CN1685921A - Milk increasing calcium aliphatate and its making method - Google Patents
Milk increasing calcium aliphatate and its making method Download PDFInfo
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- CN1685921A CN1685921A CNA2005100099484A CN200510009948A CN1685921A CN 1685921 A CN1685921 A CN 1685921A CN A2005100099484 A CNA2005100099484 A CN A2005100099484A CN 200510009948 A CN200510009948 A CN 200510009948A CN 1685921 A CN1685921 A CN 1685921A
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Abstract
A calcium salt of fatty acid for increaisng the milk output of milk cow is prepared through adding excessive solution of sodium hydroxide, to plant oil, stirring, heating to 60-70 deg.C, holding the temp of 20-40 min, stirring, adding the solution of calcium chloride, stirring, holding the temp for 12-24 hr, adding calcium chloride, stirring for depositing, filtering with nylon cloth while water flushing, and drying the solid substance. It can be directly mixed with feed.
Description
(1) technical field
What the present invention relates to is a kind of feed addictive, specifically a kind of feed addictive that improves ruminant animal nutrition.The present invention also relates to the preparation method of this feed addictive.
(2) background technology
For high yield cow, descend in lactation feed intake in early stage, the energy of taking in from daily ration can not satisfy the needs of keeping with high yield, milk cow is employed body fat in order to keep the output of milk, cause body weight to descend, too many loss of weight can produce adverse influence to the whole lactational performance of giving milk, and can prolong the breeding time of milk cow simultaneously, and that has reduced milk cow effectively utilizes the time limit.Energy is first nutritional need of milk cow.The characteristics of high yield cow are that body metabolism is vigorous, and the feed feed intake is big, the conversion ratio height.Early stage in lactation, because the supply of energy can not be satisfied the needs of giving milk, negative energy balance can cause the metabolism generation obstacle of milk cow, causes milk cow that ketoacidosis and fatty liver take place.The measure of alleviating negative energy balance mainly contains: increase the fine fodder food-intake, use rumen-undegraded fat.(3) summary of the invention
The object of the present invention is to provide a kind of can directly adding in the daily ration, can reach the milk increasing calcium aliphatate that improves dietary digestibility of energy concentration purpose.Purpose of the present invention also relates to the preparation method of this milk increasing calcium aliphatate.
The object of the present invention is achieved like this: the present invention is the product that vegetable oil adopts following method to make: adding excessive concentrations in vegetable oil is the sodium hydroxide solution of 5%-40%, stir fully the back is incubated 20-40 minute under 60-70 ℃ of temperature, after the stirring, under 60-70 ℃ of temperature, be incubated 30-60 minute once more, adding concentration is the calcium chloride solution of 15%-25% and fully stirring, under 60-70 ℃ of temperature, be incubated 12-24 hour then, in turbid liquid, the calcium chloride that adds 15%-25% once more, being stirred to a large amount of precipitations generates, under tap, use and filter greater than 200 purpose nylon cloths, flushing, make the liquid pH value that spills under the filter cloth be neutral, the solid content that filters out, air dry in air.Employed vegetable oil can be a corn oil among the present invention.
Product of the present invention is to make like this: adding excessive concentrations in vegetable oil is the sodium hydroxide solution of 5%-40%, stir fully the back is incubated 20-40 minute under 60-70 ℃ of temperature, after the stirring, under 60-70 ℃ of temperature, be incubated 30-60 minute once more, adding concentration is the calcium chloride solution of 15%-25% and fully stirring, under 60-70 ℃ of temperature, be incubated 12-24 hour then, in turbid liquid, the calcium chloride that adds 15%-25% once more has been stirred to a large amount of precipitations and has generated, and uses under tap and filters greater than 200 purpose nylon cloths, flushing, make the liquid pH value that spills under the filter cloth be neutral, the solid content that filters out, product is made in air dry in air.
Employed vegetable oil can be a corn oil among the present invention.
Add fat in the daily ration and can reach the purpose that improves dietary digestibility of energy concentration equally, and compare with cereals with starch, add fat its unique advantage is arranged: at first, being worth of fat is high, the fatty exhaustive oxidation of every gram can discharge 3807 kilojoule energy, and oxidation 1 gram sugar can only discharge 17.15 kilojoule energy.So adding fat in the dairy cow diet that can not satisfy the demand to the early stage feed intake of lactation can provide bigger energy consumption; The second, the LCFA (C in the fat
16-C
22) can directly enter the synthetic butterfat of mammary gland, therefore, the efficient height of giving milk of fat; The 3rd, add fat and both can improve the energy food-intake, certain crude fibre food-intake be can maintain again, thereby milk cow acid poisoning and other dysbolisms avoided; The 4th, add the waste that fat can also reduce metabolic heat at torridity summer, milk cow opposing heat stress is had certain effect.In addition, add the generation that fat also reduces methane, reduce energy loss.Corn oil fatty acid calcium resource is wide, is rich in unrighted acid, can improve the health care value of milk to the mankind.The present invention is that primary raw material adopts the double decomposition method with corn oil, NaOH, calcium chloride, on the basis of repetition test, has explored the production process of fatty acid calcium.And measured corn oil fatty acid calcium cross the cud performance.
The performance measurement of product of the present invention: the result that the application conventional method of analysis is analyzed product is: fat content accounts for 75.5% of sample dry weight, and calcium content is 6.7%, and the pH value is about 7, and slightly the white or the milk yellow of frankincense flavor are Powdered.Adopt the Nylon Bag method to measure the cud performance excessively of fat, to 15 bags of the oven dry fatty acid calcium Nylon Bags of weighing be housed, put into the china holstein cows cud that permanent rumen fistula is housed, test divides three phases, respectively after taking out back cleaning rumen fluid in 24 hours, 48 hours, 72 hours, put into drying in oven, weigh, measure fatty disappearance rate.The result is: through 24 hours, 48 hours, 72 hours, the average disappearance rate of fatty acid calcium was respectively 0.25%, 0.32%, 0.36%.The result shows that the cud performance excessively of fatty acid calcium is fine.
The present invention studies the processing technology of novel unrighted acid calcium-corn oil fatty acid oil calcium, has determined the optimal reaction temperature of course of reaction, the Best Times of reaction and NaOH, the suitable concentration of calcium chloride solution.Proved the good cud performance excessively of corn oil fat acid calcium, for the application of non-saturated fatty acid calcium in ruminant provides theoretical foundation.Break-through point of the present invention be success solution the washing a difficult problem, the pH value stabilization about 7, the good palatability of fresh products.Unrighted acid is to improving cla levels, particularly ω 6 content in the milk, and production human health health-care milk is significant.
Product of the present invention can be admixed in the fine fodder and be fed optimum amount 300g/ head. day.Also can directly sneak in feed, adding quantity is 1～2%.This product stability is better, needs to add antioxidant and prevents becoming sour of fat, and product stability is better after the inborn nature thing is handled.Can keep biologically active six months at normal temperature condition.Best storage temperature is below 20 ℃, and winter is can the holding time longer.
(4) specific embodiments
With corn oil, NaOH, calcium chloride are that primary raw material adopts the double decomposition method, produce its preparation technology of fatty acid calcium and are: the saponification character according to grease, under alkali condition, fat splitting is saponified into sodium soap, and use Ca then
2+Form precipitation with fatty acid radical, obtain fatty acid calcium.Concrete steps are as follows:
One, corn oil is put into bucket, adding excessive concentrations is 30% sodium hydroxide solution, puts into 65 ℃ of baking ovens after stirring fully.Question response takes out after 30 minutes, stirs, and puts back to once more in the baking oven, treat its complete reaction after, to add concentration be 20% calcium chloride solution and fully stir, and puts back in the baking oven then and spend the night.Reactant was taken out the turbid liquid of handle for bucket fatty acid calcium in second day and pour in the big basin, add concentration once more and be 20% calcium chloride, stirring promptly has a large amount of precipitations to generate.Use under tap greater than 200 purpose nylon cloths and filter, flushing makes the liquid pH value that spills under the filter cloth be neutral.The fatty acid calcium that filters out will be tiled in the big iron pan and tile, and carries out the air air dry.
Two, corn oil is put into bucket, adding excessive concentrations is 20% sodium hydroxide solution, puts into 65 ℃ of baking ovens after stirring fully.Question response takes out after 30 minutes, stirs, and puts back to once more in the baking oven, treat its complete reaction after, to add concentration be 20% calcium chloride solution and fully stir, and puts back in the baking oven then and spend the night.Reactant was taken out the turbid liquid of handle for bucket fatty acid calcium in second day and pour in the big basin, add concentration once more and be 15% calcium chloride, stirring promptly has a large amount of precipitations to generate.Use under tap greater than 200 purpose nylon cloths and filter, flushing makes the liquid pH value that spills under the filter cloth be neutral.The fatty acid calcium that filters out will be tiled in the big iron pan and tile, and carries out the air air dry.
Performance measurement: the result that the application conventional method of analysis is analyzed product is: fat content accounts for 75.5% of sample dry weight, and calcium content is 6.7%, and the pH value is about 7, and slightly the white or the milk yellow of frankincense flavor are Powdered.Adopt the Nylon Bag method to measure the cud performance excessively of fat, to 15 bags of the oven dry fatty acid calcium Nylon Bags of weighing be housed, put into the china holstein cows cud that permanent rumen fistula is housed, test divides three phases, respectively after taking out back cleaning rumen fluid in 24 hours, 48 hours, 72 hours, put into drying in oven, weigh, measure fatty disappearance rate.The result is: through 24 hours, 48 hours, 72 hours, the average disappearance rate of fatty acid calcium was respectively 0.25%, 0.32%, 0.36%.The result shows that the cud performance excessively of fatty acid calcium is fine.
Claims (3)
1, a kind of milk increasing calcium aliphatate, it is characterized in that: it is that the adding excessive concentrations is the sodium hydroxide solution of 5%-40% in vegetable oil, stir fully the back is incubated 20-40 minute under 60-70 ℃ of temperature, after the stirring, under 60-70 ℃ of temperature, be incubated 30-60 minute once more, adding concentration is the calcium chloride solution of 15%-25% and fully stirring, under 60-70 ℃ of temperature, be incubated 12-24 hour then, in turbid liquid, the calcium chloride that adds 15%-25% once more, being stirred to a large amount of precipitations generates, use under tap greater than 200 purpose nylon cloths and filter, flushing makes the liquid pH value that spills under the filter cloth be neutral, the solid content that filters out, the resulting product of air dry in air.
2, a kind of preparation method of milk increasing calcium aliphatate, it is characterized in that: adding excessive concentrations in vegetable oil is the sodium hydroxide solution of 5%-40%, stir fully the back is incubated 20-40 minute under 60-70 ℃ of temperature, after the stirring, under 60-70 ℃ of temperature, be incubated 30-60 minute once more, adding concentration is the calcium chloride solution of 15%-25% and fully stirring, under 60-70 ℃ of temperature, be incubated 12-24 hour then, in turbid liquid, the calcium chloride that adds 15%-25% once more, being stirred to a large amount of precipitations generates, use under tap greater than 200 purpose nylon cloths and filter, flushing makes the liquid pH value that spills under the filter cloth be neutral, the solid content that filters out, product is made in air dry in air.
3, the preparation method of milk increasing calcium aliphatate according to claim 2 is characterized in that: described vegetable oil is a corn oil.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2005100099484A CN100438772C (en) | 2005-04-29 | 2005-04-29 | Milk increasing calcium aliphatate and its making method |
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| CNB2005100099484A CN100438772C (en) | 2005-04-29 | 2005-04-29 | Milk increasing calcium aliphatate and its making method |
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| CN1685921A true CN1685921A (en) | 2005-10-26 |
| CN100438772C CN100438772C (en) | 2008-12-03 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103689239A (en) * | 2013-12-23 | 2014-04-02 | 宜兴市天石饲料有限公司 | Preparation method of rumen-through double-layer coated betaine |
| WO2016058283A1 (en) * | 2014-10-13 | 2016-04-21 | 浙江医药股份有限公司新昌制药厂 | Preparation method for polyunsaturated fatty acid-calcium |
| CN106278871A (en) * | 2016-08-08 | 2017-01-04 | 苏志刚 | Utilize the method that fatty acid calcium prepared by Oleum Gossypii semen |
| CN106605765A (en) * | 2015-10-22 | 2017-05-03 | 丰益(上海)生物技术研发中心有限公司 | Extraction and application of sunflower meal proteins |
| CN108077928A (en) * | 2017-11-30 | 2018-05-29 | 郭英群 | A kind of health products and preparation method thereof |
| CN112293579A (en) * | 2020-10-27 | 2021-02-02 | 中国林业科学研究院林产化学工业研究所 | Multifunctional feed additive and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566062A (en) * | 2003-06-11 | 2005-01-19 | 安致和 | Simple production process of feed additive calcium soap |
-
2005
- 2005-04-29 CN CNB2005100099484A patent/CN100438772C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103689239A (en) * | 2013-12-23 | 2014-04-02 | 宜兴市天石饲料有限公司 | Preparation method of rumen-through double-layer coated betaine |
| WO2016058283A1 (en) * | 2014-10-13 | 2016-04-21 | 浙江医药股份有限公司新昌制药厂 | Preparation method for polyunsaturated fatty acid-calcium |
| US10035750B2 (en) | 2014-10-13 | 2018-07-31 | Zhejiang Medicine Co., Ltd. Xinchang Pharmaceutical Factory | Preparation method for polyunsaturated fatty acid-calcium |
| CN106605765A (en) * | 2015-10-22 | 2017-05-03 | 丰益(上海)生物技术研发中心有限公司 | Extraction and application of sunflower meal proteins |
| CN106278871A (en) * | 2016-08-08 | 2017-01-04 | 苏志刚 | Utilize the method that fatty acid calcium prepared by Oleum Gossypii semen |
| CN108077928A (en) * | 2017-11-30 | 2018-05-29 | 郭英群 | A kind of health products and preparation method thereof |
| CN112293579A (en) * | 2020-10-27 | 2021-02-02 | 中国林业科学研究院林产化学工业研究所 | Multifunctional feed additive and preparation method thereof |
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| CN100438772C (en) | 2008-12-03 |
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