CN103265880A - High temperature anticorrosive paint comprising cycloaliphatic epoxy resin - Google Patents
High temperature anticorrosive paint comprising cycloaliphatic epoxy resin Download PDFInfo
- Publication number
- CN103265880A CN103265880A CN201310209060XA CN201310209060A CN103265880A CN 103265880 A CN103265880 A CN 103265880A CN 201310209060X A CN201310209060X A CN 201310209060XA CN 201310209060 A CN201310209060 A CN 201310209060A CN 103265880 A CN103265880 A CN 103265880A
- Authority
- CN
- China
- Prior art keywords
- parts
- epoxy resin
- cycloaliphatic epoxy
- high temperature
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 title claims abstract description 25
- 239000003973 paint Substances 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 phenolic aldehyde Chemical class 0.000 claims abstract description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000009970 fire resistant effect Effects 0.000 claims description 14
- 229920002050 silicone resin Polymers 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000031709 bromination Effects 0.000 abstract 1
- 238000005893 bromination reaction Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 22
- 238000000576 coating method Methods 0.000 description 22
- 238000005260 corrosion Methods 0.000 description 11
- 238000005336 cracking Methods 0.000 description 9
- 238000005187 foaming Methods 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
Abstract
The invention relates to a high temperature anticorrosive paint comprising cycloaliphatic epoxy resin. The high temperature anticorrosive paint is characterized by comprising the following components according to weight ratio: 20-25 parts of cycloaliphatic epoxy resin, 20-25 parts of bromination resin, 30-40 parts of phenolic aldehyde modified organic silicon resin, 5-10 parts of zinc powder, 5-10 parts of kaolin, and 5-10 parts of cyclohexanone. The prepared high temperature anticorrosive paint comprising cycloaliphatic epoxy resin can resist temperature of 500-600 DEG C, and has a good anticorrosion effect.
Description
Technical field
The present invention relates to a kind of fire-resistant anticorrosion paint, particularly relate to the fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin.
Background technology
In rapid economic development, enterprise relates to the corrosion of metal phenomenon and more and more receives publicity, owing to be in bad working environment for a long time, therefore corrosion of metal cannot be avoided, especially in the middle of some also relate to the Working environment of high temperature, people are not only high temperature resistant but also demand can rot-resistant coating is growing to having.In recent years, along with development of science and technology, requirement to fire-resistant anticorrosion paint is more and more higher, but conventional high-temperature resistant coating tolerable temperature is lower, what have has only about 200 ℃, preservative effect is also relatively poor simultaneously, and therefore, developing a kind of coating with good preservative effect with anti-comparatively high temps becomes a kind of inevitable.
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Summary of the invention
The technical problem to be solved in the present invention: conventional coating does not have high temperature resistant and corrosion resistant problem simultaneously.
Technical scheme of the present invention is: a kind of fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin, it is characterized in that being formed according to weight ratio by following composition: 20 ~ 25 parts of cycloaliphatic epoxy resins, 20 ~ 25 parts of brominated resins, 30 ~ 40 parts of phenol aldehyde modified silicone resins, 5 ~ 10 parts of zinc powders, 5 ~ 10 parts of kaolin, 5 ~ 10 parts of pimelinketone.
Beneficial effect of the present invention: above-mentioned coating evenly is sprayed on stainless steel surface, treats to carry out thermotolerance and anti-corrosion test behind the finish-drying.The thermal test temperature is 500 ~ 600 ℃, and the time is 40h.Anti-corrosion test selects for use 3wt%NaCL solution to carry out salt-fog resistant test under 30 ℃, and the time is 120 days.The fire-resistant anticorrosion paint that contains polyimide modified silicone resin can reach 500 ~ 600 ℃ by tolerable temperature, has good preservative effect simultaneously.
Embodiment
Embodiment 1
Get cycloaliphatic epoxy resin 20kg, drop in the reactor, add brominated resins 20kg again, add phenol aldehyde modified silicone resin 30kg, add zinc powder 5kg, kaolin 5kg, pimelinketone 5kg stirs, and can contain the fire-resistant anticorrosion paint of cycloaliphatic epoxy resin.Above-mentioned coating evenly is sprayed on stainless steel surface, treats to carry out thermotolerance and anti-corrosion test behind the finish-drying.The thermal test temperature is 500 ℃, time 40h.Temperature is under 500 ℃, and coating of the present invention does not have cracking foaming phenomenon in the 40h, and the coating that namely contains cycloaliphatic epoxy resin has good thermotolerance.Anti-corrosion test selects for use 3wt%NaCL solution to carry out salt-fog resistant test under 30 ℃, and the time is 120 days.Coating did not have the foaming cracking phenomena in 115 days, surpassing had the foaming phenomenon after 115 days, and coating has advantages of good anticorrosion performance.
Embodiment 2
Get cycloaliphatic epoxy resin 25kg, drop in the reactor, add brominated resins 25kg again, add phenol aldehyde modified silicone resin 40kg, add zinc powder 10kg, kaolin 10kg, pimelinketone 10kg stirs, and can contain the fire-resistant anticorrosion paint of cycloaliphatic epoxy resin.Above-mentioned coating evenly is sprayed on stainless steel surface, treats to carry out thermotolerance and anti-corrosion test behind the finish-drying.The thermal test temperature is 600 ℃, time 40h.Temperature is under 600 ℃, and coating of the present invention does not have cracking foaming phenomenon in the 35h, and above behind the 35h, coating has cracking phenomena to take place.The coating that namely contains cycloaliphatic epoxy resin has good thermotolerance.Anti-corrosion test selects for use 3wt%NaCL solution to carry out salt-fog resistant test under 30 ℃, and the time is 120 days.Coating did not have the foaming cracking phenomena in 111 days, surpassing had cracking phenomena after 111 days, and coating has advantages of good anticorrosion performance.
Embodiment 3
Get cycloaliphatic epoxy resin 25kg, drop in the reactor, add brominated resins 20kg again, add phenol aldehyde modified silicone resin 30kg, add zinc powder 5kg, kaolin 10kg, pimelinketone 5kg stirs, and can contain the fire-resistant anticorrosion paint of cycloaliphatic epoxy resin.Above-mentioned coating evenly is sprayed on stainless steel surface, treats to carry out thermotolerance and anti-corrosion test behind the finish-drying.The thermal test temperature is 600 ℃, time 40h.Temperature is under 600 ℃, and coating of the present invention does not have cracking foaming phenomenon in the 35h, and above behind the 35h, coating has cracking phenomena.The coating that namely contains cycloaliphatic epoxy resin has good thermotolerance.Anti-corrosion test selects for use 3wt%NaCL solution to carry out salt-fog resistant test under 30 ℃, and the time is 120 days.Coating did not have the foaming cracking phenomena in 119 days, surpass after 119 days, and the foaming phenomenon is arranged, and coating has advantages of good anticorrosion performance.
Claims (5)
1. a fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin is characterized in that being made up of according to weight ratio following composition: 20 ~ 25 parts of cycloaliphatic epoxy resins, 20 ~ 25 parts of brominated resins, 30 ~ 40 parts of phenol aldehyde modified silicone resins, 5 ~ 10 parts of zinc powders, 5 ~ 10 parts of kaolin, 5 ~ 10 parts of pimelinketone.
2. a kind of fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin described in claim 1 is characterized in that cycloaliphatic epoxy resin is 20 parts in the coating composition, and brominated resins is 25 parts.
3. a kind of fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin described in claim 1 is characterized in that cycloaliphatic epoxy resin is 25 parts in the coating composition, and brominated resins is 20 parts.
4. a kind of fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin described in claim 1 is characterized in that phenol aldehyde modified silicone resin is 30 parts in the coating composition.
5. a kind of fire-resistant anticorrosion paint that comprises cycloaliphatic epoxy resin described in claim 1 is characterized in that kaolin is 5 parts in the coating composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310209060.XA CN103265880B (en) | 2013-05-30 | 2013-05-30 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310209060.XA CN103265880B (en) | 2013-05-30 | 2013-05-30 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103265880A true CN103265880A (en) | 2013-08-28 |
| CN103265880B CN103265880B (en) | 2015-05-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310209060.XA Active CN103265880B (en) | 2013-05-30 | 2013-05-30 | High temperature anticorrosive paint comprising cycloaliphatic epoxy resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103265880B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670354A (en) * | 2014-11-19 | 2016-06-15 | 无锡市德林环保工程有限公司 | Anti-corrosive paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| CN1664034A (en) * | 2005-02-22 | 2005-09-07 | 大庆石油管理局 | Carbon fiber static-conducting coating and method for making same |
| CN1986711A (en) * | 2006-12-12 | 2007-06-27 | 溧阳市溧竹环境工程有限公司 | Acid-proof wear-proof anticorrosive paint and its preparing method |
| KR20080093786A (en) * | 2007-04-18 | 2008-10-22 | 현대모비스 주식회사 | Corrosion-resistant coating composition for metal part automobile |
-
2013
- 2013-05-30 CN CN201310209060.XA patent/CN103265880B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| CN1664034A (en) * | 2005-02-22 | 2005-09-07 | 大庆石油管理局 | Carbon fiber static-conducting coating and method for making same |
| CN1986711A (en) * | 2006-12-12 | 2007-06-27 | 溧阳市溧竹环境工程有限公司 | Acid-proof wear-proof anticorrosive paint and its preparing method |
| KR20080093786A (en) * | 2007-04-18 | 2008-10-22 | 현대모비스 주식회사 | Corrosion-resistant coating composition for metal part automobile |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670354A (en) * | 2014-11-19 | 2016-06-15 | 无锡市德林环保工程有限公司 | Anti-corrosive paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103265880B (en) | 2015-05-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 215211 No. 1397, Xinli Avenue, FenHu high tech Industrial Development Zone, Wujiang District, Suzhou, Jiangsu Patentee after: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. Address before: 215211 Suzhou, Jiangsu FenHu hi tech Development Zone, Santa tower, No. 551 West South Road. Patentee before: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190809 Address after: 215000 North of Fenyue East Road, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: SUZHOU AITESI ENVIRONMENTAL PROTECTION EQUIPMENT Co.,Ltd. Address before: 215211 No. 1397 Xinta Kangli Avenue, Fenhu High-tech Industrial Development Zone, Wujiang District, Suzhou City, Jiangsu Province Patentee before: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high-temperature and anti-corrosion coating containing alicyclic epoxy resin Granted publication date: 20150513 Pledgee: Bank of Jiangsu Co.,Ltd. Suzhou Branch Pledgor: SUZHOU AITESI ENVIRONMENTAL PROTECTION EQUIPMENT Co.,Ltd. Registration number: Y2024980012011 |