CN1804209A - Zero-discharge non-pollution combined production process for ecological paper pulp - Google Patents
Zero-discharge non-pollution combined production process for ecological paper pulp Download PDFInfo
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Abstract
The invention relates to a zero-release nonpollution combination production technique for ecological pulp, which uses biological decomposition as main and catalysis as complement as well as physical and mechanical break, and drafts different combination technique for variable plant material kinds and composition. This invention overcomes pollution problems in traditional technique, saves resource and cost, and has well production quality and great social and economical benefits.
Description
Technical field
The present invention relates to a kind of technology of making paper pulp, particularly relate to the combined production process for ecological paper pulp of Zero-discharge non-pollution.
Background technology
The pollution of whole world paper industry is the headachy thing of part at present, on the one hand being the international market is increasing year by year to the demand of paper, especially the Chinese market consumption figure is every year on average with 12% constantly increasing at a high speed, the pollution condition that is paper industry on the other hand is in continuous deterioration, and the main source of each big river of China, lake water pollution is a paper industry.1989 because the contaminated color of soy sauce that almost become of Huaihe River water quality, force Chinese Government disposable Basin of Huaihe River more than the 2000 tame middle-size and small-size paper mills of having closed of ordering, but after several years, the Huaihe River water that take a favorable turn slightly again gradually become color of soy sauce, river can not be used for irrigating, and can not drink, and fish is death ray also, this is because some irresponsible papermaking producers do not process just the stealthily result of discharging for economic interests to the waste liquid of pulp production.But after all basic reason is that present paper industry all is applied chemistry pulp-making method (pollution of paper industry mainly is in the slurrying stage) basically.Use alkaline process, sulphite process or acid polishing, what acid polishing was discharged is red waste liquid, what alkaline process and sulfite pulping were discharged is the black waste liquid, contain a large amount of lignins and the catabolite of carbohydrate in these waste liquids that are discharged, as vulcanize lignin, formic acid alcohol, dimethyl sulphide and Methyl disulfide compound etc., this all is the compound that can give out foul smell, this just makes in the waste liquid of pulping and contains very high COD (COD), biochemical oxygen demand (BOD) (BOD), suspended matter (SS) and adsorbable organohalogen compounds (AOX), the bleaching process of paper pulp mostly is to adopt the chlorine bleach technology, contain more than 40 kind of organochlorine compound in the waste liquid that bleaching is discharged, comprising the carcinogenic noxious material of dioxin and so on.According to " Chinese paper industry 2002 annual reports ", the paper industry wastewater discharge reaches 31.9 hundred million tons, account for national industrial total release 17.4%, wherein the discharge capacity of chemical oxygen demand COD accounts for 40.8% of national industrial wastewater pollution thing discharge capacity, though the continuous booster injection of national environmental protection department is to the controlling index of paper industry blowdown and strengthen regulatory efforts, paper industry self also continues to increase the measure and the investment of administering sewage, R﹠D institution is also constantly providing new pollution treatment technology and method, this all makes the sewage discharge of China and world's paper industry obtain improvement year by year really, no matter how advanced but problem is: pollution treatment technological means and process equipment, the sewage discharge that all can't thoroughly effect a radical cure paper industry reaches zero and pollutes, and makes our living environment constantly be subjected to the injury of papermaking blowdown.
This shows that the pollution problem of discharging of waste liquid is a global technical problem anxious to be solved in the slurrying production process of paper industry.
From the twentieth century initial stage, just the someone proposes applying biological method system paper pulp to replace chemical pulping method in the world, desire realizes eliminating paper-making pollution, go through a century, the experts and scholars of various countries pay great painstaking effort for this reason, they possess mutagenesis, hybridization even the applying gene technology that the white rot flora that can decompose the plant lignin carries out again and again and attempt to improve the capacity of decomposition of bacterium enzyme to lignin at occurring in nature is unique, but final certification, the limit capacity of biological bacteria can only be under laboratory's condition just can decompose in the plant 60% lignin through 10-20 days time.Must divide the plant of taking off more than 90% lignin in the paper pulp that paper industry needs, also differ from 30%.Up to today, who merely the applying biological method of decomposing realize the suitability for industrialized production of paper pulp.
In order to reduce the pollution of slurrying, people use the mechanical jordaning method of stone mill slurry and steel disk, because the lignin in the paper pulp of being produced is not eliminated, the easy flavescence of the paper of creating can not be preserved for a long time, and the fiber of slurry is hard, the scope of application is restricted, as bleaching, will produce waste liquid sewage discharge problem
Begin to develop from the nineties and chemical thermomechanical pulp-making method (CTMP), though the simple chemical pulping method of the waste liquid in the production process reduces, pollution problem is still very serious.
All there is the drawback of waste liquid sewage discharge in paper-making pulping no matter how at present.Difficult problem in view of the existing waste liquid sewage discharge of above-mentioned existing paper pulp manufacturing technique, the inventor is engaged on the bio-pulping application technical research practical basis for many years in summary, slurrying production technology scheme interdisciplinary, multidisciplinary composite combined has been proposed, through prolonged and repeated test, finally work out a kind of combined production process for ecological paper pulp of very good Zero-discharge non-pollution, it has changed traditional discharging of waste liquid that chemical pulping method and other method of manufcturing paper pulp brought and pollution completely.Realized Zero-discharge non-pollution, water saving, economized on electricity, economize on coal, saved raw materials for production, the excellent ecological paper pulp manufacturing technique of fiber quality.
Summary of the invention
The combined production process for ecological paper pulp that the purpose of this invention is to provide a kind of Zero-discharge non-pollution.Traditional fabrication paper pulp is to be applied to the chemical steaming production technology, produce a large amount of waste liquids, for example: produce wheat straw paper pulp with alkaline process, average dry pulp per ton will be discharged more than 300 ton of waste liquid, wherein contain 1461 kilograms of COD, 380 kilograms of BOD, 130 kilograms of SS, usually cause a little paper mill to pollute the phenomenon in a river, seriously influenced contaminated river basins people's living environment, Chinese Government every year is all at the paper pulp production line of constantly closing down some medium and small paper mills, the act that also real genus is had no way out, paper pulp manufacturing technique of the present invention is based on biological decomposition, catalysis is auxilliary, what cooperate various physics intersects manufacturing process with cracking of machinery, be combined into the new production technology of a cover, realized the ecological clean paper pulp making method of Zero-discharge non-pollution no suspended substance, thoroughly solved the blowdown hang-up of paper industry, water in the whole process of production recycles, dribs and drabs does not efflux, this is the ecological balance new technology of environmental protection and energy saving, has filled up the blank of the clean paper pulp production Technology of whole world Zero-discharge non-pollution.
Purpose of the present invention and solve its technical problem underlying and adopt following technical measures to realize.
The combined production process for ecological paper pulp of the Zero-discharge non-pollution that proposes according to the present invention is characterized in zero-emission, and pollution-free, water seal recycles.Be based on biological decomposition, catalysis is auxilliary, cooperate various physics to crack and crack the combined crosswise processing technology with machinery, and formulate different combination processing technologys according to the different biochemical composition of the kind of different plant material (containing timber or non-wood fibrous raw material) and plant, realize zero-emission, pollution-free, no suspended substance, no stink, economize on water, economize on coal, economize on electricity, conservation, the purpose that reduces production costs.
Purpose of the present invention and solve its technical problem underlying and can also be applied to the following technical measures to achieve further.
The combined production process for ecological paper pulp of aforesaid Zero-discharge non-pollution, wherein said biological decomposition, at first to from the white rot flora, filter out some kinds of more outstanding bacterial classifications and, cultivate the fungi strain of biological function with very strong breeding secretase through after hybridization and the mutagenesis.This fungi will participate in whole technological processes of whole slurrying.In each fermentation vat, fungi is torn into breeding a large amount of lignin peroxidases of secretion (LiP) and manganese peroxidase (MnP) in the velutinate plant filament being extruded to rub with the hands, the bacterium enzyme has decomposed the plant lignin, also has bacterium enzymes such as laccase (Laccase) and zytase to participate in the bleaching process of paper pulp jointly.
The combined production process for ecological paper pulp of aforesaid Zero-discharge non-pollution, wherein said catalysis is auxiliary to be to add a spot of base catalyst to be used for softening plant tissue in production process, eliminate the non-cellulose composition in the plant, as: pectin, starch, protein, fat etc., and close part impurity in the plant ash in the energy and make its precipitation, the hydrogen peroxide bleaching in again can the auxiliary multistage oxidation bleaching of catalysis.
The combined production process for ecological paper pulp of aforesaid Zero-discharge non-pollution, wherein said physics cracks technology, it is the expanded principle of applying pressure, rub the plant filament tore with the hands and put in the pressurized tank with water being extruded, be pressurized to more than the 10MPA, the hydrone in the pressurized tank is under high pressure oozed to be got in the plant cell tissue, suddenly pressure release, produce and press quick-fried stress, make string organize further cracking destruction and refinement, and dispose part lignin granule.Physics cracks method can repeatedly cooperate application repeatedly in whole manufacturing procedure, concrete number of applications will be according to raw-material material conditional decision.
The combined production process for ecological paper pulp of aforesaid Zero-discharge non-pollution, wherein said machinery cracks the raw material that is meant being processed and carries out cutting section, roll, stranding is torn, rub crowded, discongest, remove quarrel, defibrination, screening the pulp, serial processing measure such as shove, above-mentioned mechanical processing process at first can destroy the institutional framework of processed plant, and and biological decomposition, catalysis is auxiliary, physics cracks and combines, processed plant material is processed into needed fibre pulp, the pass that in process, will arrange each procedure according to the material and the biochemical composition of different plant materials.
The present invention compares with traditional chemical pulping method, is example with wheat straw paper pulp, can save 99% water, saves 70% electricity, saves 88% coal, saves 57% plant material, reduces by 53% production cost.And the more important thing is, in the entire production process,, do not contain COD, BOD, AOX in the water owing to the leading decomposition of biological bacterium makes the lignin that do not produce various chemical degradations in the whole process and the catabolite of hemicellulose and carbohydrate; Do not produce ss suspended solid, water is not smelly, and the water that last one shove operation discharged all returns in first fermentation vat again and has been recycled, and dribs and drabs does not efflux.The compound of some mineral matters that produced in silt that is brought in the plant material and the production process, post precipitation put together as byproduct, are used for making the brick of using in the architectural engineering.
In sum, the combined production process for ecological paper pulp of Zero-discharge non-pollution of the present invention, have above-mentioned many advantages, this catalysis is auxilliary to be decomposed into the master, cooperates physics to crack to crack combined crosswise with machinery to form a kind of brand-new processing technology, realize the environmental benefit of Zero-discharge non-pollution no suspended substance, this is a kind of ecological paper pulp manufacturing technique of cleaning, is a revolution to traditional paper pulp manufacturing technique, really is the new invention of a novelty, advanced person, practicality.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technological means of the present invention, and can implement according to the content of specification, below with most preferred embodiment of the present invention describe in detail as after.
The specific embodiment
Below Zero-discharge non-pollution that foundation the present invention is proposed its specific embodiment of combined production process for ecological paper pulp, requirement, feature and effect thereof, detailed description as after.
Can using production technology of the present invention, to make the plant material of paper pulp a lot, comprise the leftover bits and pieces sawdust, wood chip, wooden unit of needlebush and the skill bud of readding various timber such as Ye Mu, trees, timber-work etc.; Comprise various thick growth of grass plants and bamboos such as straw, wheat straw, reed, bagasse; Comprise plant bast and fibers such as wingceltis skin, mulberry skin, fiber crops, cotton.It all is the good raw material of ecological system paper pulp.
It is as follows that present embodiment with the reed is that raw material specifies the technological process of production in conjunction with the accompanying drawings:
Raw material sources: Panjin produces the biochemical indicator of reed:
Fibre length: 0.6～1.6mm (arithmetic average length: 1.12mm, weight average length: 1.46mm)
Fiber width: 5.9～13.4um
Fiber length-width ratio: 115
Ash: 5.73% Main Ingredients and Appearance is Sio
2
Lignin: 19.28%
Cellulose: 43.46%
Poly-pentose: 23.13%
Description of drawings
Fig. 1: with reed is raw material ecological paper pulp manufacturing technique schematic flow sheet.
The combined crosswise operation can process qualified reed pulp through above-mentioned some roads, and pulp quality can reach the standard-required of various medium-to-high grade paper such as making writing paper, copy paper, printing paper, coated paper, art paper.
The ecological paper pulp manufacturing technique of the Zero-discharge non-pollution that the present invention proposes, be based on biological decomposition, catalysis is auxilliary, cooperate physics to crack the production technology that cracks combined crosswise with machinery, has realized the environment protection clean paper pulp manufacturing technique of zero-emission, pollution-free, no suspended substance, no stink.
The ecological paper pulp manufacturing technique of the Zero-discharge non-pollution of the present invention that above-mentioned processing technology program like this constitutes all has many saving graces concerning technical staff of the same trade now, and the progressive that possesses skills really.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any type of restriction, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified to the equivalent embodiment of equivalent variations, but the substance of every combined production process for ecological paper pulp scheme that does not break away from Zero-discharge non-pollution of the present invention or according to technical spirit of the present invention to any simple modification equivalent variations and modification that above embodiment does, all belong in the scope of technical solution of the present invention.
Claims (5)
1. the combined production process for ecological paper pulp of a Zero-discharge non-pollution, it is characterized in that zero-emission, pollution-free, water seal recycles, be based on biological decomposition, catalysis is auxilliary, cooperate various physics to crack and crack the combined crosswise processing technology with machinery, and formulate different combination processing technologys according to the different biochemical composition of the kind of different plant material (containing timber or non-wood fibrous raw material) and plant, realize zero-emission, pollution-free, no suspended substance, no stink, economize on water, economize on coal, economize on electricity, conservation, the purpose that reduces production costs.
2. according to the combined production process for ecological paper pulp of claim 1 described Zero-discharge non-pollution, it is characterized in that wherein said biological decomposition, after at first will from the white rot flora, filtering out some kinds of more outstanding bacterial classifications and process hybridization and mutagenesis, cultivate the fungi strain of biological function with very strong breeding secretase, this fungi will participate in whole technological processes of whole slurrying, in each fermentation vat, fungi is torn into breeding a large amount of lignin peroxidases of secretion (LiP) and manganese peroxidase (MnP) in the velutinate plant filament being extruded to rub with the hands, the bacterium enzyme has decomposed the plant lignin, also has bacterium enzymes such as laccase (Laccase) and zytase to participate in the bleaching process of paper pulp jointly.
3. according to the combined production process for ecological paper pulp of claim 1 described Zero-discharge non-pollution, it is characterized in that it is to add a spot of base catalyst to be used for softening plant tissue in production process that wherein said catalysis is assisted, eliminate the non-cellulose composition in the plant, as: pectin, starch, protein, fat etc., and close part impurity in the plant ash in the energy and make its precipitation, the hydrogen peroxide bleaching in again can the auxiliary multistage oxidation bleaching of catalysis.
4. according to the combined production process for ecological paper pulp of claim 1 described Zero-discharge non-pollution, it is characterized in that wherein said physics cracks technology, it is the expanded principle of applying pressure, rub the plant filament tore with the hands and put in the pressurized tank with water being extruded, be pressurized to more than the 10MPA, the hydrone in the pressurized tank is under high pressure oozed to be got in the plant cell tissue, suddenly pressure release, produce and press quick-fried stress, make string organize further cracking destruction and refinement, and dispose part lignin granule.Physics cracks method can repeatedly cooperate application repeatedly in whole manufacturing procedure, concrete number of applications will be according to raw-material material conditional decision.
5. according to the combined production process for ecological paper pulp of claim 1 described Zero-discharge non-pollution, it is characterized in that wherein said machinery cracks the raw material that is meant being processed and carries out cutting section, roll, stranding is torn, rub crowded, discongest, remove quarrel, defibrination, screening the pulp, serial processing measure such as shove, above-mentioned mechanical processing process at first can destroy the institutional framework of processed plant, and and biological decomposition, catalysis is auxiliary, physics cracks and combines, the raw material of processed plant is processed into needed fibre pulp, the pass that in process, will arrange each procedure according to the material and the biochemical composition of different plant materials.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200510091822 CN1804209B (en) | 2004-09-13 | 2005-08-07 | Zero-discharge non-pollution combined production process for ecological paper pulp |
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| CN 200410050394 CN1587503A (en) | 2004-09-13 | 2004-09-13 | Grass pulp producing process combining physical breaking and biological degradation |
| CN200410050394.8 | 2004-09-13 | ||
| CN 200510091822 CN1804209B (en) | 2004-09-13 | 2005-08-07 | Zero-discharge non-pollution combined production process for ecological paper pulp |
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| CN1804209A true CN1804209A (en) | 2006-07-19 |
| CN1804209B CN1804209B (en) | 2010-05-05 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260635B (en) * | 2008-04-16 | 2013-05-29 | 烟台兴达新型环保材料开发有限公司 | Physical extraction method for agriculture waste straw fibre |
| CN103422388A (en) * | 2012-05-24 | 2013-12-04 | 金艳 | Manufacturing method of hemp paper |
| CN108406989A (en) * | 2018-02-11 | 2018-08-17 | 贵港市万升木业有限公司 | A kind of silkwood discards the environmental protection recycling method of sawdust |
| CN114808509A (en) * | 2022-05-11 | 2022-07-29 | 广州市宏晓包装制品有限公司 | Clean production equipment and process for whole pulping and papermaking process |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI420010B (en) * | 2010-09-15 | 2013-12-21 | Yuen Foong Yu Paper Mfg Co Ltd | Method for preparing non-wood fiber pulp |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001064602A1 (en) * | 2000-03-03 | 2001-09-07 | The United Nations University | Biocarbon material production from a modified lignocellulosic biomass |
| CN1300896A (en) * | 2000-07-28 | 2001-06-27 | 张新球 | Mechanical pulping technology removing lignin by biodegradation |
| CN1115437C (en) * | 2000-12-14 | 2003-07-23 | 中国科学院广州化学研究所 | Method for all chlorine free bleaching paper pulp by biological technology |
| AU2003211718A1 (en) * | 2002-02-18 | 2003-09-04 | Lisopharm Ag | Method for producing granular fertilisers |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260635B (en) * | 2008-04-16 | 2013-05-29 | 烟台兴达新型环保材料开发有限公司 | Physical extraction method for agriculture waste straw fibre |
| CN103422388A (en) * | 2012-05-24 | 2013-12-04 | 金艳 | Manufacturing method of hemp paper |
| CN108406989A (en) * | 2018-02-11 | 2018-08-17 | 贵港市万升木业有限公司 | A kind of silkwood discards the environmental protection recycling method of sawdust |
| CN114808509A (en) * | 2022-05-11 | 2022-07-29 | 广州市宏晓包装制品有限公司 | Clean production equipment and process for whole pulping and papermaking process |
| CN114808509B (en) * | 2022-05-11 | 2023-08-22 | 广州市宏晓包装制品有限公司 | Clean production equipment and process for whole pulping and papermaking process |
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| CN1804209B (en) | 2010-05-05 |
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Assignee: Nanchong Chunxing plant fiber technology development Co. Ltd. Assignor: Ge Wenyu Contract fulfillment period: 2007.10.10 to 2027.6.23 contract change Contract record no.: 2008510000007 Denomination of invention: Zero-discharge non-pollution combined production process for ecological paper pulp License type: General permission Record date: 2008.8.19 |
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Free format text: COMMON LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.10.10 TO 2027.6.23; CHANGE OF CONTRACT Name of requester: NANCHONG CHUNXING PLANT FIBER SCIENCE DEVELOPMENT Effective date: 20080819 |
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Address after: 116015, room 101, building 32, mountain screen garden, No. 51 South Central Road, Zhongshan District, Liaoning, Dalian Patentee after: Ge Wenyu Address before: 116011 No. 27 North Street, Xigang District, Liaoning, Dalian Patentee before: Ge Wenyu |
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