830873A CN1830873A (en) 2006-09-13
CN1830873B true CN1830873B (en) 2011-05-11

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CN2006102002685A Expired - Fee Related CN1830873B (en) 2006-03-23 2006-03-23 Bricks made of magnesium slag and the production method therefor

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101190838B (en) * 2006-11-22 2011-12-28 贵州世纪天元矿业有限公司 Method for preparing ceramic aggregate from magnesium-smelting reduction slag
CN102225852A (en) * 2011-04-19 2011-10-26 沈阳工业大学 Method for preparing autoclaved brick by using refined magnesium slags and fly ash

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1236747A (en) * 1999-04-17 1999-12-01 徐玉忠 Mortar powder of magnesium slag ash and its product
CN1673168A (en) * 2004-03-25 2005-09-28 上海静安新建材科研所有限公司 Three-slag mixed material with waste gypsum modified flyash

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1236747A (en) * 1999-04-17 1999-12-01 徐玉忠 Mortar powder of magnesium slag ash and its product
CN1673168A (en) * 2004-03-25 2005-09-28 上海静安新建材科研所有限公司 Three-slag mixed material with waste gypsum modified flyash

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JP昭58-45174A 1983.03.16
张习贤 等.工业废料镁矿渣的路用研究.《中南公路工程》.1997,第22卷(第2期),第35-40页. *

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Granted publication date: 20110511

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