CN115322647A - Antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint and preparation method thereof - Google Patents
Antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint and preparation method thereof Download PDFInfo
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- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 48
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 48
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000000843 powder Substances 0.000 title claims abstract description 35
- 239000004593 Epoxy Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 19
- 239000003973 paint Substances 0.000 title claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- 239000006258 conductive agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- -1 polysiloxane Polymers 0.000 claims abstract description 9
- 238000005087 graphitization Methods 0.000 claims abstract description 8
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- 229920000098 polyolefin Polymers 0.000 claims abstract description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- 238000010902 jet-milling Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical group 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229910021389 graphene Inorganic materials 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 description 12
- 238000004659 sterilization and disinfection Methods 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 5
- 239000011231 conductive filler Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of coatings, in particular to an antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint and a preparation method thereof, wherein the preparation method comprises the following steps: 1) Preparing carbon fiber micro powder with high graphitization rate; 2) Adding a conductive agent into the epoxy resin, and stirring and dispersing at a high speed; 3) And after the mixture is uniformly dispersed, sequentially adding a flatting agent, a polyolefin wax rheological agent, a polysiloxane solvent antifoaming agent, an antibacterial agent and a halogen-free phosphorus-nitrogen flame retardant, uniformly stirring, adding a color filler, and stirring and dispersing at a high speed to obtain the antistatic epoxy floor coating. The antistatic epoxy floor coating has the advantages of good permanent conductivity, antistatic property, wear resistance, solvent resistance, antibacterial property, flame retardance and the like, has no solvent, is easy to color, does not contain heavy metal, meets the environmental protection requirement, and meanwhile, has the advantages of simple preparation method, low cost and strong applicability, and can be used for large-scale production.
Description
Technical Field
The invention relates to the field of coatings, in particular to an epoxy floor coating and a preparation method thereof.
Background
The ground level is easy to accumulate a large amount of static charges due to frequent friction, thereby hindering the production process and influencing the product quality, and in severe cases, accidents such as fire, explosion and the like are caused. The antistatic terrace coating can endow the terrace with conductivity to eliminate the harm of static electricity, so that the antistatic terrace coating is widely applied to the high and new technical fields of electronics, microelectronics, communication, precision instruments, computers, aerospace, military and the like in recent years.
Along with the stricter trend of environmental protection regulations, the solvent-free antistatic self-leveling epoxy floor coating becomes a main product antistatic floor coating of the antistatic floor coating due to the advantages of attractive appearance, good comprehensive performance and the like, belongs to a functional coating, conductive fillers are added into the coating, and a conductive network is generated by the contact of the conductive fillers to form a continuous conductive network or approach to each other, and electrons cross a potential barrier due to a tunnel effect to form an electron circulation network. The conductive filler is usually conductive carbon fiber, metal filler, graphite powder, conductive mica, etc. and needs a sufficient filling amount to form a conductive chain. However, the dispersion is difficult due to the excessive filling amount, the self-leveling thick coating is settled, even the conductive filler is not uniformly distributed, and the appearance of the coating surface layer is damaged. And the surface of the epoxy floor paint produced at present is easy to generate mould, is inflammable and has other defects.
Therefore, developing a brand new antibacterial, flame retardant and antistatic epoxy floor paint is one of the technical problems to be solved urgently in the field.
Disclosure of Invention
The invention aims to provide the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro powder type epoxy floor paint which is simple in preparation process, controllable, low in cost and suitable for large-scale production and the preparation method.
In order to achieve the purpose, the invention provides the following technical scheme:
a preparation method of an antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint comprises the following steps:
(1) Preparing the carbon fiber micro powder with high graphitization rate: taking back the collected carbon fibers or the chopped carbon fibers, adding a ferrous sulfate solution, slowly adding hydrogen peroxide, reacting for a period of time, and carrying out suction filtration and drying to obtain the carbon fibers with high graphitization rate; finally, crushing the high-graphitization-rate carbon fibers into carbon fiber micro-powder with different particle sizes by a jet milling method, thereby preparing the high-graphitization-rate carbon fiber micro-powder;
(2) Adding a conductive agent into the epoxy resin, and stirring and dispersing at a high speed;
(3) And after the mixture is uniformly dispersed, sequentially adding a flatting agent, a polyolefin wax rheological agent, a polysiloxane solvent antifoaming agent, an antibacterial agent and a halogen-free phosphorus-nitrogen flame retardant, uniformly stirring, adding a color filler, and stirring and dispersing at a high speed to obtain the antistatic epoxy floor coating.
Wherein the mass fraction of the ferrous sulfate solution in the step (1) is 8-30%.
Wherein the mass fraction of the hydrogen peroxide solution in the step (1) is 3-15%.
Wherein the reaction time in the step (1) is 1-5h.
Wherein, the conductive agent in the step (2) is one or a composition of the high-graphitization-rate carbon fiber micro powder, the common carbon fiber micro powder, the carbon nano tube and the graphene prepared in the step (1), and the addition part of the conductive agent in each 100 parts of the epoxy resin is 0.3-2 parts.
Wherein, the leveling agent in the step (3) is one or a composition of acrylates, fluorocarbon modified polyacrylates and modified organic siloxane, and the addition part is 0.3-1 part.
Wherein the addition part of the polysiloxane solvent antifoaming agent in the step (3) is 0.4-1 part.
Wherein, the antibacterial agent in the step (3) is one or a composition of quaternary ammonium salts, silver ions and acylaniline, and the adding part is 0.1-0.5 part.
Wherein the addition part of the halogen-free phosphorus-nitrogen flame retardant in the step (3) is 4-10 parts.
Compared with the prior art, the invention has the beneficial effects that:
the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint has the advantages of better permanent conductivity and antistatic property, better coloring performance, wear resistance, solvent resistance, antibacterial property, flame retardance and the like, has the advantages of no solvent or heavy metal, meets the environmental protection requirement, and meanwhile, is simple in preparation method, low in cost and strong in applicability, and can be used for large-scale production.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
(1) Preparing carbon fiber micro powder with high graphitization rate: adding 100g of recovered carbon fibers or chopped carbon fibers into 150ml of 10% ferrous sulfate solution, slowly adding 50ml of 10% hydrogen peroxide, reacting for 3 hours, carrying out suction filtration and drying to obtain high-graphitization-rate carbon fibers, and finally crushing the high-graphitization-rate carbon fibers into carbon fiber micro-powder with different particle sizes by using a jet milling method to obtain the high-graphitization-rate carbon fiber micro-powder.
(2) 0.5 part of carbon fiber micro powder with high graphitization rate is added into 100 parts of epoxy resin and stirred and dispersed for 30min at the speed of 1200 r/min.
(3) After the mixture is uniformly dispersed, 0.5 part of flatting agent (fluorocarbon modified polyacrylate), 0.2 part of polyolefin wax rheological agent, 0.6 part of polysiloxane solvent defoaming agent, 0.1 part of antibacterial agent (quaternary ammonium salt), 6 parts of halogen-free phosphorus-nitrogen flame retardant and other auxiliary agents are sequentially added, after uniform stirring, other auxiliary agents such as color filler and the like are added, and the mixture is stirred and dispersed for 30min at the speed of 1200r/min, so that the antistatic epoxy floor coating is prepared.
After being cured, the surface of the material is flat and smooth, has no phenomena of flooding, no bubbles and the like, and has the surface resistance of 5 multiplied by 10 4 Omega, flame retardant grade V0, and sterilization rate not less than 90%.
Example 2
The difference between this example and example 1 is that the part of the conductive agent high graphitization ratio carbon fiber fine powder in step (2) is 1 part, and the other treatment means are the same as those in example 1.
The prepared product has flat and smooth surface, no flooding, no bubble and other phenomena after being cured, and the surface resistance of the product is 3.4 multiplied by 10 4 Omega, flame retardant grade V0, and sterilization rate not less than 90%.
Example 3
The present example differs from example 1 in that: in the step (2), the part of the conductive agent high-graphitization-rate carbon fiber micro powder is 0.3, and other treatment means are the same as those in the embodiment 1.
The product has smooth surface, no color floating, no bubble, and surface resistance of 2.6 × 10 5 Omega, flame retardant grade V0, and sterilization rate not less than 90%.
Example 3
This example differs from example 1 in that: the conductive agent in the step (2) is common carbon fiber micro powder, and other processing means are the same as those in the embodiment 1.
After the product is cured, the surface is flat and smooth, no flooding color, no bubble and other phenomena exist, the surface resistance is 9.6 multiplied by 107 omega, the flame retardant grade is V0, and the sterilization rate is not lower than 90 percent.
Example 4
The present example differs from example 1 in that: the conductive agent in step (2) is carbon nanotubes, and other treatment methods are the same as those in example 1.
The product has smooth surface, no floating color, no bubble, and surface resistance of 1 × 10 5 Omega, flame retardant grade V0, sterilization rate not less than 90％。
Example 5
The present example differs from example 1 in that: the leveling agent in the step (3) is acrylate, and other treatment means are the same as those in the example 1.
The product has smooth surface, no floating color, no bubble, and surface resistance of 5.9 × 10 4 Omega, flame retardant grade V0, and sterilization rate not less than 90%.
Example 6
This example differs from example 1 in that: the antibacterial agent in the step (3) is silver ions, and other treatment means are the same as those in the example 1.
The product has smooth surface, no color floating, no bubble, and surface resistance of 5.9 × 10 4 Omega, flame retardant grade V0, and sterilization rate not less than 85%.
Example 7
The present example differs from example 1 in that: the addition part of the halogen-free phosphorus-nitrogen flame retardant in the step (3) is 4. The other treatment methods were the same as in example 1.
The product has smooth surface, no floating color, no bubble, and surface resistance of 5.9 × 10 4 Omega, flame retardant grade V1, and sterilization rate not less than 85%.
To highlight the advantageous effects of the present invention, the following comparative example experiments are exemplified.
Comparative example 1
The present example differs from example 1 in that: the step (2) was carried out without adding a conductive agent, and the other treatment methods were the same as those in example 1.
The prepared product has flat and smooth surface, no flooding, no bubbles and other phenomena after being cured, and the surface resistance of the product is 1 multiplied by 10 14 Omega, flame retardant grade V0, and the sterilization rate is not less than 90 percent.
Comparative example 2
This example differs from example 1 in that: no flame retardant was added in step (3), and the other treatment methods were the same as in example 1.
The obtained product has flat and smooth surface and no defects after being curedFloating color, no bubbles, etc., and surface resistance of 5.6 × 10 4 Omega, flame retardant grade V2, and the sterilization rate is not less than 90 percent.
Comparative example 3
This example differs from example 1 in that: in step (3), no antimicrobial agent was added, and the other treatment methods were the same as those in example 1.
The prepared product has flat and smooth surface, no flooding, no bubble and other phenomena after being cured, and the surface resistance of the product is 6.6 multiplied by 10 4 Omega, flame retardant grade V0, and the sterilization rate is less than 5%.
Comparative example 4
This example differs from example 1 in that: in the step (2), the part of the conductive agent high-graphitization-rate carbon fiber micro powder is 10 parts, and other treatment means are the same as those in the embodiment 1.
The prepared product has flat and smooth surface, no flooding, no bubble and other phenomena after being cured, and the surface resistance of the product is 2 multiplied by 10 3 Omega, flame retardant grade V0, and the sterilization rate is not less than 90 percent.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint is characterized by comprising the following steps of:
(1) Preparing the carbon fiber micro powder with high graphitization rate: taking back the collected carbon fibers or the chopped carbon fibers, adding a ferrous sulfate solution, slowly adding hydrogen peroxide, reacting for a period of time, and performing suction filtration and drying to obtain the carbon fibers with high graphitization rate; finally, crushing the high-graphitization-rate carbon fibers into carbon fiber micro-powder with different particle sizes by using a jet milling method, thereby preparing the high-graphitization-rate carbon fiber micro-powder;
(2) Adding a conductive agent into the epoxy resin, and stirring and dispersing at a high speed;
(3) After the mixture is uniformly dispersed, sequentially adding a flatting agent, a polyolefin wax rheological agent, a polysiloxane solvent defoamer, an antibacterial agent and a halogen-free phosphorus-nitrogen flame retardant, stirring uniformly, adding a color filler, and stirring at a high speed for dispersion to obtain the antistatic epoxy floor coating.
2. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the mass fraction of the ferrous sulfate solution in the step (1) is 8-30%.
3. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the mass fraction of the hydrogen peroxide solution in the step (1) is 3-15%.
4. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the reaction time in the step (1) is 1-5h.
5. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the conductive agent in the step (2) is one or a composition of the high-graphitization-rate carbon fiber micro powder prepared in the step (1), common carbon fiber micro powder, carbon nano tubes and graphene, and the addition amount of the conductive agent in each 100 parts of epoxy resin is 0.3-2 parts.
6. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the leveling agent in the step (3) is one or a composition of acrylates, fluorocarbon modified polyacrylates and modified organic siloxane, and the addition part of the leveling agent is 0.3-1 part.
7. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1, which is characterized by comprising the following steps of: in the step (3), the addition part of the polysiloxane solvent defoaming agent is 0.4-1 part.
8. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: the antibacterial agent in the step (3) is one or a composition of quaternary ammonium salts, silver ions and acylaniline, and the adding part is 0.1-0.5 part.
9. The preparation method of the antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint according to claim 1 is characterized by comprising the following steps of: 4-10 parts of halogen-free phosphorus-nitrogen flame retardant in the step (3).
10. The antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint prepared by the preparation method of any one of claims 1-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210794573.0A CN115322647A (en) | 2022-07-05 | 2022-07-05 | Antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210794573.0A CN115322647A (en) | 2022-07-05 | 2022-07-05 | Antibacterial flame-retardant antistatic high-graphitization-rate carbon fiber micro-powder type epoxy floor paint and preparation method thereof |
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| CN115322647A true CN115322647A (en) | 2022-11-11 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1664034A (en) * | 2005-02-22 | 2005-09-07 | 大庆石油管理局 | Carbon fiber static-conducting coating and method for making same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1664034A (en) * | 2005-02-22 | 2005-09-07 | 大庆石油管理局 | Carbon fiber static-conducting coating and method for making same |
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