CN101844952B - Formula and production method of humic acid liquid fertilizer - Google Patents
Formula and production method of humic acid liquid fertilizer Download PDFInfo
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- CN101844952B CN101844952B CN200910119648XA CN200910119648A CN101844952B CN 101844952 B CN101844952 B CN 101844952B CN 200910119648X A CN200910119648X A CN 200910119648XA CN 200910119648 A CN200910119648 A CN 200910119648A CN 101844952 B CN101844952 B CN 101844952B
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- Prior art keywords
- humic acid
- kilogram
- sulfate
- zinc
- fertilizer
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000004021 humic acid Substances 0.000 title claims abstract description 24
- 239000003337 fertilizer Substances 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 title claims abstract description 7
- 238000009472 formulation Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title abstract description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052796 boron Inorganic materials 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052802 copper Inorganic materials 0.000 claims abstract description 8
- 239000010949 copper Substances 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 8
- 239000011733 molybdenum Substances 0.000 claims abstract description 8
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 6
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 5
- 239000011609 ammonium molybdate Substances 0.000 claims description 5
- 229940010552 ammonium molybdate Drugs 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 5
- 229960001763 zinc sulfate Drugs 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011573 trace mineral Substances 0.000 claims description 3
- 235000013619 trace mineral Nutrition 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 abstract description 6
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000035558 fertility Effects 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000008635 plant growth Effects 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 241000234282 Allium Species 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- JJEJDZONIFQNHG-UHFFFAOYSA-N [C+4].N Chemical compound [C+4].N JJEJDZONIFQNHG-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 235000021251 pulses Nutrition 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a formula and a production method of a humic acid liquid fertilizer, and relates to the field of agricultural fertilizers. The production method is characterized in that more than or equal to 2% of any two or more than of more than or equal to 8% of humic acid, 0.2-1% of Fe, 0.6-1% of manganese, 0.3-1% of zinc, 0.2-1% of copper, 0.5-1% of boron and 0.2-1% of molybdenum can be mixed with water to be fully stirred and kept stand for 1-2 hours, and the product can be obtained by sub-packaging. The product can not only balance soil fertility, activate soil nutrient, promote the full absorption of nutrients, regulate plant growth, increase yield, but also improve crop quality and fertilizer utilization rate. Compared with similar products, the product has the characteristics of good fertilizer effect, simple preparation process, easy obtainment of raw materials and low preparation cost.
Description
Affiliated technical field
The present invention relates to a kind of humic acid liquid fertilizer formula and production method, this product is mainly used in the fertilising of the agricultural-food such as capsicum, leek, onion, garlic, Radix Dauci Sativae.
Background technology
At present, known humic acid fertilizer has a lot, for example number of patent application 98118973, denomination of invention is wherein urea 3-45, diammonium phosphate 12-50, Repone K or the vitriolate of tartar 6-42, brown coal 14-55, ammoniacal liquor 3-10, wilkinite 2-4, water glass 1-2, trace element zinc, boron, the manganese 1-2 that make of proportioning raw materials of humic acid combined fertilizer and preparation method thereof, and above unit is weight percentage.Wherein change above each component content and can make respectively the special fertilizer of paddy rice, corn, pulse family, fruit tree, tobacco, characteristics of the present invention can improve soil, increase Crop yield and quality, improve cold-resistant disease-resistant drought-resistant ability, promote crop precocious, be applicable to the needed nutrient of multiple kinds of crops growth, the present invention also provides the production method of humic acid combined fertilizer.Number of patent application is 200410090688, and denomination of invention is the wherein composition of composite biological humic acid fertilizer of a kind of composite biological humic acid fertilizer and manufacture method thereof: urea: 25-27, Repone K: 25-27, ammonium phosphate: 30-32, additive: 5-0, humic acid: 15-16, carbon ammonium: 5.Manufacturing processed adopts the raw material of common inorganic composite fertilizer to do carrier, mix with humic acid, again through granule, oven dry, cooling, the solid microbe preparation that adds again small packages when packing after screening, advantage of the present invention is: it is the multifunctional compound fertilizer that a kind of biological organic fertilizer and inorganic fertilizer mix, its existing bio-organic fertilizer long-lasting has again the wholesomeness of improvement soil concurrently, is a kind of new-type fertilizer of desirable development green agriculture product.
Summary of the invention
The present invention is take humic acid 〉=8%, iron 0.2-1%, manganese 0.6-1%, zinc 0.3-1%, copper 0.2-1%, boron 0.5-1%, molybdenum 0.2-1% etc. as raw material, the humic acid liquid fertilizer that the certain physical method of process is prepared from, this product can not only balance soil fertility, the activating soil nutrient, promote fully absorption of nutrient, regulating crop growth, increase output, and can improve crop quality, improve utilization rate of fertilizer.Compared with similar products, have fertilizer efficiency good, preparation technology is simple, and raw material is easy to get, the characteristics that preparation cost is cheap.The formula of this humic acid fertilizer: humic acid 〉=8%, iron 0.2-1%, manganese 0.6-1%, zinc 0.3-1%, copper 0.2-1%, two or more arbitrary combination trace element 〉=2% of boron 0.5-1%, molybdenum 0.2-1%, ferrous sulfate 1-5%, manganous sulfate 1.7-2.9%, zinc sulfate 0.9-3.1%, copper sulfate 0.8-4%, borax 5-10%, ammonium molybdate 0.4-2%.The preparation method of this humic acid is: (1) to make 81 kilograms of mixed solutions standby by mixing at 1: 12.5, shaking up with humic acid and water.(2) ferrous sulfate 1-5 kilogram, manganous sulfate 1.7-2.9 kilogram, zinc sulfate 0.9-3.1 kilogram, copper sulfate 0.8-4 kilogram, borax 5-10 kilogram, ammonium molybdate 0.4-2 kilogram are added in the mixed solution that step (1) makes by said ratio, make iron, manganese, zinc, copper, boron, two or more arbitrary combination of molybdenum 〉=2 kilograms, then weigh, 100 kilograms of waters of less than are supplied, the rear placement 1 ~ 2 hour that stirs namely gets product by the specification packing.
Embodiment
Humic acid 〉=8%, iron 0.2-1%, manganese 0.6-1%, zinc 0.3-1%, copper 0.2-1%, boron 0.5-1%, two or more arbitrary combination of molybdenum 0.2-1% 〉=2%, the preparation method of this humic acid is: (1) to make 81 kilograms of mixed solutions standby by mixing at 1: 12.5, shaking up with humic acid and water.(2) ferrous sulfate 1-5 kilogram, manganous sulfate 1.7-2.9 kilogram, zinc sulfate 0.9-3.1 kilogram, copper sulfate 0.8-4 kilogram, borax 5-10 kilogram, ammonium molybdate 0.4-2 kilogram are added in the mixed solution that step (1) makes by said ratio, make iron, manganese, zinc, copper, boron, two or more arbitrary combination of molybdenum 〉=2 kilograms, then weigh, 100 kilograms of waters of less than are supplied, the rear placement 1 ~ 2 hour that stirs namely gets product by the specification packing.
Claims (2)
1. humic acid liquid fertilizer, it is characterized in that: its formulation content is: humic acid 〉=8%, ferrous sulfate 1-5%, manganous sulfate 1.7-2.9%, zinc sulfate 0.9-3.1%, copper sulfate 0.8-4%, borax 5-10%, ammonium molybdate 0.4-2%, and, the trace element of iron, manganese, zinc, copper, boron, the two or more arbitrary combination of molybdenum 〉=2%.
2. the preparation method of a humic Liquid Fertilizer is characterized in that:
1) humic acid and water are mixed, shake up to make 81 kilograms of mixed solutions standby by 1:12.5;
2) with ferrous sulfate 1-5 kilogram, manganous sulfate 1.7-2.9 kilogram, zinc sulfate 0.9-3.1 kilogram, copper sulfate 0.8-4 kilogram, borax 5-10 kilogram, ammonium molybdate 0.4-2 kilogram, add in the mixed solution that step (1) makes by said ratio, make iron, manganese, zinc, copper, boron, the two or more arbitrary combination of molybdenum 〉=2 kilograms, then weigh, 100 kilograms of waters of less than are supplied, rear placement 1-2 hour that stirs namely gets product by the specification packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910119648XA CN101844952B (en) | 2009-03-24 | 2009-03-24 | Formula and production method of humic acid liquid fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910119648XA CN101844952B (en) | 2009-03-24 | 2009-03-24 | Formula and production method of humic acid liquid fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101844952A CN101844952A (en) | 2010-09-29 |
| CN101844952B true CN101844952B (en) | 2013-06-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910119648XA Expired - Fee Related CN101844952B (en) | 2009-03-24 | 2009-03-24 | Formula and production method of humic acid liquid fertilizer |
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| CN (1) | CN101844952B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111010A (en) * | 2015-07-28 | 2015-12-02 | 成都市四友化学工业有限责任公司 | Trace element-containing humic acid plant nutrient solution |
| CN105016887A (en) * | 2015-07-28 | 2015-11-04 | 成都市四友化学工业有限责任公司 | Method for preparing humic acid plant nutrient solution containing trace elements |
| CN106748175A (en) * | 2016-12-27 | 2017-05-31 | 贵州大学 | A kind of special chelating Water soluble fertilizer of carrot and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169976A (en) * | 1996-07-08 | 1998-01-14 | 中国科学院山西煤炭化学研究所 | High concentrative non-flocculant humic acids complexed nutrient liquid and preparation thereof |
| CN1424291A (en) * | 2001-12-10 | 2003-06-18 | 山东仙丰复合肥有限公司 | Humic acid fertilizer |
| CN1669990A (en) * | 2005-03-29 | 2005-09-21 | 姚力群 | Chemical fertilizer synergist and its preparation method and application |
| CN1693292A (en) * | 2005-03-31 | 2005-11-09 | 马增禄 | Liquid furtilizer containing humic acid multi nutritive element and mfg. method thereof |
| CN1765850A (en) * | 2005-08-26 | 2006-05-03 | 四川大学 | Garlic special foliar fertilizer |
-
2009
- 2009-03-24 CN CN200910119648XA patent/CN101844952B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169976A (en) * | 1996-07-08 | 1998-01-14 | 中国科学院山西煤炭化学研究所 | High concentrative non-flocculant humic acids complexed nutrient liquid and preparation thereof |
| CN1424291A (en) * | 2001-12-10 | 2003-06-18 | 山东仙丰复合肥有限公司 | Humic acid fertilizer |
| CN1669990A (en) * | 2005-03-29 | 2005-09-21 | 姚力群 | Chemical fertilizer synergist and its preparation method and application |
| CN1693292A (en) * | 2005-03-31 | 2005-11-09 | 马增禄 | Liquid furtilizer containing humic acid multi nutritive element and mfg. method thereof |
| CN1765850A (en) * | 2005-08-26 | 2006-05-03 | 四川大学 | Garlic special foliar fertilizer |
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| Publication number | Publication date |
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| CN101844952A (en) | 2010-09-29 |
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Granted publication date: 20130619 Termination date: 20200324 |