CN1693552A - Functional fibre - Google Patents
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- CN1693552A CN1693552A CN 200410010249 CN200410010249A CN1693552A CN 1693552 A CN1693552 A CN 1693552A CN 200410010249 CN200410010249 CN 200410010249 CN 200410010249 A CN200410010249 A CN 200410010249A CN 1693552 A CN1693552 A CN 1693552A
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Abstract
The invention discloses a functional fiber, composed of animal protein, high molecular polymer and metal element-containing matter in weight shares of A, B and C, where 1<=A<=98, 0<C<1 or 5<C<23, and B the rest. The invention also discloses a manufacturing method for this functional fiber. This functional fiber has better skin affinity and humidity transmitting property, and simultaneously, has higher bacterial inhibiting and shielding ratios, as well as far infrared emitting function and can produce higher-concentration negative ions, and also has higher UV absorptivity and many good functions, such as absorbing electromagnetic waves, protecting radiation, etc.
Description
Technical field
The invention belongs to synthetic fiber, relate in particular to fiber with functional effect.
Background technology
General synthetic fiber skin-friendly, gas permeability are relatively poor, I am 02109966.9 in the patent No. for this reason, name is called " plant protein synthetic fiber and manufacture method thereof " and other people and is 03111814.3 at application number, is called in the document of " a kind of soylon and manufacture method thereof " and all discloses proteinaceous fiber and manufacture method, the fiber that makes by foregoing invention, skin-friendly, lead moist, pliability and gloss all fine, but these fibers other is functional relatively poor; Application number is to disclose " a kind of process technology of the keratin functional fibre of regenerating " in 0215540.7 the patent documentation, the fiber that adopts this process technology to produce has certain function such as antistatic, antibiotic, but because protein component only has keratin in the component of this fiber, metal ingredient also only is a spot of metal oxide, therefore utilize this technology not only can not utilize resource widely, and the functional fiber kind of producing is also less.
Summary of the invention
The object of the present invention is to provide a kind of not only skin-friendly, lead moist better, and fiber with multiple function; And utilize various animal proteins to do the method for this fiber of raw material production.
The objective of the invention is to be achieved through the following technical solutions: a kind of functional fiber, it is made up of the material of animal protein, high molecular polymer and containing metal element, and animal protein accounts for A part of total amount, high molecular polymer accounts for B part of total amount, the material of containing metal element accounts for C part of total amount, then: 1≤A≤98,0＜C＜1 or 5＜C＜23, surplus are high molecular polymer B.
Animal protein content is 1＜A＜45.
Described animal protein is milk casein, keratin, collagen or insect protein.
Described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
Described high molecular polymer is cellulose or vinyl acetate.。
Described metallic element is a kind of metallic element.
Described metallic element is at least two kinds of different metallic elements.
The material of described containing metal element is the composition of metal oxide, metallic compound, containing metal element and metal complex, metallo-organic compound.
This functional fiber can be in order to the below manufactured: the material that takes by weighing protein, high molecular polymer and containing metal element earlier by proportioning, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the material of metallic element by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing protein and high molecular polymer by proportioning earlier, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing protein by proportioning earlier it is made solution, the material that adds the containing metal element of proportional quantity part again reacts by it, the high molecular polymer that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain metalloenzyme by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing high molecular polymer by proportioning earlier, it is made solution, the containing metal elemental substance that adds proportional quantity part again reacts by it, the protein that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing protein, high molecular polymer by proportioning earlier and contain the material of metallic element, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain metalloenzyme by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing protein and high molecular polymer by proportioning earlier, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing protein by proportioning earlier it is made solution, the material that contains metallic element that adds proportional quantity part again reacts by them, the high molecular polymer that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: take by weighing high molecular polymer by proportioning earlier, it is made solution, the material that contains metallic element that adds proportional quantity part again reacts by them, the protein that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
This functional fiber can also be in order to the below manufactured: the material that takes by weighing protein, high molecular polymer and containing metal element earlier by proportioning, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation.
This functional fiber can also be in order to the below manufactured: take by weighing protein, high molecular polymer by proportioning earlier and contain the material of metallic element, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation.
Fiber internal cause with manufacturing of the present invention contains animal protein and high molecular polymer, therefore its institutional framework is changed to some extent, produced preferably skin-friendly and led moist, again because of the kind difference of contained animal protein in the fiber, the content difference, and the containing metal material difference that adds, therefore if adjust the protein content of making fiber or and composition or add the kind of metallics, the scope of choosing of albumen and metallics is more widely arranged among the present invention, so can produce flexible in various degree fiber according to people's needs, the fiber of gas permeability and multiple function; The sample of these fibers detects through detection department of country and learns, their fabric not only skin-friendly, lead moist better, also have higher bacteriostasis rate and screening rate respectively or simultaneously, have far-infrared transmitting function, also can produce higher negative ion concentration, also have higher absorption of UV and absorb multiple good function such as electromagnetic wave, radiation proof.
The specific embodiment
Embodiment 1, the milk casein is added the alkaline solution dissolving, solution temperature is 15 ℃-95 ℃, and course of dissolution should stir, then leave standstill, separate and remove waste residue, leachate, in leachate, add hydrochloric acid, transfer the leachate isoelectric point must separate protein; The isolated protein that makes is dissolved in the alkaline solution that contains triethanolamine, makes protein solution; Directly add the polyvinyl alcohol of having washed in the protein solution, make its blend copolymerization, make the spinning solution that contains milk casein protein and polyvinyl alcohol, adding boric acid stirs and makes spinning solution in this solution again, containing doing of milk casein protein in this spinning solution, to measure A admittedly be 10 weight portions, it is 89.5 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains aluminium oxide, salicly in this body lotion do that to measure C admittedly be 0.5 weight portion, then tow is through air draft, wet bath drawing-off, do drawing-off and HEAT SETTING and make semi-finished product, semi-finished product promptly become finished product again after acetalation and arrangement.
Embodiment 2, get keratin and polyvinyl alcohol and make solution jointly, make their blend copolymerization make spinning solution, keraticly in this spinning solution do that to measure A admittedly be 44.5 weight portions, it is 31 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters and contains in the talcous coagulation bath of 12.5 weight portions, then tow is again through air draft, wet bath drawing-off and dried drawing-off, enter and contain the chlorophyllous style keeping liquid of 10 weight portions and then make semi-finished product, semi-finished product promptly become finished product again after acetalation and arrangement.
Embodiment 3, get collagen and polyacrylonitrile is made spinning solution, containing doing of collagen in this spinning solution, to measure A admittedly be 5 weight portions, it is 75 weight portions that the doing of polyacrylonitrile measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 10 weight portion oxidized hemes, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, semi-finished product promptly become finished product after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains 10 weight portion tourmaline again.
Embodiment 4, get protein, polyacrylonitrile and acrylonitrile are made spinning solution, proteinaceously in this spinning solution do that to measure A admittedly be 28.9 weight portions, it is 50 weight portions that the doing of polyacrylonitrile measured B admittedly, the dried solid amount of acrylonitrile is 3 weight portions, protein herein is the mixture of collagen and insect protein, wherein the dried solid amount of insect protein is 16 weight portions, it is 12.9 weight portions that collagenic protein is done solid amount, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 4.1 weight portion di-iron trioxides, then tow is again through air draft, wet bath drawing-off and dried drawing-off, then enter to contain in the magnesian style keeping liquid of 10 weight portions and carry out making semi-finished product after the HEAT SETTING, semi-finished product promptly become finished product after putting into the dyeing and finishing body lotion dyeing and finishing that contains 4 weight portion tri-iron tetroxides again.
Embodiment 5, get keratin, polyvinyl alcohol and polyacrylonitrile and make spinning solution, containing doing of keratin protein in this spinning solution, to measure A admittedly be 47 weight portions, the solid amount of doing of polyvinyl alcohol and polyacrylonitrile is respectively 27 weight portions and 13 weight portions, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters coagulation bath, enter after drawing-off in the style keeping liquid that contains 2.4 weight portion calcium phosphate and 10.6 parts by weight of titanium dioxide, making behind the semi-finished product promptly becomes finished product again after acetalation and arrangement.
Embodiment 6, collagen added in the acid solution dissolve, course of dissolution should stir, then leave standstill, separate and remove waste residue, leachate, in leachate, add NaOH, transfer the leachate isoelectric point must separate protein; The isolated protein that makes is dissolved in the acid solution that contains triethanolamine, makes protein solution; Directly add polyvinyl alcohol and the acrylonitrile washed in the protein solution, make its blend copolymerization, make and contain collagenic protein, the spinning solution of polyvinyl alcohol and acrylonitrile, the adding borax stirs and makes spinning solution in this solution again, containing doing of collagen in this spinning solution, to measure A admittedly be 97 weight portions, it is 1.1 weight portions that the doing of polyacrylonitrile measured B admittedly, the dried solid amount of acrylonitrile is 1 weight portion, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath, then tow is again through air draft, wet bath drawing-off, make semi-finished product after doing drawing-off and HEAT SETTING, semi-finished product are put into the dyeing and finishing body lotion that contains 0.6 weight portion cobalt particulate and 0.3 weight portion chrome green and are carried out dyeing and finishing, then become finished product.
Embodiment 7, get insect protein and cellulose is made spinning solution, containing doing of insect protein in this spinning solution, to measure A admittedly be 60 weight portions, cellulosicly do that to measure B admittedly be 39.55 weight portions, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters and contains in the kaolinic coagulation bath, after drawing-off, enter in the style keeping liquid that contains alkyl aluminum and finalize the design, make semi-finished product, put into the dyeing and finishing body lotion that contains nanoscale nickel and thorium again and carry out dyeing and finishing, then become finished product, the material of the containing metal element that is added do solid amount with C be 0.45 part, wherein kaolin is 0.1 part, alkyl aluminum respectively is 0.15 part, and nickel and thorium respectively are 0.1 part.
Embodiment 8, insect protein added in the distilled water dissolve, course of dissolution should stir, and makes protein solution; Directly add the cellulose of having washed in the protein solution, make its blend copolymerization, make and contain insect protein and spinning of cellulose solution, containing doing of insect protein in the solution, to measure A admittedly be 33 weight portions, cellulose is done and measured B admittedly is 66.05 weight portions, in this solution, add triethyl aluminum then, it is 0.95 weight portion that the doing of triethyl aluminum measured C admittedly, make their copolymerization make spinning solution, then spinning solution is carried out adopting dry spinning to make tow after the deaeration, this tow becomes finished product after drawing-off, typing, acetalation and arrangement.
Embodiment 9, milk casein, hair protein, polyvinyl alcohol, vinyl acetate are made solution respectively, then they are mixed, in this mixed liquor, add cupric oxide again, make spinning solution, the solid amount of doing of milk casein and hair protein is 20 weight portions in the spinning solution, vinyl acetate and polyvinyl alcohol are 25.5 weight portions, cupric oxide is 5 weight portions, spinning solution adopts wet spinning after deaeration, fiber enters in the coagulation bath that contains 4 weight portion zeolite powders, and after drawing-off, typing, acetalation and arrangement become finished product.
Embodiment 10, take by weighing hair protein, collagen, polyacrylonitrile and acrylonitrile by dosage, make them be dissolved in the distilled water jointly, make solution, wherein the dried solid amount of hair protein and collagen respectively is 0.5 weight portion, it is 98 weight portions that polyacrylonitrile is done solid amount, the dried solid amount of acrylonitrile is 0.89 weight portion, in this mixed liquor, add the ferrocene of 0.01 weight portion and the antimonous oxide of 0.1 weight portion again, make spinning solution jointly, after deaeration, adopt dry spinning, and after typing, acetalation and arrangement become finished product.
Embodiment 11, make spinning solution with the animal protein and the acrylonitrile that contain insect protein, hair protein, collagen and milk casein, wherein the solid amount of doing of every kind of protein is 9 weight portions, it is 58.5 weight portions that acrylonitrile is done solid amount, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath, through drawing-off, typing and acetalation, then enter in the dyeing and finishing body lotion that contains 3 weight portion montmorillonites and 2.5 weight portion silver oxides and carry out becoming finished product after the dyeing and finishing.
Embodiment 12, make spinning solution with insect protein and vinyl acetate, the dried solid amount of insect protein is 25 weight portions, it is 74 weight portions that vinyl acetate is done solid amount, carry out spinning with dry-jet wet spinning after the spinning solution deaeration, tow enters coagulation bath, through drawing-off, then enters in the style keeping liquid that contains 1 weight portion, three carbonyl cyclopentadiene manganese, acetalation liquid through containing 10 weight portion cupric oxide carries out acetalation again, then becomes finished product after the arrangement.
Embodiment 13, make spinning solution with insect protein, polyvinyl alcohol, polyacrylonitrile, acrylonitrile and sepiolite powder, the dried solid amount of insect protein is 15 weight portions, it is 10.5 weight portions that polyvinyl alcohol is done solid amount, it is 20 weight portions that polyacrylonitrile is done solid amount, it is 40.5 weight portions that acrylonitrile is done solid amount, sepiolite is 6 weight portions, use the dry-jet wet spinning spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains 7 weight portion magnesium chlorides, after drawing-off, enter in the style keeping liquid that contains 1 weight portion, three carbonyl benzene chromium and finalize the design, again through containing 0.5 weight portion intermetallic compound Pd
3After carrying out dyeing and finishing in the dyeing and finishing body lotion of Si, become finished product.
Embodiment 14, make mixed liquor with animal protein and vinyl acetate, in mixed liquor, add people's zinc oxide and make spinning solution, animal protein herein is a keratin, the milk casein, the mixture of collagen and insect protein, use the dry-jet wet spinning spinning after the spinning solution deaeration, tow enters and contains in the chlorophyllous coagulation bath, through drawing-off, after HEAT SETTING and the acetalation, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains cobalt particulate and chrome green, become finished product, wherein, keratin, the milk casein, the solid amount of doing of collagen and insect protein is 7.5 weight portions, it is 64.3 weight portions that vinyl acetate is done solid amount, and zinc oxide is 7.18 weight portions, and chlorophyll is 8.22 weight portions, cobalt is 0.2 weight portion, and chrome green is 0.1 weight portion.
Embodiment 15, make solution with the milk casein protein, in solution, add the magnesium chloride blend, they make spinning solution with cellulose solution again, after deaeration, use wet spinning, tow enters in the coagulation bath that contains cobalt, and after drawing-off and typing, enter again in the acetalation liquid that contains three carbonyl benzene chromium and carry out acetalation, after become finished product after the dyeing and finishing, it is 26 weight portions that the casein protein of wherein suckling is done solid amount, and magnesium chloride is 0.3 weight portion, and it is 62.7 weight portions that cellulose is done solid amount, cobalt is 10.5 weight portions, and three carbonyl benzene chromium are 0.5 weight portion.
In the present embodiment, also available phytoprotein and magnesium chloride are made solution jointly, add cellulose solution then and make its blend make spinning solution.
Embodiment 16, make mixed liquor with keratin and acrylonitrile, in mixed liquor, add calcium chloride and make spinning solution, after deaeration, use dry spinning, tow enters HEAT SETTING in the style keeping liquid that contains iron granules after drawing-off, enter in the acetalation liquid that contains basic zirconium phosphate and tourmaline powder again and carry out acetalation, entering at last in the dyeing and finishing liquid that contains di-iron trioxide becomes finished product after the dyeing and finishing.Wherein, it is 37 weight portions that keratin is done solid amount, and acrylonitrile is 45.5 weight portions, and calcium chloride is 1 weight portion, and iron is 0.5 weight portion, and basic zirconium phosphate is 10 weight portions, and tourmaline is 3 weight portions, and di-iron trioxide is 3 weight portions.
Embodiment 17, make spinning solution with insect protein, collagen and acrylonitrile, after deaeration, use the dry-jet wet spinning spinning, tow enters and contains in the kaolinic coagulation bath, after drawing-off and typing, enter in the acetalation liquid that contains the thorium particulate and carry out acetalation, entering at last in the dyeing and finishing liquid that contains zeolite powder becomes finished product after the dyeing and finishing.Wherein, it is 30 weight portions that insect protein is done solid amount, and it is 12 weight portions that collagen is done solid amount, and it is 37 weight portions that acrylonitrile is done solid amount, and kaolin is 8 weight portions, and thorium is 4 weight portions, and zeolite powder is 9 weight portions.
Embodiment 18, use collagen, the milk casein is made mixed liquor, in mixed liquor, add the triethyl aluminum blend, make spinning solution with acrylonitrile solution then, after deaeration, use dry spinning, tow is after drawing-off and typing, enter to contain in the magnesian acetalation liquid and carry out acetalation, enter again in the dyeing and finishing liquid that contains ferrocene and become finished product after the dyeing and finishing, wherein, it is 7 weight portions that collagen is done solid amount, and it is 28 weight portions that the milk casein is done solid amount, triethyl aluminum is 2 weight portions, it is 59 weight portions that acrylonitrile is done solid amount, and magnesia is 2 weight portions, and ferrocene is 2 weight portions.
Embodiment 19, make mixed liquor with keratin and cellulose, in mixed liquor, add chrome green, make spinning solution, after deaeration, use wet spinning, tow enters in the coagulation bath that contains silver oxide, after drawing-off, enter HEAT SETTING in the style keeping liquid that contains nickel particle, enter again in the acetalation liquid that contains cupric oxide and carry out acetalation, after become finished product after containing the dyeing and finishing liquid dyeing and finishing of cobalt.Wherein, it is 76.1 weight portions that keratin is done solid amount, and it is 16.5 weight portions that vinyl acetate is done solid amount, and chrome green is 0.2 weight portion, and silver oxide is that 1.5 weight portions, nickel particle are 0.2 weight portion, and cupric oxide is that 0.5 weight portion, cobalt are 5 weight portions.
Embodiment 20, with hair protein, directly through being that fe and the cellulose of 10nm made spinning solution, after deaeration, use the dry-jet wet spinning spinning, tow enters in the coagulation bath that contains antimonous oxide, enter HEAT SETTING in the style keeping liquid that contains silver oxide after drawing-off, entering in the dyeing and finishing liquid that contains magnesium chloride becomes finished product after the dyeing and finishing again.Wherein, it is 39.6 weight portions that hair protein is done solid amount, and fe content is that the dried solid amount of 8 weight portions, cellulose is 52 weight portions, and antimonous oxide is 0.2 weight portion, and silver oxide is 0.1 weight portion, and magnesium chloride is 0.1 weight portion.
Embodiment 21, make spinning solution with keratin, NaOH and cellulose, after deaeration, use dry spinning, tow enters HEAT SETTING in the style keeping liquid that contains iron granules after drawing-off, enter again in the acetalation liquid that contains basic zirconium phosphate and tourmaline powder and carry out acetalation, after become finished product after the dyeing and finishing.Wherein, keratin is done and measured admittedly is that the dried solid amount of 70 weight portions, NaOH is that dried the measuring admittedly of 9 weight portions, cellulose is 9.2 weight portions, and iron is 0.5 weight portion, and basic zirconium phosphate is 1.3 weight portions, and tourmaline is 10 weight portions.
Embodiment 22, make mixed liquor with collagen and cellulose, in mixed liquor, add magnesia and make spinning solution, after deaeration, use dry spinning, tow is after drawing-off and typing, enter in the acetalation liquid that contains calcium phosphate and carry out acetalation, entering in the dyeing and finishing liquid that contains the cobalt particulate becomes finished product after the dyeing and finishing again.Wherein, it is 50 weight portions that collagen is done solid amount, and it is 34 weight portions that cellulose is done solid amount, and magnesia is 5 weight portions, and calcium phosphate is 6 weight portions, and cobalt is 5 weight portions.
Embodiment 23, use keratin, collagen, polyacrylonitrile and acrylonitrile are made mixed liquor, in mixed liquor, add triethyl aluminum, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters and contains in the kaolinic coagulation bath, after drawing-off, enter HEAT SETTING in the style keeping liquid that contains magnesium chloride, enter again in the acetalation liquid that contains calcium chloride and carry out acetalation, enter at last in the dyeing and finishing body lotion that contains cupric oxide and be finished product after the dyeing and finishing, keratin wherein, the solid amount of doing of collagen is 80 weight portions, the dried solid amount of polyacrylonitrile and acrylonitrile is respectively 10 weight portions and 9.4 weight portion triethyl aluminums are 0.1 weight portion, kaolin is 0.2 weight portion, magnesium chloride is 0.1 weight portion, and calcium chloride is 0.1 weight portion, and cupric oxide is 0.1 weight portion.
Embodiment 24, make mixed liquor with milk casein, polyacrylonitrile, in mixed liquor, add zeolite powder, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains ferrocene and antimonous oxide, be finished product through drawing-off, typing, acetalation and arrangement, it is 98 weight portions that the casein of wherein suckling is done solid amount, and it is 45 weight portions that polyacrylonitrile is done solid amount, and zeolite powder is 0.1 weight portion, ferrocene is 0.1 weight portion, and antimonous oxide also is 0.1 weight portion.
Embodiment 25, make solution with insect protein and polyvinyl alcohol, then add simple substance cerium micro mist and spinning solution is made in their blend, this stoste is used wet spinning after deaeration, the tow that is come out by spinning machine enters in the coagulation bath, enters after drawing-off and contains intermetallic compound Pd
3After the style keeping liquid typing of Si, enter again in the acetalation liquid that contains montmorillonite powder and carry out acetalation, after be finished product after the dyeing and finishing, wherein the dried solid amount of insect protein is 5 weight portions, it is 94.3 weight portions that polyvinyl alcohol is done solid amount, and it is that 4 weight portions, montmorillonite are 0.3 weight portion that simple substance cerium micro mist is done solid amount.
In each embodiment, if adopt wet spinning technology, then can use dry-jet wet spinning process instead, same if adopt dry-jet wet spinning process, also can use wet spinning technology instead.
When making spinning solution, all can adopt the method that is adopted in embodiment 1,6 and 8, or disclosed all methods of the prior art.
The material of the containing metal element among the present invention described in each embodiment is the oxide or the metallic compound of any simple metal atom or molecule, metal ion, also can select metal containing compositions and metallo-chelate or complex compound, metal complex, metallo-organic compound, intermetallic compound for use, if metal oxide in an embodiment or compound are soluble, then can the solution form add or add with particulate form, also can add nano level metallic element, but the size of particulate can not influence the weaving of fiber.
Claims (18)
1, a kind of functional fiber, it is characterized in that: it is made up of the material of animal protein, high molecular polymer and containing metal element, and animal protein accounts for A part of total amount, high molecular polymer accounts for B part of total amount, the material of containing metal element accounts for C part of total amount, then: 1≤A≤98,0＜C＜1 or 5＜C＜23, surplus are high molecular polymer B.
2, fiber according to claim 1 is characterized in that: animal protein content is 1＜A＜45.
3, fiber according to claim 1 is characterized in that: described animal protein is milk casein, keratin, collagen or insect protein.
4, fiber according to claim 1 is characterized in that: described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
5, fiber according to claim 1 is characterized in that: described high molecular polymer is cellulose or vinyl acetate.
6, functional fiber according to claim 1 is characterized in that: described metallic element is a kind of metallic element.
7, fiber according to claim 1 is characterized in that: described metallic element is at least two kinds of different metallic elements.
8, according to claim 6 or 7 described fibers, it is characterized in that: the material of described containing metal element is the composition of metal oxide, metallic compound, containing metal element and metal complex, metallo-organic compound.
9, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: the material that takes by weighing protein, high molecular polymer and containing metal element earlier by proportioning, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the material of metallic element by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
10, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: take by weighing protein and high molecular polymer by proportioning earlier, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
11, make as claim 1,2,3,4,5, the method of 6 or 7 described fibers, it is characterized in that: take by weighing protein by proportioning earlier it is made solution, the material that adds the containing metal element of proportional quantity part again reacts by it, the high molecular polymer that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain metalloenzyme by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
12, make as claim 1,2,3,4,5, the method of 6 or 7 described fibers, it is characterized in that: take by weighing high molecular polymer by proportioning earlier, it is made solution, the containing metal elemental substance that adds proportional quantity part again reacts by it, the protein that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread coagulation bath, style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
13, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: elder generation takes by weighing protein, high molecular polymer by proportioning and contains the material of metallic element, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain metalloenzyme by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
14, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: take by weighing protein and high molecular polymer by proportioning earlier, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
15, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: take by weighing protein by proportioning earlier it is made solution, the material that contains metallic element that adds proportional quantity part again reacts by them, the high molecular polymer that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
16, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: take by weighing high molecular polymer by proportioning earlier, it is made solution, the material that contains metallic element that adds proportional quantity part again reacts by them, the protein that then adds proportional quantity part again, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation; In this process, contain the metallic element material by at least a liquid in thread style keeping liquid, acetalation liquid and the dyeing and finishing liquid that are entered of spinning machine ejection.
17, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: the material that takes by weighing protein, high molecular polymer and containing metal element earlier by proportioning, make spinning solution jointly with them, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, enter after drawing-off and make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation.
18, manufacturing is as the method for claim 1,2,3,4,5,6 or 7 described fibers, it is characterized in that: elder generation takes by weighing protein, high molecular polymer by proportioning and contains the material of metallic element, make spinning solution jointly with them, again spinning solution is carried out carrying out dry spinning after the deaeration, entered after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product enter acetalation liquid through being finished product again after the dyeing and finishing of dyeing and finishing liquid after the acetalation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410010249 CN1693552A (en) | 2004-05-09 | 2004-05-09 | Functional fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410010249 CN1693552A (en) | 2004-05-09 | 2004-05-09 | Functional fibre |
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| Publication Number | Publication Date |
|---|---|
| CN1693552A true CN1693552A (en) | 2005-11-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410010249 Pending CN1693552A (en) | 2004-05-09 | 2004-05-09 | Functional fibre |
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| CN (1) | CN1693552A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102366175A (en) * | 2011-08-26 | 2012-03-07 | 常熟市恒沁制衣有限责任公司 | Radiation-proof fabric |
| CN103343396A (en) * | 2013-07-31 | 2013-10-09 | 韩晓根 | Flame-retardant soybean protein fiber production method and product thereof |
| CN103388195A (en) * | 2013-07-31 | 2013-11-13 | 韩晓根 | Production method of antibacterial soybean protein fiber and product of antibacterial soybean protein fiber |
| CN105442087A (en) * | 2015-12-28 | 2016-03-30 | 苏州东胜化纤纺织有限公司 | Automatic heating polypropylene fibers |
| CN106637467A (en) * | 2016-11-09 | 2017-05-10 | 上海全宇生物科技遂平有限公司 | A boron-containing nanometer zinc oxide/polyvinyl alcohol composite fiber and a preparing method thereof |
| CN110359127A (en) * | 2019-08-01 | 2019-10-22 | 丹阳市三江纤维材料有限公司 | A kind of composite fibre and its textile fabric |
| CN115012054A (en) * | 2022-07-08 | 2022-09-06 | 中国核动力研究设计院 | X-ray shielding material, preparation method and application |
-
2004
- 2004-05-09 CN CN 200410010249 patent/CN1693552A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102366175A (en) * | 2011-08-26 | 2012-03-07 | 常熟市恒沁制衣有限责任公司 | Radiation-proof fabric |
| CN103343396A (en) * | 2013-07-31 | 2013-10-09 | 韩晓根 | Flame-retardant soybean protein fiber production method and product thereof |
| CN103388195A (en) * | 2013-07-31 | 2013-11-13 | 韩晓根 | Production method of antibacterial soybean protein fiber and product of antibacterial soybean protein fiber |
| CN103388195B (en) * | 2013-07-31 | 2015-06-24 | 韩晓根 | Production method of antibacterial soybean protein fiber and product of antibacterial soybean protein fiber |
| CN105442087A (en) * | 2015-12-28 | 2016-03-30 | 苏州东胜化纤纺织有限公司 | Automatic heating polypropylene fibers |
| CN106637467A (en) * | 2016-11-09 | 2017-05-10 | 上海全宇生物科技遂平有限公司 | A boron-containing nanometer zinc oxide/polyvinyl alcohol composite fiber and a preparing method thereof |
| CN106637467B (en) * | 2016-11-09 | 2018-11-09 | 上海全宇生物科技遂平有限公司 | A kind of boracic nano zine oxide/polyvinyl alcohol composite fiber and preparation method thereof |
| CN110359127A (en) * | 2019-08-01 | 2019-10-22 | 丹阳市三江纤维材料有限公司 | A kind of composite fibre and its textile fabric |
| CN115012054A (en) * | 2022-07-08 | 2022-09-06 | 中国核动力研究设计院 | X-ray shielding material, preparation method and application |
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