CN107674796A - A kind of osmanthus flower fragrant soap paper and preparation method thereof - Google Patents

A kind of osmanthus flower fragrant soap paper and preparation method thereof Download PDF

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Publication number
CN107674796A
CN107674796A CN201710953825.9A CN201710953825A CN107674796A CN 107674796 A CN107674796 A CN 107674796A CN 201710953825 A CN201710953825 A CN 201710953825A CN 107674796 A CN107674796 A CN 107674796A
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soap
film
osmanthus
water
flower fragrant
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CN201710953825.9A
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Chinese (zh)
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李丹丹
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Individual
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Individual
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Publication of CN107674796A publication Critical patent/CN107674796A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039Coated compositions or coated components in the compositions, (micro)capsules
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753Polyvinylalcohol; Ethers or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of osmanthus flower fragrant soap paper and preparation method thereof, the osmanthus flower fragrant soap paper bag contains the soap-film for being covered with water-solubility membrane, wherein, the soap-film is embedded with sweet osmanthus petal, and the raw material for preparing the water-solubility membrane includes polyvinyl alcohol, water-based quick dry agent, paraffin.The osmanthus flower fragrant soap paper of the present invention by two surfaces of soap-film by being covered with water-solubility membrane, so as to play a part of moistureproof, fade-proof, anti-spices volatilization, further improve portability, realize simultaneously and sweet osmanthus petal is embedded in soap paper, and the phenomenon that soap-film is damaged in extruding, drying process is avoided, greatly improve the outward appearance ornamental value of osmanthus flower fragrant soap paper.

Description

A kind of osmanthus flower fragrant soap paper and preparation method thereof
Technical field
The invention belongs to field of fine chemical, and in particular to a kind of osmanthus flower fragrant soap paper for being embedded with sweet osmanthus petal and its system Preparation Method.
Background technology
Soap paper is that a kind of of common block bar soap or perfumed soap improves form, has the advantages of hygienic, portable, especially suitable Conjunction is gone on business, tourism uses.Main flow soap paper is broadly divided into two types at present, and one kind is to immerse paper handkerchief or non-woven fabrics in soap lye to fill Divide and absorb soap lye and dry, however, such soap paper has the residual of paper handkerchief or non-woven fabrics when in use;Another kind is to decontamination Film forming agent is added in the active ingredients such as agent, is directly shaped to film-form, then cuts into the small pieces of various moulding, is put into packaging In cylinder or packaging bag, so manufactured soap paper using when can be completely dissolved and rinse well, noresidue, usage experience is more excellent.However, When soap paper is placed for a long time in atmosphere made of the latter, certain hygroscopicity is had, so that soap paper produces glutinous soapy feeling, and The fragrance component contained in soap paper constantly volatilizees, fugitive color, the serious pot-life for restricting soap paper and preservation condition, generally needs It is loaded into closed packing tube and is sold.
Horn of plenty product diversity, the soap paper that soap paper is made to various odor types is studied, typically by adding into soap body Enter the plants essential oil with aromatic odor(For example, osmanthus essential oil), can not be from vision however, only adding plants essential oil to realize Upper improvement product appearance characteristic, therefore, inventor considers to add fresh petal or dry petal in soap lye, and phase is embedded among production Answer the odor type soap paper of petal, however, because the other materials in soap lye can not be in contact with petal well, in soap lye solidification and During extruding film forming, embedding petalled position is very easy to be separated with the other parts of film, and in drying process by It is different in shrinkage factor, above-mentioned separation also easily occurs, causes breakage, defect rate improves.
The content of the invention
In order to solve the above technical problems, the present inventor changes preparation technology, the soap-film both sides of sweet osmanthus petal will be embedded with One layer of water-soluble hyaline membrane is respectively covered, is then extruded and is dried again, avoids embedding petalled film part from occurring damaged, meanwhile, The effect of isolation air can also be functioned well as, soap-film moisture absorption is avoided and caused glutinous soapy feeling, fragrance volatilizing can be avoided again and taken off Color, and soap letterweight can be obtained it is very thin, can directly bind into book form son or book form, avoid the use of packing tube, enter one Step improves portability, so as to complete the present invention.
Therefore, in one aspect, the invention provides a kind of osmanthus flower fragrant soap paper, the osmanthus flower fragrant soap paper bag, which contains, to be covered with The soap-film of water-solubility membrane, wherein, the soap-film is embedded with sweet osmanthus petal, and the raw material for preparing the water-solubility membrane includes poly- second Enol, water-based quick dry agent, paraffin.
The raw material for preparing the soap-film comprises at least film forming agent, plasticizer, surfactant, antiseptic, solvent, sweet osmanthus essence Oil and sweet osmanthus petal.
The film forming agent can be gelatin, starch, dextrin, polyvinyl alcohol, cellulose etc., preferred starch and dextrin.
The plasticizer is glyceride, succinate, tartrate.
The surfactant can be dodecyl sodium sulfate, Cocoamidopropyl betaine, octyl phenol polyoxyethylene Ether or their mixture.
The antiseptic is triclosan, triclocarban, allantoin.
The solvent is glycerine, water, ethanol.
In addition, the conventional additives such as NMF can also be added when preparing the soap-film of the present invention.The NMF such as glass Uric acid, tartaric acid, sorbierite etc..
In another aspect, present invention also offers the preparation method of the osmanthus flower fragrant soap paper, methods described to include:
(1)Film forming agent, plasticizer, surfactant, antiseptic, osmanthus essential oil are added in solvent, stirred at 60-70 DEG C mixed Close uniformly, then add sweet osmanthus petal, form continuous film with film applicator, solid-state soap-film is solidified as in 80 DEG C of dryings;
(2)Polyvinyl alcohol, water-based quick dry agent, paraffin are dissolved in 80 DEG C of water, formed continuously with film applicator after stirring Mould, peeled off after drying, form water-solubility membrane;
(3)The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then pressed into by extruder thin Piece, then block is then cut into through heated-air drying at 95-105 DEG C, obtain the osmanthus flower fragrant soap paper.
Preferably, methods described further comprises binding into book form on the osmanthus flower fragrant soap paper.
The osmanthus flower fragrant soap paper of the present invention is moistureproof, anti-so as to play by the way that two surfaces of soap-film are covered with into water-solubility membrane Fade, the effect of anti-spices volatilization, be advantageous to bind into book form on soap paper, compared to the manner of packing of packing tube, further improve Portability, on the other hand, also well sweet osmanthus petal is embedded in soap paper, and avoids the soap-film in extruding, drying process damaged Phenomenon, greatly improve the outward appearance ornamental value of osmanthus flower fragrant soap paper.
Embodiment
The present invention is further described with reference to specific embodiment.
Embodiment 1
By 20g starch, 30g dextrin, 35g ethyl succinates, 15g dodecyl sodium sulfates, 15g Cocoamidopropyl betaines, 0.2g triclosans, 1g osmanthus essential oils are dissolved in 10mL glycerine, 100mL water, the in the mixed solvent of 5mL ethanol composition, are stirred at 70 DEG C Mix it is well mixed, then add 5g dried sweet-scented osmanthus petals, using film applicator formed continuous film, be solidified as solid-state soap in 80 DEG C of dryings Film.
50g polyvinyl alcohol, the water-based quick dry agents of 5g, 10g paraffin are dissolved in 80 DEG C of water, film applicator is used after stirring The progressive die is formed, is peeled off after drying, forms water-solubility membrane.
The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then pressed into by extruder thin Piece, then cut into 5cm × 4cm fritter through heated-air drying at 95-105 DEG C, bind into book form, obtain osmanthus flower fragrant soap paper.
Embodiment 2
50g polyvinyl alcohol, 35g ethyl succinates, 10g dodecyl sodium sulfates, 12g Cocoamidopropyl betaines, 15g is pungent Base phenol polyethenoxy ether, 0.1g triclosans, 2g sorbierites, 0.8g osmanthus essential oils are dissolved in 10mL glycerine, 100mL water, 5mL ethanol groups Into in the mixed solvent, be uniformly mixed at 60 DEG C, then add the fresh sweet osmanthus petals of 10g, use film applicator formed connect Continuous film, solid-state soap-film is solidified as in 80 DEG C of dryings.
50g polyvinyl alcohol, the water-based quick dry agents of 5g, 10g paraffin are dissolved in 80 DEG C of water, film applicator is used after stirring The progressive die is formed, is peeled off after drying, forms water-solubility membrane.
The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then pressed into by extruder thin Piece, then cut into 5cm × 4cm fritter through heated-air drying at 95-105 DEG C, bind into book form, obtain osmanthus flower fragrant soap paper.
Osmanthus flower fragrant soap paper prepared by 1-2 of the embodiment of the present invention without obvious breakage, tears to take and washes the used time and distribute osmanthus at petal Flowery odour, and after being placed 10 days in the environment of humidity 60%, soap paper outward appearance is almost unchanged.
Above only describes the better embodiment of the present invention, but the present invention is not limited to above-described embodiment.This area skill Art personnel all should fall into the present invention it is understood that any same or similar means of the technology of the present invention effect can be realized Protection domain in.

Claims (9)

1. a kind of osmanthus flower fragrant soap paper, the osmanthus flower fragrant soap paper bag contains the soap-film for being covered with water-solubility membrane, wherein, in the soap-film Embedded with sweet osmanthus petal, and the raw material for preparing the water-solubility membrane includes polyvinyl alcohol, water-based quick dry agent, paraffin.
2. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that prepare the soap-film raw material comprise at least into Film, plasticizer, surfactant, antiseptic, solvent, osmanthus essential oil and sweet osmanthus petal.
3. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the film forming agent be gelatin, starch, dextrin, Polyvinyl alcohol, cellulose etc., preferred starch and dextrin.
4. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the plasticizer be glyceride, succinate, Tartrate.
5. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the surfactant is dodecyl sodium sulfonate Sodium, Cocoamidopropyl betaine, OPEO or their mixture.
6. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the antiseptic be triclosan, triclocarban, Allantoin.
7. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the raw material for preparing the soap-film also includes moisturizing Agent.
8. osmanthus flower fragrant soap paper according to claim 1, it is characterised in that the NMF is sodium hyaluronate, tartaric acid, sorb Alcohol.
9. the preparation method of the osmanthus flower fragrant soap paper any one of claim 1-8, methods described include:
(1)Film forming agent, plasticizer, surfactant, antiseptic, osmanthus essential oil are added in solvent, stirred at 60-70 DEG C mixed Close uniformly, then add sweet osmanthus petal, form continuous film with film applicator, solid-state soap-film is solidified as in 80 DEG C of dryings;
(2)Polyvinyl alcohol, water-based quick dry agent, paraffin are dissolved in 80 DEG C of water, formed continuously with film applicator after stirring Mould, peeled off after drying, form water-solubility membrane;
(3)The water-solubility membrane is covered in two surfaces of the soap-film by laminating machine, is then pressed into by extruder thin Piece, then block is then cut into through heated-air drying at 95-105 DEG C, obtain the osmanthus flower fragrant soap paper.
CN201710953825.9A 2017-10-13 2017-10-13 A kind of osmanthus flower fragrant soap paper and preparation method thereof Withdrawn CN107674796A (en)

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Application Number Priority Date Filing Date Title
CN201710953825.9A CN107674796A (en) 2017-10-13 2017-10-13 A kind of osmanthus flower fragrant soap paper and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108220014A (en) * 2018-03-22 2018-06-29 南平博士达节能科技有限公司 A kind of osmanthus flower fragrant soap paper and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108220014A (en) * 2018-03-22 2018-06-29 南平博士达节能科技有限公司 A kind of osmanthus flower fragrant soap paper and preparation method thereof

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Application publication date: 20180209