CN1669990A - Chemical fertilizer synergist and its preparation method and application - Google Patents

Chemical fertilizer synergist and its preparation method and application Download PDF

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Publication number
CN1669990A
CN1669990A CN 200510059625 CN200510059625A CN1669990A CN 1669990 A CN1669990 A CN 1669990A CN 200510059625 CN200510059625 CN 200510059625 CN 200510059625 A CN200510059625 A CN 200510059625A CN 1669990 A CN1669990 A CN 1669990A
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synergistic agent
sulfate
fertilizer
fertilizer synergistic
weight percent
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CN 200510059625
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姚力群
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Individual
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Individual
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Abstract

The invention relates to a fertilizer synergist, the process for preparation and use for combining with fertilizers, which comprises 50-70 wt% humic acid and 30-50 wt% tracer element composition, wherein the tracer element composition comprises (by weight ratio) calcium sulphate 35-70%, magnesium sulfate 10-20%, borax 0.5-1%, ferrous sulfate 2.75-5.5%, manganese sulfate 0.5-1%, zinc sulfate 0.5-1%, copper sulfate 0.5-1%, ammonium molybdate 0.25-0.5%.

Description

Fertilizer synergistic agent and its production and application
Technical field:
The present invention relates to a kind of synergistic agent, particularly relate to a kind of fertilizer synergistic agent, reach preparation method and application.
Background technology:
At present, the mankind are being faced with the population growth, the serious challenge such as minimizing, environmental pollution of ploughing, and in order to satisfy the demand of the growing grain of people and other agricultural-food, must increase output, and apply the main means that chemical fertilizer is an agricultural produce.
Though traditional fertilizer such as diammonium phosphate, bicarbonate of ammonia, ammonium sulfate etc. can be directly by plant absorbing, disadvantage is that volatilization is fast, utilization ratio is low, plant absorbing is few, influence environment.Urea belongs to amides nitrogenous fertilizer, because it is in soil in the decomposition course, needed for three steps transformed: the first step, earlier discharge the urine enzyme by bacterium, fungi, actinomycetes, form volatile salt and bicarbonate of ammonia behind the urine enzyme decomposing urea, and they very easily are decomposed into ammonia, carbonic acid gas, water, a large amount of easily volatilizations, cause direct economic loss, the urea utilization ratio reduces thus; In second step, volatile salt and bicarbonate of ammonia are decomposed into nitrite nitrogen by nitrite bacteria, and nitrite nitrogen is owing to be negatively charged ion, are not easy by negatively charged ion-soil colloid particle adsorbedly, cause loss; In the 3rd step, the nitrite nitrogen element is decomposed by nitrobacteria, become the negatively charged ion nitric nitrogen, and the as easy as rolling off a log loss of nitric nitrogen causes the loss for the third time of urea.Lose very seriously, the utilization ratio of common urea has only about 30%.And life-time service easily causes soil compaction, lacks micro-, soil fertility decline.
Summary of the invention:
The objective of the invention is to, solve the deficiencies in the prior art, a kind of enhancing fertilizer efficiency is provided, overcome soil fertility and descend, replenish the fertilizer synergistic agent of soil trace element.
Another object of the present invention provides the preparation method of above-mentioned fertilizer synergistic agent.
The invention still further relates to the application of above-mentioned fertilizer synergistic agent when combining with chemical fertilizer.
Above-mentioned purpose of the present invention can realize by following technical scheme:
Fertilizer synergistic agent of the present invention is made up of following raw materials by weight:
Humic acids 50%-70%
Microelement composition 30%-50%.
Wherein said microelement composition is made up of the following raw materials according that accounts for the microelement composition total weight percent: calcium sulfate 35%-70%, sal epsom 10%-20%, borax 0.5%-1%, ferrous sulfate 2.75%-5.5%, manganous sulfate 0.5%-1%, zinc sulfate 0.5%-1%, copper sulfate 0.5%-1%, ammonium molybdate 0.25%-0.5%.
The preparation method of fertilizer synergistic agent of the present invention comprises by following steps and forming:
(1) is mixed with microelement composition by the following raw materials according that accounts for the microelement composition total weight percent: calcium sulfate 35%-70%, sal epsom 10%-20%, borax 0.5%-1%, ferrous sulfate 2.75%-5.5%, manganous sulfate 0.5%-1%, zinc sulfate 0.5%-1%, copper sulfate 0.5%-1%, ammonium molybdate 0.2 5%-0.5%;
(2) get the humic acids that accounts for described fertilizer synergistic agent total weight percent 50%-70%, add the microelement composition that accounts for described fertilizer synergistic agent total weight percent 30%-50%;
(3) carry out granulation by prilling granulator, again by the heating unit heating, drying;
(4) after the oven dry, filter out the single-size of humic acids trace element, obtain the fertilizer synergistic agent finished product with roller grizzly.
As preferably, the prilling granulator described in the step (3) can be that diameter is the pelletizing disks of 1-2 rice.Heating unit can be a process furnace, and heating 18-25 rice cylinder continues 10-30 minute to 600-800 ℃.
The application of fertilizer synergistic agent of the present invention when combining with chemical fertilizer comprises the following step, and it is standby by the pack of 35-45 kilogram amount to get chemical fertilizer respectively; It is standby by the pack of 5-15 kilogram amount to get humic acids trace element particle; Can mix to spare and use again: chemical fertilizer 70%-90% with above-mentioned raw materials by following weight ratio during fertilising; Humic acids trace element particle 10%-30%.
The present invention has following advantage:
(1) can activating soil, overcome and harden.Use common chemical fertilizer can make soil compaction, secondary salinization, life-time service, soil fertility descends, and structure deteriorate causes the underproduction even total crop failure.Humic acids can chessom, overcomes and hardens, and recovers soil fertility, improves output, and very magical effect is arranged.
(2) utilization ratio of raising urea, the saving fund reduces and drops into, and increases the benefit.Because the loss of fertilizer, utilization ratio has only about 30%, wastes very serious, and because adsorption, the complexing action of humic acids, can effectively improving the soil effect, the loss of minimizing urea, increase operation rate, reduce input-output ratio, increase the benefit, not only get bumper crops but also have a good harvest.
(3) fertilizer synergistic agent is used in combination with chemical fertilizer, and competent nitrogen element not only can be provided, and for soil provides the trace element of capacity, can improve crop yield rapidly, replenishes soil fertility.
Embodiment:
Below in conjunction with specific embodiment the present invention is further detailed, does not therefore limit the present invention among the described scope of embodiments.
Embodiment 1
Prepare fertilizer synergistic agent of the present invention:
(1) gets 35 kilograms in calcium sulfate, 10 kilograms in sal epsom, 0.5 kilogram of borax, 2.75 kilograms in ferrous sulfate, 0.5 kilogram of manganous sulfate, 0.5 kilogram in zinc sulfate, 0.5 kilogram in copper sulfate, 0.25 kilogram of ammonium molybdate, be mixed with microelement composition;
(2) get the 120 kg humic acids, add above-mentioned microelement composition;
(3) using diameter is that 1.5 meters pelletizing disks carries out granulation, re-uses process furnace, heat 18 meters cylinders to 600 ℃, lasting 10 minutes;
(4) after the oven dry, filter out the single-size of humic acids trace element with roller grizzly.
Embodiment 2
Prepare fertilizer synergistic agent of the present invention:
(1) gets 70 kilograms in calcium sulfate, 20 kilograms in sal epsom, 1 kilogram of borax, 5.5 kilograms in ferrous sulfate, 1 kilogram of manganous sulfate, 1 kilogram in zinc sulfate, 1 kilogram in copper sulfate, 0.5 kilogram of ammonium molybdate, be mixed with microelement composition;
(2) get 100 kilograms of humic acidss, add above-mentioned microelement composition;
(3) using diameter is that 2 meters pelletizing disks carries out granulation, re-uses process furnace, heat 25 meters cylinders to 800 ℃, lasting 30 minutes;
(4) after the oven dry, filter out the single-size of humic acids trace element with roller grizzly.
Embodiment 3
Application when chemical synergists of the present invention combines with chemical fertilizer:
It is standby by 35 kilograms of amount packs to get urea; It is standby by 5 kilograms of amount packs to get humic acids trace element particle; Can mix evenly when using by the time, use then.
Embodiment 4
Application when chemical synergists of the present invention combines with chemical fertilizer:
It is standby by 45 kilograms of amount packs to get diammonium phosphate; It is standby by 15 kilograms of amount packs to get humic acids trace element particle; Can mix evenly when using by the time, use then.
The simultaneous test data of estimating humic acids trace element fertilizer synergistic agent of the present invention synergism are provided below:
Table one
Crop Fertilising Each fertilising back output kilogram/50m 2 Mean yield Volume increase
The 1st time The 2nd time The 3rd time
Crowndaisy chrysanthemum Common urea ??67.2 ????64.0 ????65.3 ??65.5 ??34.2%
Add the urea of synergistic agent ??83.6 ????90.4 ????89.7 ??87.9
Celery Common diammonium phosphate ??241.0 ????258.0 ????264.3 ??254.4 ??14.4%
Add the diammonium phosphate of synergistic agent ??300.4 ????281.0 ????291.5 ??291.0
Conclusion:
Find that by experimental observation crowndaisy chrysanthemum, celery apply synergistic agent of the present invention and compare with the single chemical fertilizer of contrast: (1) robust plant, fast growth, obvious effect of increasing production, volume increase reaches 14.4%-34.2%; (2) quality of vegetable improves, and economic benefit obviously improves.

Claims (6)

1. fertilizer synergistic agent is characterized in that it is made of by weight percentage following raw materials according:
Humic acids 50%-70%
Microelement composition 30%-50%
Wherein said microelement composition is made up of the following raw materials according that accounts for the microelement composition total weight percent: calcium sulfate 35%-70%, sal epsom 10%-20%, borax 0.5%-1%, ferrous sulfate 2.75%-5.5%, manganous sulfate 0.5%-1%, zinc sulfate 0.5%-1%, copper sulfate 0.5%-1%, ammonium molybdate 0.25%-0.5%.
2. the preparation method of fertilizer synergistic agent as claimed in claim 1 is characterized in that this method comprises successively to be made up of following steps:
(1) is mixed with microelement composition by the following raw materials according that accounts for the microelement composition total weight percent: calcium sulfate 35%-70%, sal epsom 10%-20%, borax 0.5%-1%, ferrous sulfate 2.75%-5.5%, manganous sulfate 0.5%-1%, zinc sulfate 0.5%-1%, copper sulfate 0.5%-1%, ammonium molybdate 0.25%-0.5%;
(2) get the humic acids that accounts for described fertilizer synergistic agent total weight percent 50%-70%, add the microelement composition that accounts for described fertilizer synergistic agent total weight percent 30%-50%;
(3) carry out granulation by prilling granulator, again by the heating unit heating, drying;
(4) after the oven dry, filter out the single-size of humic acids trace element, obtain the fertilizer synergistic agent finished product with roller grizzly.
3. the preparation method of fertilizer synergistic agent as claimed in claim 2 is characterized in that the prilling granulator described in the step (3) is that diameter is the pelletizing disks of 1-2 rice.
4. the preparation method of fertilizer synergistic agent as claimed in claim 2 is characterized in that the heating unit described in the step (3) is a process furnace, and heating 18-25 rice cylinder continues 10-30 minute to 600-800 ℃.
5. the application of fertilizer synergistic agent as claimed in claim 1 is characterized in that: in when fertilising is that the fertilizer synergistic agent of 10%-30% is mixed to spare with the chemical fertilizer of 70%-90% and used with weight percent.
6. the application of fertilizer synergistic agent as claimed in claim 5 is characterized in that described chemical fertilizer is urea, diammonium phosphate or composite fertilizer.
CN 200510059625 2005-03-29 2005-03-29 Chemical fertilizer synergist and its preparation method and application Pending CN1669990A (en)

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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844952A (en) * 2009-03-24 2010-09-29 甘肃省农业科学院植物保护研究所 Formula and production method of humic acid liquid fertilizer
CN101913940A (en) * 2010-02-10 2010-12-15 南京信息工程大学 Horsebean biological compound fertilizer prepared from ardealite, preparation method thereof and use thereof
CN101774838B (en) * 2010-01-08 2011-03-16 南京信息工程大学 Corn growth promoting agent containing phosphogypsum and as well as preparation method and application thereof
CN102153396A (en) * 2010-05-12 2011-08-17 北京雷力农用化学有限公司 Process for manufacturing algae medium trace element compound granular fertilizer
CN101786924B (en) * 2010-01-25 2012-06-13 南京信息工程大学 Tomato yield increasing agent containing phosphogypsum, preparation method and application thereof
CN102701868A (en) * 2012-06-27 2012-10-03 中国农业科学院农业资源与农业区划研究所 Modified glutamic acid fertilizer synergist and production method and application thereof
CN110521479A (en) * 2019-09-06 2019-12-03 广西壮族自治区林业科学研究院 A method of it improving China fir and phosphorus nutrients is utilized

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844952A (en) * 2009-03-24 2010-09-29 甘肃省农业科学院植物保护研究所 Formula and production method of humic acid liquid fertilizer
CN101844952B (en) * 2009-03-24 2013-06-19 甘肃省农业科学院植物保护研究所 Formula and production method of humic acid liquid fertilizer
CN101774838B (en) * 2010-01-08 2011-03-16 南京信息工程大学 Corn growth promoting agent containing phosphogypsum and as well as preparation method and application thereof
CN101786924B (en) * 2010-01-25 2012-06-13 南京信息工程大学 Tomato yield increasing agent containing phosphogypsum, preparation method and application thereof
CN101913940A (en) * 2010-02-10 2010-12-15 南京信息工程大学 Horsebean biological compound fertilizer prepared from ardealite, preparation method thereof and use thereof
CN101913940B (en) * 2010-02-10 2013-01-02 南京信息工程大学 Horsebean biological compound fertilizer prepared from ardealite, preparation method thereof and use thereof
CN102153396A (en) * 2010-05-12 2011-08-17 北京雷力农用化学有限公司 Process for manufacturing algae medium trace element compound granular fertilizer
CN102153396B (en) * 2010-05-12 2013-08-07 北京雷力农用化学有限公司 Process for manufacturing algae medium trace element compound granular fertilizer
CN102701868A (en) * 2012-06-27 2012-10-03 中国农业科学院农业资源与农业区划研究所 Modified glutamic acid fertilizer synergist and production method and application thereof
CN110521479A (en) * 2019-09-06 2019-12-03 广西壮族自治区林业科学研究院 A method of it improving China fir and phosphorus nutrients is utilized

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