CN107674795A - A kind of soap paper and preparation method thereof - Google Patents
A kind of soap paper and preparation method thereof Download PDFInfo
- Publication number
- CN107674795A CN107674795A CN201710952985.1A CN201710952985A CN107674795A CN 107674795 A CN107674795 A CN 107674795A CN 201710952985 A CN201710952985 A CN 201710952985A CN 107674795 A CN107674795 A CN 107674795A
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- CN
- China
- Prior art keywords
- soap
- film
- water
- soap paper
- paper
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of Novel soap paper and preparation method thereof, wherein, after soap lye is shaped to soap-film, water-soluble hyaline membrane is covered with its upper and lower two surface, so as to function well as the effect of isolation air, avoid soap-film moisture absorption and caused glutinous soapy feeling, fragrance volatilizing and colour fading can be avoided again, and soap letterweight can be obtained to very thin, the form of can directly bind into book form son or book, the use of packing tube is avoided, further improves portability.
Description
Technical field
The invention belongs to field of fine chemical, and in particular to a kind of soap paper and preparation method thereof.
Background technology
Soap paper is that a kind of of common block bar soap or perfumed soap improves form, has the advantages of hygienic, portable, especially suitable
Conjunction is gone on business, tourism uses.Main flow soap paper is broadly divided into two types at present, and one kind is to immerse paper handkerchief or non-woven fabrics in soap lye to fill
Divide and absorb soap lye and dry, however, such soap paper has the residual of paper handkerchief or non-woven fabrics when in use;Another kind is to decontamination
Film forming agent is added in the active ingredients such as agent, is directly shaped to film-form, then cuts into the small pieces of various moulding, is put into packaging
In cylinder or packaging bag, so manufactured soap paper using when can be completely dissolved and rinse well, noresidue, usage experience is more excellent.However,
When soap paper is placed for a long time in atmosphere made of the latter, certain hygroscopicity is had, so that soap paper produces glutinous soapy feeling, and
The fragrance component contained in soap paper constantly volatilizees, fugitive color, the serious pot-life for restricting soap paper and preservation condition, generally needs
It is loaded into closed packing tube and is sold.
The content of the invention
In order to solve the above technical problems, inventor developed a kind of Novel soap paper, after soap lye is shaped to soap-film, at it
Upper and lower two surfaces are covered with water-soluble hyaline membrane, so as to function well as the effect of isolation air, avoid soap-film moisture absorption and produce
Glutinous soapy feeling, fragrance volatilizing and colour fading can be avoided again, and soap letterweight can be obtained it is very thin, can directly bind into book form son or book
Form, avoid the use of packing tube, further improve portability, so as to complete the present invention.
Therefore, in one aspect, the invention provides a kind of soap paper, the soap paper bag to contain the soap-film for being covered with water-solubility membrane,
Wherein, the raw material for preparing the water-solubility membrane includes polyvinyl alcohol, water-based quick dry agent, paraffin.
The raw material for preparing the soap-film comprises at least film forming agent, plasticizer, surfactant, antiseptic, solvent.
The film forming agent can be gelatin, starch, dextrin, polyvinyl alcohol, cellulose etc., preferred starch and dextrin.
The plasticizer is glyceride, succinate, tartrate.
The surfactant can be dodecyl sodium sulfate, Cocoamidopropyl betaine, octyl phenol polyoxyethylene
Ether or their mixture.
The antiseptic is triclosan, triclocarban, allantoin.
The solvent is glycerine, water, ethanol.
In addition, the conventional additives such as NMF, pigment and spices can also be added when preparing the soap-film of the present invention.The guarantor
For humectant such as sodium hyaluronate, tartaric acid, sorbierite, the pigment is the perfume (or spice) such as famille rose, lemon yellow, indigo and light blue
Expect such as plants essential oil(Osmanthus essential oil, jasmine essential oil, rose ethereal oil, yulan flower essential oil etc.).
In another aspect, present invention also offers the preparation method of the soap paper, methods described to include:
(1)Film forming agent, plasticizer, surfactant, antiseptic are added in solvent, are uniformly mixed at 60-70 DEG C, so
Continuous film is formed with film applicator afterwards, is solidified as solid film in 80 DEG C of dryings, then soap-film is pressed into by extruder;
(2)Polyvinyl alcohol, water-based quick dry agent, paraffin are dissolved in 80 DEG C of water, formed continuously with film applicator after stirring
Mould, peeled off after drying, form water-solubility membrane;
(3)The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then cut into block, described in acquisition
Soap paper.
In some embodiments, in step(1)In, while NMF, pigment and spices etc. are added into solvent, then carry out
Film.
Preferably, methods described further comprises binding into book form on the soap paper.
In some embodiments, spray printing pattern or logo, raising soap paper can also be viewed and admired on the water-solubility membrane
Property.
The soap paper of the present invention by two surfaces of soap-film by being covered with water-solubility membrane, so as to play moistureproof, fade-proof, anti-perfume (or spice)
Expect the effect of volatilization, be advantageous to bind into book form on soap paper, compared to the manner of packing of packing tube, further improve portability.And
And preparation technology is simple, suitably amplification production.
Embodiment
The present invention is further described with reference to specific embodiment.
Embodiment 1
By 20g starch, 30g dextrin, 35g ethyl succinates, 15g dodecyl sodium sulfates, 15g Cocoamidopropyl betaines,
0.2g triclosans, 1g yulan flower essential oils are dissolved in 10mL glycerine, 100mL water, the in the mixed solvent of 5mL ethanol composition, at 70 DEG C
It is uniformly mixed, then forms continuous film using film applicator, be solidified as solid film in 80 DEG C of dryings, then be pressed into by extruder
Thickness about 0.08mm soap-film.
50g polyvinyl alcohol, the water-based quick dry agents of 5g, 10g paraffin are dissolved in 80 DEG C of water, film applicator is used after stirring
The progressive die is formed, is peeled off after drying, forms water-solubility membrane.
The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then cut into 5cm × 4cm's
Fritter, bind into book form, obtain yulan floral type soap paper.
Embodiment 2
50g polyvinyl alcohol, 35g ethyl succinates, 10g dodecyl sodium sulfates, 12g Cocoamidopropyl betaines, 15g is pungent
Base phenol polyethenoxy ether, 0.1g triclosans, 2g sorbierites, 0.8g famille roses are dissolved in 10mL glycerine, 100mL water, 5mL ethanol composition
In the mixed solvent, be uniformly mixed at 60 DEG C, then form continuous film using film applicator, be solidified as in 80 DEG C of dryings solid
State film, then it is pressed into by extruder thickness about 0.08mm soap-film.
50g polyvinyl alcohol, the water-based quick dry agents of 5g, 10g paraffin are dissolved in 80 DEG C of water, film applicator is used after stirring
The progressive die is formed, is peeled off after drying, forms water-solubility membrane.
The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then cut into 5cm × 4cm's
Fritter, bind into book form, obtain red soap paper.
Comparative example 1
By 20g starch, 30g dextrin, 35g ethyl succinates, 15g dodecyl sodium sulfates, 15g Cocoamidopropyl betaines,
0.2g triclosans, 1g yulan flower essential oils are dissolved in 10mL glycerine, 100mL water, the in the mixed solvent of 5mL ethanol composition, at 70 DEG C
It is uniformly mixed, then forms continuous film using film applicator, be solidified as solid film in 80 DEG C of dryings, then be pressed into by extruder
Thickness about 0.08mm soap-film.
The soap-film is cut into 5cm × 4cm fritter, obtains the yulan floral type soap paper for not being covered with any film.
Comparative example 2
50g polyvinyl alcohol, 35g ethyl succinates, 10g dodecyl sodium sulfates, 12g Cocoamidopropyl betaines, 15g is pungent
Base phenol polyethenoxy ether, 0.1g triclosans, 2g sorbierites, 0.8g famille roses are dissolved in 10mL glycerine, 100mL water, 5mL ethanol composition
In the mixed solvent, be uniformly mixed at 60 DEG C, then form continuous film using film applicator, be solidified as in 80 DEG C of dryings solid
State film, then it is pressed into by extruder thickness about 0.08mm soap-film.
The soap-film is cut into 5cm × 4cm fritter, obtains the red soap paper for not being covered with any film.
The embodiment 1-2 and comparative example 1-2 soap paper prepared is placed in the environment of humidity 60% and placed 10 days, by the present invention
Soap paper outward appearance prepared by embodiment 1-2 is almost unchanged, and tears and take the soap paper for washing used time embodiment 1 still to have yulan flowery odour,
However, the soap paper surface of comparative example 1 and 2 is swollen, feel becomes glutinous greasy, and discolouration phenomena occurs in the soap paper that comparative example 2 obtains, and
Fade uneven, have a strong impact on product appearance, and soap paper yulan flowery odour prepared by comparative example 1 becomes very light, it is not easy to hear
Arrive.
Above only describes the better embodiment of the present invention, but the present invention is not limited to above-described embodiment.This area skill
Art personnel all should fall into the present invention it is understood that any same or similar means of the technology of the present invention effect can be realized
Protection domain in.
Claims (8)
1. a kind of soap paper, the soap paper bag contains the soap-film for being covered with water-solubility membrane, and the raw material for preparing the water-solubility membrane includes poly- second
Enol, water-based quick dry agent, paraffin.
2. soap paper according to claim 1, it is characterised in that the raw material for preparing the soap-film comprises at least film forming agent, increased
Mould agent, surfactant, antiseptic, solvent.
3. soap paper according to claim 1, it is characterised in that the film forming agent be gelatin, starch, dextrin, polyvinyl alcohol,
Cellulose etc., preferred starch and dextrin.
4. soap paper according to claim 1, it is characterised in that the plasticizer is glyceride, succinate, tartaric acid
Ester.
5. soap paper according to claim 1, it is characterised in that the surfactant is dodecyl sodium sulfate, cocounut oil
Amido propyl betaine, OPEO or their mixture.
6. soap paper according to claim 1, it is characterised in that the antiseptic is triclosan, triclocarban, allantoin.
7. soap paper according to claim 1, it is characterised in that prepare the raw material of the soap-film also comprising NMF, pigment
At least one of with spices.
8. the preparation method of the soap paper any one of claim 1-7, methods described include:
(1)Film forming agent, plasticizer, surfactant, antiseptic are added in solvent, are uniformly mixed at 60-70 DEG C, so
Continuous film is formed with film applicator afterwards, is solidified as solid film in 80 DEG C of dryings, then soap-film is pressed into by extruder;
(2)Polyvinyl alcohol, water-based quick dry agent, paraffin are dissolved in 80 DEG C of water, formed continuously with film applicator after stirring
Mould, peeled off after drying, form water-solubility membrane;
(3)The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then cut into block, described in acquisition
Soap paper.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710952985.1A CN107674795A (en) | 2017-10-13 | 2017-10-13 | A kind of soap paper and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710952985.1A CN107674795A (en) | 2017-10-13 | 2017-10-13 | A kind of soap paper and preparation method thereof |
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CN107674795A true CN107674795A (en) | 2018-02-09 |
Family
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CN201710952985.1A Withdrawn CN107674795A (en) | 2017-10-13 | 2017-10-13 | A kind of soap paper and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108877483A (en) * | 2018-07-09 | 2018-11-23 | 庄亚新 | It is a kind of for the environmental protection label of textile product, preparation method and clothes |
CN109055061A (en) * | 2018-10-10 | 2018-12-21 | 南通季德胜科技有限公司 | A kind of antipruritic perfumed soap of anti-mite and preparation process |
CN109097217A (en) * | 2018-10-10 | 2018-12-28 | 南通季德胜科技有限公司 | A kind of anti-mite repellent antipruritic perfumed soap and preparation process |
CN112625815A (en) * | 2020-11-27 | 2021-04-09 | 华南理工大学 | Disposable nano antibacterial soap paper and preparation method and application thereof |
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---|---|---|---|---|
CN1093746A (en) * | 1994-03-28 | 1994-10-19 | 李淑琴 | The method of putting-on shell for soap |
CN2235976Y (en) * | 1996-02-13 | 1996-09-25 | 杨翔 | Health-care paper toilet soap |
CN1186111A (en) * | 1996-12-24 | 1998-07-01 | 俞炳彦 | Thin layered soup containing foam and laminated cellulose film thereon |
CN1259565A (en) * | 1999-12-16 | 2000-07-12 | 西安交通大学 | Toilet soap membrane |
CN1772862A (en) * | 2004-11-11 | 2006-05-17 | 沙德成 | Water-soluble membrane soap |
CN101033437A (en) * | 2006-03-06 | 2007-09-12 | 深圳市深蓝德精细化工科技有限公司 | Soap paper |
CN101203593A (en) * | 2005-06-02 | 2008-06-18 | 吉万奥丹股份有限公司 | Solid detergent bar |
-
2017
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---|---|---|---|---|
CN1093746A (en) * | 1994-03-28 | 1994-10-19 | 李淑琴 | The method of putting-on shell for soap |
CN2235976Y (en) * | 1996-02-13 | 1996-09-25 | 杨翔 | Health-care paper toilet soap |
CN1186111A (en) * | 1996-12-24 | 1998-07-01 | 俞炳彦 | Thin layered soup containing foam and laminated cellulose film thereon |
CN1259565A (en) * | 1999-12-16 | 2000-07-12 | 西安交通大学 | Toilet soap membrane |
CN1772862A (en) * | 2004-11-11 | 2006-05-17 | 沙德成 | Water-soluble membrane soap |
CN101203593A (en) * | 2005-06-02 | 2008-06-18 | 吉万奥丹股份有限公司 | Solid detergent bar |
CN101033437A (en) * | 2006-03-06 | 2007-09-12 | 深圳市深蓝德精细化工科技有限公司 | Soap paper |
Non-Patent Citations (1)
Title |
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中国包装技术协会编: "《中国包装年鉴》", 31 December 2001 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108877483A (en) * | 2018-07-09 | 2018-11-23 | 庄亚新 | It is a kind of for the environmental protection label of textile product, preparation method and clothes |
CN108877483B (en) * | 2018-07-09 | 2021-04-20 | 庄亚新 | Environment-friendly label for textile products, preparation method and clothes |
CN109055061A (en) * | 2018-10-10 | 2018-12-21 | 南通季德胜科技有限公司 | A kind of antipruritic perfumed soap of anti-mite and preparation process |
CN109097217A (en) * | 2018-10-10 | 2018-12-28 | 南通季德胜科技有限公司 | A kind of anti-mite repellent antipruritic perfumed soap and preparation process |
CN112625815A (en) * | 2020-11-27 | 2021-04-09 | 华南理工大学 | Disposable nano antibacterial soap paper and preparation method and application thereof |
CN112625815B (en) * | 2020-11-27 | 2022-03-29 | 华南理工大学 | Disposable nano antibacterial soap paper and preparation method and application thereof |
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