CN1395002A - Pulp-making process using biological fermentation method - Google Patents
Pulp-making process using biological fermentation method Download PDFInfo
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- CN1395002A CN1395002A CN 02125571 CN02125571A CN1395002A CN 1395002 A CN1395002 A CN 1395002A CN 02125571 CN02125571 CN 02125571 CN 02125571 A CN02125571 A CN 02125571A CN 1395002 A CN1395002 A CN 1395002A
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Abstract
The pulp-making process by using microbial fermentation process is mainly aimed at solving the problem of black liquor polluting environment, and incldues the following steps: cutting wheat (rice) straw or wood material, moistening cut wheat (rice) straw or wood material, inoculating the moistened cut wheat (rice) straw or wood material with bacteria or actino mycetes, fermenting and heating, continuously fermenting and zymolysis so as to obtain straw (wood) pulp.
Description
Technical field
Technical field under the present invention is a field of papermaking, especially utilizes the technical field of microbe fermentation method papermaking.
Background technology
What the general paper-making technology in each paper mill generally adopted now is that wheat (rice) grassland material, caustic soda, digestant are heated in rotary spherical digester, pressurize, through behind the certain hour, complicated compositions such as lignin in wheat (rice) the grassland material, polysaccharide, pectin, protein are dissolved in the caustic lye of soda, make and separate with cellulose and obtain the method for paper pulp fiber.The shortcoming of this method maximum be the black liquor that produces be difficult to administer or control expense very high.Black liquor enters in the river, causes the severe contamination to river water source.At present, papermaking wastewater yellow, Basin of Huaihe River pollutes the common space in a newspaper of report at water source, downstream.Black liquor is endangering the downstream people's life and life security constantly.State Council hereinafter require 2000 the end of the year Huaihe River flowing water become clear purpose substantially and do not reach yet so far.Each enterprise, governments at all levels all once dropped into substantial contribution and were used for the pollution treatment engineering, but it is still undesirable to produce effects.This has become the Chinese first pollution treatment hang-up.Middle-size and small-size papermaking enterprise is carried out " shutting down, stop, merge and change ", caused great economic loss both for these enterprises, also cause the shortage of cultural paper simultaneously.
About the technological innovation information of paper-making industry, the applicant has not only carried out news retrieval but also carried out professional technical information retrieval.Report related to the present invention among the result of news retrieval is the article of the title of publication in 19 days " Guangming Daily " Mays calendar year 2001 for " Shandong University realizes ' Project 211 ' construction object ".Report in the article, the state natural sciences fund key project that Shandong University carries out " the mechanism research of microbial degradation lignocellulose " has initiative influence, check and accept by the concluding of expert group of state natural sciences fund committee, and obtain Ministry of Education of the state's scientific and technological progress first prize.The applicant retrieves by technical information, and found the relevant patent application data of Shandong University: application number is 01107892.8, and publication number is CN1310258A, and denomination of invention is " Biological Pretreatment prepares the technology of chemical mechanical straw pulp ".Its core technology step is: 1. forage raw material; 2. boiling sterilization; 3. microbial pretreatment; 4. chemical presoaking; 5. the machinery mill is separated; 6. chlorine-free bleaching; 7. bleached pulp.Wherein only be that forage has been made microbial pretreatment, rather than thoroughly make paper pulp with microorganism.Wherein still there is the step of carrying out chemical presoaking with caustic soda.Microorganism that it should be noted that its utilization is a Mycophyta.
Microorganism comprises bacterium, fungi, virus and actinomyces etc.The microorganism that the present invention utilized is bacterium and actinomyces rather than fungi.
By retrieval, the applicant has also found the technology of utilizing microorganism that paper pulp is carried out the technology of chlorine-free bleaching and utilizes the microbial treatment black liquor.These technology and the present invention exist the difference of essence.
Summary of the invention
Technical problem to be solved by this invention is that the characteristic of utilizing microorganism (bacterium is or/and actinomyces) is fermented (fermentation is decomposed and the enzyme decomposition) to paper making raw material and produced paper pulp.
The present invention controls the decomposition of multiple bacterial classification to cellulose, lignin.Suppress bacterial classification to cellulosic destruction, the effect of giving full play to the enzyme that decomposes lignin makes lignin obtain decomposing as far as possible.Decomposing what remove that lignin leans on is lignin decomposition enzyme in the microbial body, and this kind of enzyme only could discharge in the body after microorganism is dead the lignin branch is taken off, and is very important condition so control temperature.
Concrete processing step of the present invention is:
1. shred wheat (rice) grass or timber;
2. the wheat of the moistening chopping of water (rice) grass or timber;
3. inoculated bacteria or actinomyces, fermentation calefaction;
4. continuing fermentation;
5. enzymolysis goes out grass (wood) slurry.
It is identical with original paper technology to produce grass (wood) slurry technology afterwards.
Described forage is wheat straw, straw or its mixture; Described timber is wood chip, wood powder or its mixture; Described forage and timber can alternative each otherly use between the two.
Described bacterial classification is given birth to even mould of spore actinomyces, good hot bacillus, good hot gemma clostridium, the good heat of brown as: common thermophilic actinomyces, good hot tearing.Can release other bacterium or actinomyces by above-mentioned subordinate concept with identical effect.These bacterial classifications can be used with, also can singly use.
The part by weight of described wheat (rice) grass or timber and production bacterial classification is 100: (3～15), preferred proportion is 100: (5～10), optimal proportion is 100: 7 among the embodiment.
Described temperature-rise period is a liberated heat voluntarily when utilizing biofermentation earlier, wheat (rice) grass or timber raw material is heated up, and as early as possible temperature is risen to more than 50 ℃, is controlled at last between 70～80 ℃, can not be above 80 ℃.
Described continuing fermentation process is meant in temperature control fermented between 70～80 ℃ 2～15 days, can not be above 15 days.If fermentation time is long, the cellulose yield is reduced.
Described culture of strains is a prior art.The water-moistened water yield of described usefulness is that those skilled in the art can grasp as the case may be, and such as 1: (1～1.5) can certainly be other suitable ratio.
The invention has the beneficial effects as follows the method for abandoning original chemical pulping process fully and adopting biofermentation.The present invention is in particular in the advantage that existing pulping process is compared: 1. energy savings, exempt of the requirement of rotary spherical digester equipment to harsh technical conditions such as high temperature, high pressure; 2. without caustic soda, exempt the pollution of alkaline waste water (being black liquor) to water source and river environment; 3. the waste water of Pai Chuing can be used as the irrigation water in farmland, also can be used as the water source of plantation lotus rhizome; 4. need not to build the input of sewage disposal device and fund, and the high operating cost of pollution treatment instrument.
What need stress is the waste water handling problem of biological fermentation process slurrying.At first, the waste water of discharging after the biofermentation slurrying can fully utilize.Because not adding during the fermentation anyly has the chemical substance of pollution effect to environment, the water that ejects is near neutral.Monose in the plant material, polysaccharide, pectin, mucilaginous substance, hemicellulose, protein all are the microorganism available materials.Microorganism utilizes these materials can breed growth in a large number.The lignin decomposition enzyme that the microorganism of raised growth discharges at last is the effective enzyme that decomposes lignin.This also is the important place that utilizes the slurrying of biotechnology energy.Contain a large amount of microorganism corpse in the waste water, and contain higher protein in the corpse, thus when being used for the irrigated farmland, this waste water provides good N element for crops, highly beneficial to plant growth.And other organic matter also can improve the farmland because of a large amount of soil compaction problems of using chemical fertilizer to cause.
After this technology is adopted in large-scale paper mill, when the wastewater flow rate of generation is big, enter the river, can in the lower reaches of river small watershed, develop large tracts of land lotus rhizome planting base, to adjust the agricultural products structure, finally waste water consumption in the farmland, and can not cause pollution to the downstream.This situation is adapted at the water-deficient area most and promotes, to reach the purpose of comprehensive utilization.
The specific embodiment
Embodiment 1
Get 100 tons of choppings of wheat straw; Getting 100 tons of water carries out moistening to the wheat straw of shredding; 9 tons of common thermophilic actinomyces are inoculated in the wheat straw heap, when utilizing common thermophilic actinomycete fermentation voluntarily liberated heat make forage heat up the 15 day time of temperature controlled fermentation when being warming up to 70 ℃; Making behind the straw pulp routinely, technology continues deep processing.
Embodiment 2
Get 100 tons of choppings of straw; Getting 130 tons of water carries out moistening to the straw that shreds; The good heat of 6 tons of brown is connected moulds is inoculated in the stack of rice straw, when utilizing the good heat of brown to connect mold fermentation voluntarily liberated heat forage is risen wets the 14 day time of temperature controlled fermentation when being warming up to 80 ℃; Making behind the straw pulp routinely, technology continues deep processing.
Embodiment 3
Get 100 tons of the mixtures of wood chip and wood powder; Getting 150 tons of water carries out moistening to timber; The become reconciled mixture of hot gemma clostridium of spore actinomyces, good hot bacillus is given birth in 7 tons good hot tearings is inoculated in the rollway, when utilizing strain fermentation voluntarily liberated heat make timber heat up the 15 day time of temperature controlled fermentation when being warming up to 75 ℃; Making behind the wood pulp routinely, technology continues deep processing.
Claims (4)
1, a kind of pulp-making process using biological fermentation method, its method step is: 1. shred wheat straw, straw or timber; 2. the forage of the moistening chopping of water or timber; 3. inoculated bacteria or actinomyces, fermentation calefaction; 4. continuing fermentation; 5. enzymolysis goes out grass (wood) slurry.
2, a kind of pulp-making process using biological fermentation method according to claim 1 is characterized in that:
1. Jie Zhong bacterium or actinomyces have common thermophilic actinomyces, good hot tearing to give birth to even mould of spore actinomyces, good hot bacillus, good hot gemma clostridium or the good heat of brown;
2. the part by weight of forage or timber and bacterial classification is 100: (3～15);
3. behind the bacterial classification inoculation, when utilizing biofermentation voluntarily liberated heat forage or timber are heated up, and as soon as possible temperature is risen to more than 50 ℃, be controlled at last between 70～80 ℃, temperature control was fermented between 70～80 ℃ 2～15 days;
4. be controlled at 1 with the water-moistened water yield: between (1～1.5).
3, a kind of pulp-making process using biological fermentation method according to claim 1 and 2, it is characterized in that: the part by weight of forage or timber and bacterial classification is 100: (5～10).
4, a kind of pulp-making process using biological fermentation method according to claim 1 and 2, it is characterized in that: the part by weight of forage or timber and bacterial classification was at 100: 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02125571 CN1267605C (en) | 2002-03-28 | 2002-07-22 | Pulp-making process using biological fermentation method |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN021163561 | 2002-03-28 | ||
| CN02116356.1 | 2002-03-28 | ||
| CN02116356 | 2002-03-28 | ||
| CN 02125571 CN1267605C (en) | 2002-03-28 | 2002-07-22 | Pulp-making process using biological fermentation method |
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| Publication Number | Publication Date |
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| CN1395002A true CN1395002A (en) | 2003-02-05 |
| CN1267605C CN1267605C (en) | 2006-08-02 |
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| CN 02125571 Expired - Fee Related CN1267605C (en) | 2002-03-28 | 2002-07-22 | Pulp-making process using biological fermentation method |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7294228B2 (en) | 2003-02-26 | 2007-11-13 | Yuen Foong Yu Paper Mfg. Co. Ltd. | Biopulp for non-woody fiber plants and biopulping method thereof |
| CN100368628C (en) * | 2006-03-27 | 2008-02-13 | 西北农林科技大学 | Pulp making process employing straw to make environment-friendly paper film |
| US7452445B2 (en) | 2003-02-26 | 2008-11-18 | Yeun Foong Yu Paper Mfg Co. Ltd. | Non-woody fiber mulching mat and production method thereof |
| CN101135119B (en) * | 2007-09-26 | 2010-04-14 | 陈淑华 | Method for manufacturing pulp raw material by biofermentation and culture method for the bacterial |
| CN101225614B (en) * | 2008-02-02 | 2011-07-27 | 陈淑华 | Paper-making technique employing bio-fermentation pulping method instead of chemical pulping technique |
| CN102174399A (en) * | 2010-12-31 | 2011-09-07 | 广西赛尔纸业有限公司 | Method for preparing herbal biological fiber and biological paper pulp |
| CN105237297A (en) * | 2015-09-28 | 2016-01-13 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic mixed fertilizer by using black liquid extracted through pulping of biological enzyme pre-treatment alkaline wheat straw |
| CN105254447A (en) * | 2015-09-21 | 2016-01-20 | 宁夏紫荆花纸业有限公司 | Method for producing organic fertilizer through from black liquor extracted from biological enzyme pretreated wheat straws |
| CN105254448A (en) * | 2015-09-21 | 2016-01-20 | 宁夏紫荆花纸业有限公司 | Method for producing organic fertilizer through from black liquor extracted from biological enzyme pretreated reeds |
| CN105347998A (en) * | 2015-09-28 | 2016-02-24 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic hybrid fertilizer by using black liquor extracted from alkaline pulping with cornstalks pre-treated with biological enzyme |
| CN105367322A (en) * | 2015-09-28 | 2016-03-02 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic mixed fertilizer from black liquor extracted from biological enzyme preprocessed alkaline straw pulp |
-
2002
- 2002-07-22 CN CN 02125571 patent/CN1267605C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7294228B2 (en) | 2003-02-26 | 2007-11-13 | Yuen Foong Yu Paper Mfg. Co. Ltd. | Biopulp for non-woody fiber plants and biopulping method thereof |
| US7452445B2 (en) | 2003-02-26 | 2008-11-18 | Yeun Foong Yu Paper Mfg Co. Ltd. | Non-woody fiber mulching mat and production method thereof |
| CN100368628C (en) * | 2006-03-27 | 2008-02-13 | 西北农林科技大学 | Pulp making process employing straw to make environment-friendly paper film |
| CN101135119B (en) * | 2007-09-26 | 2010-04-14 | 陈淑华 | Method for manufacturing pulp raw material by biofermentation and culture method for the bacterial |
| CN101225614B (en) * | 2008-02-02 | 2011-07-27 | 陈淑华 | Paper-making technique employing bio-fermentation pulping method instead of chemical pulping technique |
| CN102174399A (en) * | 2010-12-31 | 2011-09-07 | 广西赛尔纸业有限公司 | Method for preparing herbal biological fiber and biological paper pulp |
| CN102174399B (en) * | 2010-12-31 | 2013-08-14 | 广西赛尔纸业有限公司 | Method for preparing herbal biological fiber and biological paper pulp |
| CN105254447A (en) * | 2015-09-21 | 2016-01-20 | 宁夏紫荆花纸业有限公司 | Method for producing organic fertilizer through from black liquor extracted from biological enzyme pretreated wheat straws |
| CN105254448A (en) * | 2015-09-21 | 2016-01-20 | 宁夏紫荆花纸业有限公司 | Method for producing organic fertilizer through from black liquor extracted from biological enzyme pretreated reeds |
| CN105237297A (en) * | 2015-09-28 | 2016-01-13 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic mixed fertilizer by using black liquid extracted through pulping of biological enzyme pre-treatment alkaline wheat straw |
| CN105347998A (en) * | 2015-09-28 | 2016-02-24 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic hybrid fertilizer by using black liquor extracted from alkaline pulping with cornstalks pre-treated with biological enzyme |
| CN105367322A (en) * | 2015-09-28 | 2016-03-02 | 宁夏紫荆花纸业有限公司 | Method for producing organic-inorganic mixed fertilizer from black liquor extracted from biological enzyme preprocessed alkaline straw pulp |
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| Publication number | Publication date |
|---|---|
| CN1267605C (en) | 2006-08-02 |
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