CN1676689A - Protein functional fiber - Google Patents

Protein functional fiber Download PDF

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Publication number
CN1676689A
CN1676689A CN 200410010164 CN200410010164A CN1676689A CN 1676689 A CN1676689 A CN 1676689A CN 200410010164 CN200410010164 CN 200410010164 CN 200410010164 A CN200410010164 A CN 200410010164A CN 1676689 A CN1676689 A CN 1676689A
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Prior art keywords
spinning
finished product
protein
spinning solution
high molecular
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CN 200410010164
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Chinese (zh)
Inventor
李官奇
李贺泽
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Individual
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Individual
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Priority to CN 200410010164 priority Critical patent/CN1676689A/en
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Abstract

This invention discloses a kind of functional fiber which contains protein. It is made up of protein, high polymer and the substances containing metallic element. Among these, the protein takes up A of the total quantity, the high polymer taking up B and the substances containing non-metallic element taking up C. Then we get 1<=A<=67, 10<=B<99 and 0<C<=23. This invention also publishes the producing method of this fiber. This fiber makes the skin feeling comfortable and has good wetness conductivity. Also, it has high ratio of bacteriostasis and occultation, and it can send out far IR, producing high ratio of negative ions. What is more, it has the UV-absorbing ratio of 99.8% and it can absorb the Hertz wave and it offers radiation protection, and so on.

Description

The protein function fiber
Technical field
The invention belongs to synthetic fiber, relate in particular to fiber with functional effect.
Background technology
General synthetic fiber skin-friendly, gas permeability are relatively poor, I am that ZL99116636.1, name are called " synthetic plant protein filaments and manufacture method thereof " and application number and are 03111814.3, are called in the document of " a kind of soylon and manufacture method thereof " and disclose proteinaceous fiber and manufacture method in the patent No. for this reason, the fiber that makes by foregoing invention, skin-friendly, lead moist, pliability and gloss all fine, but these fibers do not have other functional effect.
Summary of the invention
The object of the present invention is to provide a kind of not only skin-friendly, lead moist better, and have antibacterial, antibiotic, uvioresistant, radiation proof, absorption electromagnetic wave function and have far-infrared functional and the fiber of negative oxygen ion radiation function.
The objective of the invention is to be achieved through the following technical solutions: a kind of protein function fiber, it is made up of the material of protein, high molecular polymer and containing metal element.
Protein accounts for A part of total amount, and high molecular polymer accounts for B part of total amount, and the material of containing metal element accounts for C part of total amount, then: 1≤A≤67,10≤B<99,0<C≤23.
Described protein is at least a in phytoprotein and the animal protein.
Described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
Described high molecular polymer is a cellulose.
Described high molecular polymer is a vinyl acetate.
Described metallic element is a kind of metallic element.
Described metallic element is at least two kinds of different metallic elements.
The material of described containing metal element is metallic atom, metallic molecule, metal ion, metal oxide, metallic compound, the composition that contains metallic element or intermetallic compound.
This functional fiber can be made by the following method:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning.
C, the synthetic fibre tows that is come out by spinning machine enter in the coagulation bath that contains metallic element, and after make semi-finished product after drawing-off and the HEAT SETTING, semi-finished product are finished product through arrangement and acetalation again.
This functional fiber also can be made by the following method:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out being used in the method spinning after the deaeration;
C, the synthetic fiber that come out by spinning machine are finished product through arrangement and acetalation again through drawing-off and HEAT SETTING.
This functional fiber also can be made by the following method:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, enter after drawing-off in the curling liquid that contains metallic element, make semi-finished product, are finished product through arrangement and acetalation again.
This functional fiber also can be made by the following method:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
This functional fiber also can be made by the following method:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath that contains metallic element, make semi-finished product after drawing-off and typing, are finished product through arrangement and acetalation again.
This functional fiber also can be made by the following method:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, enter after drawing-off in the curling liquid that contains metallic element, make semi-finished product, are finished product through arrangement and acetalation again.
This functional fiber also can be made by the following method:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
This functional fiber also can be made by the following method:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath that contains metallic element, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
Fiber internal cause with manufacturing of the present invention contains protein and high molecular polymer, therefore its institutional framework is changed to some extent, produced preferably skin-friendly and led moistly, because of the content difference of fiber inner macromolecule polymer, therefore can produce flexible in various degree fiber again according to people's needs.The sample of this fiber detects through detection department of country and learns, have higher bacteriostasis rate and screening rate simultaneously with a kind of fabric, has far-infrared transmitting function, and can produce higher negative ion concentration, also have 99.8% absorption of UV and absorb multiple good function such as electromagnetic wave, radiation proof.
The specific embodiment
Embodiment 1, get animal protein and polyvinyl alcohol is made spinning solution, containing doing of animal protein in this spinning solution, to measure A admittedly be 50 weight portions, it is 49.5 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains aluminium oxide, it is 0.5 weight portion that the doing of aluminium oxide measured C admittedly, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, and semi-finished product promptly become finished product again after arrangement and acetalation.
Embodiment 2, get phytoprotein and polyvinyl alcohol is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 67 weight portions, it is 10 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 13 weight portion di-iron trioxides, then tow is again through air draft, wet bath drawing-off and dried drawing-off, enter the style keeping liquid that contains 10 weight portion tri-iron tetroxides again and then make semi-finished product, semi-finished product promptly become finished product again after arrangement and acetalation.
Embodiment 3, get phytoprotein and polyacrylonitrile is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 27.2 weight portions, it is 55 weight portions that the doing of polyacrylonitrile measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 9.8 weight portion di-iron trioxides, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, semi-finished product promptly become finished product after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains 8 weight portion silica again.
Embodiment 4, get protein and polyacrylonitrile is made spinning solution, proteinaceously in this spinning solution do that to measure A admittedly be 20.9 weight portions, it is 70 weight portions that the doing of polyacrylonitrile measured B admittedly, protein herein is the mixture of phytoprotein and animal protein, wherein the dried solid amount of phytoprotein is 8 weight portions, it is 12.9 weight portions that animal protein is done solid amount, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 4.1 part by weight of zinc oxide, then tow is again through air draft, wet bath drawing-off and dried drawing-off, then enter in the curling liquid that contains 3 weight portion boron element particulates and carry out making semi-finished product after the HEAT SETTING, semi-finished product promptly become finished product after putting into the dyeing and finishing body lotion dyeing and finishing that contains 2 parts by weight of titanium dioxide again.
Embodiment 5, get animal protein and polyvinyl alcohol is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 50 weight portions, it is 37 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters coagulation bath, enter after drawing-off in the curling liquid that contains 2.4 weight portion chrome greens and 10.6 part by weight of zinc oxide, making behind the semi-finished product promptly becomes finished product again after arrangement and acetalation.
Embodiment 6, get phytoprotein and polyacrylonitrile is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 1 weight portion, it is 96 weight portions that the doing of polyacrylonitrile measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, semi-finished product are put into the dyeing and finishing body lotion that contains 1.5 parts by weight of titanium dioxide, 1 weight portion iron oxide and 0.5 weight portion nickel and are carried out dyeing and finishing, then become finished product.
Embodiment 7, get protein and polyvinyl alcohol is made spinning solution, proteinaceously in this spinning solution do that to measure A admittedly be 60 weight portions, it is 35 weight portions that the doing of polyacrylonitrile measured B admittedly, protein herein is the mixture of phytoprotein and animal protein, wherein phytoprotein and animal protein respectively account for 50% of total protein, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains silver oxide, after drawing-off, enter in the curling liquid that contains cupric oxide and finalize the design, make semi-finished product, put into the dyeing and finishing body lotion that contains antimonous oxide and zinc oxide again and carry out dyeing and finishing, then become finished product, add the containing metal element material do solid amount with C be 5 parts, wherein silver oxide and cupric oxide respectively are 1 part, antimonous oxide and zinc oxide respectively are 1.5 parts.
Embodiment 8, phytoprotein and cellulose solution are mixed, containing doing of phytoprotein in the solution, to measure A admittedly be 30 weight portions, cellulose is done and measured B admittedly is 66 weight portions, in this solution, add nano level Ni element then, it is 4 weight portions that the doing of Ni element measured C admittedly, make their copolymerization make spinning solution, then spinning solution is carried out adopting dry spinning to make tow after the deaeration, this tow becomes finished product after drawing-off, typing, arrangement and acetalation.
Embodiment 9, animal protein, phytoprotein, vinyl acetate and polyvinyl alcohol are made solution respectively, then they are mixed, in this mixed liquor, add phosphoric acid titanium salt and the magnesium chloride of particle diameter again less than 100 nanometers, make spinning solution, the solid amount of doing of animal protein and phytoprotein is 20 weight portions in the spinning solution, vinyl acetate and polyvinyl alcohol are 28 weight portions, magnesium chloride is 1 weight portion, the phosphoric acid titanium salt is 2 weight portions, spinning solution adopts wet spinning after deaeration, fiber enters in the coagulation bath that contains 1 weight portion alundum (Al, and after drawing-off, typing, arrangement and acetalation become finished product.
Embodiment 10, make solution jointly with animal protein and polyacrylonitrile, wherein the dried solid amount of animal protein is 1 weight portion, it is 98.99 weight portions that polyacrylonitrile is done solid amount, the particle diameter that adds 0.01 weight portion in this mixed liquor is less than 1 micron iron, make spinning solution jointly, after deaeration, adopt dry spinning, and after typing, arrangement and acetalation become finished product.
Embodiment 11, make spinning solution with phytoprotein, polyvinyl alcohol and acrylonitrile, wherein the dried solid amount of phytoprotein is 57 weight portions, it is 10 weight portions that polyvinyl alcohol is done solid amount, it is 13 weight portions that acrylonitrile is done solid amount, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath, through drawing-off, typing, then enters in the dyeing and finishing body lotion that contains 20 weight portion magnesium chlorides and carries out becoming finished product after the dyeing and finishing.
Embodiment 12, make spinning solution with animal protein and polyacrylonitrile, the dried solid amount of animal protein is 15 weight portions, it is 84 weight portions that polyacrylonitrile is done solid amount, carry out spinning with dry-jet wet spinning after the spinning solution deaeration, tow enters coagulation bath, through drawing-off, then enter in the style keeping liquid that contains 1 weight portion phosphoric acid zirconates, after arrangement and acetalation, become finished product again.
Embodiment 13, use animal protein, polyacrylonitrile, the tourmaline of acrylonitrile and particle diameter 100 nanometers (Main Ingredients and Appearance is alundum (Al and silica) is made spinning solution, the dried solid amount of animal protein is 30 weight portions, it is 20 weight portions that polyacrylonitrile is done solid amount, it is 45.5 weight portions that acrylonitrile is done solid amount, tourmaline is 1 weight portion, use the dry-jet wet spinning spinning after the spinning solution deaeration, tow enters and contains in the magnesian coagulation bath of 2 weight portions, after drawing-off, enter in the style keeping liquid that contains 1 weight portion nickel and finalize the design, after carrying out dyeing and finishing in the dyeing and finishing body lotion through containing 0.5 weight portion silver oxide again, become finished product.
Embodiment 14, animal protein and polyvinyl alcohol are made spinning solution, the dried solid amount of animal protein is 30 weight portions, it is 65.5 weight portions that polyvinyl alcohol is done solid amount, be used in the method spinning after the spinning solution deaeration, tow enters after drawing-off in the curling liquid that contains 4.5 weight portion silica and finalizes the design, and becomes finished product again after arrangement and acetalation.
Embodiment 15, phytoprotein and polyvinyl alcohol, acrylonitrile are made spinning solution, the dried solid amount of phytoprotein is 30 weight portions, it is 30 weight portions that polyvinyl alcohol is done solid amount, it is 30 weight portions that acrylonitrile is done solid amount, adopt dry spinning after the spinning solution deaeration, tow is after drawing-off, typing, and entering in the dyeing and finishing body lotion that contains 10 weight portion selenium becomes finished product after the dyeing and finishing.
Embodiment 16, make solution with phytoprotein, animal protein and polyacrylonitrile, in solution, add calcium phosphate and make spinning solution, spinning solution adopts dry spinning after deaeration is filtered, tow enters in the curling liquid that contains the boron element particulate and finalizes the design, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains silica again, become finished product, wherein the dried solid amount of phytoprotein is 10 weight portions, it is 10 weight portions that animal protein is done solid amount, it is 70 weight portions that polyacrylonitrile is done solid amount, calcium phosphate is 5 weight portions, and boron is 3 weight portions, and silica is 2 weight portions.
Embodiment 17, make spinning solution with animal protein, polyvinyl alcohol and titanium oxalate, after deaeration, use the wet spinning spinning, tow enters in the coagulation bath that contains zinc oxide, enter in the curling liquid that contains the cobalt particulate again and finalize the design, then be finished product through arrangement and acetalation again, wherein the dried solid amount of phytoprotein is 50 weight portions, it is 35 weight portions that polyvinyl alcohol is done solid amount, titanium oxalate is 5 weight portions, and zinc oxide is 9 weight portions, and cobalt is 1 weight portion.
Embodiment 18, make mixed liquor with animal protein, phytoprotein and cellulose, in mixed liquor, add kaolin and make spinning solution, after deaeration, use wet spinning, tow enters in the coagulation bath, then enter in the curling liquid that contains the thorium elementary particle and finalize the design, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains cupric oxide and zeolite again, become finished product, wherein the dried solid amount of animal protein is 10 weight portions, it is 15 weight portions that phytoprotein is done solid amount, and it is 70 weight portions that cellulose is done solid amount, and thorium is 0.5 weight portion, cupric oxide is 3 weight portions, and zeolite is 1.5 weight portions.
Embodiment 19, make mixed liquor, in mixed liquor, add nano level Pd with animal protein, phytoprotein and vinyl acetate 3Si makes spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains nanometre grade cobalt, after drawing-off and HEAT SETTING, enters in the dyeing and finishing body lotion that contains magnesium chloride and antimonous oxide after the dyeing and finishing, become finished product, wherein, it is 30 weight portions that animal protein is done solid amount, and it is 15 weight portions that phytoprotein is done solid amount, it is 35 weight portions that vinyl acetate is done solid amount, Pd 3Si is 2 weight portions, and cobalt is 2 weight portions, and magnesium chloride is 8 weight portions, and antimonous oxide is 8 weight portions.
Embodiment 20, make mixed liquor with phytoprotein and polyacrylonitrile, in mixed liquor, add zeolite powder, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains the titanium dioxide phthalein, after drawing-off, enter in the curling liquid that contains the calcium oxide particulate and finalize the design, be finished product through arrangement and acetalation again, wherein the dried solid amount of phytoprotein is 28 weight portions, it is 57 weight portions that polyacrylonitrile is done solid amount, zeolite powder is 5 weight portions, and the titanium dioxide phthalein is 5 weight portions, and calcium oxide is 5 weight portions.
Embodiment 21, make mixed liquor with phytoprotein and polyacrylonitrile, in mixed liquor, add floats, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains calcium phosphate, after drawing-off, typing, enter in the dyeing and finishing body lotion that contains the metallic cerium particulate and be finished product after the dyeing and finishing, wherein the dried solid amount of phytoprotein is 8 weight portions, and it is 80 weight portions that polyacrylonitrile is done solid measuring, and floats are 3 weight portions, calcium phosphate is 4 weight portions, and cerium is 5 weight portions.
Embodiment 22, make mixed liquor with phytoprotein, polyacrylonitrile, the particulate that in mixed liquor, adds silver, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains cobalt particulate and cupric oxide, be finished product through drawing-off, typing, arrangement and acetalation, wherein phytoprotein 45 is done to measure admittedly and is that it is 45 weight portions that weight portion, polyacrylonitrile are done solid measuring, and silver is 4 weight portions, cobalt is 2 weight portions, and cupric oxide is 4 weight portions.
The material of the containing metal element among the present invention described in each embodiment is the oxide or the metallic compound of any simple metal atom or molecule, metal ion, also can select metal containing compositions and metallo-chelate or complex compound for use, if metal oxide in an embodiment or compound are soluble, then can the solution form add or add with particulate form, also can add nano level metallic element, but the size of particulate can not influence the weaving of fiber.
In each embodiment, if adopt wet spinning technology, then can use dry-jet wet spinning process instead, same if adopt dry-jet wet spinning process, also can use wet spinning technology instead.

Claims (17)

1, a kind of protein function fiber is characterized in that: it is made up of the material of protein, high molecular polymer and containing metal element.
2, protein function fiber according to claim 1 is characterized in that: protein accounts for A part of total amount, and high molecular polymer accounts for B part of total amount, and the material of containing metal element accounts for C part of total amount, then: 1≤A≤67,10≤B<99,0<C≤23.
3, protein function fiber according to claim 1 is characterized in that: described protein is at least a in phytoprotein and the animal protein.
4, protein function fiber according to claim 1 is characterized in that: described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
5, protein function fiber according to claim 1 is characterized in that: described high molecular polymer is a cellulose.
6, protein function fiber according to claim 1 is characterized in that: described high molecular polymer is a vinyl acetate.
7, protein function fiber according to claim 1 is characterized in that: described metallic element is a kind of metallic element.
8, protein function fiber according to claim 1, it is characterized in that: described metallic element is at least two kinds of different metallic elements.
9, according to claim 7 or 8 described protein function fibers, it is characterized in that: the material of described containing metal element is metallic atom, metallic molecule, metal ion, metal oxide, metallic compound, the composition that contains metallic element or intermetallic compound.
10, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6,7 or 8 described fibers:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning.
C, the synthetic fibre tows that is come out by spinning machine enter in the coagulation bath that contains metallic element, and after make semi-finished product after drawing-off and the HEAT SETTING, semi-finished product are finished product through arrangement and acetalation again.
11, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6,7 or 8 described fibers:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting dry spinning after the deaeration;
C, the synthetic fiber that come out by spinning machine are finished product through arrangement and acetalation again through drawing-off and HEAT SETTING.
12, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6,7 or 8 described fibers:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, enter after drawing-off in the curling liquid that contains metallic element, make semi-finished product, are finished product through arrangement and acetalation again.
13, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6,7 or 8 described fibers:
A, choose protein and high molecular polymer is made spinning solution by proportioning;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
14, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6 or 8 described fibers:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath that contains metallic element, make semi-finished product after drawing-off and typing, are finished product through arrangement and acetalation again.
15, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6 or 8 described fibers:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, enter after drawing-off in the curling liquid that contains metallic element, make semi-finished product, are finished product through arrangement and acetalation again.
16, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6 or 8 described fibers:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
17, manufacturing is characterized in that as the method for claim 1,2,3,4,5,6 or 8 described fibers:
A, the material of choosing protein, high molecular polymer and containing metal element by proportioning are made spinning solution;
B, spinning solution is carried out adopting after the deaeration wet spinning or dry-jet wet spinning spinning;
C, the synthetic fiber that come out by spinning machine enter in the coagulation bath that contains metallic element, make semi-finished product, after semi-finished product are put into the dyeing and finishing body lotion that contains metallic element and carried out dyeing and finishing, become finished product.
CN 200410010164 2004-03-29 2004-03-29 Protein functional fiber Pending CN1676689A (en)

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CN 200410010164 CN1676689A (en) 2004-03-29 2004-03-29 Protein functional fiber

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Application Number Priority Date Filing Date Title
CN 200410010164 CN1676689A (en) 2004-03-29 2004-03-29 Protein functional fiber

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006081749A1 (en) * 2005-02-05 2006-08-10 Guanqi Li Spinning dope of a protein-containing, wave absorbing, shielding, heatabsorbing fibre and the process thereof
WO2012012920A1 (en) * 2010-07-30 2012-02-02 Mao Yingjun Chemical fiber with rapid temperature-reducing and cooling effect under conditions of wind and textile thereof
CN101709511B (en) * 2009-11-26 2012-05-23 毛盈军 Chemical fiber quickly increasing temperature and heating when encountering light and textile containing fiber
WO2013170544A1 (en) * 2012-05-14 2013-11-21 Mao Yingjun Warming and heat storage fiber, and preparation method and textile thereof
WO2013170546A1 (en) * 2012-05-14 2013-11-21 Mao Yingjun Temperature-reducing and cooling fiber, preparation method, and textile
CN106700565A (en) * 2016-12-02 2017-05-24 江苏新瑞贝科技股份有限公司 Imitated protein fiber fabric printing masterbatch suitable for print-forming technology

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006081749A1 (en) * 2005-02-05 2006-08-10 Guanqi Li Spinning dope of a protein-containing, wave absorbing, shielding, heatabsorbing fibre and the process thereof
CN101709511B (en) * 2009-11-26 2012-05-23 毛盈军 Chemical fiber quickly increasing temperature and heating when encountering light and textile containing fiber
WO2012012920A1 (en) * 2010-07-30 2012-02-02 Mao Yingjun Chemical fiber with rapid temperature-reducing and cooling effect under conditions of wind and textile thereof
WO2013170544A1 (en) * 2012-05-14 2013-11-21 Mao Yingjun Warming and heat storage fiber, and preparation method and textile thereof
WO2013170546A1 (en) * 2012-05-14 2013-11-21 Mao Yingjun Temperature-reducing and cooling fiber, preparation method, and textile
CN106700565A (en) * 2016-12-02 2017-05-24 江苏新瑞贝科技股份有限公司 Imitated protein fiber fabric printing masterbatch suitable for print-forming technology

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