CN1686907A - Bricks and mortar made from fly ash and preparation method - Google Patents

Bricks and mortar made from fly ash and preparation method Download PDF

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CN1686907A
CN1686907A CNA2004100695168A CN200410069516A CN1686907A CN 1686907 A CN1686907 A CN 1686907A CN A2004100695168 A CNA2004100695168 A CN A2004100695168A CN 200410069516 A CN200410069516 A CN 200410069516A CN 1686907 A CN1686907 A CN 1686907A
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flyash
lime
brick
aggregate
cement
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CN1278982C (en
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江学艺
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Wei Liuqing
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The present invention belongs to a building brick made of fly ash, mortar and their production method. The raw material composition of brick includes (by wt%) fly ash 70-80, lime 7-13, gypsum 0-1.3, cement 0-5 and the rest is aggregate, and the raw material composition of mortar includes fly ash 70-80, lime 7-13, cement 0-5 and the rest is aggregate. Besides, said invention also provides the concrete steps of their production method.

Description

A kind of flyash brick, mortar and production method thereof
Technical field
The present invention relates to the production method of building brick, mortar and this brick and mortar that a kind of flyash of discharging with power plant makes.
Background technology
Up to the present, the existing building brick made from flyash, otherwise technology is complicated, and the cost of manufacture height can't be applied, or the intensity of brick is not high, can't be used for the bearing wall of Highrise buildings.No. 89109385.0 patents of invention of China once disclosed a kind of " free of calcining and steam curing flyash brick and preparation method thereof ".According to the contriver, this invention has to select materials and requires lowly, and raw material sources are extensive, and are simple for production, less energy consumption, the characteristic that cost is low.But in the proportioning raw materials that should invent, flyash only accounts for the 55%-65% of raw material gross weight, and promptly the flyash consumption does not reach 70% of raw material gross weight, thereby can not be called flyash brick.And also need use lime and the cement of 4%-7% or the gypsum of 1%-5% of 14%-20% in its raw material, we know, the price of lime, cement and gypsum is more much higher than the price of flyash, in the raw material of its " flyash brick ", need with so lime, cement or the gypsum of vast scale, will inevitably make the on the high side of " flyash brick " produced.In addition, the working conditions to the cinder of one of raw material in this invention is also relatively stricter, requires its particle diameter must be less than 6mm, otherwise must be through broken (in fact, the particle diameter of cinder often is greater than 6mm, thereby makes fragmentation become requisite operation in this invention).Even like this, the intensity of " flyash brick " that this invention is made also can only reach the limited standard to No. 100 bricks No. 75, and can't reach among China ministerial standard JC239-2001 " flyash brick " requirement of the Mu15 level of regulation, thereby it can not be used for the bearing wall of high-rise building more than eight layers.This also is that this brick does not obtain one of real reason of applying so far.China's No. 89102223.6 patent applications disclosed " naturally-cured powdered coal ash brick ", 97109228.1 number patent application disclosed " a kind of production technique of high-strength fly-ash brick " and No. 01138341.0 patent application disclosed " normal temperature compressed flyash brick and method for making thereof " all need operating weight per-cent to be no less than 6% cement, thereby its production cost does not hang down.Wherein, the consumption of the flyash of No. 89102223.6 " naturally-cured powdered coal ash bricks " does not reach the requirement of " flyash brick " very little; 01138341.0 number " normal temperature compressed flyash brick and method for making thereof " also need use the outfield force of sound wave, ultrasonic wave, microwave or various rays and so on just can make the brick moulding, then also will the brick that drying is good be immersed in and carry out WATER REPELLENT in the aqueous silicate solution, the technology of this complexity, will improve the production cost of brick greatly, be unfavorable for applying of flyash brick.China's No. 90109978.3 patent applications disclosed " a kind of flyash brick and preparation method thereof " are though the cement that uses has only 3%-12%, but it needs in whipping process material ageing 2-4 hour, this has just reduced production efficiency widely, thereby the production cost of brick is improved.China's No. 01103113.1 patent application disclosed " a kind of flyash brick and manufacture method thereof ", No. 02133006.9 patent application disclosed " being used for the cold district high blended quantity vapor pressed flyash brick " and No. 00126147.9 patent application disclosed " steaming-pressing technology for forming high-strength powdered coal ash bricks " are three kinds of flyash brick or the production technique that can make raw material without cement, its raw materials cost can reduce, but No. 01103113.1 " a kind of flyash brick and manufacture method thereof " need through the process of plasticating of No. three feed backs or through grind, the activation treatment of roasting and so on; 02133006.9 need putting into slaking silos, the compound of number " being used for the cold district high blended quantity vapor pressed flyash brick " digested 4 hours; 00126147.9 number " steaming-pressing technology for forming high-strength powdered coal ash bricks " then needs through the three sections different times of precompressed, moulding, maintenance and the pressing process of friction-motion speed, these methods all are that complex process, cost are higher, the production that is unfavorable for brick and applying, or even can't implement in a large number, can't be applied to suitability for industrialized production, do not have vitality.
Summary of the invention
Task of the present invention is the weak point that will overcome above-mentioned flyash brick and production method thereof, provide a kind of few with or without cement, technology is simple, production cost is low, the product strength height, flyash brick, fly-ash mortar and their production method of suitable large-scale pipeline suitability for industrialized production.
Flyash brick of the present invention is finished by following scheme: it comprises flyash, lime, gypsum, cement and aggregate, its proportioning raw materials (% is than meter by weight) is: flyash 70-80, lime 7-13, gypsum 0-1.3, cement 0-5, the aggregate surplus, described flyash is to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, described lime comprises unslaked lime and white lime, the quantity of unslaked lime is no less than the 2%-5% of lime total amount, and the granularity of lime and gypsum is more than 200 orders, and aggregate is the medium coarse sand or the stone flour of two district's gratings.
In above-mentioned prescription, the consumption of gypsum is about 1/10th of lime consumption, and it mainly acts on is the water that generates in the absorption reaction, when the amount of unslaked lime in the lime is enough, can add gypsum, when all being white lime in the lime, need to add the gypsum of lime consumption 1/10th.
Fly-ash mortar of the present invention is realized by following scheme: it comprises flyash, lime, cement and aggregate, its proportioning raw materials (% is than meter by weight) is: flyash 70-80, lime 7-13, cement 0-5, the aggregate surplus, the granularity of lime and gypsum is more than 200 orders.
The flyash that power plant's fluidizing furnace is discharged has system ash, first level flour coal ash and three kinds of ranks of second class powered coal ash.The system ash is exactly the original ash that is varied by the granularity that power plant's fluidizing furnace is discharged, and its quality is minimum in three kinds of other flyash of level.In such scheme, the flyash that is used for brickmaking is the system ash, and being used to make the flyash of building by laying bricks or stones with mortar also is the system ash, but is used to make the flyash of decoration mortars such as sticking brick or mosaic, must use one-level or second class powered coal ash.
The lime that uses among the present invention, existing white lime also has unslaked lime, and unslaked lime needn't be fully through clearing up processing, and the quantity of unslaked lime is no less than the 2%-5% of lime total amount, in the lime half-cooked lime can not be arranged.The gypsum that uses among the present invention just must use in the brickmaking technology that adopts natural curing, can use in the brickmaking technology that adopts steam press maintenance, also can.No matter cement described in the present invention be in brickmaking or in the system mortar, all available or need not, and the label of used cement is not strict with.The aggregate that uses among the present invention when making heavy-load bearing brick, must adopt the medium coarse sand or the stone flour of two district's gratings, when making nonweight-bearing light cinder brick or mortar, can use, and also can.
The method that realizes above-mentioned brickmaking scheme is: flyash, the aggregate of described proportioning raw materials sent into stirred (all need not to add water in the whole process of stirring) in the muller formula mulling stirrer, rolled 2-3 minute, again with lime, perhaps again and gypsum, perhaps add in the stirrer with cement again and stir, roll about 5 minutes, make mixing of materials even, compound is sent in the brick machine with the pressure compression moulding that is not less than 1,600 thousand Ns, at last adobe is carried out natural curing or vapor cure certain hour, promptly got the flyash brick finished product.
The method that realizes above-mentioned system mortar scheme is: with the flyash and the lime of described proportioning raw materials, perhaps again and cement, send into together and add water in the muller formula mulling stirrer and stir, roll about 10 minutes, amount of water is decided according to the humidity of the mortar of required production, promptly gets the fly-ash mortar finished product.
Because the flyash of consumption maximum is that fluidizing furnace burns the mass fly ashes that nature is stacked at the stock ground among the present invention, not only price is low for it, and itself has the moisture of 15%-18%, and (popular discrimination method is to pick up a system ash with hand, hold that it can be agglomerating in the hand, it can scatter to unclamp hand, illustrate that promptly its water content is fit to), thereby raw material need not to add water in the whole process that stirs.Owing in the used lime unslaked lime of 2%-5% is at least arranged, and the ratio that used flyash cooperates with lime is more reasonable, and the pressure of compression moulding is appropriate, thereby makes raw material by stirring, pressure forming and maintenance processes, can fully fully react, generate the silicate product.Particularly unslaked lime is wherein not only directly participated in reaction, but the water that is generated in the absorption reaction, thereby the balance of reaction is moved to the direction that generates silicate, it can play the effect that intensifies, what help reacting fully carries out, so in the production process of flyash brick of the present invention, just need not increase other manufacturing procedure and handled, thereby the production technique of flyash brick of the present invention is simple especially, can prepare burden at that time, stirred at that time, compression moulding at that time, be particularly suitable for the extensive continuous industry production of streamline, the production cost of brick low (production cost of brick is also low on the production cost specific viscosity of flyash brick of the present invention) not only, and the resistance to compression of brick, the folding strength height, can reach the Mu10 and the Mu15 level of regulation among the JC239-2001 " flyash brick " easily, and because the compact structure of brick, thereby the sound insulation of brick, heat insulation, good seepage-proof property, do not absorb water, counter tide (because hydrated glass etc. can not cause the raw material or the medium of counter tide) not, the quality of brick is also more stable in production in enormous quantities.Fly-ash mortar of the present invention then has the following advantages: hanging is firm, bonding force is strong, do back slurry mouth does not ftracture, can be used for laying bricks, batch ash etc., built operation by laying bricks or stones, also can be used for decorative operations such as sticking brick, mosaic, reach saving cement, the purpose that reduces cost.
The drawing explanation
Fig. 1 is the technological process of production figure of flyash brick of the present invention.
Embodiment
Enforcement of the present invention is to finish on the production line of Laibin City, Guangxi hawk Building Materials Factory.3000 square metres of the production site deficiencies of this factory are under-capitalized 2,000,000 yuan, employee's less than 25 people, adopt the present invention after, can produce 3000 per year surplus ten thousand flyash standard bricks.The product of implementing is produced in batches and sampling by the on-the-spot supervision of official that Guang Xiqiang corrects, send the building material product quality monitoring testing station check of Administration of Quality and Technology Supervision of autonomous region then respectively and entrust national building materials industry wall roofing quality of materials supervision and inspection center to detect, all project all meets the requirement of JC239-2001 " flyash brick " standard MU15 level salable product and acceptable end product: the ultimate compression strength mean value of brick is 15.7MPa, and the monolithic minimum value is 14.7Mpa; Folding strength mean value is 4.6MPa, and the monolithic minimum value is 3.7Mpa; Freezing back ultimate compression strength mean value is 14.6Mpa, and dry mass loss monolithic value is 0.2-0.5%; Dry shrinkage is 0.72mm/m; Intensity is 13.0Mpa after the carbonization, and COEFFICIENT K c is 0.83.Guang Xiqiang corrects and just requires as early as possible the present invention to be applied in the whole district and the whole nation.
First example of the invention process is: the proportioning raw materials of flyash brick (% is than meter by weight) is flyash 70%, lime 13%, aggregate 17%, described flyash is to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, described lime comprises unslaked lime and white lime, the quantity of unslaked lime is no less than the 2%-5% of lime total amount, the granularity of lime is more than 200 orders, and aggregate is the medium coarse sand of two district's gratings.Its production method is, the flyash of weight ratio 70% and 17% aggregate are sent into stirring in the muller formula mulling stirrer, rolled 2-3 minute, again 13% lime added restir in the stirrer, roll about 5 minutes, make mixing of materials even, compound sent into the pressure with 1,600 thousand Ns is pressed into the standard adobe that specification is 240 * 115 * 53mm in the YZP160-8A type disc-rotation type octal brick pressing machine, with adobe natural curing 5-7 days and leave standstill 23-21 days (also can regard natural curing 28 days together as), promptly get standard flour coal-dust brick finished product at last.
Second example implementing is: the proportioning raw materials of flyash brick is a flyash 80%, lime 7%, aggregate 13%, described flyash is to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, and described lime comprises unslaked lime and white lime, and the quantity of unslaked lime is no less than the 2%-5% of lime total amount, the granularity of lime is more than 200 orders, and aggregate is the stone flour of two district's gratings.Its production method is, the flyash of weight ratio 80% and 13% aggregate are sent into stirring in the muller formula mulling stirrer, rolled 2-3 minute, again 7% lime added restir in the stirrer, roll about 5 minutes, make mixing of materials even, compound sent into the pressure with 1,600 thousand Ns is pressed into the standard adobe that specification is 240 * 115 * 53mm in the YZP160-8A type disc-rotation type octal brick pressing machine, at last adobe is sent into and used atmospheric steam curing 24 hours in the curing kilns, promptly get the flyash brick finished product.
The 3rd example of implementing is: the proportioning raw materials of flyash brick is a flyash 80%, lime 10%, gypsum 1%, aggregate 9%, described flyash are to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, and the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, described lime comprises unslaked lime and white lime, the quantity of unslaked lime is no less than the 2%-5% of lime total amount, and the granularity of lime and gypsum is more than 200 orders, and aggregate is the stone flour of two district's gratings.Its production method is, the aggregate of the flyash of weight ratio 80% and 9% sent in the muller formula mulling stirrer stirred 2-3 minute, again the gypsum of 10% lime and 1% is added in the stirrer restir about 5 minutes, make mixing of materials even, compound sent into the pressure with 1,600 thousand Ns is pressed into the standard adobe that specification is 240 * 115 * 53mm in the YZP160-8A type disc-rotation type octal brick pressing machine, at last adobe is sent in the curing kilns, under 1-1.3MPa pressure and 170-200 ℃ of temperature vapor cure 6-8 hour, promptly get the flyash brick finished product.
The 4th example of implementing is: the proportioning raw materials of flyash brick is a flyash 80%, lime 7%, gypsum 1%, cement 3%, aggregate 9%, described flyash is to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, described lime comprises unslaked lime and white lime, the quantity of unslaked lime is no less than the 2%-5% of lime total amount, the granularity of lime and gypsum is more than 200 orders, and aggregate is the medium coarse sand of two district's gratings.Its production method is, the aggregate of the flyash of weight ratio 80% and 9% sent in the muller formula mulling stirrer stirred 2-3 minute, again the cement of 10% lime, 1% gypsum and 3% is added in the stirrer restir about 5 minutes, make mixing of materials even, compound sent into the pressure with 1,600 thousand Ns is pressed into the standard adobe that specification is 240 * 115 * 53mm in the YZP160-8A type disc-rotation type octal brick pressing machine, at last adobe is sent in the curing kilns, under 1-1.3MPa pressure and 170-200 ℃ of temperature vapor cure 6-8 hour, promptly get the flyash brick finished product.
The 5th example of implementing is: the proportioning raw materials of fly-ash mortar is a flyash 70%, lime 13%, and aggregate 17%, the granularity of lime is more than 200 orders.Its production method is, above-mentioned raw materials sent into together add water (amount of water is decided according to the humidity of required mortar) in the muller formula mulling stirrer and stirred about 10 minutes, makes mixing of materials even, promptly gets the fly-ash mortar finished product.
The 6th example of implementing is: the proportioning raw materials of fly-ash mortar is a flyash 80%, lime 7%, and cement 5%, aggregate 18%, the granularity of lime is more than 200 orders.Its production method is, above-mentioned raw materials sent into together add water (amount of water is decided according to the humidity of required mortar) in the muller formula mulling stirrer and stirred about 10 minutes, makes mixing of materials even, promptly gets the fly-ash mortar finished product.

Claims (9)

1, a kind of flyash brick, it comprises flyash, lime, gypsum, cement and aggregate, it is characterized in that: its proportioning raw materials (% is than meter by weight) is: flyash 70-80, lime 7-13, gypsum 0-1.3, cement 0-5, aggregate surplus, described flyash are to burn the mass fly ashes that nature is stacked at the stock ground with fluidizing furnace, and the content sum of silicon-dioxide in this mass fly ashes and ferric oxide is more than 35%, described lime comprises unslaked lime and white lime, the quantity of unslaked lime is no less than the 2%-5% of lime total amount, and the granularity of lime and gypsum is more than 200 orders, and aggregate is the medium coarse sand or the stone flour of two district's gratings.
2, by the described a kind of flyash brick of claim 1, it is characterized in that: its proportioning raw materials (% is than meter by weight) is: flyash 70%, lime 13%, aggregate 17%.
3, by the described a kind of flyash brick of claim 1, it is characterized in that: its proportioning raw materials (% is than meter by weight) is: flyash 80%, lime 7%, aggregate 13%.
4, by the described a kind of flyash brick of claim 1, it is characterized in that: its proportioning raw materials (% is than meter by weight) is: flyash 80%, lime 10%, gypsum 1%, aggregate 9%.
5, by the described a kind of flyash brick of claim 1, it is characterized in that: its proportioning raw materials (% is than meter by weight) is: flyash 80%, lime 7%, gypsum 1%, cement 3%, aggregate 9%
6, a kind of fly-ash mortar, it is characterized in that: it comprises flyash, lime, cement and aggregate, its proportioning raw materials (% is than meter by weight) is: flyash 70-80, lime 7-13, cement 0-5, aggregate surplus, the granularity of lime and gypsum is more than 200 orders, and aggregate is the medium coarse sand or the stone flour of two district's gratings.
7, production method by claim 1 or 2 or 3 or 4 or 5 described a kind of flyash bricks, it is characterized in that: flyash, the aggregate of described proportioning raw materials are sent in the muller formula mulling stirrer stirred 2-3 minute, again with lime, perhaps again and gypsum, perhaps add in the stirrer with cement again and stirred about 5 minutes, make mixing of materials even, compound is sent in the brick machine with the pressure compression moulding that is not less than 1,600 thousand Ns, at last adobe is carried out natural curing or vapor cure certain hour, promptly got the flyash brick finished product.
8, by the production method of the described a kind of flyash brick of claim 7, it is characterized in that: described brick machine is a YZP160-8A type disc-rotation type octal brick pressing machine.
9, production method by the described a kind of fly-ash mortar of claim 6, it is characterized in that: with the flyash and the lime of described proportioning raw materials, perhaps again and cement, send into together and add water stirring about 10 minutes in the muller formula mulling stirrer, amount of water is decided according to the humidity of the mortar of required production, promptly gets the fly-ash mortar finished product.
CNB2004100695168A 2004-06-30 2004-06-30 Bricks and mortar made from fly ash and preparation method Expired - Fee Related CN1278982C (en)

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100588525C (en) * 2008-09-05 2010-02-10 北京工业大学 Wall heat insulation material preparing method
CN101216388B (en) * 2007-12-28 2010-08-11 西安墙体材料研究设计院 Mortar for wall brick strength test
CN101844904A (en) * 2010-06-10 2010-09-29 西北大学 Brucite fiber reinforced fly ash composite material
CN105254278A (en) * 2015-10-17 2016-01-20 无为县华标新型墙体材料有限公司 Red fly ash sintered brick material
CN105272095A (en) * 2015-10-17 2016-01-27 无为县华标新型墙体材料有限公司 Light fly-ash brick
CN106348698A (en) * 2016-08-28 2017-01-25 北海金匠水泥制品有限责任公司 Manufacturing method of chemical-erosion-resistant cement brick
CN106365590A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Energy-saving cement brick
CN106365568A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Method for preparing energy-saving cement brick
CN106365589A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Method for preparing environmental-friendly cement brick
CN106396583A (en) * 2016-08-28 2017-02-15 北海金匠水泥制品有限责任公司 Manufacturing method of compression resistant cement brick
CN106396605A (en) * 2016-08-28 2017-02-15 北海金匠水泥制品有限责任公司 Preparation method of environment-friendly cement bricks
CN106746995A (en) * 2016-12-19 2017-05-31 吴硕 A kind of concrete inhales acoustic brick and preparation method thereof
CN107555959A (en) * 2017-09-27 2018-01-09 宿州市埇桥区三八街道九里村兴农服务有限公司 A kind of porous acoustic brick and its production method
CN107663047A (en) * 2017-09-27 2018-02-06 宿州市埇桥区三八街道九里村兴农服务有限公司 A kind of flyash brick and its production method
CN110451910A (en) * 2019-09-05 2019-11-15 徐州永腾建材有限公司 A kind of manufacturing method for hardening flyash brick
CN110467471A (en) * 2019-09-05 2019-11-19 徐州永腾建材有限公司 A kind of manufacture craft of flyash brick
CN113277826A (en) * 2021-06-15 2021-08-20 太原钢铁(集团)有限公司 Method for preparing autoclaved fly ash standard brick by utilizing ceramsite
CN114735983A (en) * 2022-05-09 2022-07-12 同济大学 High-strength fly ash brick containing fluidized bed sulfur fixation ash and preparation method thereof
CN116514503A (en) * 2023-06-30 2023-08-01 上海交通大学内蒙古研究院 Regenerated glass fiber reinforced autoclaved fly ash brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101216388B (en) * 2007-12-28 2010-08-11 西安墙体材料研究设计院 Mortar for wall brick strength test
CN100588525C (en) * 2008-09-05 2010-02-10 北京工业大学 Wall heat insulation material preparing method
CN101844904A (en) * 2010-06-10 2010-09-29 西北大学 Brucite fiber reinforced fly ash composite material
CN101844904B (en) * 2010-06-10 2012-12-05 西北大学 Brucite fiber reinforced fly ash composite material
CN105254278A (en) * 2015-10-17 2016-01-20 无为县华标新型墙体材料有限公司 Red fly ash sintered brick material
CN105272095A (en) * 2015-10-17 2016-01-27 无为县华标新型墙体材料有限公司 Light fly-ash brick
CN106396583A (en) * 2016-08-28 2017-02-15 北海金匠水泥制品有限责任公司 Manufacturing method of compression resistant cement brick
CN106365590A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Energy-saving cement brick
CN106365568A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Method for preparing energy-saving cement brick
CN106365589A (en) * 2016-08-28 2017-02-01 北海金匠水泥制品有限责任公司 Method for preparing environmental-friendly cement brick
CN106348698A (en) * 2016-08-28 2017-01-25 北海金匠水泥制品有限责任公司 Manufacturing method of chemical-erosion-resistant cement brick
CN106396605A (en) * 2016-08-28 2017-02-15 北海金匠水泥制品有限责任公司 Preparation method of environment-friendly cement bricks
CN106746995A (en) * 2016-12-19 2017-05-31 吴硕 A kind of concrete inhales acoustic brick and preparation method thereof
CN107555959A (en) * 2017-09-27 2018-01-09 宿州市埇桥区三八街道九里村兴农服务有限公司 A kind of porous acoustic brick and its production method
CN107663047A (en) * 2017-09-27 2018-02-06 宿州市埇桥区三八街道九里村兴农服务有限公司 A kind of flyash brick and its production method
CN110451910A (en) * 2019-09-05 2019-11-15 徐州永腾建材有限公司 A kind of manufacturing method for hardening flyash brick
CN110467471A (en) * 2019-09-05 2019-11-19 徐州永腾建材有限公司 A kind of manufacture craft of flyash brick
CN113277826A (en) * 2021-06-15 2021-08-20 太原钢铁(集团)有限公司 Method for preparing autoclaved fly ash standard brick by utilizing ceramsite
CN114735983A (en) * 2022-05-09 2022-07-12 同济大学 High-strength fly ash brick containing fluidized bed sulfur fixation ash and preparation method thereof
CN114735983B (en) * 2022-05-09 2023-02-17 同济大学 Coal ash brick containing fluidized bed sulfur fixation ash and preparation method thereof
CN116514503A (en) * 2023-06-30 2023-08-01 上海交通大学内蒙古研究院 Regenerated glass fiber reinforced autoclaved fly ash brick and preparation method thereof

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