CN104250083B - A kind of metallurgical slag air entrained concrete and processing technology and application - Google Patents

A kind of metallurgical slag air entrained concrete and processing technology and application Download PDF

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Publication number
CN104250083B
CN104250083B CN201310270315.3A CN201310270315A CN104250083B CN 104250083 B CN104250083 B CN 104250083B CN 201310270315 A CN201310270315 A CN 201310270315A CN 104250083 B CN104250083 B CN 104250083B
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China
Prior art keywords
air entrained
entrained concrete
metallurgical slag
siccative
slag
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Expired - Fee Related
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CN201310270315.3A
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CN104250083A (en
Inventor
韩甲兴
杨刚
王幼琴
金强
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Upper Hypon Smelting Slag Comprehensive Exploitation Industrial Co Ltd
MCC Baosteel Technology Services Co Ltd
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Upper Hypon Smelting Slag Comprehensive Exploitation Industrial Co Ltd
MCC Baosteel Technology Services Co Ltd
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Priority to CN201310270315.3A priority Critical patent/CN104250083B/en
Publication of CN104250083A publication Critical patent/CN104250083A/en
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Publication of CN104250083B publication Critical patent/CN104250083B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention relates to building material field, be specifically related to a kind of metallurgical slag air entrained concrete and processing technology and application. Metallurgical slag air entrained concrete of the present invention, its composition comprises siccative, additive and water; The composition of described siccative comprises by weight percentage: cement 5~12wt%, and steel-making slag powder 2~4wt%, slag powders 3~5wt%, metallurgy is ion dust mud contaning 15~25wt% not, flyash 36~50wt%, quick lime 15~20wt%, gypsum: 3~5wt%; Additive comprises water reducer and aluminium powder, and the content of water reducer is 0.5~2.0wt% of siccative weight, and the content of aluminium powder is 0.04~0.2wt% of siccative weight; The mass ratio of water and siccative is 0.45~0.6:1. Metallurgical slag air entrained concrete of the present invention has the effects such as profit useless environmental protection, heat preservation and soundproof and fire prevention, belongs to the recycling of industrial waste, reduces environmental pollution, meets the requirement of sustainable development.

Description

A kind of metallurgical slag air entrained concrete and processing technology and application
Technical field
The present invention relates to building material field, be specifically related to a kind of metallurgical slag air entrained concrete and processing technology and application.
Background technology
The present invention relates to a kind of method of metallurgical slag air entrained concrete and preparation thereof, is not contain with steel-making slag powder, slag powders, metallurgyThe trade wastes such as iron dirt mud and flyash are primary raw material, belong to the recycling of Industrial Solid refuse, applicable to insulation, everyThe light building material such as sound and fire proofing material field.
Air entrained concrete is taking calcareous material and siliceous material as solvent, forms loose structure with the method for chemical gas generation,Obtain the artificial stone material of lightweight of intensity by steam press maintenance. It has high-strength light, heat-insulation and heat-preservation, fire prevention, sound insulation, water resistantThe characteristics such as damping, are novel energy-saving environment-friendly type construction materials, in the engineerings such as high building wall system work, insulation and linerArrive application widely.
Along with the development of building trade, construction material resource and the energy in short supply, trade waste is as a kind of idle resource,More and more be used in building material field, played the work of saving energy and reduce the cost, reducing costs and alleviate carrying capacity of environmentWith.
Metallurgical slag comprises not ion dust mud contaning of slag, slag, metallurgy herein.
Slag is the waste residue of steel industry. Its mineral composition comprises olivine, dicalcium silicate, tricalcium silicate and free on a small quantityThe compositions such as calcium oxide, magnesia, vitreum. There is certain aquation from hard ability, after superfine powder activation processing, canTo solve preferably free calcium oxide, magnesian expansion issues, there is certain activity.
Metallurgy not ion dust mud contaning is nonferrous ash, slag, mud in steel mill, in broad terms, is also the one of steel slag resource. SmeltingGold not ion dust mud contaning is of a great variety, has contained metallurgical production whole process. Its state mostly is subparticle, in concrete productPlay fine effect of gathering materials.
Slag is also referred to as granulated blast-furnace slag, water-granulated slag or grain slag, is that smelter floats on molten iron while smelting iron in iron-smelting furnaceThe slag on surface, when discharge, water quenching obtains. Granulated blast-furnace slag contains CaO, SiO simultaneously2、A12O3, be calcium--aluminium--Silicon ternary system, it is called ground slag after levigate. There is higher lateral reactivity. Under alkaline environment, can occurHydration and hardening and produce intensity. Self also can there is hydration and hardening reaction in ground slag, have from hard under certain fineness conditionProperty.
Flyash is the flue dust of coal-fired power plant's discharge, obtains through gathering dust. Flyash through pyroprocess and gather dust fastSpeed cooling procedure. its product with glass state material for leading and containing a small amount of crystalline state material. The chemical composition of flyash is with SiO2、A12O3Be main, the content sum of the two is generally between 60%-85%, and its thing phase morphology is taking vitreum as main, thereby has latentIn activity. Flyash belongs to light material compared with cement and other solid waste things, can reduce the unit mass of material.
Steel-making slag powder, slag powders, flyash and metallurgy not ion dust mud contaning all belong to industrial solid castoff, are a kind of idle moneySource, if do not loop recycling, not only causes the significant wastage of resource, takies a large amount of lifes but also pollute the environmentProduce place.
Summary of the invention
The object of the invention is to solve the problem that in prior art, industrial solid castoff pollutes, a kind of metallurgical slag aerating is providedConcrete and preparation technology thereof. Metallurgical slag air entrained concrete of the present invention has the works such as profit useless environmental protection, heat preservation and soundproof and fire preventionWith, and belong to the recycling of Industrial Solid refuse, and turn waste into wealth, reduce environmental pollution.
First the present invention discloses a kind of metallurgical slag air entrained concrete, and its composition comprises siccative, additive and water; Described siccativeComposition, comprise by weight percentage: cement 5~12wt%, steel-making slag powder 2~4wt%, slag powders 3~5wt%, metallurgyNot ion dust mud contaning 15~25wt%, flyash 36~50wt%, quick lime 15~20wt%, gypsum 3~5wt%; Outside describedAdd agent and comprise water reducer and aluminium powder cream, wherein the content of water reducer is 0.5~2.0wt% of siccative weight, and the content of aluminium powder cream is0.04~0.2wt% of siccative weight; The mass ratio of water and siccative is 0.45~0.6:1.
Preferably, metallurgical slag air entrained concrete of the present invention, its dry apparent density is 500kg/m3~800kg/m3
Siccative:
Cement of the present invention is the conventional cement in this area, preferred, is 42.5 grades of Portland cements.
Steel-making slag powder of the present invention is by levigate the making of converter slag process; Preferably, the specific area of described steel-making slag powder >=400m2/ kg. Preferred, the contained free calcium oxide≤3wt% of steel-making slag powder. Steel-making slag powder is real by upper Hypon smelting slag comprehensive exploitationIndustry Co., Ltd provides.
Institute of the present invention slag powders is made up through grinding of granulation blast furnace granulated slag; Preferably, the specific area of described slag powders >= 400m2/ kg. Slag powders is by Shanghai Baotian New Type Building Material Co., Ltd.
Metallurgy of the present invention not ion dust mud contaning is lime stone mud and/or dolomite mud. Described lime stone mud is raw for manufacturingThe limestone crushing dedusting damping mud producing in lime process; Described dolomite mud is produced by manufacturing in quick lime processDolomite clean sludge. By Shanghai Baosteel, Co., Ltd provides.
Additive:
Preferably, described water reducer is naphthalene water reducer. More excellent, described water reducer model is FDN-2 type. By five smelting collectionThe Shang Haiyuan of group builds building material Co., Ltd to be provided.
Aluminium powder cream of the present invention meets national standard " aluminium powder of getting angry " (GB/T2084) and " air entrained concrete aluminiumPowder cream " (JC/T407) requirement.
Second aspect present invention discloses the processing technology of aforementioned metallurgical slag air entrained concrete, comprises the steps:
1) according to the composition of described metallurgical slag air entrained concrete by not ion dust mud contaning, powder of cement, steel-making slag powder, slag powders, metallurgyCoal ash, quick lime, gypsum uniform stirring, obtain siccative mixture;
2) in the siccative mixture obtaining to previous step, add water reducer, water and aluminium powder cream, uniform stirring 5~30 minutes,Obtain slurry;
3) slurry of preparation is imported to injection molding in hopper, through steam precuring, steam press maintenance, obtains metallurgical slag air entrained concrete.Preferably, the method for precuring is described in step 3): 40 DEG C~45 DEG C of temperature, and in the chamber precuring 2~4h that rests.
Further, after steam precuring, the part that acquisition intensity reaches 0.2-0.3MPa carries out moulding cutting.
Preferably, described in step 3), the method for steam press maintenance is: pressure 0.8~1.3MPa, steam press maintenance 8-9 in pressing steaming stillHour.
The present invention finally discloses the application of aforementioned metallurgical slag air entrained concrete in building material field.
The each performance indications of air entrained concrete that the present invention utilizes compound metallurgical ground-slag to prepare meet standard GB/T 11968-2006The requirement of " autoclave aerated concrete building block ".
The invention has the advantages that and utilize industrial solid castoff for raw material, by steel-making slag powder, slag powders, flyash and metallurgy notIon dust mud contaning carries out compound, and the potential volcanic ash effect that makes full use of steel-making slag powder, slag powders and flyash replaces part of cement,Not only reduce production cost, but also can reduce the heat of hydration of cement, improved the later strength of concrete product. UtilizeMetallurgical not ion dust mud contaning fine gathered materials effect as the filler of air-entrained concrete building block, the aerating of preparing after steam press maintenanceConcrete strength is high, corrosion resistance is strong, has the effects such as insulation, sound insulation, fire prevention simultaneously, belongs to the profit again of Industrial Solid refuseWith, turn waste into wealth, not only save energy resources day by day in short supply, and protected again our living environment, at one stroke many.
Brief description of the drawings
Fig. 1: air entrained concrete preparation technology line map of the present invention
Detailed description of the invention
Before further describing the specific embodiment of the invention, should be understood that protection scope of the present invention is not limited to following spyFixed specific embodiments; It is also understood that the term using in the embodiment of the present invention is in order to describe specific concrete enforcementScheme, instead of in order to limit the scope of the invention.
Embodiment 1
The concrete formula of the present invention is by weight: the slag powders of the cement of 10wt%, the steel-making slag powder of 3wt%, 4wt%, 20wt%'sThe flyash of metallurgical not ion dust mud contaning, 41wt%, the quick lime of 18wt%, the gypsum uniform stirring of 4wt%;
Then add the water reducer of siccative weight 0.8wt%, the aluminium powder cream of 0.16wt% and the water of 50wt%, uniform stirring;
The slurry of mixing is imported to injection molding in hopper, push 45 DEG C of chamber precuring of resting and within 3 hours, treat that part intensity reaches 0.25MPaShi Jinhang moulding cutting, then enters to press to steam in still and carries out steam press maintenance 9 hours, goes out afterwards still and piles up. Then survey apparent dryDensity is 604kg/m3, intensity is 4.0MPa.
Embodiment 2
The concrete formula of the present invention is by weight: the slag powders of the cement of 10wt%, the steel-making slag powder of 3wt%, 4wt%, 20wt%'sThe flyash of metallurgical not ion dust mud contaning, 41wt%, the quick lime of 18wt%, the gypsum uniform stirring of 4wt%;
Then add the water reducer of siccative weight 0.8wt%, the aluminium powder cream of 0.20wt% and the water of 50wt%, uniform stirring;
The slurry of mixing is imported to injection molding in hopper, push 45 DEG C of chamber precuring of resting and within 3 hours, treat that part intensity reaches 0.25MPaShi Jinhang moulding cutting, then enters to press to steam in still and carries out steam press maintenance 9 hours, goes out afterwards still and piles up. Then survey apparent dryDensity is 511kg/m3, intensity is 3.1MPa.
Embodiment 3
The concrete formula of the present invention is by weight: the slag powders of the cement of 10wt%, the steel-making slag powder of 3wt%, 4wt%, 20wt%'sThe flyash of metallurgical not ion dust mud contaning, 41wt%, the quick lime of 18wt%, the gypsum uniform stirring of 4wt%;
Then add the water reducer of siccative weight 0.8wt%, the aluminium powder cream of 0.04wt% and the water of 50wt%, uniform stirring;
The slurry of mixing is imported to injection molding in hopper, push 45 DEG C of chamber precuring of resting and within 3 hours, treat that part intensity reaches 0.25MPaShi Jinhang moulding cutting, then enters to press to steam in still and carries out steam press maintenance 9 hours, goes out afterwards still and piles up. Then survey apparent dryDensity is 818kg/m3, intensity is 7.8MPa.
Embodiment 4
The concrete formula of the present invention is by weight: the slag powders of the cement of 5wt%, the steel-making slag powder of 4wt%, 5wt%, the smelting of 25wt%The flyash of golden not ion dust mud contaning, 36wt%, the quick lime of 20wt%, the gypsum uniform stirring of 5wt%;
Then add the water reducer of siccative weight 0.5wt%, the aluminium powder cream of 0.16wt% and the water of 60wt%, uniform stirring;
The slurry of mixing is imported to injection molding in hopper, push 40 DEG C of chamber precuring of resting and within 4 hours, treat that part intensity reaches 0.25MPaShi Jinhang moulding cutting, then enters to press to steam in still and carries out steam press maintenance 9 hours, goes out afterwards still and piles up. Then survey apparent dryDensity is 612kg/m3, intensity is 3.6MPa.
Embodiment 5
The concrete formula of the present invention is by weight: the slag powders of the cement of 12wt%, the steel-making slag powder of 2wt%, 3wt%, 15wt%'sThe flyash of metallurgical not ion dust mud contaning, 50wt%, the quick lime of 15wt%, the gypsum uniform stirring of 3wt%;
Then add the water reducer of siccative weight 2.0wt%, the aluminium powder cream of 0.16wt% and the water of 45wt%, uniform stirring;
The slurry of mixing is imported to injection molding in hopper, push 45 DEG C of chamber precuring of resting and within 2 hours, treat that part intensity reaches 0.25MPaShi Jinhang moulding cutting, then enters to press to steam in still and carries out steam press maintenance 8 hours, goes out afterwards still and piles up. Then survey apparent dryDensity is 609kg/m3, intensity is 4.3MPa.

Claims (10)

1. a metallurgical slag air entrained concrete, its composition comprises siccative, additive and water; The composition of described siccative by weight percentageMeter comprises: cement 5~12wt%, and steel-making slag powder 2~4wt%, slag powders 3~5wt%, metallurgy is ion dust mud contaning 15~25wt% not,Flyash 36~50wt%, quick lime 15~20wt%, gypsum 3~5wt%; Described additive comprises water reducer and aluminium powderCream, wherein the content of water reducer is 0.5~2.0wt% of siccative weight, the content of aluminium powder cream be 0.04 of siccative weight~0.2wt%; The mass ratio of water and siccative is 0.45~0.6:1; The processing technology of described metallurgical slag air entrained concrete, bagDraw together following steps:
1) according to the composition of described metallurgical slag air entrained concrete by not ion dust mud contaning, powder of cement, steel-making slag powder, slag powders, metallurgyCoal ash, quick lime, gypsum uniform stirring, obtain siccative mixture;
2) in the siccative mixture obtaining to previous step, add water reducer, water and aluminium powder cream, uniform stirring 5~30 minutes,Obtain slurry;
3) slurry of preparation is imported to injection molding in hopper, through steam precuring, steam press maintenance, obtains metallurgical slag air entrained concrete;Step 3) method of described precuring is: 40 DEG C~45 DEG C of temperature, in the chamber precuring 2~4h that rests; Step 3) instituteThe method of stating steam press maintenance is: pressure 0.8~1.3MPa, steams steam press maintenance 8-9 hour in still in pressing.
2. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, described cement is 42.5 grades of normal silicatesCement.
3. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, the specific area of described steel-making slag powder >=400m2/kg。
4. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, the specific area of described slag powders >=400m2/kg。
5. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, described metallurgy not ion dust mud contaning is lime stone dirtMud and/or dolomite mud.
6. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, described water reducer is naphthalene water reducer.
7. metallurgical slag air entrained concrete as claimed in claim 6, is characterized in that, described water reducer model is FDN-2 type.
8. metallurgical slag air entrained concrete as claimed in claim 1, is characterized in that, described metallurgical slag air entrained concrete dry apparentDensity is 500kg/m3~800kg/m3
9. the processing technology of metallurgical slag air entrained concrete described in the arbitrary claim of claim 1-8, comprises the steps:
1) according to the composition of described metallurgical slag air entrained concrete by not ion dust mud contaning, powder of cement, steel-making slag powder, slag powders, metallurgyCoal ash, quick lime, gypsum uniform stirring, obtain siccative mixture;
2) in the siccative mixture obtaining to previous step, add water reducer, water and aluminium powder cream, uniform stirring 5~30 minutes,Obtain slurry;
3) slurry of preparation is imported to injection molding in hopper, through steam precuring, steam press maintenance, obtains metallurgical slag air entrained concrete;Step 3) method of described precuring is: 40 DEG C~45 DEG C of temperature, in the chamber precuring 2~4h that rests; Step 3) instituteThe method of stating steam press maintenance is: pressure 0.8~1.3MPa, steams steam press maintenance 8-9 hour in still in pressing.
Described in the arbitrary claim of claim 1-8 metallurgical slag air entrained concrete in the application of building material field.
CN201310270315.3A 2013-06-28 2013-06-28 A kind of metallurgical slag air entrained concrete and processing technology and application Expired - Fee Related CN104250083B (en)

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CN110342896A (en) * 2019-07-29 2019-10-18 江苏禾吉新材料科技有限公司 A kind of concrete aerated brick of steel slag coal ash and preparation method thereof
CN110540397B (en) * 2019-08-27 2021-10-29 江苏博拓新型建筑材料有限公司 Anti-cracking energy-saving heat-insulating aerated concrete block and preparation method thereof
CN110734300A (en) * 2019-10-09 2020-01-31 湖南工程学院 aerated concrete blocks and preparation process thereof
CN112679173A (en) * 2020-12-10 2021-04-20 广东广业检测有限公司 Stainless steel slag carbonized aerated brick and preparation method thereof

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CN103011877A (en) * 2012-12-11 2013-04-03 上海宝冶钢渣综合开发实业有限公司 Waste-utilizing foam concrete and preparation process thereof

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RU2362755C1 (en) * 2008-03-13 2009-07-27 Государственное образовательное учреждение высшего профессионального образования "Сибирский государственный индустриальный университет" Mix for light concrete preparation
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