CN1781355A - Sea sedge treating method for removing hetoro alga of sea sedge and preventing and curing pest and sea sedge treating agent - Google Patents
Sea sedge treating method for removing hetoro alga of sea sedge and preventing and curing pest and sea sedge treating agent Download PDFInfo
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- CN1781355A CN1781355A CNA2005101291005A CN200510129100A CN1781355A CN 1781355 A CN1781355 A CN 1781355A CN A2005101291005 A CNA2005101291005 A CN A2005101291005A CN 200510129100 A CN200510129100 A CN 200510129100A CN 1781355 A CN1781355 A CN 1781355A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G33/00—Cultivation of seaweed or algae
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
Abstract
A laver treating method utilizes an electrolyzed solution as laver-treating agent which is obtained by electrolyzing an organic acid seawater solution, wherein the organic acid is at least one of organic acids having acid dissociation exponents (pKa) of >=4, for various alga exterminating and disease control of laver, wherein the electrolyzed solution is used in dipping process or dispersing process of the laver net.
Description
Technical field
The present invention relates to a kind of assorted algae expeling of sea sedge and the sea sedge processing method and sea sedge inorganic agent of disease control of being used for, it can be removed effectively culturing and adhering to the assorted algae headed by the diatom and grow nonparasitically upon another plant with wedge shape algae, shank algae etc. of being grown nonparasitically upon another plant on the sea sedge cause the bacterium classes such as needle-like bacterium of needle-like bacteriosis (ス ミ ノ リ disease) in sea sedge leaf surface, and then control can be infected sea sedge leaf somatic cell and bring bacteriosiss such as the green statin disease of very big harm, doubtful white rot, red rot, gyalectiform bacterium disease effectively, thereby cultivates healthy breed sea sedge.
Background technology
All the time, have multiple assorted algae and disease of growing nonparasitically upon another plant on the breed sea sedge, this comprises: the wedge shape algae (Licmophora flabellate) that belongs to diatoms, shank algae (Synedra sp.), the Enteromorpha (Enteromorupha prolofera) that belongs to green algae, flat Enteromorpha assorted algae such as (E.compressa), belonging to bacterium with pythium spp (Pythium) is the red rot of pathogen, to intend oil can (Olpidiopsis) genus bacterium is the gyalectiform bacterium disease of pathogen, and be the needle-like bacteriosis (ス ミ ノ リ disease) of pathogen with Flavobacterium (Flavobacterium) or vibrio (Vibrio) bacterium class, the green statin disease, bacteriosiss such as doubtful white rot etc.
As the expeling of these assorted algaes, disease, prevent and treat method, it generally is the tidal period of utilizing tidewater, the sea sedge net is risen to aerial certain hour carry out drying, algae is driven away, disease control to utilize assorted algae and pathogen and sea sedge to mix for the difference of the tolerance of drying.
But, do in the floating streaming breed of operation at the morning and evening tides that can't utilize tidewater, be difficult to handle the expeling of mix algae, pathogen by the drying of sea sedge net.In addition,, look the different of the kind of disease and degree, only can not fully carry out disease control sometimes by doing operation even in the column support type that the morning and evening tides that can utilize tidewater is done operation is cultured.As its solution, developed acid treatment technology (for example special public clear 56-12601 communique), and be widely used.
In the acid treatment technology that at present institute generally uses, use be with organic acid as the preparation of principal component and be diluted to pH with on-the-spot seawater and be about 2 solution, still but have problem to marine environment generation organic loading.In addition, still have these acid treatments the assorted algae and the disease that are difficult to drive away.
For fear of, solve these the problems of the prior art, people always developmental research energetically to environmental influence little and treatment technology efficiently.As one of its R﹠D direction, attempt utilizing electrolyte exactly.These technology be all utilize the electrolyte that obtains by electrolytic seawater or aqueous chloride solution to sea sedge adhere to diatom, particle-bound bacteria is driven away and carrying out washing treatment etc. (for example spy open flat 7-313007 communique, spy open flat 8-140512 communique, spy and open 2003-174828 communique, spy and open 2003-235373 communique, spy and open 2004-33195 communique, spy and open that 2004-81186 communique, spy are opened the 2004-97042 communique, the spy opens the 2004-155706 communique), but the situation of reality is that these technology also do not become perfect practical technique.
Therefore, in the industry cycle urgent practicability of wishing the as far as possible little and sea sedge treatment technology that validity is high of a kind of load to marine environment.
On the other hand, although there has been this technology that has been established of electrolytic sterilizing method, can not but why using the assorted algae of this technology, assorted bacterium treatment technology in sea sedge breed field be by practicability successfully? it is big as the sea sedge net of 1.8m * 18m that one of them big reason is considered to its processing object, and organic amount is very big.
When utilizing electrolyte to carry out sterilizing, this electrolyte typically uses the strong oxidized water that utilizes diaphragm electrolytic cell and generate in the anode chamber.Employed barrier film is that certain ion that produces of a kind of electrolysis or electronics can see through but be difficult to the film of freely through microsecond structure with the many molecules headed by the water in this electrolytic cell.
On the other hand, as the sea sedge net of handling object, its volume is big and the organic matter amount is big, and because of the assorted algae that will drive away coexists and must optionally drive away with the sea sedge that can not damage, so there is the too high problem of concentration of the sterilization components such as chlorine that can not make electrolyte.
Therefore, the a large amount of electrolyte of essential use in processing, thereby it is just discarded after employed electrolyte and the non-once use, but preferably recycle repeatedly, but when making the circulate electrolyte of having handled the sea sedge net that has a large amount of pollutions, in diaphragm electrolytic cell, be easy to generate the obstruction and the breakage of barrier film, be difficult to equipmentization.
In electrolysis mode, it also is known not using the no barrier film mode of barrier film, but the sterilizing power that does not have diaphragm type is poor usually.It is relevant with the pH value of electrolyte that the reason that sterilizing power is low is considered to.Although free effective chlorine density height in the diaphragm-free electrolysis liquid, the pH value is faintly acid～alkalescent.In order to remedy this shortcoming, also the diaphragm-free electrolysis water that has added hydrochloric acid has been carried out studying (for example special fair 4-94785 communique, special permission No. 2619756 communique, characteristic No. 2627100 communique, spy open flat 10-128336 communique, and the spy opens flat 10-266733 communique).
But when the solution of hydrochloric acid had been added in electrolysis, the hydrochloric acid that is added was also by electrolysis, had therefore that the pH value changes in the electrolytic process, its bactericidal action problem of unstable.
In addition, also knownly a kind ofly in by electrolyte, add various organic acid technical schemes for the pH value that reduces electrolyte (for example the spy opens flat 7-313982 communique, Te Kaiping 8-299961 communique, Te Kaiping 10-314746 communique, the spy opens the 2003-170167 communique), when the acid of using acid disassociation index (pKa) less than 4, lactic acid for example, malic acid, citric acid, tartaric acid, during fumaric acid etc., the acid that the material that the oxidisability such as chlorine that electrolysis generated are strong and these degree of ionization are big reacts, therefore how the redox potential and the effective chlorine density of electrolyte can not rise, and, even in case rise, if end to apply electrolysis power, redox potential and effective chlorine density also can promptly reduce, and the problem of the electrolyte with sterilizing power can't be stably supplied with in existence.
Summary of the invention
The present invention is in view of above-mentioned prior art problems and present situation, and attempt to address these problems, its purpose is to provide a kind of assorted algae expeling of sea sedge and the sea sedge processing method and sea sedge inorganic agent of disease control of being used for, it can be at culturing assorted algae such as the diatom that grown nonparasitically upon another plant on the sea sedge and causing the various diseases of bacteriosis such as needle-like bacteriosis etc. to be carried out effectively and control efficiently or prevention, and can be the least possible to the load of marine environment.
The present inventor is in order to solve above-mentioned prior art problems, carried out positive research, found that: as the method that assorted algae is driven away and the disease bacterium prevents and treats of culturing sea sedge, the electrolyte of the particular characteristics that utilizes electrolysis to add specific organic acid seawater and obtain is handled the sea sedge net, can obtain above-mentioned sea sedge processing method and sea sedge inorganic agent thus, thereby finish the present invention.
That is, the present invention includes following (1)～(a 8) content.
(1) a kind of sea sedge processing method, it is to be used to utilize electrolysis organic acid sea water solution and the electrolyte that obtains carries out that the assorted algae of sea sedge is driven away and the disease control of sea sedge, wherein, above-mentioned organic acid contain acid disassociation index (pKa) be 4 or above organic acid at least a.
(2) as above-mentioned (1) described sea sedge processing method, wherein, organic acid is be selected from propionic acid, acetate, succinic acid at least a.
(3) as above-mentioned (1) or (2) described sea sedge processing method, wherein, the pH value of organic acid sea water solution is 2～5 scope.
(4) as each described sea sedge processing method of above-mentioned (1)～(3), wherein, electrolysis mode is not for being provided with the no diaphragm type of barrier film between anode and negative electrode.
(5) as each described sea sedge processing method of above-mentioned (1)～(4), wherein, the pH value of electrolyte is 3～5 scope, and redox potential be 1140mv or more than, free available chlorine concentration be 1ppm or more than.
(6) a kind of sea sedge processing method, it uses the electrolyte for preparing under each described condition of above-mentioned (1)～(5), and by impregnation process or dispersion treatment the sea sedge net is handled.
(7) a kind of sea sedge processing method, wherein, the preparation of electrolyte is to carry out in the electrolytic cell on being arranged on the sea sedge operation ship, carry out the processing of sea sedge net simultaneously in the treatment trough on being arranged on the sea sedge operation ship, and electrolytic cell and treatment trough are to use pump to carry out the circulation of electrolyte, carry out electrolysis to keep the characteristic of above-mentioned (5) described treatment fluid in the sea sedge processing procedure.
(8) a kind of sea sedge inorganic agent, it contains the electrolyte for preparing under each described condition of above-mentioned (1)～(5).
In the present invention, so-called " sea sedge processing " to be meant in order driving away to grow nonparasitically upon another plant and to hinder the growth of sea sedge, the assorted algae such as diatoms that cause quality to descend culturing on the sea sedge, drive away, control or prevention grow nonparasitically upon another plant or colonize in sea sedge leaf surface and the bacterium class, and the disease bacterium of green statin disease, doubtful white rot etc. that cause needle-like bacteriosis etc., perhaps make purposes such as sea sedge activation, use the present invention, the sea sedge net is immersed in the treatment fluid, or uses treatment fluid by distribution.
Wherein, above-mentioned " assorted algae expeling " is meant and optionally will grows nonparasitically upon another plant or mix the assorted algae such as diatom that give birth on sea sedge and kill and remove.In addition, what is called " expeling of pathogenetic bacteria class, control " is meant and removes killing with the bacterium class that causes green statin disease, doubtful white rot etc. headed by the needle-like bacterium that causes the needle-like bacteriosis.And then so-called " control of disease and prevention " is meant that the treatment of sea sedge disease or prevention sea sedge suffer disease.In addition, so-called " activation of sea sedge " is meant the growth that promotes sea sedge, improves qualities such as the color of sea sedge, bright-coloured degree.
In addition, in the present invention, so-called " dipping (liquid soaks) is handled " is meant and uses cylinder etc. that the grow sea sedge that adheres to of sea sedge is netted Unwinding and goes in the treatment trough and flood certain hour or make sea sedge Netcom cross treatment fluid.In addition, so-called " scatter and handle ", be meant by sea sedge processing ship (being called latent ship again) or square ship and slip into the below of sea sedge net, the sea sedge net is risen in the air, use shower head or diffusing nozzle for liquid etc. to scatter treatment fluid from the below or the top of sea sedge net with propulsion plant.
According to the present invention, a kind of sea sedge processing method and sea sedge inorganic agent can be provided, its can drive away existing inorganic agent effectively the shank algae of the diatom that grows nonparasitically upon another plant that is difficult to drive away, and can drive away the noxious bacteria class that causes the needle-like bacteriosis at short notice simultaneously effectively, in addition, compare with existing inorganic agent, its load to marine environment is little.
Description of drawings
Fig. 1 is an example of embodiment of the present invention, is the schematic diagram that sea sedge that expression is equipped with employed sea sedge treating apparatus in the sea sedge processing method is handled the system of ship.
Fig. 2 is the plane of an example of employed electrolysis generating apparatus in the sea sedge processing method.
Embodiment
Below, embodiment of the present invention are described in detail.
Sea sedge processing method of the present invention is to utilize electrolysis organic acid sea water solution and the electrolyte that obtains carries out that the assorted algae of sea sedge is driven away and the disease control of sea sedge, wherein, above-mentioned organic acid contain acid disassociation index (pKa) be 4 or above organic acid at least a.
In the present invention, be used to prepare electrolyte by electrolyte (stoste) by contain acid disassociation index (pKa) by 4 or above at least a organic acid sea water solution of organic acid constituted, and its pH value is preferably 2～5 scope.
It is 4 or at least a kind (a kind of separately separately or mixture of two or more) of above organic acid, for example propionic acid (pKa 4.87), acetic acid (pKa 4.76), succinic acid (pKa 4.21), butyric acid (pKa 4.8), valeric acid (pKa 4.8), caproic acid (pKa 4.8) etc. that operable organic acid can list acid disassociation index (pKa).From viewpoints such as stink are few and easy to use, preferred succinic acid, acetic acid, propionic acid at least a kind.
In addition, (dissociation constant surpasses 1 * 10-4) acid when using acid disassociation index (pKa) less than 4, lactic acid (pKa 3.86) for example, malic acid (pKa 3.40), citric acid (pKa 3.16), tartaric acid (pKa 3.06), during fumaric acid (pKa 3.02) etc., the acid that the material that the oxidisability such as chlorine that electrolysis produces are strong and these degree of ionization are big reacts, thereby the redox potential of electrolyte (ORP) and free available chlorine (ACC) concentration do not rise, and, even in case rise, when stopping applying electrolysis power, redox potential and free available chlorine concentration also can reduce rapidly, the problem of the electrolyte with sterilizing power can not be stably supplied with in existence, because of rather than preferred.
In the present invention, as organic acid, be 4 or during at least a kind of above organic acid when using above-mentioned acid disassociation index (pKa), reactive low with electrolyte, be difficult for causing the decline of redox potential and effective chlorine density, therefore can supply with stable electrolyte.
In addition, if acid disassociation index (pKa) be 4 or above organic acid, for example succinic acid, acetic acid, propionic acid among compare, the reactivity of acetic acid is high slightly, and succinic acid and propionic acid are much at one, all have the reactive low character with electrolyte.If other rerum natura of these two kinds of organic acids relatively, succinic acid does not almost have volatility at normal temperatures, and the volatility height of acetic acid and propionic acid is emitted foul smell in the use on-the-spot meeting of electrolyte, therefore when using in a large number as the sea sedge inorganic agent that uses under open condition, usability is relatively poor.On the other hand, although succinic acid has good character aspect the stability of electrolyte and the fixedness under the normal temperature, but it is not so good to the dissolubility of water, from this point, in preparation some inconvenience a little during as the stoste of the aqueous solution of electrolysis adjuvant.
Therefore, in the present invention, and then from viewpoints such as usability, preferably be principal component (in organic acid, account for 50 weight % or more than), and then also contain propionic acid and/or acetate with the succinic acid.Can supply with better electrolyte thus.
In the present invention, can directly be used natural sea-water by the solvent of electrolyte, also can further in natural sea-water, add the electrolyte ingredient such as salt, calcium chloride of Sq (1～10 weight %), also can use by salinity the artificial seawater that saline solution constituted identical in addition with seawater.
In addition, preferably above-mentioned pH value by electrolytic solution (stoste) is adjusted to 2～5 scope.The adjusting of this pH value can wait and regulate according to employed organic acid kind, usage amount, and with respect to the total amount of sea water solution, the concentration of acid such as above-mentioned organic acid is generally 0.01～0.5 weight % (about 0.00001～0.1mol).
If this pH value less than 2, the then chlorine (Cl of molecular state in the electrolyte
2) contain proportional rising, the danger that produces chlorine raises, and on the other hand, if pH value surpasses 5, then kills the algae bactericidal effect and descends, so be not preferred.
In the present invention, electrolyte obtains in the following way: be dissolved with contain above-mentioned acid disassociation index (pKa) be 4 or at least a organic acid of above organic acid and pH value be to put into the electrode of forming by anode and negative electrode in the sea water solution (by electrolyte) of 2～5 scope, to wherein feeding DC current, obtain electrolyte.In addition, from easily device being guarded the angle of management,, the no diaphragm type of barrier film is not set between negative and positive the two poles of the earth preferably as electrolysis mode.
In order more effectively to bring into play effect of the present invention, resulting electrolyte is as long as the pH value is acid, but preferred pH value is 3～5.If the pH value less than 3 of this electrolyte, the then chlorine (Cl of the molecular state of chlorine compound in the electrolyte
2) contain proportional rising, the danger that produces chlorine increases, on the other hand, if pH value above 5, the relatively poor hypochlorite ion (OCl of sterilizing power then
-) ratio raise, can find that the algae bactericidal effect reduces extremely, be not preferred therefore.Therefore, preferred pH value is 3～5 scope, can prevent to produce pernicious gas in this pH scope, and the ratio of sterilization, hypochlorous acid (HOCl) that algae killing effect is high increases.
In addition, the redox potential (ORP) of employed electrolyte was so long as be expressed as the 1140mv or the above state of oxidation with the hydrogen electrode scaled value during sea sedge was handled, and demonstrating the characteristic that produces 1ppm or above free available chlorine concentration (ACC) gets final product, preferred redox potential (ORP) be 1150mv or more than, 1150～1220mv more preferably, effective chlorine density (ACC) be preferably 3ppm or more than, 3～15ppm more preferably.
In the present invention, for pH value, redox potential (ORP) state of the electrolyte that keeps being suitable for the above-mentioned scope of effective sea sedge in handling, preferably in the implementation process that sea sedge is handled, also continue complement lysis new acid acid solution with continue to apply the voltage (energising) that is used for electrolysis.Acid solution is preferably by being that index is replenished with the liquid-feeding pump of pH meter interlock, with the pH value, the continuation of energising is preferably by being that index is switched on the supply unit of residual chlorine meter interlock, with free available chlorine concentration, or by being that index is switched on the supply unit of oxidation-reduction potentiometer interlock, with the redox potential.
What in the present invention, employed sea sedge inorganic agent (liquid) was made up of the electrolyte of preparation under these conditions in treatment trough.By in filling the treatment trough of this electrolyte, carrying out impregnation process (infusion process, impregnation process), perhaps this electrolyte is spread on this breeds sea sedge (distribution method, scatter processing) and carry out the processing of sea sedge culturing sea sedge.
In these sea sedges are handled, the time of contact of electrolyte and sea sedge, the processing time of being, according to the characteristic of prepared electrolyte and as the difference of the assorted algae of processing object, pathogen and difference is preferably 1 second～1 minute, more preferably 5 seconds～30 seconds.
After in above-mentioned treatment trough, handling, put back to the sea sedge net in the seawater immediately and proceed common breed.
In the present invention, the electrolysis of above-mentioned organic acid sea water solution is to carry out in the electrolytic cell on being arranged on the sea sedge operation ship, and use circulating pump prepared electrolyte to be supplied in the treatment trough that is arranged on equally on the sea sedge operation ship, in this treatment trough, carry out the processing of sea sedge.Between electrolytic cell and the treatment trough, use circulating pump in running, to carry out the circulation of electrolyte all the time.Electrolytic cell and treatment trough can be in abutting connection with and incorporate structure also can be the diverse location that is separately positioned on operation ship, and the structure that connects by circulating pump, circulation pipe.
For employed electrode in the employed electrolytic cell among the present invention, anode can use carbon, platinum, palladium, iridium etc., considers from aspects such as electrolytic efficiencies, preferably uses platinum or platinum electrode coated.Negative electrode can use iron, stainless steel or titanium etc., from etch-proof viewpoint, preferably uses stainless steel or titanium.
In the present invention, as carrying out the concrete device that sea sedge is handled continuously, can use lift-launch for example shown in Figure 1 sea sedge treating apparatus 20 on sea sedge processing ship 10.Among the figure, 21 is that treatment trough, 22 is managed for electrolyte replenishes, 28 is that electrolyte recovery tube, 29 is the sea sedge net for free chloro concentration controller or ORP controller, 27 for pH value controller, 26 with sour stoste storage tank, 25 for electrolysis for electrolytic cell, 24 for electrolyte storage tank, 23.
Employed above-mentioned electrolyte is that to contain acid disassociation index (pKa) by electrolysis be 4 or the electrolyte that obtains of above at least a organic acid sea water solution of organic acid in treatment trough 21, therefore to the dispel effects of diatomss such as shank algae and to the dispel effect height of disease mushrooms such as needle-like bacterium, these assorted algae, disease mushroom are only contacted 5 seconds with electrolyte～about 20 seconds, just can access almost 100% dispel effect.
In the present embodiment, the assorted algae that can culture sea sedge is at short notice continuously driven away and disease control.That is, if the processing ship of system shown in Figure 1 forwards moves with for example about 10～20 meters/minute speed, then processed sea sedge net 29 can be implemented the sea sedge processing in 5 seconds～30 seconds in treatment trough 21.
In the present invention, as shown in Figure 1, the preparation of employed electrolyte is to carry out in the electrolytic cell 23 that is being arranged on the sea sedge operation ship 10 in treatment trough 21, makes it to proceed free available chlorine concentration or the redox potential (ORP) of electrolysis to keep setting in linkage with the free chloro concentration meter or the oxidation-reduction potentiometer (free chloro concentration controller or ORP controller 26) of watch-dog.In addition, the pH value of electrolyte preferably by with the liquid-feeding pump of pH meter (pH controller 25) interlock from electrolysis with the sour stoste of sour stoste storage tank 24 supplies, thereby be adjusted to the pH value of setting all the time.
In addition, the variation of the less pH value of electrolyte can not exert an influence to algae killing effect, bactericidal effect, but the above-mentioned organic acid concentration that the pH value is exerted an influence can produce very big influence to the redox potential of electrolyte, even influence algae killing effect, bactericidal effect, therefore preferably in running, regulate the pH value all the time.
Sea sedge of the present invention is handled operation, for example as shown in Figure 1, can be handled by sea sedge and carry out when ship 10 slips into the below of sea sedge net 29.Move the sea sedge net 29 that imports in the treatment trough 21 by the propelling of sea sedge processing ship 10 and be submerged in the electrolyte, aloft move along with handling advancing of ship 10 then, and get back to the sea at the rear of handling ship 10 towards the rear.During this, be about 10～20 meters/minute if handle the gait of march of ship, and the length of the y direction of treatment trough 21 is 2～4m, then the immersion liquid processing time in treatment trough 21 is 6～24 seconds short period.In addition, the y direction of the treatment trough on the sea sedge processing ship is of a size of 2～4 meters.
In the present invention, can supply with the electrolyte of preparation under these conditions continuously, handle by impregnation process or distribution and carry out the sea sedge processing to treatment trough 21.
The present invention of Gou Chenging as mentioned above, be that to utilize electrolysis to contain acid disassociation index (pKa) be 4 or the electrolyte that obtains of above at least a organic acid sea water solution of the organic acid assorted algae that carries out sea sedge is driven away and the disease control of sea sedge, in electrolytic process, can observe the rapid rising of redox potential (ORP) and free available chlorine concentration (ACC), can access the pH value and change little and stable electrolyte, simultaneously, after stopping energising, even through 24 hours, electrolyte also has good stable, therefore can remove the shank algae that adheres to diatom that existing inorganic agent is difficult to drive away etc. effectively, and can prevent and treat effectively and continuously at short notice, obtain a kind of sea sedge processing method and the sea sedge inorganic agent that can cultivate healthy breed sea sedge with the disease mushroom headed by the needle-like bacteriosis.
Embodiment
Below, by the embodiment that constitutes the test example the present invention is carried out more specific description.
In following embodiment 1～3, use the sea sedge treating apparatus with treatment trough 1 (total capacity is 4 liters) and electrolytic cell 2 (total capacity is 1 liter) shown in Figure 2.Employed DC current is to supply with by dc constant voltage and constant-current supply PR36-3A that Kenwood T.M.I company makes in electrolysis.Electrolysis mode is no diaphragm type, and what electrolysis electrode used is following test example 1～3 described electrode.In order to prevent corrosion, circulating pump 3 uses its liquid contacting part to divide the plastic pump that does not use metal, and its internal circulating load is whole amount of liquid circulation in 3 minutes 1 time.
The mensuration of ORP and pH value is to use the Personal pH/ORP of Dongxing chemical company manufacturing to count and measures, and " residual chlorine is measured with Rapid DPD reagent " that effective chlorine density (ACC) is to use Northeast chemical company to make detected.
(test example 1)
Use hydrochloric acid, succinic acid, acetic acid and propionic acid to prepare the sea water solution (by electrolyte) of a plurality of pH levels respectively, carry out electrolysis then respectively, measure the variation that the characteristic of each electrolyte produces along with the variation of conduction time.
In addition, use the electrolyte of energising beginning after 30 minutes, carry out as the bactericidal assay of killing algae test, needle-like bacterium of the shank algae that adheres to diatom of sea sedge and wedge shape algae and to the somatic nocuity test of sea sedge leaf.In killing algae test, bactericidal assay, the time is short more then high more to the dispel effect that adheres to diatom and needle-like bacterium, and in the nocuity test, the time is long more then just more little to the injury (harmful effect) that sea sedge produced.
In electrolysis, anode uses carbon, and negative electrode uses iron, and electrolysis power is 6V * 0.35A.
The temperature that the preparation of electrolyte and sea sedge leaf body are handled is 11 ℃.
The result of these tests is shown in following table 1～table 4.
Table 1 [adding the electrolyte of the seawater of hydrochloric acid]
| Concentration (%) | The electrolyte characteristic | Conduction time (minute) | Kill shortest time algae time | The sterilizing time shortest time | The sea | ||||
| 0 | 5 | 10 | 15 | 30 | |||||
| 0.0105 | ORP (mv) | 827 | 1146 | 1161 | 1166 | 1184 | 5 seconds | 5 seconds | 30 seconds |
| ACC (ppm) | 0 | 2.5 | 5.5 | 6.5 | 10.2 | ||||
| pH | 3.00 | 3.01 | 3.06 | 3.09 | 3.06 | ||||
| 0.007 | ORP (mv) | 606 | 1136 | 1157 | 1161 | 1171 | 4 | 4 | 4 minutes |
| ACC (ppm) | 0 | 0.5 | 4.7 | 5.5 | 7.5 | ||||
| pH | 3.93 | 4.32 | 4.55 | 4.91 | 5.31 | ||||
| 0.006 | ORP (mv) | 607 | 9.8 | 1138 | 1148 | 1159 | 8 | 8 | 8 minutes |
| ACC (ppm) | 0 | 0 | 0.9 | 2.9 | 5.1 | ||||
| pH | 5.03 | 5.17 | 5.24 | 5.35 | 5.56 | ||||
ACC: free available chlorine concentration
Table 2 [adding the electrolyte of the seawater of succinic acid]
| Concentration (%) | The electrolyte characteristic | Conduction time (minute) | Kill shortest time algae time | The sterilizing time shortest time | The sea | ||||
| 0 | 5 | 10 | 15 | 30 | |||||
| 0.40 | ORP (mv) | 1040 | 1146 | 1159 | 1164 | 1183 | 5 seconds | 5 | 4 minutes |
| ACC (ppm) | 0 | 2.5 | 5.1 | 6.1 | 10.0 | ||||
| pH | 3.00 | 3.04 | 3.06 | 3.07 | 3.07 | ||||
| 0.04 | ORP (mv) | 850 | 1147 | 1163 | 1170 | 1192 | 5 seconds | 5 | 4 minutes |
| ACC (ppm) | 0 | 2.7 | 5.9 | 7.3 | 11.8 | ||||
| pH | 4.00 | 3.99 | 4.02 | 4.06 | 4.11 | ||||
| 0.017 | ORP (mv) | 649 | 1142 | 1155 | 1161 | 1172 | 10 seconds | 10 | 4 minutes |
| ACC (ppm) | 0 | 1.7 | 4.3 | 5.5 | 7.7 | ||||
| pH | 5.00 | 5.03 | 5.10 | 5.15 | 5.29 | ||||
ACC: free available chlorine concentration
Table 3 [adding the electrolyte of the seawater of acetic acid]
| Concentration (%) | The electrolyte characteristic | Conduction time (minute) | Kill shortest time algae time | The sterilizing time shortest time | The sea | ||||
| 0 | 5 | 10 | 15 | 30 | |||||
| 0.40 | ORP (mv) | 750 | 410 | 367 | 305 | 1170 | 5 seconds | 5 | 4 minutes |
| ACC (ppm) | 0 | 0 | 0 | 0.5 | 7.0 | ||||
| pH | 3.08 | 3.08 | 3.08 | 3.09 | 3.10 | ||||
| 0.04 | ORP (mv) | 520 | 1100 | 1150 | 1155 | 1175 | 5 seconds | 5 | 4 minutes |
| ACC (ppm) | 0 | 0 | 4.0 | 4.8 | 8.0 | ||||
| pH | 4.00 | 4.00 | 4.00 | 4.10 | 4.02 | ||||
| 0.02 | ORP (mv) | 670 | 1095 | 1145 | 1150 | 1165 | 10 seconds | 10 | 4 minutes |
| ACC (ppm) | 0 | 0 | 3.0 | 4.0 | 6.0 | ||||
| pH | 5.10 | 5.10 | 5.15 | 5.15 | 5.20 | ||||
ACC: free available chlorine concentration
Table 4 [adding the electrolyte of the seawater of propionic acid]
| Concentration (%) | The electrolyte characteristic | Conduction time (minute) | Kill shortest time algae time | The sterilizing time shortest time | The sea | ||||
| 0 | 5 | 10 | 15 | 30 | |||||
| 0.40 | ORP(mv) | 880 | 1060 | 1140 | 1155 | 1180 | 5 seconds | 5 | 4 minutes |
| ACC(ppm) | 0 | 0.1 | 2.8 | 5.0 | 10.0 | ||||
| pH | 3.24 | 3.24 | 3.24 | 3.25 | 3.26 | ||||
| 0.04 | ORP(mv) | 321 | 1062 | 1145 | 1157 | 1190 | 5 seconds | 5 | 4 minutes |
| ACC(ppm) | 0 | 0.5 | 2.5 | 5.2 | 11.0 | ||||
| pH | 4.30 | 4.30 | 4.33 | 4.50 | 4.30 | ||||
| 0.02 | ORP(mv) | 280 | 1050 | 1140 | 1150 | 1175 | 10 seconds | 10 | 4 minutes |
| ACC(ppm) | 0 | 0.5 | 2.0 | 4.8 | 7.2 | ||||
| pH | 5.15 | 5.20 | 5.20 | 5.25 | 5.30 | ||||
ACC: free available chlorine concentration
From the result of table 1 as can be seen, in the seawater that adds hydrochloric acid, when the pH value before the electrolysis is 3.00, do not find that the pH value because of electrolysis big variation takes place, can produce free available chlorine (ACC) well, the algae killing effect of diatoms is also high.But, the pH value be 4 or above by electrolyte in, pH rises bigger, the ACC concentration of generation is lower, the remarkable variation of diatom algae killing effect and bactericidal effect.This may be because hydrochloric acid also by electrolysis, and because a little less than the cushioning effect of hydrochloric acid, the altering a great deal of pH value, therefore, diatom kills algae and acts on and also dying down.
In contrast, from last table 2～4 as can be known, in succinic acid electrolyte, acetic acid electrolyte and propionic acid electrolyte, it is all very slight that the pH value is that the pH value in arbitrary electrolyte of 3～5 changes, and the generation of ACC in order.Therefore conclude and to generate the electrolyte that diatom kills algae and bactericidal effect height and stable performance.
(test example 2)
Electrolysis is by following sea water solution constituted by electrolyte: added the sea water solution of the propionic acid of the acetic acid of sea water solution, the succinic acid that has added 0.05 weight % and 0.025 weight % of propionic acid of sea water solution, the sea water solution that has added the hydrochloric acid of 0.007 weight %, the succinic acid that has added 0.05 weight % and 0.05 weight % of acetic acid of the succinic acid of 0.05 weight % and 0.05 weight % and 0.025 weight %, measure in the galvanization and the electrolyte characteristic after stopping to switch on over time.In electrolytic process, use embodiment 1 employed electrolytic cell, but anode uses platinum, negative electrode uses stainless steel, carries out electrolysis with the electrolysis power of 6V * 0.5A.In addition, use the electrolyte of energising beginning after 30 minutes, carry out as the grow nonparasitically upon another plant bactericidal assay of killing algae test, needle-like bacterium of the shank algae of diatom and wedge shape algae and of sea sedge to the somatic nocuity test of sea sedge leaf.
The liquid handling temperature of the preparation of electrolyte and sea sedge is 11 ℃.
These result of the tests are shown in following table 5 and table 6.
Table 5
[added 0.05 weight % succinic acid+0.05 weight % acetic acid seawater electrolyte, added the electrolyte of seawater of the hydrochloric acid of 0.007 weight %]
[having added the electrolyte of seawater of propionic acid of succinic acid+0.05 weight % of 0.05 weight %]
[electrolyte of the seawater of the propionic acid of the acetic acid of the succinic acid of 0.05 weight %+0.025 weight %+0.025 weight %]
| Concentration (%) | The electrolyte characteristic | Conduction time (minute) | Time after stopping (hour) | |||||
| 0 | ?5 | 10 | 20 | 30 | ?3 | 24 | ||
| Succinic acid+acetic acid | ?ORP(mv) | 785 | ?1159 | 1175 | ?1203 | 1234 | ?1228 | 1194 |
| ?ACC(ppm) | 0 | ?5 | 9 | ?13 | 13 | ?10 | 5 | |
| ?pH | 3.43 | 3.47 | ?3.53 | 3.54 | ?3.50 | 3.48 | ||
| Hydrochloric acid | ?ORP(mv) | 600 | ?333 | 278 | ?1173 | 1187 | ?1185 | 1161 |
| ?ACC(ppm) | 0 | ?0 | 3 | ?9 | 12 | ?13 | 6 | |
| ?pH | 3.4l | 3.38 | ?3.73 | 4.44 | ?4.50 | 5.02 | ||
| Succinic acid+propionic acid | ?ORP(mv) | 803 | ?1156 | 1180 | ?1210 | 1230 | ?1230 | 1225 |
| ?ACC(ppm) | 0 | ?5 | 10 | ?12 | 14 | ?14 | 10 | |
| ?pH | 3.57 | 3.57 | ?3.58 | 3.58 | ?3.57 | 3.57 | ||
| Succinic acid+acetic acid+propionic acid | ?ORP(mv) | 790 | ?1157 | 1170 | ?1195 | 1210 | ?1210 | 1196 |
| ?ACC(ppm) | 0 | ?5 | 10 | ?9 | 13 | ?13 | 10 | |
| ?pH | ?3.50 | 3.51 | ?3.51 | 3.52 | ?3.51 | 3.50 | ||
ACC: free available chlorine concentration
Table 6
| Concentration (%) | Kill the algae time (shortest time) | Sterilizing time (shortest time) | The sea sedge injury time |
| Succinic acid+acetic acid | 5 seconds | 5 | 4 minutes |
| Hydrochloric acid | 5 seconds | 5 seconds | 30 seconds |
| Succinic acid+propionic acid | 5 seconds | 5 | 4 minutes |
| Succinic acid+acetic acid+propionic acid | 5 seconds | 5 | 4 minutes |
Can find from the result of last table 5 and table 6: the sea water solution of the propionic acid of the acetic acid of sea water solution, the succinic acid that has added 0.05 weight % and the 0.025 weight % of the propionic acid of sea water solution, the succinic acid that has added 0.05 weight % and the 0.05 weight % of the acetic acid of succinic acid that has added 0.05 weight % and 0.05 weight % and 0.025 weight %, after energising, can observe the rapid rising of redox potential (ORP) and free available chlorine concentration (ACC), can obtain the pH value and change little and stable electrolyte.Even the stability of this electrolyte stop the energising after also can be maintained through 24 hours.Therefore conclude and to generate the electrolyte that diatoms kills algae and bactericidal effect height and stable performance.
In contrast, the sea water solution that has added hydrochloric acid is after energising, and the rising of ORP and ACC need expend time in, although electrolyte has demonstrated oxidisability, needs 20 minutes conduction time.In addition, when ORP raises, begin the pH value and just rise, energising can observe after 30 minutes pH value rising 1.0 or more than.Even the rising of this pH value stop the energising after also can continue, can observe after 24 hours the pH value further raise 0.5 or more than.In this test, also be to add succinic acid, acetic acid than adding the electrolyte that hydrochloric acid more can generate stability.
(test example 3)
Electrolysis is as propionic acid, acetic acid, the lactic acid of monocarboxylic acid, as the succinic acid of dicarboxylic acids, malic acid, tartaric acid, fumaric acid and as the sea water solution of tricarboxylic citric acid, measure after the galvanization neutralization stops to switch on the electrolyte characteristic over time.
Each organic acid concentration is 0.1%, 0.2% and 0.4%, and electrolysis is to use in the test example 1 and 2 employed experimental provision to implement.Electrolysis electrode is that anode uses carbon, and negative electrode uses titanium, and electrolysis power is 6V * 0.2A.Electrolysis temperature is 11 ℃.
These result of the tests are as shown in table 7 below.
Table 7
[adding the electrolyte of the organic acid seawater of various concentration]
| Organic acid (pKa) | Concentration (%) | The electrolyte characteristic | Conduction time (minute) | After stopping to switch on (minute) | |||||
| 0 | 5 | 10 | 20 | 40 | 10 | 40 | |||
| Propionic acid (4.87) | 0.1 | ORP(mv) | 226 | 1065 | 1144 | 1160 | 1181 | 1179 | 1174 |
| ACC (ppm) | 0 | 0.5 | 2.1 | 5.3 | 9.6 | 9.2 | 8.1 | ||
| pH | 3.85 | 3.85 | |||||||
| 0.2 | ORP(mv) | 948 | 1144 | 1152 | 1160 | 1175 | 1173 | 1169 | |
| ACC (ppm) | 0 | 2.1 | 3.7 | 5.3 | 8.4 | 7.9 | 7.1 | ||
| pH | 3.52 | 3.55 | |||||||
| 0.4 | ORP(mv) | 886 | 1065 | 1147 | 1161 | 1173 | 1170 | 1166 | |
| ACC (ppm) | 0 | 0.1 | 2.7 | 5.5 | 7.9 | 7.8 | 6.5 | ||
| pH | 3.24 | 3.27 | |||||||
| Acetic acid (4.76) | 0.1 | ORP(mv) | 331 | 1121 | 1155 | 1169 | 1181 | 1181 | 1178 |
| ACC (ppm) | 0 | 0.5 | 4.3 | 7.1 | 9.6 | 9.6 | 9.0 | ||
| pH | 3.62 | 3.66 | |||||||
| 0.2 | ORP(mv) | 911 | 1145 | 1154 | 1168 | 1178 | 1179 | 1177 | |
| ACC (ppm) | 0 | 2.3 | 4.1 | 6.9 | 9.0 | 9.2 | 8.8 | ||
| pH | 3.32 | 3.36 | |||||||
| 0.4 | ORP(mv) | 750 | 410 | 367 | 280 | 1170 | 1170 | 1167 | |
| ACC (ppm) | 0 | 0 | 0 | 0.5 | 7.3 | 7.3 | 6.7 | ||
| pH | 3.08 | 3.10 | |||||||
| Lactic acid (3.86) | 0.1 | ORP(mv) | 261 | 1133 | 1143 | 1143 | 1129 | -27 | 192 |
| ACC (ppm) | 0 | 0.1 | 1.9 | 1.9 | 0.5 | 0.1 | 0 | ||
| pH | 3.03 | 2.96 | |||||||
| 0.2 | ORP(mv) | 886 | 1132 | 1126 | 172 | -132 | -129 | -111 | |
| ACC (ppm) | 0 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0 | ||
| pH | 2.71 | 2.68 | |||||||
| 0.4 | ORP(mv) | 585 | 369 | 298 | 141 | -122 | -119 | -103 | |
| ACC (ppm) | 0 | 0 | 0 | 0.1 | 0 | 0 | 0 | ||
| pH | 2.47 | 2.46 | |||||||
[adding the electrolyte of the organic acid seawater of various concentration] (continuing)
| Organic acid (pKa) | Concentration (%) | The electrolyte characteristic | Conduction time (minute) | After stopping to switch on (minute) | |||||
| 0 | 5 | 10 | 20 | 40 | 10 | 40 | |||
| Succinic acid (4.21) | 0.1 | ORP(mv) | 345 | 1119 | 1148 | 1159 | 1175 | 1174 | 1170 |
| ACC (ppm) | 0 | 0.5 | 2.9 | 5.1 | 8.4 | 8.1 | 7.3 | ||
| pH | 3.45 | 3.42 | |||||||
| 0.2 | ORP(mv) | 958 | 1150 | 1158 | 1164 | 1176 | 1177 | 1175 | |
| ACC (ppm) | 0 | 3.3 | 4.9 | 6.1 | 8.6 | 8.8 | 8.4 | ||
| pH | 3.11 | 3.14 | |||||||
| 0.4 | ORP(mv) | 996 | 1145 | 1156 | 1166 | 1181 | 1181 | 1177 | |
| ACC (ppm) | 0 | 2.3 | 4.5 | 6.5 | 9.6 | 9.6 | 8.8 | ||
| pH | 2.87 | 2.80 | |||||||
| Malic acid (3.40) | 0.1 | ORP(mv) | 283 | 1128 | 1136 | 278 | 216 | 159 | 210 |
| ACC (ppm) | 0 | 0.5 | 0.5 | 0.1 | 0.1 | 0 | 0 | ||
| pH | 2.94 | 2.85 | |||||||
| 0.2 | ORP(mv) | 540 | 1112 | 255 | -11 | -139 | -135 | -114 | |
| ACC (ppm) | 0 | 0.1 | 0.1 | 0 | 0 | 0 | 0 | ||
| pH | 2.62 | 2.62 | |||||||
| 0.4 | ORP(mv) | 539 | 320 | 278 | 179 | -114 | -110 | 45 | |
| ACC (ppm) | 0 | 0.1 | 0.1 | 0 | 0 | 0 | 0 | ||
| pH | 2.39 | 2.40 | |||||||
| Tartaric acid (3.06) | 0.1 | ORP(mv) | 528 | 1116 | 1132 | 1120 | -129 | -127 | -59 |
| ACC (ppm) | 0 | 0.5 | 0.5 | 0.5 | 0 | 0 | 0 | ||
| pH | 2.72 | 2.71 | |||||||
| 0.2 | ORP(mv) | 620 | 1137 | 1133 | 221 | -102 | -86 | 112 | |
| ACC (ppm) | 0 | 0.7 | 0.5 | 0.1 | 0 | 0 | 0 | ||
| pH | 2.46 | 2.46 | |||||||
| 0.4 | ORP(mv) | 534 | 336 | 234 | 106 | -108 | -102 | -75 | |
| ACC (ppm) | 0 | 0.5 | 0.1 | 0.1 | 0 | 0 | 0 | ||
| pH | 2.24 | 2.25 | |||||||
[adding the electrolyte of the organic acid seawater of various concentration] (continuing)
| Organic acid (pKa) | Concentration (%) | The electrolyte characteristic | Conduction time (minute) | After stopping to switch on (minute) | |||||
| 0 | 5 | 10 | 20 | 40 | 10 | 40 | |||
| Fumaric acid (3.02) | 0.1 | ORP (mv) | 412 | 193 | 72 | 14 | -15 | -18 | -3 |
| ACC (ppm) | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| pH | 2.63 | 2.62 | |||||||
| 0.2 | ORP (mv) | 362 | 226 | 151 | 93 | 53 | 67 | 52 | |
| ACC (ppm) | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| pH | 2.38 | 2.40 | |||||||
| 0.4 | ORP (mv) | 401 | 530 | 205 | 143 | 135 | 131 | 148 | |
| ACC (ppm) | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| pH | 2.18 | 2.19 | |||||||
| Citric acid (3.16) | 0.1 | ORP (mv) | 480 | 992 | 1131 | 1130 | -131 | -126 | 75 |
| ACC (ppm) | 0 | 0.1 | 0.5 | 0.5 | 0 | 0 | 0 | ||
| pH | 2.93 | 2.90 | |||||||
| 0.2 | ORP (mv) | 843 | 387 | 301 | 212 | -106 | -96 | 28 | |
| ACC (ppm) | 0 | 0.1 | 0.1 | 0 | 0 | 0 | 0 | ||
| pH | 2.60 | 2.61 | |||||||
| 0.4 | ORP (mv) | 553 | 346 | 258 | 201 | -68 | 49 | 94 | |
| ACC (ppm) | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| pH | 2.38 | 2.37 | |||||||
From the result of last table 7 as can be known, after the energising beginning, redox potential (ORP) and free available chlorine concentration (ACC) even rise the most soon and in high concentrated acid solution, also can generate these free available chlorines etc. oxidation material, what also can stably keep is propionic acid and succinic acid.It is acetic acid that the next one demonstrates ejusdem generis, but in the situation of acetic acid, if concentration raises, then the generation of the rising of ORP and ACC all needs the time.
The acid disassociation index (pKa) of these propionic acid, succinic acid and acetic acid is respectively 4.87,4.21 and 4.76, all is that pKa is the acid more than 4.
In contrast, in lactic acid, malic acid and tartaric low concentration electrolyte, can confirm the rising to a certain degree of ORP, although and be that low concentration has also produced ACC.But,, can find that then ORP reduces on the contrary and demonstrates negative potential if conduction time is elongated.In addition, even stop after the energising, this variation is also continuing or is obtaining promoting.Moreover in these organic acid high concentration liquids, ORP does not rise, but reduces along with the prolongation of conduction time.The acid disassociation index (pKa) of these acid is respectively 3.86,3.40,3.06.
In addition, in fumaric acid and citric acid, the free available chlorine of generation is minimum, particularly can confirm not produce fully free available chlorine in fumaric acid.Because the chlorine that generates is few, the rising of ORP is also low, and ORP reaches 1000mv or above situation is a period of time of the citric acid of low concentration.The acid of these acid disassociation index (pKa) is, fumaric acid is 3.02, citric acid is 3.16.
Based on the above results as can be known, contain for electrolysis that to be selected from acid disassociation index (pKa) be 4 or above succinic acid, acetic acid, the organic acid sea water solution that the organic acid of propionic acid is at least a and the sea sedge inorganic agent that obtains, in electrolytic process, can observe the rapid rising of redox potential (ORP) and free available chlorine concentration (ACC), can obtain the pH value and change little and stable electrolyte, simultaneously, after stopping energising, even through 24 hours, electrolyte also has good stable, therefore can conclude to access and a kind ofly can drive away the shank algae that adheres to diatom that existing inorganic agent is difficult to drive away etc. effectively, and can effectively and continuously prevent and treat with the disease mushroom headed by the needle-like bacteriosis at short notice, can obtain to cultivate sea sedge processing method and the sea sedge inorganic agent of healthy breed sea sedge.
Claims (11)
1, a kind of sea sedge processing method, it is to be used to utilize electrolysis organic acid sea water solution and the electrolyte that obtains carries out that the assorted algae of sea sedge is driven away and the disease control of sea sedge, wherein, described organic acid contain acid disassociation index (pKa) be 4 or above organic acid at least a.
2, sea sedge processing method as claimed in claim 1, wherein, organic acid is be selected from propionic acid, acetic acid, succinic acid at least a.
3, sea sedge processing method as claimed in claim 1, wherein, the pH value of organic acid sea water solution is 2～5 scope.
4, sea sedge processing method as claimed in claim 1, wherein, electrolysis mode is not for being provided with the no diaphragm type of barrier film between anode and negative electrode.
5, sea sedge processing method as claimed in claim 3, wherein, electrolysis mode is not for being provided with the no diaphragm type of barrier film between anode and negative electrode.
6, sea sedge processing method as claimed in claim 1, wherein, the pH value of electrolyte is 3～5 scope, and redox potential be 1140mv or more than, free available chlorine concentration be 1ppm or more than.
7, sea sedge processing method as claimed in claim 5, wherein, the pH value of electrolyte is 3～5 scope, and redox potential be 1140mv or more than, free available chlorine concentration be 1ppm or more than.
8, sea sedge processing method as claimed in claim 7, wherein, organic acid is be selected from propionic acid, acetic acid, succinic acid at least a.
9, a kind of sea sedge processing method, wherein, the preparation of electrolyte is to carry out in the electrolytic cell on being arranged on the sea sedge operation ship, carry out the processing of sea sedge net simultaneously in the treatment trough on being arranged on the sea sedge operation ship, and electrolytic cell and treatment trough are to use pump to carry out the circulation of electrolyte, carry out the characteristic of electrolysis with each described treatment fluid of maintenance claim 6～8 in the sea sedge processing procedure.
10, as each described sea sedge processing method of claim 1～8, wherein, this method is handled by impregnation process or distribution the sea sedge net is handled.
11, a kind of sea sedge inorganic agent, it contains the electrolyte for preparing by under each described condition of claim 1～8.
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| JP5239069B2 (en) * | 2007-08-20 | 2013-07-17 | 国立大学法人佐賀大学 | Anti-sminori disease bacteriophage and method for preventing minori disease in cultured laver |
| KR102549525B1 (en) * | 2020-01-29 | 2023-06-30 | 공주대학교 산학협력단 | Active Treatment Agent Composition for Simultaneous Control of Olpidiopsis blight and Red-Rot Disease |
| JP7429470B1 (en) | 2023-04-05 | 2024-02-08 | 株式会社山田鉄工 | Seaweed net processing method |
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| JPH11169000A (en) * | 1997-12-08 | 1999-06-29 | Fuso Chemical Co Ltd | Culture of laver |
| JP2001151610A (en) * | 1999-11-24 | 2001-06-05 | Daiichi Seimou Co Ltd | Method for repelling alga/bacterium for the purpose of laver culture |
| JP4340472B2 (en) * | 2003-05-23 | 2009-10-07 | 第一製網株式会社 | Seaweed treatment method for controlling seaweeds and controlling nobacterial fungi |
| JP4344273B2 (en) * | 2004-03-31 | 2009-10-14 | 第一製網株式会社 | Seaweed treatment method for controlling seaweeds and disease control of seaweed |
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