CN1664034A - Carbon fiber static-conducting coating and method for making same - Google Patents
Carbon fiber static-conducting coating and method for making same Download PDFInfo
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Abstract
The invention relates to the carbon fiber conducting static electricity paint and the preparing method, comprising: (a) graphitizing the carbon fiber and adjuvant, stirring them in organic solvent for reaction for 10-20 minutes; (b) adding adjuvant to the mixture said above and stirring in organic solvent then treating with supersonic wave for 20-40 minutes; (c)mixing the dispersed solvent with epoxide resin, treating with supersonic wave for 10-20 minutes; (d)putting the dispersed matter into the sand mill, adding pigment while stirring at low speed, then stirring at high speed for 20-40 minutes, mixing and dispersing adequately, grinding; (e) adding the firming agent into the organic solvent, stirring; (f) mixing the two matter during the process intimately, solidifying and painting. The product is characterized by the little consumption, durable antistatic effect, oil resistance, corrosion-resisting, fire-resisting property, solvent resistance and good vapor-proof property, having no pollution to oil product and the long service life.
Description
Technical field:
The present invention relates to a kind of coating and preparation method thereof, belong to a kind of carbon fiber static-conducting coating and preparation method thereof.
Background technology:
Static conductive coating is an a kind of range of application coating very widely, and static charge that can the accumulation of derived materials surface is eliminated static.In the storage and transport process of petroleum products, anti-electrostatic is a special problem deserving of attention, and static conductive coating is the effective measure of anti-electrostatic.State Bureau of Technical Supervision is as far back as the mandatory standard GB 13348-92 of in January, 1992 issue, and " reservoir walls should be used the anti-electrostatic etching ground to regulation, and the coating body resistivity is lower than 10
9Ω cm, surface resistivity is lower than 10
8Ω cm.Issue standard GB 16906-1997 " Oil Tank static conductive coating determination of resistivity method " in July, 1997 again, petroleum products storage tank anti-electrostatic anticorrosive coating is made the standard of material of paint resistivity and delivery receiving acceptance.Put into effect " ou Safe Rest Conductivity of Light Fuel Oil " national standard September calendar year 2001 again, be numbered GB6590-2001, the enforcement of series standard has effectively prevented the fire and the explosion disaster that are caused by static.
The present storage tank that uses, mainly be to be the electric static coating of conductive functional filler with metal, carbon black or metal oxide, shortcomings such as its over-all properties is unsatisfactory, and relatively poor and work-ing life is short as contaminated product, sticking power and antiseptic property can't reach the technological standard of the new promulgation of country.
It is conductive functional filler that first-generation storage does not have the static conductive coating of jar usefulness to adopt metal or graphite, metal is easily oxidized, lose easily and lead the electrostatic function, now do not use, and the add-on of graphite functive must be more than 15%-20%, though had the electrostatic of leading function, but other performance of static conductive coating has been subjected to having a strong impact on, even more serious is, because the add-on of graphite is many, oil product is easy to graphite is extracted from coating, and the graphite that is suspended in the oil product is not easily separated, will have a strong impact on the quality of oil product.Therefore, be that the static conductive coating of conducting function is not used as the storage tank static conductive coating by petroleum chemical industry suggestion with graphite.Occur the nineties in 20th century with SnO
2/ SbO
2The mica that coats is as conductive functional filler, owing to be oxide compound, it has overcome the shortcoming of the easy oxidation of metal, and self is of light color, is easy to prepare homogeneity or colour is led electrostatic coating, so development in recent years is very fast, but it is with there being the excessive problem of add-on, influenced other performance of coating, for example, its sticking power and antiseptic property just can not well satisfy the requirement of storage tank to coating.Storage tank requires also should to have functions such as good anticorrosion, antiseep when having good electrostatic conductive performance with static conductive coating, and the various static conductive coatings that use at present distinct issues in implementation process are that antistatic property is lasting inadequately, water tolerance is bad, general look black, oil resistance anticorrosion performance and static resistance can be taken into account, and lack and the filler contaminated product work-ing life of coating.
Summary of the invention:
Lasting inadequately in order to solve existing static conductive coating antistatic property, water tolerance is bad, general look black, oil resistance anticorrosion performance and static resistance can be taken into account, work-ing life of coating short and filler contaminated product problem, the invention provides a kind of carbon fiber static-conducting coating and preparation method thereof, it is few that the product of this method preparation has a consumption, the lasting oil-proofness of antistatic property, erosion resistance, thermotolerance, solvent resistance and resistance steam boiling water excellent property, pollution-free to oil product, long service life.
The technical solution adopted in the present invention is: carbon fiber static-conducting coating of the present invention this coating by weight percentage is composed of the following components:
Resins, epoxy 20-40 part
Carbon fiber 0.2-2 part
Color stuffing 20-40 part
Auxiliary agent 0.5-10 part
Organic solvent 5-20 part
Solidifying agent 10-50 part
Above-mentioned said carbon fiber static-conducting coating Resins, epoxy is selected from least a among Resins, epoxy E-20, epoxy resin E-44 or the Resins, epoxy E-12; Color stuffing is selected from least a in iron oxide red, zinc phosphate, titanium dioxide, zinc oxide, talcum powder or the barium sulfate; Auxiliary agent is selected from polyacrylic ester, modified polyurethane, silane coupling agent, titanate coupling agent, at least a in Span, Tween, OP or the hexadecyl amine bromide; Organic solvent is selected from least a in dimethylbenzene, propyl carbinol or the pimelinketone; Solidifying agent is selected from least a among TY650, SUNMIDE390, SUNMIDE305, NX-2040, NX-2003, NX-2007 or the NX-2015; The average caliber of carbon fiber is 0.5nm-500nm, and length is 200nm-40 μ m.
The method for preparing carbon fiber static-conducting coating comprises by following steps to be formed:
(a) being 0.5-500 through graphited caliber, length is under the carbon fiber of 200-40 and the state that auxiliary agent stirs in organic solvent, hybrid reaction 10-20 minute;
(b) with after a certain amount of auxiliary agent of adding stirs in the above-mentioned mixture that mixes, use ultrasonication 20-40 minute again in certain amount of organic solvent;
(c) above-mentioned finely dispersed solution and a certain amount of Resins, epoxy are mixed, use ultrasonication 10-20 minute again;
(d) with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add color stuffing, high-speed stirring 20-40 minute, blending dispersion was even, was ground to the regulation fineness through sand mill and got final product;
(e) solidifying agent is dissolved in the certain amount of organic solvent stirs;
(f) when construction,, after fully solidifying, carry out application with above-mentioned two groups of material uniform mixing.
The invention has the beneficial effects as follows: have the nano material of special effects because this static conductive coating adopts---carbon fiber is as leading the static body, by it is carried out suitable surface treatment, make it can adapt to the protective system system, thereby it is few to prepare consumption, the lasting oil-proofness of antistatic property, erosion resistance, thermotolerance, solvent resistance and resistance steam boiling water excellent property, pollution-free to oil product, the product of long service life.
Embodiment:
The several embodiment of various details, but content of the present invention is not limited to this fully.
Embodiment 1:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.4 gram of 200-40,0.4 gram silane coupling agent TM-10 and 2.5 gram dimethylbenzene, n-butanol mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.4 gram dispersion agent EKFA4010,0.4 gram dispersion agent DP9100 and 2.5 gram dimethylbenzene, n-butanol mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.2 gram EFKA4009,0.2 gram EFKA2022,7 gram Resins, epoxy E-20 mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 1.6 gram titanium dioxides successively, 2.8 gram talcum powder, 1.6 the color stuffing high-speed stirring of gram barium sulfate 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 2.5 gram solidifying agent TY650 with 1 gram dimethylbenzene, n-butanol mixed solvent dilution, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.8 hours is done solid work 20 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Embodiment 2:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.4 gram of 200-40,0.4 gram silane coupling agent TM-10 and 2.5 gram dimethylbenzene, propyl carbinol, the pimelinketone mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.4 gram dispersion agent EKFA4010,0.4 gram dispersion agent DP9100 and 2.5 gram dimethylbenzene, propyl carbinol pimelinketone mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.2 gram EFKA4009,0.2 gram EFKA2022,7 gram epoxy resin E-44s mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 1.7 gram iron oxide red powder successively, 1.8 gram zinc phosphate, 2.5 restrain talcous color stuffing high-speed stirring 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 8.5 gram solidifying agent SUNMIDE390 with 1 gram dimethylbenzene, propyl carbinol, the dilution of pimelinketone mixed solvent, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.9 hours is done solid work 18 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Embodiment 3:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.4 gram of 200-40,0.4 gram silane coupling agent KH-560 and 2.5 gram dimethylbenzene, n-butanol mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.4 gram dispersion agent EKFA4010,0.4 gram dispersion agent DP9100 and 2.5 gram dimethylbenzene, n-butanol mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.2 gram EFKA4009,0.2 gram EFKA2022,7 gram Resins, epoxy E-20 mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 1.6 gram titanium dioxides successively, 2.8 gram talcum powder, 1.6 the color stuffing high-speed stirring of gram barium sulfate 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 2.5 gram solidifying agent TY650 with 1 gram dimethylbenzene, n-butanol mixed solvent dilution, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.9 hours is done solid work 19 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Embodiment 4:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.4 gram of 200-40,0.4 gram silane coupling agent KH560 and 2.5 gram dimethylbenzene, propyl carbinol, the pimelinketone mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.4 gram dispersion agent EKFA4010,0.4 gram dispersion agent DP9100 and 2.5 gram dimethylbenzene, propyl carbinol, the pimelinketone mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.2 gram EFKA4009,0.2 gram EFKA2022,7 gram epoxy resin E-44s mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 1.7 gram iron oxide red powder successively, 1.8 gram zinc phosphate, 2.5 restrain talcous color stuffing high-speed stirring 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 8.5 gram solidifying agent SUNMIDE390 with 1 gram dimethylbenzene, n-butanol mixed solvent dilution, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.9 hours is done solid work 18 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Embodiment 5:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.2 gram of 200-40,0.2 gram silane coupling agent TM-10 and 1.5 gram dimethylbenzene, n-butanol mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.2 gram dispersion agent EKFA4010,0.2 gram dispersion agent DP9100 and 3.5 gram dimethylbenzene, n-butanol mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.1 gram EFKA4009,0.1 gram EFKA2022,7 gram Resins, epoxy E-20 mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 1.8 gram titanium dioxides successively, 3.4 gram talcum powder, 1.8 the color stuffing high-speed stirring of gram barium sulfate 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 2.5 gram solidifying agent TY650 with 1 gram dimethylbenzene, n-butanol mixed solvent dilution, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.7 hours is done solid work 18 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Embodiment 6:
Being 0.5-500 through graphited caliber, length is carbon fiber 0.2 gram of 200-40,0.2 gram silane coupling agent KH-560 and 1.5 gram dimethylbenzene, propyl carbinol, the pimelinketone mixed solvent is under whipped state, hybrid reaction 20 minutes, add 0.2 gram dispersion agent EKFA4010,0.2 gram dispersion agent DP9100 and 3.5 gram dimethylbenzene, propyl carbinol, the pimelinketone mixed solvent, after stirring, with ultrasonication 30 minutes, add 0.1 gram EFKA4009,0.1 gram EFKA2022,7 gram epoxy resin E-44s mix, used ultrasonication again 20 minutes, with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add 2.0 gram iron oxide red powder successively, 2.0 gram zinc phosphate, 3.0 restrain talcous color stuffing high-speed stirring 30 minutes, blending dispersion is even, be ground to the regulation fineness through sand mill, promptly make a kind of component 20 grams of coating; 8.5 gram solidifying agent SUNMIDE390 with 1 gram dimethylbenzene, n-butanol mixed solvent dilution, after stirring, are promptly made another component of coating; With two component uniform mixing, after fully solidifying, carry out application.The static conductive coating electrical conductor consumption that forms according to above-mentioned technology is few, oil-proofness, and the excellent performance of erosion resistance, solvent resistance, pollution-free to oil product, surface drying time 1.9 hours is done solid work 18 hours time, surface resistivity＜10
8W, snappiness≤1mm, strong adhesion, shock strength 〉=50Kgcm.
Claims (8)
1, a kind of carbon fiber static-conducting coating is characterized in that: this coating is composed of the following components by weight percentage:
Resins, epoxy 20-40 part
Carbon fiber 0.2-2 part
Color stuffing 20-40 part
Auxiliary agent 0.5-10 part
Organic solvent 5-20 part
Solidifying agent 10-50 part
2, a kind of carbon fiber static-conducting coating according to claim 1 is characterized in that: Resins, epoxy is selected from least a among Resins, epoxy E-20, epoxy resin E-44 or the Resins, epoxy E-12.
3, a kind of carbon fiber static-conducting coating according to claim 1 is characterized in that: color stuffing is selected from least a in iron oxide red, zinc phosphate, titanium dioxide, zinc oxide, zinc sulfide white, talcum powder or the barium sulfate.
4, a kind of carbon fiber static-conducting coating according to claim 1, it is characterized in that: auxiliary agent is selected from polyacrylic ester, modified polyurethane, silane coupling agent, titanate coupling agent, at least a in Span, Tween, OP or the hexadecyl amine bromide.
5, a kind of carbon fiber static-conducting coating according to claim 1 is characterized in that: organic solvent is selected from least a in dimethylbenzene, propyl carbinol or the pimelinketone.
6, a kind of carbon fiber static-conducting coating according to claim 1 is characterized in that: solidifying agent is selected from least a among TY650, SUNMIDE390, SUNMIDE305, NX-2040, NX-2003, NX-2007 or the NX-2015.
7, a kind of carbon fiber static-conducting coating according to claim 1 is characterized in that: the average caliber of carbon fiber is 0.5nm-500nm, and length is 200nm-40 μ m.
8, the preparation method of the described carbon fiber static-conducting coating of a kind of claim 1 is characterized in that: this method comprises by following steps to be formed:
(a) being 0.5nm-500nm through graphited caliber, length is under the carbon fiber of 200nm-40 μ m and the state that auxiliary agent stirs in organic solvent, hybrid reaction 10-20 minute;
(b) with after a certain amount of auxiliary agent of adding stirs in the above-mentioned mixture that mixes, use ultrasonication 20-40 minute again in certain amount of organic solvent;
(c) above-mentioned finely dispersed solution and a certain amount of Resins, epoxy are mixed, use ultrasonication 10-20 minute again;
(d) with the uniform material of above-mentioned blending dispersion, join in the sand mill, under the stirring at low speed state, add color stuffing, high-speed stirring 20-40 minute, blending dispersion was even, was ground to the regulation fineness through sand mill and got final product;
(e) solidifying agent is dissolved in the certain amount of organic solvent stirs;
(f) when construction,, after fully solidifying, carry out application with above-mentioned two groups of material uniform mixing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510009767 CN1286931C (en) | 2005-02-22 | 2005-02-22 | Carbon fiber static-conducting coating and method for making same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510009767 CN1286931C (en) | 2005-02-22 | 2005-02-22 | Carbon fiber static-conducting coating and method for making same |
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| CN1664034A true CN1664034A (en) | 2005-09-07 |
| CN1286931C CN1286931C (en) | 2006-11-29 |
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| CN 200510009767 Expired - Fee Related CN1286931C (en) | 2005-02-22 | 2005-02-22 | Carbon fiber static-conducting coating and method for making same |
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| CN101379161B (en) * | 2006-02-01 | 2013-04-17 | 徐光锡 | Basic solution washable antistatic composition and polymer products manufactured by using the same |
| CN103265880A (en) * | 2013-05-30 | 2013-08-28 | 苏州艾特斯环保材料有限公司 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
| CN104449212A (en) * | 2014-11-13 | 2015-03-25 | 无锡信大气象传感网科技有限公司 | Conductive anticorrosion chip |
| CN105153877A (en) * | 2015-09-30 | 2015-12-16 | 国网山东省电力公司临沂供电公司 | Anticorrosive coating for grounding down conductor |
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- 2005-02-22 CN CN 200510009767 patent/CN1286931C/en not_active Expired - Fee Related
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| CN102952438A (en) * | 2012-11-13 | 2013-03-06 | 西安交通大学 | Carbon fiber grounding grid anti-corrosive paint and preparation and application methods thereof |
| CN102952438B (en) * | 2012-11-13 | 2014-12-10 | 西安交通大学 | Carbon fiber grounding grid anti-corrosive paint and preparation and application methods thereof |
| CN103265880A (en) * | 2013-05-30 | 2013-08-28 | 苏州艾特斯环保材料有限公司 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
| CN103265880B (en) * | 2013-05-30 | 2015-05-13 | 苏州艾特斯环保材料有限公司 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
| CN104449212A (en) * | 2014-11-13 | 2015-03-25 | 无锡信大气象传感网科技有限公司 | Conductive anticorrosion chip |
| CN105153877A (en) * | 2015-09-30 | 2015-12-16 | 国网山东省电力公司临沂供电公司 | Anticorrosive coating for grounding down conductor |
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| CN105348991A (en) * | 2015-12-03 | 2016-02-24 | 梅庆波 | Preparation method of anti-static corrosion and rust prevention coating |
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| CN107310877A (en) * | 2017-07-08 | 2017-11-03 | 深圳市深通石化工程设备有限公司 | Do not excavate with high polymer material two-compartment oil tank and oil tank remodeling method a kind of tank field |
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