CN1724321A - Impact resistance high wearing-proof conveyer belt - Google Patents

Impact resistance high wearing-proof conveyer belt Download PDF

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Publication number
CN1724321A
CN1724321A CN 200510035572 CN200510035572A CN1724321A CN 1724321 A CN1724321 A CN 1724321A CN 200510035572 CN200510035572 CN 200510035572 CN 200510035572 A CN200510035572 A CN 200510035572A CN 1724321 A CN1724321 A CN 1724321A
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China
Prior art keywords
parts
conveyer belt
impact resistance
resistance high
high wearing
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Granted
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CN 200510035572
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Chinese (zh)
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CN100372746C (en
Inventor
姜必多
姚雪容
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BEISHAN GELATINIZING Co Ltd YANGJIANG CITY
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BEISHAN GELATINIZING Co Ltd YANGJIANG CITY
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Priority to CNB2005100355724A priority Critical patent/CN100372746C/en
Publication of CN1724321A publication Critical patent/CN1724321A/en
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Publication of CN100372746C publication Critical patent/CN100372746C/en
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Abstract

An anti-impact and anti-wear conveying belt features that the rubber layer covered on its surface is proportionally prepared from natural rubber, synthetic rubber, sulfur, zinc oxide, stearic acid, promoter, reinforcing agent, softening agent and anti-ageing agent.

Description

Impact resistance high wearing-proof conveyer belt
Technical field
The present invention relates to the load-transfer device that a kind of belt conveyer is used, particularly a kind of impact resistance high wearing-proof conveyer belt that is applicable to the material transportation of industries such as metallurgy, chemical industry, building materials.
Background technology
Load-transfer device is the component part of belt conveyer, and ancillary engineering facility rubber, belt conveyer transported material have continuously and characteristics of high efficiency.No matter be long-distance and short distance.Open-air and indoor, heavy and light-duty, level and bending, inclination can be used under various transport condition with vertical.From the mine to the harbour, from the supermarket to the airport, can see its figure.It is the important means of logistics dispersion and concentration.The popularity of conveyor application reflects a province, city or regional modernization level to a certain extent in China, compares with automobile, railway transportation, and it can improve the gradient, shortens haul distance, reduce construction costs and traffic cost.Along with the building industry high speed development, driven the growth of the load-transfer device market demand.At present the load-transfer device framework material is to nylon and polyester development, nylon and the polyester backbone material 60-70% that accounted for, and NN-200, NN-300, EP-200, belt carcass materials such as EP-300 have obtained widespread use.The syntheticfibres belt carcass is powerful big, warping strength, meets wet mildew and rot.The absciss layer that uses cotton canvas to occur in the past, belt carcass is cross-section, quality problems such as glue and cloth delamination seldom, emphasis is reflection rubber cover poor flexibility and non-abrasion performance, the problem that lack service life.The economic benefit of belt conveyer except that the purchase cost of band, also has running expense, shutdown loss maintaining expense etc.Load-transfer device is the functor of belt conveyer, also is the easily-consumed products of high material-consumption, improves the quality, and prolongs product and economizes on resources exactly service life, improves environment (adhesive tape of scrapping can not be regenerated, and becomes rubbish) exactly, walks the road of sustainable development exactly.
Summary of the invention
Technical matters to be solved by this invention provides a kind of impact resistance high wearing-proof conveyer belt that good impact elasticity has abrasion resistance simultaneously again concurrently that has.
The present invention is achieved through the following technical solutions: design a kind of impact resistance high wearing-proof conveyer belt, comprise belt carcass and rubber cover, the preparation material of described rubber cover comprises following component and weight content: natural gum 60-80 part, rubber polymer 20-40 part, sulphur 1.5-2.5 part, zinc oxide 4-6 part, stearic acid 2-3 part, accelerator 1.5-2.5 part, reinforcing agent 50-60 part, soften flux 10-15 part, aging inhibitor 2-4 part.
As wherein preferable a kind of embodiment, the following set of dispense side of optional usefulness: 70 parts of natural gums, 30 parts of rubber polymers, 1.8 parts in sulphur, 5 parts in zinc oxide, 2.5 parts of stearic acid, 1.8 parts of accelerators, 55 parts of reinforcing agents, 11.5 parts of soften fluxs, 3 parts in aging inhibitor.
The physical property of described rubber cover requires: brute force 〉=18.0Mpa.Elongation at failure 〉=450%, wear loss≤100mm3, hardness 55-65A (Shao Er).Described rubber polymer is cis-butadiene cement or butadiene-styrene rubber; The material of described belt carcass is nylon canvas, polyester canvas or polyester/nylon canvas; Described reinforcing agent is intermediate super abrasion furnace black N220 and high wear-resistant carbon black N330, and wherein N220 selects 15-20 part for use, and N330 selects 35-40 part for use; Described soften flux is the miscellany of solid coumarone and machine oil.
Compared with prior art, of the present invention have following advantage and a beneficial effect:
1) owing to selected for use premium-quality material and reasonable scientific formula to form, shop characteristic is good, excellent product performance, the belt smooth surface of producing, apparent defect seldom, its rubber cover had both had good shock resistance and had also had high-wear resistance and good aging properties concurrently, and this is initiative at home.Its impact elasticity 〉=40%, abrasion≤100mm 3Can resist the impact of the bigger stone of drop or other material, long-term under the strong abrasive conditions of coarse bulk or grain, self wear away few, long service life, powerful big, rubber cover is difficult for collapsing piece, tears in the transportation of sharp keen lump material, is specially adapted to the use of large-scale stone field HI high impact, high drop conveyer and large-scalely adopts the use that sand height speed is transported river sand.
2) generally speaking, rubber hardness height then wear hardness is good, but anti-impact force is poor; Hardness is hanged down then good springiness, shock resistance, but wear hardness is poor.Rubber cover of the present invention has both shock resistance and two kinds of performances of high abrasion simultaneously, has solved contradiction between the two.
3) service life of impact resistance high wearing-proof conveyer belt be normal tape 2-3 doubly, only than the high 20-30% of normal tape, cost performance is very high for its price, and the economic benefit that improves the user is played good effect.
4) load-transfer device of the present invention is pollution-free in process of production.Because adhesive tape is two to three times of normal tape service life, thereby reduces the pollution of scrapping adhesive tape, helps the saving of environmental protection and resource, make sustainableization of development.
Description of drawings
Fig. 1 is the technological process of production figure of impact resistance high wearing-proof conveyer belt of the present invention.
Fig. 2 is the structure cross-sectional schematic of load-transfer device of the present invention.
The specific embodiment
The present invention will be helped to understand by following embodiment, but content of the present invention and protection domain can not be limited.
Embodiment one: the structure of load-transfer device of the present invention is made up of last rubber cover 1, cushion compound 2, belt carcass 3, following rubber cover 4 and limit glue 5 as shown in Figure 2.Reach the double effects of shock resistance and high abrasion, the making of rubber cover is crucial.The rubber cover of present embodiment prepares material and comprises following component and weight content: 70 parts of natural gums, and 30 parts of rubber polymers, 1.8 parts in sulphur, 5 parts in zinc oxide, 2.5 parts of stearic acid, 1.8 parts of accelerators, 55 parts of reinforcing agents, soften flux 11.5,3 parts in aging inhibitor adds up to 180.6 parts.
The elastomeric material aspect, natural gum elasticity, brute force, adhesive bonding property, shop characteristic are all fine, but wear hardness is slightly poor, and impact elasticity is less than cis-butadiene cement.The cis-butadiene cement resistance to abrasion is fine, and elasticity is also good than butadiene-styrene rubber, natural gum, be as the reasonable glue kind of impact resistance high wearing-proof conveyer belt rubber cover, but its brute force is low, and viscosity is poor, and shop characteristic is bad, can only and use with natural gum.Butadiene-styrene rubber is general rubber polymer, and powerful better than cis-butadiene cement, wear hardness is better than natural gum, but elastic ratio cis-butadiene cement and natural gum are poor.More than in three kinds of rubber production based on natural gum, the part of suitably arranging in pairs or groups cis-butadiene cement or butadiene-styrene rubber.
In order to satisfy the performance requriements of impact-resistant and high-wear-resistant, need below be to describe in detail to reinforcing agent, soften flux, vulcanizing system and aging inhibitor research experiment in the prescription and preferred:
The reinforcing agent aspect is because that the brute force of the rubber cover of impact resistance high wearing-proof conveyer belt requires is high, so select for use us to do many tests to reinforcing agent.From test results, the performance of Maoming intermediate super abrasion furnace black (N220) is good, and this carbon black physical property after chemically examining is: tensile strength at break 25.9Mpa, elongation at failure 475%, DBP absorption value 115 * 10 -5m 3/ Kg.Resistance to abrasion was good after prescription added N220, and pulling strengrth is also big, and resistance to abrasion exceeds 10-20% with respect to high wear-resistant carbon black (N330), and hardness has then increased 2-3A (Shao Er).Maoming high abrasion (N330) is also good to the reinforcing property and the wear hardness of sizing material, and physical property is after chemically examining: tensile strength at break 25Mpa, elongation at failure 450%, DBP absorption value 110 * 10 -5m 3/ Kg.Two kinds of N220 and N330 and time spent, N220 uses 15-20 part generally speaking, and N330 uses 35-40 part, and two kinds add up to 55 parts.And this prescription chemical examination back physical property tensile strength at break is 19-21Mpa, and abrasion are at 40-80mm 3Between.
Reinforcing agent is made owing to add more carbon black in the prescription in the soften flux aspect, just can make sizing material in refining glue and rolling out film technology the favorable manufacturability energy be arranged so must add certain soften flux.Soften flux commonly used has solid coumarone resin, pitch, machine oil and pine tar, and these several soften fluxs to the influence of tensile strength, elongation at failure, elasticity and the abrasion of prescription are:
Tensile strength: solid coumarone>pitch>machine oil>pine tar
Elongation at failure: pine tar>machine oil>pitch>solid coumarone
Elasticity: pine tar>machine oil>pitch>solid coumarone
Wear hardness: pitch<solid coumarone<machine oil<pine tar
Consider from physical property and shop characteristic, preferably select solid coumarone and machine oil and usefulness for use.Because gum content is higher in the prescription, if add pine tar then sizing material viscosity is excessive, the molding procedure inconvenient operation, though and pitch wear resistance ratio coumarone is better, reinforcing property is less than coumarone.
The vulcanizing system aspect adopts sulfur cross-linking owing to added partly rubber polymer, sulfur consumption during greater than 2 parts hardness want height a bit, aged properties is also a little bit poorer, thus sulfur consumption be 1.8 parts proper.
General aging inhibitor commonly used can be used in the aging inhibitor aspect, can reach aging requirement about 3 parts, and about elongation at failure-5%, percentage elongation is about-10~15% after 70 ℃ * 168h rubber cover is aging.
The following two kinds of canvas of optional usefulness are as the framework material of impact-resistant and high-wear-resistant: a kind of is the nylon dipped canvas, nylon fiber claims nylon fibre again, be that present adhesive tape uses maximum framework materials, nylon fibre is a kind of fiber powerful higher in the syntheticfibres of suitability for industrialized production, its hydroscopicity is very low, the elasticity height, fatigue durability is good, the rebound degree of nylon fibre is 98-100%, nylon cloth and rubber adhesion power through impregnation are higher, the adhesive tape that company produces, generally (standard 〉=4.5N) is so can stand HI high impact at 7-9N/mm for the nylon cloth interlayer adhesion, high-speed cruising is difficult for absciss layer, be difficult for coming unstuck, because adhesive tape is made up of the multilayer canvas.Cloth and cloth, layer of cloth and glue-line are bonding good, are difficult for absciss layer and destruction when being hit power.Another kind is the EP canvas, claims the polyester/nylon canvas again, and its warp-wise is a poly-ester fibres, and broadwise is a nylon fiber, its powerful high, good heat resistance, warp-stretch is little, and the adhesive tape made from it extends little in operational process, dimensionally stable, but its hardness is big, deflects performance less than nylon canvas.
With reference to flow scheme shown in Figure 1, the production technology of impact resistance high wearing-proof conveyer belt of the present invention is described as follows:
1) rubber mixing technique: rubber cover can carry out in mill, also can carry out in Banbury mixer.But Banbury mixer is effective, and sizing material is uniformly dispersed, error is little.But just can carry out mixing after cis-butadiene cement must refine evenly with natural gummed, if do not close refining evenly carry out mixing because cis-butadiene cement is stronger than natural gum to the affinity of carbon black, the carbon black that cis-butadiene cement is sneaked into will prior to greater than natural gum, thereby causing the irregularity of sizing material, the brute force of sizing material is also low.We have done test at rubber mixing technique: cis-butadiene cement and natural gum close evenly back rubber Hui Leng of refining earlier, and second day mixing again sizing material do not close refining and the mixing powerful big 2-3Mpa of sizing material than two kinds of glue.From the section of vulcanizate, the latter can see grain, this glue again with mill repeatedly thin-pass also be difficult for being uniformly dispersed.
2) calendering technology: the sandwich layer of impact resistance high wearing-proof conveyer belt adopts the NN canvas or the EP canvas of duck conveyor belt.Its rubber cover rolling out film and normal tape difference are little, because its rubber gum content height, semi-manufactured goods quality requires high, want strict so go out blade technolgy, the thick refining and the refining of sizing material carried out in technological operation, and the film size that guarantee to extrude is accurate, smooth surface, do not have cold line, no bubble.
3) forming process: the viscosity of rubber cover is good, film is powerful big, the relatively good operation of molding procedure, but under the environment of weather sweltering heat, if sizing material viscosity is excessive, operate also pretty troublesome, the chill roll of major control rolling out film machine at this moment, temperature will be hanged down, and film operation after fully cooling off does not just have too big inconvenience.Perhaps standing time is longer after the slice.
4) sulfuration process: little with the normal tape difference, but because gum content height, sizing material is more sticking, thus the time of the sprinkling of the water-soluble silicon oil before will noting vulcanizing and and concentration, before sulfuration, sprayed in 1 to 2 minute, behind the adhesive tape sulfuration matched moulds 1 to 2 minute the time pine press two to three times, at this moment silicone oil is vaporized after heating, and the air of tape surface can be discharged smoothly when pine is pressed, and the product mold filling performance of sulfuration is good, smooth surface, outward appearance is good.
Physical property such as following table through the chemical examination load-transfer device:
The rubber cover performance Interventions Requested Unit Industry standards Testing result Conclusion
(1) (2)
Pulling strengrth Mpa ≥18.0 20.2 22.5 Qualified
Elongation rate of tensile failure ≥450 490 516 Qualified
Abrasion loss mm 3 ≤100 75 75 The platform lattice
Hardness (Shao Er) A 55-65 58 64 Qualified
Elasticity ≥40 43 45 Qualified
Aging after drawing change rate of strength ±25 -3.5 -6 Qualified
Break elongation change after aging ±25 -10.2 -13 Qualified
Cloth interlayer bond strength Whole sample means N/mm ≥4.5 8.2 7.3 Qualified
Whole sample minimum peaks N/mm ≥3.9 5.6 6.5 Qualified
The bonding aviation value of rubber cover and cloth N/mm ≥3.5 9.2 8.5 Qualified
The through thickness longitudinal tensile strength N/mm ≥1200 1300 Qualified
≥1000 1094 Qualified
From assay, every performance of rubber cover all reaches the requirement of standard code.
Domestic load-transfer device technical standard (load-transfer device has the general applications fabric core conveyor belt GB/T7984-2001 of rubber or plastics covering) is as follows with applicant's company standard contrast:
Project The GB/T7984-2001 national standard The north glue standard Q/YJBJ03 of incorporated business
The H type The D type The L type
Rubber cover Pulling strengrth Mpa 〉= 24.0 18.0 15.0 18.0
Elongation at failure % 〉= 450 400 350 450
Wear loss mm 3 120 100 200 100
Elasticity % 〉= No index No index No index 40
Hardness A (Shao Er) No index No index No index 55-65
User's condition of service: because the rubber cover that this band is planted is powerful big, standard code 〉=18.0Mpa, the finished product brute force is controlled at about 18-20Mpa, 15Mpa height than normal tape, can resist the big impact of stone drop, use the glue that collapses that normal tape often occurs in the past, limit portion phenomenon such as tears and is improved.Its rubber cover good springiness, wear hardness are good, generally speaking than one times to three times of normal tape long service life, or longer.Transport ore as XX ore deposit, Yunfu, originally use 900X6 (6+2) X42 rice, the general rubber cover that just wore and tore in 3 months that uses of NN-200 normal tape, now use the shock resistance band used 6 months also fine, estimation can also be used 3 months: the large-scale sand ship of adopting of the yellow XX of three water, use NN-200 nylon 1200X5 (4+1.5) X24 rice fortune sand ribbon in the past, because this band running speed is very high, per minute is up to 500 meters, with normal tape generally also is about 2 months, now can use 6 months with high abrasion resistance tape, transport the sand ribbon at a high speed than long about 3 times of normal tape life-span: Jiujiang, South Sea xx sand dredger use NN-200 nylon 11 00X5 (5+2), past just wore away with general use of normal tape in 1 month, used now five months also fine, estimation can also be used more than 3 months.
Embodiment two: production technology aspect and embodiment one are basic identical, the material component of rubber cover is done suitably to adjust, and adopts following prescription: 75 parts of natural gums, 35 parts of rubber polymers, 2 parts in sulphur, 5 parts in zinc oxide, 3 parts of stearic acid, 2 parts of accelerators, 60 parts of reinforcing agents, soften flux 13,4 parts in aging inhibitor adds up to 199 parts.
Certainly, the present invention is not limited to above-mentioned illustrated embodiment, under main intention design of the present invention, the embodiment of some variations can also be arranged, and also should belong within protection scope of the present invention.

Claims (7)

1. impact resistance high wearing-proof conveyer belt, comprise belt carcass and rubber cover, it is characterized in that the preparation material of described rubber cover comprises following component and weight content: natural gum 60-80 part, rubber polymer 20-40 part, sulphur 1.5-2.5 part, zinc oxide 4-6 part, stearic acid 2-3 part, accelerator 1.5-2.5 part, reinforcing agent 50-60 part, soften flux 10-15 part, aging inhibitor 2-4 part.
2. impact resistance high wearing-proof conveyer belt according to claim 1, it is characterized in that, the preparation material of described rubber cover comprises following component and weight content: 70 parts of natural gums, 30 parts of rubber polymers, 1.8 parts in sulphur, 5 parts in zinc oxide, 2.5 parts of stearic acid, 1.8 parts of accelerators, 55 parts of reinforcing agents, 11.5 parts of soften fluxs, 3 parts in aging inhibitor.
3. impact resistance high wearing-proof conveyer belt according to claim 1 and 2 is characterized in that, the physical property requirement of described rubber cover is: brute force 〉=18.0Mpa, elongation at failure 〉=450%, wear loss≤100mm 3, hardness 55-65A (Shao Er).
4. impact resistance high wearing-proof conveyer belt according to claim 1 and 2 is characterized in that, described rubber polymer is cis-butadiene cement or butadiene-styrene rubber.
5. impact resistance high wearing-proof conveyer belt according to claim 1 and 2 is characterized in that, the material of described belt carcass be nylon canvas, polyester canvas or the polyester/nylon canvas.
6. impact resistance high wearing-proof conveyer belt according to claim 1 and 2 is characterized in that, described reinforcing agent is intermediate super abrasion furnace black N220 and high wear-resistant carbon black N330, and wherein N220 selects 15-20 part for use, and N330 selects 35-40 part for use.
7. impact resistance high wearing-proof conveyer belt according to claim 1 and 2 is characterized in that, described soften flux is the miscellany of solid coumarone and machine oil.
CNB2005100355724A 2005-06-24 2005-06-24 Impact resistance high wearing-proof conveyer belt Expired - Fee Related CN100372746C (en)

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Cited By (14)

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Publication number Priority date Publication date Assignee Title
CN101020530B (en) * 2007-03-23 2010-05-19 无锡宝通带业股份有限公司 Anti-tearing and wear-resistant conveying belt
CN101214880B (en) * 2008-01-11 2010-07-28 浙江东南橡胶机带有限公司 Tearing-proof high temperature resisting conveyer belt
CN102140191A (en) * 2011-03-04 2011-08-03 杭州顺豪橡胶工程有限公司 High-wear resistance skirt rubber material for reconstruction of conveyer belt on damage site and skirt on-site reconstruction method
CN102146172A (en) * 2011-03-13 2011-08-10 衡水起行橡塑有限公司 Super wear-resistant rubber-plastic conveyer belt
CN102643459A (en) * 2012-05-08 2012-08-22 无锡宝通带业股份有限公司 Super-wear-resistant covering rubber for conveying belt and preparation method thereof
CN102924757A (en) * 2011-08-12 2013-02-13 招远市泰仑特塑胶化工有限公司 External-layer low-hardness rubber fender
CN103183199A (en) * 2011-12-30 2013-07-03 青岛橡六输送带有限公司 Patterned conveying belt and manufacturing method thereof
CN103665701A (en) * 2013-11-26 2014-03-26 际华三五一七橡胶制品有限公司 Novel composite resin-ancient pine resin and preparation method thereof
CN106867044A (en) * 2017-01-05 2017-06-20 开封铁塔橡胶(集团)有限公司 High resiliency, wear-resistant, shock resistance conveyer belt and preparation method thereof
CN107828090A (en) * 2017-11-27 2018-03-23 谢彬彬 A kind of wear-resisting ageing-resistant rubber and preparation method thereof
CN110158511A (en) * 2019-06-26 2019-08-23 李辰 Rotate guardrail
CN110643081A (en) * 2019-09-27 2020-01-03 江苏冠联新材料科技股份有限公司 Wear-resistant flame-retardant conveyor belt natural rubber material and preparation method thereof
CN113621205A (en) * 2021-08-23 2021-11-09 三河市长城橡胶有限公司 Rubber plate for excrement channel and preparation method and application thereof
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CN1428393A (en) * 2001-12-24 2003-07-09 贾剑珉 High-strength flexible covering rubber and its making method
CN1260280C (en) * 2002-08-01 2006-06-21 阜新橡胶有限责任公司 Smokeless flame resistant conveying belt without halide

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CN101020530B (en) * 2007-03-23 2010-05-19 无锡宝通带业股份有限公司 Anti-tearing and wear-resistant conveying belt
CN101214880B (en) * 2008-01-11 2010-07-28 浙江东南橡胶机带有限公司 Tearing-proof high temperature resisting conveyer belt
CN102140191A (en) * 2011-03-04 2011-08-03 杭州顺豪橡胶工程有限公司 High-wear resistance skirt rubber material for reconstruction of conveyer belt on damage site and skirt on-site reconstruction method
CN102140191B (en) * 2011-03-04 2013-04-24 杭州顺豪橡胶工程有限公司 High-wear resistance skirt rubber material for reconstruction of conveyer belt on damage site and skirt on-site reconstruction method
CN102146172A (en) * 2011-03-13 2011-08-10 衡水起行橡塑有限公司 Super wear-resistant rubber-plastic conveyer belt
CN102924757A (en) * 2011-08-12 2013-02-13 招远市泰仑特塑胶化工有限公司 External-layer low-hardness rubber fender
CN103183199B (en) * 2011-12-30 2016-03-30 青岛橡六输送带有限公司 A kind of pattern conveyor belt and manufacture method thereof
CN103183199A (en) * 2011-12-30 2013-07-03 青岛橡六输送带有限公司 Patterned conveying belt and manufacturing method thereof
CN102643459A (en) * 2012-05-08 2012-08-22 无锡宝通带业股份有限公司 Super-wear-resistant covering rubber for conveying belt and preparation method thereof
CN103665701A (en) * 2013-11-26 2014-03-26 际华三五一七橡胶制品有限公司 Novel composite resin-ancient pine resin and preparation method thereof
CN106867044A (en) * 2017-01-05 2017-06-20 开封铁塔橡胶(集团)有限公司 High resiliency, wear-resistant, shock resistance conveyer belt and preparation method thereof
CN107828090A (en) * 2017-11-27 2018-03-23 谢彬彬 A kind of wear-resisting ageing-resistant rubber and preparation method thereof
CN110158511A (en) * 2019-06-26 2019-08-23 李辰 Rotate guardrail
CN110643081A (en) * 2019-09-27 2020-01-03 江苏冠联新材料科技股份有限公司 Wear-resistant flame-retardant conveyor belt natural rubber material and preparation method thereof
CN113621205A (en) * 2021-08-23 2021-11-09 三河市长城橡胶有限公司 Rubber plate for excrement channel and preparation method and application thereof
CN113621205B (en) * 2021-08-23 2023-06-06 三河市长城橡胶有限公司 Rubber plate for manure tracks and preparation method and application thereof
CN115504159A (en) * 2022-10-19 2022-12-23 吴善聪 Ultrahigh wear-resistant anti-tearing conveying belt

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