CN1772862A - Water-soluble membrane soap - Google Patents
Water-soluble membrane soap Download PDFInfo
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- CN1772862A CN1772862A CN 200410086629 CN200410086629A CN1772862A CN 1772862 A CN1772862 A CN 1772862A CN 200410086629 CN200410086629 CN 200410086629 CN 200410086629 A CN200410086629 A CN 200410086629A CN 1772862 A CN1772862 A CN 1772862A
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Abstract
The water soluble soap flake is prepared with soap material in 20-80 wt% and water soluble filming material pullulan in 20-80 wt%, and preferably with soap material in 8-80 wt%, water soluble filming material pullulan in 10-50 wt%, and supplementary material 9-45 wt%. The soap material includes surfactant 3-55 wt%, disinfectant 1-5 wt%, skin care component 2-10 wt%, soap perfume 1-5 wt% and coating agent 1-5 wt%. The water soluble soap flake may be dissolved fast in water at 4-100 deg.c to release various kinds of cleaning, disinfecting and skin care components to reach the set functions.
Description
Technical field
The present invention relates to a kind of water-soluble membrane soap, particularly relate to a kind of water-soluble diaphragm perfumed soap with cleaning, sterilization, skin care effect.
Background technology
At present, perfumed soap has obtained using widely in daily life as a kind of cleaning supplies, but, there are many inconvenient parts that get in the perfumed soap of traditional form when some specific occasions is used, for example, when travelling away from home, on train, automobile, steamer and aircraft, provide for oneself after perfumed soap finishes using, the perfumed soap humidity is clamminess and is not easy to preserve once more.Some public arena has public perfumed soap as the communal bathroom of restaurant, hotel and hospital, but many people are reluctant to use or seldom use for the fear to cross infection.Before the present invention proposes, there is the inventor to propose to be different from the traditional form perfumed soap, other forms of cleaning supplies with perfumed soap function, as Liquid soap and hand-washing film etc., but, there is the defective of carrying inconvenience in use equally in Liquid soap, and simultaneously, there is the possibility of cross infection in the many equally in public people of the packing of Liquid soap when using; Though the hand-washing film product has overcome the defective of the said products, but, all inventions before the present invention proposes all do not overcome the other defective that has of product itself, as, product can absorb airborne moisture deliquescing adhesion because of film forming material when humidity is big, be not easy to use and preserve, and in special exsiccant environment, the diaphragm fragmentation that can become fragile.
Summary of the invention
When the objective of the invention is to be to keep every function of traditional perfumed soap, proposed a kind of have be easy to carry, disposable use, prevent the water-soluble membrane soap of cross infection, sterilizing skin-protective new feature.
For achieving the above object, the present invention takes following technical scheme:
A kind of water-soluble membrane soap, this membrane soap are to be made with raw material and water soluble film-forming material by soap, and wherein, water soluble film-forming material includes pulullan.
The selected water soluble film-forming material of the present invention is a pulullan, pulullan is a kind of novel polysaccharide, this polysaccharide is a kind of amylopectin, and this amylopectin is the derivative of natural polysaccharide, and it is produced by starch hydrolyzates, sucrose or other carbohydrate direct fermentation.For Pullulanase acts on the extracellular polysaccharide that polysaccharide produces.Basic structure is trisaccharide maltose, and promptly glucose is pressed a-1, and 4 bonds are synthesized trisaccharide maltose, and two ends are again with a-1, and 6 keys are connected to form macromolecule polysaccharide so repeatedly with other trisaccharide maltose combination.A-1,4 keys and a-1, the ratio of 6 keys is 2: 1.The polymerization degree (D.P.) is 100～5000.Molecular-weight average is 40,000～2,000,000, and the size of molecular weight is difference with the fermentative production condition, pulullan P102 every technical requirements according to the invention that Japanese woods protobiochemistry institute produces.This polysaccharide has the suitable film product of making of following characteristics:
1, toxicity: the margin amount of the medial lethal dose LD50 of polysaccharide is 15 gram/kilograms, and polysaccharide can not cause the generation of any biology toxicity and error state (ERST), and it is foolproof being used for makeup and cleaning supplies.
2, the feature of environmental protection: polysaccharide can decompose under the effect of microbial enzyme, disappears at nature, does not cause environmental pollution.Polysaccharide COD value is lower one times than polyvinyl alcohol.
3, solvability: the solubleness of polysaccharide in water is unlimited in theory, and the hot water or cold water all has good solvability.Dissolution rate is fast than other macromolecular water-soluble material.Solution neutral, not ionization, non-crystallizable.
4, with the mutual solubility of water-soluble high-molecular substance: polysaccharide can be with carboxymethyl cellulose, carboxyethyl cellulose, sodium alginate, polyacrylic acid, polyacrylamide, polyvinylpyrrolidone, starch, gelatin, polyvinyl alcohol, polyoxyethylene is fine dissolves each other.
5, viscosity: the viscosity of polysaccharide is much lower than other polysaccharide, and the viscosity of the aqueous solution becomes greatly with the increase of strength of solution, but wants little many than the variation of other polysaccharide.
6, moisture absorption: polysaccharide is nonhygroscopic substantially below 70% in relative humidity, non-glued conglomeration.
7, plasticity-: the aqueous solution of 5～20% polysaccharide is coated on the film of making different thickness on sheet glass, the metal sheet easily, simple polysaccharide films water white transparency, elasticity are strong, but snappiness, ductility are bad, add suitable softening agent or with other macromolecular material mixing mouldings, can improve snappiness and ductility.
8, property of thin film: the polysaccharide films transparency is good, and elasticity is strong, and is water-soluble extremely strong, and fast 3 times than polyvinyl alcohol, skin friction coefficient is little, and special nature is that all gases all almost completely can not see through film.Have only polyvinyl alcohol to compare.
Therefore, make up the membrane soap of making, overcome the defective of other products before the present invention proposes by this pulullan or with other macromolecular materials.
The molecular weight ranges of the pulullan that the present invention is selected is 10-50 ten thousand, and molecular weight ranges preferably is 10-20 ten thousand, and optimum molecular weight ranges is 200,000.Pulullan weight percentage ranges in membrane soap is 5-97 weight %, and suitable weight percentage ranges is 20-80 weight %, and weight percentage ranges preferably is 10-50 weight %.
In membrane soap of the present invention, the content of described pulullan can be 5-97 weight %, and soap can be 3-95 weight % with the content of raw material.In membrane soap of the present invention, the content of preferred described pulullan is 20-80 weight %, and soap is 20-80 weight % with the content of raw material.
The pulullan film forming material that is proposed among the present invention can use jointly with other various water-soluble polymer film forming materials, so that make film have needed characteristic better, can comprise with the common film forming water-soluble high-molecular material of this polysaccharide: Vltra tears, Natvosol, hydroxypropylcellulose, polyvinylpyrrolidone, carboxymethyl cellulose, polyvinyl alcohol, sodium alginate, polyoxyethylene glycol, xanthan gum, carrageenin, Viscogum BE, Sudan Gum-arabic, polyacrylic acid, the methyl methacrylate multipolymer, carboxy vinyl polymer, amylose starch, high amylose, hydroxypropyl starch, dextrin, colloid, chitin, chitosan, Polylevulosan, collagen, gelatinum, zein, seitan, the soybean protein monomer, whey-protein monomer, casein food grade.
In water-soluble membrane soap of the present invention, xanthan gum, carrageenin and Viscogum BE are as stablizer, can guarantee that the film quality that is become is even, its weight percentage ranges in the film perfumed soap is 0-10 weight %, and optimum weight percentage ranges is 1-5 weight %.
In water-soluble membrane soap of the present invention, polyvinylpyrrolidone, polyvinyl alcohol are as the activator of snappiness and ductility, and its weight percentage ranges in the film perfumed soap is 0-80 weight %, and optimum weight percentage ranges is 5-25 weight %.
In water-soluble membrane soap of the present invention, membrane soap of the present invention also comprises thickening material, tackiness agent and softening agent best the composition.First-selected thickening material is carboxymethyl cellulose and sodium alginate, and its weight percentage ranges in the film perfumed soap is 0-10 weight %, and optimum weight percentage ranges is 1-5 weight %.First-selected tackiness agent is an amylose starch, high amylose, and hydroxypropyl starch, its weight percentage ranges in the film perfumed soap is 0-10 weight %, optimum weight percent is 1-5 weight %.First-selected softening agent is soil temperature-80, olein, and its weight percentage ranges in the film perfumed soap is 0-8 weight %, and optimum weight percentage ranges is 1-5 weight %.
The present invention is owing to selected for use above-mentioned with the film forming material combination of pulullan as main component, guaranteed become film to have characteristics such as good instantly-soluble, snappiness, ductility, moisture resistance, hypotoxicity, the feature of environmental protection, elasticity, therefore, leeway widely such as in selection, had to the composition that plays the decontamination cleaning effect and sterilizing skin-protective composition.
Tensio-active agent as cleaning decontamination composition can be cats product, anion surfactant, nonionogenic tenside and amphoterics.First-selected tensio-active agent is sodium laurylsulfate, polyoxyethylenated alcohol sodium sulfate, Ninol and cocamidopropyl betaine etc., and wherein, sodium laurylsulfate uses as whipping agent, and remaining tensio-active agent uses as sanitising agent.Their weight percents in the film perfumed soap are 1-50 weight %, and optimum weight percentage ranges is 10-40 weight %.
In addition, in order to improve cleaning performance to greasy dirt and proteic substance, in membrane soap, also comprise active protease, in order to keep the biological activity of active protease, improve its effective rate of utilization, used cyclodextrin in the membrane soap, active protease is wrapped up as coating material, to keep its biological activity, the content of active protease is the 1-5 weight % of film perfumed soap weight.
It is 2,4 that the present invention selects sterilization component for use, 4-three chloro-2-dihydroxy diphenyl ethers, Levofloxacin, and above sterilant can be used alone, but also also mix together, and its content is percent 0.1-5 of film perfumed soap weight, and its optimum content is percent 0.3-3.The usage quantity of sterilant is lower than percent 0.1 sterilization effects and reduces, and is higher than percent 1, can cause product cost to improve, 2,4,4-three chloro-2-dihydroxy diphenyl ethers, Levofloxacin are wide-spectrum bactericide, wherein 2,4, the harmful germ of kind surplus 4-three chloro-2-dihydroxy diphenyl ethers can kill nearly 60, more than the dissolving fully in organic solvent of two kinds of sterilant, slightly soluble in water is selected this two kinds of sterilant for use, has enlarged bactericidal range, improve sterilization effect, prolonged sterilization working lipe.
Membrane soap of the present invention also comprises various skin care effective constituents, and they are selected from following material: lanolin, natural phant essence, fibroin, silk peptide, tartaric acid, vitamin-E, water-soluble silicon oil and honey etc.First-selected water-soluble lanolin of skin care ingredient and vitamin-E.Its weight percent in the film perfumed soap is 0-10 weight %, and optimum weight percentage ranges is 1-5 weight %.
In water-soluble membrane soap of the present invention, described water soluble film-forming material also includes auxiliary, and wherein, the content of described pulullan is 10-50 weight %, and soap is 8-80 weight % with the content of raw material, and the content of auxiliary is 9-45 weight %.
In water-soluble membrane soap of the present invention, it is that 1-5 weight %, activator are that 5-25 weight %, thickening material are that 1-5 weight %, tackiness agent are that 1-5 weight %, softening agent are 1-5 weight % that described auxiliary includes stablizer; Described soap includes tensio-active agent 3-55 weight %, sterilant 1-5 weight %, skin care ingredient 2-10 weight %, soap perfume 1-5 weight %, coating agent 1-5 weight % with raw material.This is comparatively preferred first technical scheme of the present invention.
In water-soluble membrane soap of the present invention, it is that 1-5 weight %, activator are that 5-25 weight %, thickening material are that 1-5 weight %, tackiness agent are that 1-5 weight %, softening agent are 1-5 weight % that described auxiliary includes stablizer; Described soap includes tensio-active agent 2-50 weight %, sterilant 1-5 weight %, skin care ingredient 2-10 weight %, soap perfume 1-5 weight %, coating agent 1-5 weight %, active protease 1-5 weight % with raw material.This is comparatively preferred second technical scheme of the present invention.Second technical scheme compared with first technical scheme, and except that containing active protease (content of tensio-active agent is also different), all the other are all identical more.
In water-soluble membrane soap of the present invention, described stablizer is one or more in xanthan gum, carrageenin and the Viscogum BE; Described activator is polyvinylpyrrolidone and/or polyvinyl alcohol; Described thickening material is carboxymethyl cellulose and/or sodium alginate; Described tackiness agent is one or more in starch, amylose starch, high amylose and the hydroxypropyl starch; Described softening agent is soil temperature-80 and/or olein.
In water-soluble membrane soap of the present invention, described tensio-active agent is one or more in sodium laurylsulfate, polyoxyethylenated alcohol sodium sulfate, Ninol and the cocamidopropyl betaine; Described sterilant is 2,4,4-three chloro-2-dihydroxy diphenyl ether and/or Levofloxacin; Described skin care ingredient is selected from one or more in lanolin, natural phant essence, fibroin, silk peptide, tartaric acid, vitamin-E, water-soluble silicon oil and the honey.
In water-soluble membrane soap of the present invention, described coating agent is a cyclodextrin.
The preparation side of water-soluble membrane soap of the present invention is as follows:
(1), gets the raw materials ready by content range of the present invention;
(2), tensio-active agent, skin care ingredient (as lanolin etc.) are dissolved in the water, make solution A;
(3), again join in the solution A that are heated to 60 degree after pulullan and auxiliary (as polyvinyl alcohol, xanthan gum, sodium alginate, starch etc.) being mixed, fully stir and make viscous solution B;
(4), sterilant is dissolved in makes solution C in the dehydrated alcohol then;
(5), again coating agent (as cyclodextrin etc.) with the olein dissolving, is added vitamin-E, soap perfume and active protease to make solution D again;
(6), then three kinds of solution of above-mentioned B, C, D are mixed, dilute with water stirs, and filters, and is stand-by;
(7), afterwards above-mentioned solution is uniformly coated on the sheet glass, heating, drying can obtain flexible film;
(8), at last film is taken off from sheet glass, cut, pack and make finished product.
First concrete optimized technical scheme of the present invention can be:
2,4,4-three chloro-2-dihydroxy diphenyl ether 1-5 weight %
Cocamidopropyl betaine 1-20 weight %
Sodium laurylsulfate 1-15 weight %
Polyoxyethylenated alcohol sodium sulfate 1-20 weight %
Cyclodextrin 1-5 weight %
Lanolin 1-5 weight %
Vitamin e1---5 weight %
Soap perfume 1-5 weight %
Pulullan 10-50 weight %
Polyvinyl alcohol 5-25 weight %
Xanthan gum 1-5 weight %
Sodium alginate 1-5 weight %
Starch 1-5 weight %
Olein 1-5 weight %.
Second concrete optimized technical scheme of the present invention can be:
2,4,4-three chloro-2-dihydroxy diphenyl ether 1-5 weight %
Cocamidopropyl betaine 0.5-17.5 weight %
Sodium laurylsulfate 1-15 weight %
Polyoxyethylenated alcohol sodium sulfate 0.5-17.5 weight %
Cyclodextrin 1-5 weight %
Lanolin 1-5 weight %
Vitamin e1---5 weight %
Soap perfume 1-5 weight %
Pulullan 10-50 weight %
Polyvinyl alcohol 5-25 weight %
Xanthan gum 1-5 weight %
Sodium alginate 1-5 weight %
Starch 1-5 weight %
Olein 1-5 weight %
Active protease 1-5 weight %.
Advantage of the present invention is:
Membrane soap proposed by the invention be can be in temperature be 4-100 degree scope dissolving films rapidly, the diaphragm-operated dissolution rate is not subjected to the Temperature Influence and the restriction of water.After the membrane soap dissolving, can discharge various cleaning decontaminations, sterilizing skin-protective effective constituent rapidly, give full play to every function that membrane soap sets.
The present invention uses a kind of novel polysaccharide as film forming material, overcome the defective of prior art, this is before the present invention proposes, other inventions do not relate to, the applied film forming material of the present invention has the good property loaded with, simultaneously can be with the compound use of many macromolecular materials, make that membrane soap involved in the present invention can be when possessing all perfumed soap cleaning functions, the specific function that also has other, support skin water retaining function etc. as sterilizing function and skin care, the present invention has proposed new method to the making of membrane soap simultaneously.
Embodiment
Experimental example:
2,4,4-three chloro-2-dihydroxy diphenyl ethers to intestinal bacteria,
Streptococcus aureus, the report of Candida albicans quantitative disinfecting test
One, equipment
1, test strain: in the 7th generation of intestinal bacteria (8099), in the 7th generation of streptococcus aureus (ATCC 6538), in the 6th generation of Candida albicans (ATCC 10231), sterilization inspection center of preventive medicine academy of sciences provides.
2, sterilizing agent composition: 2,4,4-three chloro-2-dihydroxy diphenyl ethers (content is 0.3 weight %).
3. neutralizing agent composition: the PBS solution of 0.2 weight % Yelkin TTS, 2.0 weight % soil temperatures-80,0.1 weight % Sulfothiorine.
4, support methods is used in this experiment.
Two, method
5, test basis: the Ministry of Health's " disinfection technology standard " (third edition) first fascicle 2＞6 in 1999.
6, sterilizing agent preparation:
A, get 2,4,4-three chloro-2-dihydroxy diphenyl ethers, the content of add pulullan, xanthan gum, polyvinyl alcohol, sodium alginate, starch, tensio-active agent cocamidopropyl methyl betaine, sodium laurylsulfate, aliphatic alcohol polyethenoxy sodium sulfate, olein, lanolin, vitamin-E, cyclodextrin, making above composition is respectively the aqueous solution of 0.3 weight %, 10 weight %, 1 weight %, 5 weight %, 1 weight %, 2 weight %, 6 weight %, 3 weight %, 6 weight %, 1 weight %, 1 weight %, 1 weight %, 1 weight %.PH?6.5
B, above solution for later use.
7, bactericidal assay: test temperature 20 degree, the sterilizing agent test uses 2,4 respectively, and the content of 4-three chloro-2-dihydroxy diphenyl ethers is the soup of 0.3 weight % and 0.1 weight %, and test repeats 3 times.
8, bacteria suspension, carrier-pellet preparation, viable bacteria are cultivated counting respectively with reference to the Ministry of Health's " disinfection technology standard " (third edition) first fascicle 22 in 1999.
Three, result
Test repeats 3 times under temperature 20 degree conditions, experimental result shows experiment sterilizing agent 2,4, the content of 4-three chloro-2-dihydroxy diphenyl ethers is 0.3% solution effects 1 minute, and the killing rate of intestinal bacteria, streptococcus aureus, Candida albicans is all reached 99.90%; Experiment is with sterilizing agent 2,4, and the content of 4-three chloro-2-dihydroxy diphenyl ethers is the solution effects 1 minute of 0.1 weight %, and the killing rate of intestinal bacteria, streptococcus aureus, Candida albicans is all reached 98.50% conclusion
Test-results shows, 2,4, and 4-three chloro-2-dihydroxy diphenyl ethers have good killing effect to intestinal bacteria, streptococcus aureus, Candida albicans when strength of solution is 0.3 weight %; With 2,4, when the concentration of 4-three chloro-2-dihydroxy diphenyl ethers was reduced to 0.1 weight %, sterilization effect decreased, but still met " sterilization and disinfection standard " requirement.
Embodiment 1
Get 60 gram polyoxyethylenated alcohol sodium sulfate, 30 gram sodium laurylsulfates, 60 gram cocamidopropyl betaine, 10 gram lanolin and be dissolved in 600 milliliters the water, make solution A; 100 gram pulullans, 50 gram polyvinyl alcohol, 10 gram xanthan gum, 10 gram sodium alginates, 10 gram starch powders are joined in the solution A that is heated to 60 degree after mixing, fully stir and make viscous solution B; Get 10 grams 2,4,4-three chloro-2-dihydroxy diphenyl ethers are dissolved in 20 milliliters of dehydrated alcohols makes solution C; Get 10 gram cyclodextrin with 10 gram olein dissolvings, add 10 gram vitamin-Es, 10 gram soap perfumes and 10 gram active proteases and make solution D; Above-mentioned B, C, three kinds of solution of D are mixed, be diluted with water to 1000 milliliters, stir, filter, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the sheet glass, and heating, drying can obtain thickness and be 0.04 millimeter flexible film.Film is taken off from sheet glass, cut, pack and make finished product.
Embodiment 2
Get 60 gram polyoxyethylenated alcohol sodium sulfate, 30 gram sodium laurylsulfates, 60 gram cocamidopropyl betaine, 10 gram lanolin and be dissolved in 600 milliliters the water, make solution A; 100 gram pulullans, 50 gram polyvinyl alcohol, 10 gram xanthan gum, 10 gram sodium alginates, 10 gram starch powders are joined in the solution A that is heated to 60 degree after mixing, fully stir and make viscous solution B; Get 10 grams 2,4,4-three chloro-2-dihydroxy diphenyl ethers are dissolved in 20 milliliters of dehydrated alcohols makes solution C; Get 10 gram cyclodextrin and dissolve with 10 gram oleins, adding 10 gram vitamin-Es and 10 gram soap perfumes are made solution D; Above-mentioned B, C, three kinds of solution of D are mixed, be diluted with water to 1000 milliliters, stir, filter, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the sheet glass, and heating, drying can obtain thickness and be 0.04 millimeter flexible film.Film is taken off from sheet glass, cut, pack and make finished product.
Embodiment 3
Get 60 gram polyoxyethylenated alcohol sodium sulfate, 30 gram sodium laurylsulfates, 60 gram cocamidopropyl betaine, 10 gram lanolin and be dissolved in 600 milliliters the water, make solution A; 190 gram pulullans are joined in the solution A that is heated to 60 degree, fully stir and make viscous solution B; Get 10 grams 2,4,4-three chloro-2-dihydroxy diphenyl ethers are dissolved in 20 milliliters of dehydrated alcohols makes solution C; After two kinds of solution mixing of above-mentioned B, C, add 10 gram vitamin-Es and 10 gram soap perfumes again, be diluted with water to 1000 milliliters then, stir, filter, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the sheet glass, and heating, drying can obtain thickness and be 0.04 millimeter flexible film.Film is taken off from sheet glass, cut, pack and make finished product.
Embodiment 1,2,3 made membrane soaps are carried out the test of effect, the cleaning decontamination of the membrane soap that embodiment 1,2,3 is made, the ability of skin care all can reach the cleaning decontamination of common perfumed soap, the effect of skin care, and particularly embodiment 1,2,3 made membrane soaps have the killing effect to intestinal bacteria, streptococcus aureus, Candida albicans.And embodiment 1,2,3 made membrane soaps are being can dissolve rapidly in the 4-100 degree scope in temperature all.
Claims (8)
1, a kind of water-soluble membrane soap is characterized in that: this membrane soap is to be made with raw material and water soluble film-forming material by soap, and wherein, water soluble film-forming material includes pulullan.
2, water-soluble membrane soap according to claim 1 is characterized in that: the content of described pulullan is 20-80 weight %, and soap is 20-80 weight % with the content of raw material.
3, water-soluble membrane soap according to claim 1, it is characterized in that: described water soluble film-forming material also includes auxiliary, and wherein, the content of described pulullan is 10-50 weight %, soap is 8-80 weight % with the content of raw material, and the content of auxiliary is 9-45 weight %.
4, water-soluble membrane soap according to claim 3 is characterized in that: it is that 1-5 weight %, activator are that 5-25 weight %, thickening material are that 1-5 weight %, tackiness agent are that 1-5 weight %, softening agent are 1-5 weight % that described auxiliary includes stablizer; Described soap includes tensio-active agent 3-55 weight %, sterilant 1-5 weight %, skin care ingredient 2-10 weight %, soap perfume 1-5 weight %, coating agent 1-5 weight % with raw material.
5, water-soluble membrane soap according to claim 4 is characterized in that: it is that 1-5 weight %, activator are that 5-25 weight %, thickening material are that 1-5 weight %, tackiness agent are that 1-5 weight %, softening agent are 1-5 weight % that described auxiliary includes stablizer; Described soap includes tensio-active agent 2-50 weight %, sterilant 1-5 weight %, skin care ingredient 2-10 weight %, soap perfume 1-5 weight %, coating agent 1-5 weight %, active protease 1-5 weight % with raw material.
6, according to claim 4 or 5 described water-soluble membrane soaps, described stablizer is one or more in xanthan gum, carrageenin and the Viscogum BE; Described activator is polyvinylpyrrolidone and/or polyvinyl alcohol; Described thickening material is carboxymethyl cellulose and/or sodium alginate; Described tackiness agent is one or more in starch, amylose starch, high amylose and the hydroxypropyl starch; Described softening agent is soil temperature-80 and/or olein.
7, according to claim 4 or 5 described water-soluble membrane soaps, it is characterized in that: described tensio-active agent is one or more in sodium laurylsulfate, polyoxyethylenated alcohol sodium sulfate, Ninol and the cocamidopropyl betaine; Described sterilant is 2,4,4-three chloro-2-dihydroxy diphenyl ether and/or Levofloxacin; Described skin care ingredient is selected from one or more in lanolin, natural phant essence, fibroin, silk peptide, tartaric acid, vitamin-E, water-soluble silicon oil and the honey.
8, according to claim 4 or 5 described water-soluble membrane soaps, it is characterized in that: described coating agent is a cyclodextrin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410086629 CN1772862A (en) | 2004-11-11 | 2004-11-11 | Water-soluble membrane soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410086629 CN1772862A (en) | 2004-11-11 | 2004-11-11 | Water-soluble membrane soap |
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| Publication Number | Publication Date |
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| CN1772862A true CN1772862A (en) | 2006-05-17 |
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Family Applications (1)
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| CN 200410086629 Pending CN1772862A (en) | 2004-11-11 | 2004-11-11 | Water-soluble membrane soap |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101932689B (en) * | 2007-10-12 | 2012-05-30 | 荷兰联合利华有限公司 | Laundry detergent with pretreatment additive and its use |
| CN103937623A (en) * | 2014-03-28 | 2014-07-23 | 王素贞 | Air conditioner cleaning agent and manufacturing method thereof |
| CN107674795A (en) * | 2017-10-13 | 2018-02-09 | 李丹丹 | A kind of soap paper and preparation method thereof |
| CN107828562A (en) * | 2017-12-20 | 2018-03-23 | 刁广祥 | Diatom beauty soap |
| CN108441350A (en) * | 2018-03-23 | 2018-08-24 | 浙江工业大学 | A kind of kitchen cleaning agent and preparation method thereof based on bio-based compounds |
| FR3064473A1 (en) * | 2017-04-03 | 2018-10-05 | Basf Beauty Care Solutions France Sas | PROTECTIVE INGREDIENT FOR THE BALANCE OF THE MICROBIAL SKIN FLORA AND / OR MUCOSAL |
| CN109863237A (en) * | 2016-10-27 | 2019-06-07 | 蒙诺苏尔有限公司 | Water-solubility membrane with low-friction coefficient |
| CN115161126A (en) * | 2022-07-25 | 2022-10-11 | 黄华伟 | Bath soap flakes containing amino acid and preparation method thereof |
-
2004
- 2004-11-11 CN CN 200410086629 patent/CN1772862A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101932689B (en) * | 2007-10-12 | 2012-05-30 | 荷兰联合利华有限公司 | Laundry detergent with pretreatment additive and its use |
| CN103937623A (en) * | 2014-03-28 | 2014-07-23 | 王素贞 | Air conditioner cleaning agent and manufacturing method thereof |
| CN109863237A (en) * | 2016-10-27 | 2019-06-07 | 蒙诺苏尔有限公司 | Water-solubility membrane with low-friction coefficient |
| FR3064473A1 (en) * | 2017-04-03 | 2018-10-05 | Basf Beauty Care Solutions France Sas | PROTECTIVE INGREDIENT FOR THE BALANCE OF THE MICROBIAL SKIN FLORA AND / OR MUCOSAL |
| WO2018185408A1 (en) * | 2017-04-03 | 2018-10-11 | Basf Beauty Care Solutions France Sas | Protective ingredient for balancing the cutaneous and/or mucosal microbial flora |
| CN107674795A (en) * | 2017-10-13 | 2018-02-09 | 李丹丹 | A kind of soap paper and preparation method thereof |
| CN107828562A (en) * | 2017-12-20 | 2018-03-23 | 刁广祥 | Diatom beauty soap |
| CN108441350A (en) * | 2018-03-23 | 2018-08-24 | 浙江工业大学 | A kind of kitchen cleaning agent and preparation method thereof based on bio-based compounds |
| CN115161126A (en) * | 2022-07-25 | 2022-10-11 | 黄华伟 | Bath soap flakes containing amino acid and preparation method thereof |
| CN115161126B (en) * | 2022-07-25 | 2024-05-28 | 黄华伟 | Amino acid-containing bath soap flake and preparation method thereof |
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