CN1651181A - Solid welding wire for lifting welding joint fatigne performance - Google Patents
Solid welding wire for lifting welding joint fatigne performance Download PDFInfo
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- CN1651181A CN1651181A CN 200510013183 CN200510013183A CN1651181A CN 1651181 A CN1651181 A CN 1651181A CN 200510013183 CN200510013183 CN 200510013183 CN 200510013183 A CN200510013183 A CN 200510013183A CN 1651181 A CN1651181 A CN 1651181A
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Abstract
A solid welding wire for improving the fatigue performance of welded joint contains proportionally C, Mn, Cr, Ni, Mo, Nb, Ti, Si and Fe. Its solid phase-change temp range is 100-350 deg.C.
Description
Technical field
The present invention relates to a kind of solid core welding wire, relate in particular to a kind of solid core welding wire of high fatigue property.
Technical background
Compare with other interconnection technique, welding is topmost method of attachment in engineering is produced, and has weldedly accounted for more than 50% of iron and steel total output with steel weight, and this ratio of industrially developed country is near 70%.Yet fracture accident takes place in Welding Structure constantly, and wherein 90% is fatigue failure.Show that according to present statistics fatigue is welded main failure mode, its reason is that the stress that is surface cracks at welding toe of joint is concentrated and the residual-tensile stress effect, makes the fatigue behaviour of welding point be lower than the fatigue behaviour of base metal significantly.Therefore, in order to guarantee structural reliability, when the Welding Structure of alternate load was born in design, regulation and stipulation was with the fatigue behaviour of the welding point fatigue behaviour of structure as a whole, and do not adopt the fatigue behaviour of base metal, and obviously this causes significant wastage.Even so, under the effect of joint stress raisers and welding residual-tensile stress, integrally-built premature fatigue still can take place lost efficacy, cause tremendous loss, or even human casualty accident.Therefore improving fatigue properties of welded joints has great economic benefit and social benefit.At present both at home and abroad have that TIG moltenly amends the law, grinder buffing method, local machined method, ballistic method, hammering method, shot-peening method, transship method, local heat method, local rolling process, explosion method, laser cladding method and Gent (Gunnert) method or the like in advance about the main method that improves fatigue properties of welded joints.As above a common shortcoming is arranged is to belong to postwelding processing to method, and promptly postwelding has increased by a procedure, especially for large welded structures spare, can greatly increase the amount of labour and cost.The inventor once invented " welding rod that is used to improve welded joint fatigue strength ", and China Patent No. is ZL01130810.9, but it only is suitable for manual electric arc welding, and production efficiency is lower, can not realize Automation of Welding.
Summary of the invention
The objective of the invention is to overcome shortcoming and defect of the prior art, providing a kind of need not process, can reduce labour cost significantly, enhance productivity, can realize Automation of Welding and effective flux-cored wire that improves fatigue properties of welded joints by postwelding.
The solid core welding wire of high fatigue property of the present invention, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.5～2.0, Cr=5.0～12.0, Ni=4.0～11.0, Mo=0.1～1.0, Nb=0.1～1.0, Ti=0.1～1.0, Si=0.1～1.0, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 100～350 ℃.
Preferred solid core welding wire of the present invention, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.8～1.2, Cr=8.0～10.0, Ni=8.0～10.0, Mo=0.3～0.6, Nb=0.3～0.6, Ti=0.3～0.6, Si=0.5～0.8, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 150～250 ℃.
Economical solid core welding wire of the present invention, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.8～1.2, Cr=5.0～8.0, Ni=5.0～8.0, Mo=0.3～0.6, Nb=0.3～0.6, Ti=0.3～0.6, Si=0.5～0.8, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 250～350 ℃.
Solid core welding wire of the present invention, its tissue should be low-carbon (LC) lath martensite tissue and austenite structure, and content is respectively 60～95% and 40～5%.In the zone of She Fule (Schaeffler) tissue Figure 12≤Creq+1.25Nieq≤25.
The invention has the beneficial effects as follows, general flux-cored wire has great raising at fatigue strength with on fatigue life, and can remove the postwelding manufacturing procedure from, greatly reduce the amount of labour and labour cost, compare with " being used to improve the welding rod of welded joint fatigue strength " patented technology of ZL01130810.9, can be used for multiple welding, and can realize the automation of welding.The present invention can be widely used in bearing the Welding Structure of fatigue load, and especially the huge many large welded structures of weld seam quantity as bridge, steamer, oil platform, vehicles or the like, also can be applied to the reparation of product fatigue fracture.Has huge economic and social benefit.
Description of drawings
Fig. 1 is the cooling expansion curve figure of high fatigue property solid core welding wire and common solid core welding wire deposited metal;
Fig. 2 is the influence figure of the phase transition temperature of weld metal to residual stress;
Fig. 3 is She Fule (Schaeffler) organization chart, and LW is solid core welding wire organization chart of the present invention zone among the figure;
Fig. 4 is the used test specimen figure of experiment on fatigue properties;
Fig. 5 is the vertical view of the used test specimen figure of experiment on fatigue properties.
The Reference numeral of Fig. 4, Fig. 5 is:
1--mainboard 2--gusset joint plate 3--weld seam
The specific embodiment
Below in conjunction with drawings and Examples the present invention is further described.
Ferrous materials can produce structural transformation in cooling procedure, this structural transformation is attended by volumetric expansion, for most ferrous materials, structural transformation (greater than plasticity temperature of material) under higher temperature finishes, this moment, material was in mecystasis, thereby volumetric expansion can not influence welding residual stress; But ferrous materials for certain alloying component, its phase transformation starting point and end point all appear at lower temperature, this moment, material was in elastoplasticity or elastic stage, the phase transformation volumetric expansion will reduce the residual-tensile stress that the welding thermal field causes, the volumetric expansion amount is big more, and residual-tensile stress is more little, even compressive residual stress occurs, this will reduce the reduction of residual-tensile stress to fatigue properties of welded joints, thereby improve the fatigue behaviour of welding point.The present invention will invent the solid core welding wire that a kind of weld metal produces big phase change expansion amount at low temperatures, and the residual-tensile stress of weld metal is reduced or the generation compression stress, thereby improves the fatigue behaviour of welding point.
The actual measurement cooling expansion curve of the present invention and common solid core welding wire deposited metal as shown in Figure 1.
Curve 1 is the cooling expansion curve of common solid core welding wire deposited metal, curve the 2, the 3rd, and the cooling expansion curve of the solid core welding wire deposited metal of high fatigue property, wherein curve 3 is the expansion stage.Ms is a martensite phase transformation starting point, and Mf is a martensite phase transformation end point, and Ts is the phase transition strain starting point, and Tf is the phase transition strain end point.
The cooling procedure of common solid core welding wire weld metal changes along curve 1 or 2, the structural transformation of its weld metal is in beginning more than 350 ℃, the phase change expansion strain has only about 0.11-0.35%, and whole phase transition process does not have the generation of transformation stress all in mecystasis.After phase transformation finished, the weld metal volume continued to shrink, and along with the reduction and the flexible answer of temperature, the yield behavior (varying with temperature) that the tensile stress appearance also constantly increases to material is maintained to room temperature.The cooling procedure of the solid core welding wire weld metal of high fatigue property changes along curve 3 and 4, and before phase transformation, weld metal is along with the reduction and the flexible answer of temperature, and tensile stress occurs and the material yield performance when constantly increasing to starting temperature of transformation.At starting temperature of transformation Ms point, austenite begins to martensite transfor mation, but because martensitic quantity is also less, the phase change expansion strain is not enough to offset the austenitic temperature contraction strain, and curve continues to descend, up to phase strain starting point Ts, curve begins to rise, the phase change expansion that is weld metal just really begins, and up to phase strain end point Tf, Tf should equal room temperature in theory.Phase change expansion dependent variable ε p is big more, and the residual-tensile stress in the weld metal is more little, and weld metal also just may obtain residual compressive stress, thereby improves the fatigue behaviour of welding point.The key that the solid core welding wire of high fatigue property can make weld metal produce compression stress has 2 points: one, Tf is near room temperature for weld metal phase strain end point, because the phase expansion strain peaks when Tf, at this moment can obtain maximum phase expansion strain amount.They are two years old; Maximal phase variable expansion strain stress p should be greater than the tensile elasticity strain stress s of material.
On basis, developed the high fatigue property solid core welding wire that is suitable for mild steel and low-alloy high-strength steel use according to above principle and analysis.Solid core welding wire adopts electric arc furnace smelting, with the base alloy system of Cr-Ni-Mn-Mo system as the development solid core welding wire, should control phosphorus content to guarantee the formation of low-carbon martensite.Smelting is made wire rod after reaching the composition of regulation, is drawn into solid core welding wire; diameter can be 1.2mm, 1.6mm, 3.2mm and 4.0mm; the above two mainly can be used for gas shielded arc welding, also can be used to add a non-melt pole welding method, and both are mainly used in submerged-arc welding the back.The weld structure of high fatigue property solid core welding wire of the present invention is a low-carbon martensite, and obtaining martensitic purpose is to make weld seam volumetric expansion when the martensite phase transformation, produces compressive residual stress, and low-carbon martensite has good comprehensive mechanical properties such as toughness.
The starting temperature of transformation of weld metal to the influence of phase change expansion strain as shown in Figure 2.
By curve as can be seen, starting temperature of transformation is between 100～350 ℃, and the strain of weld metal phase change expansion is greater than 0.35%, and it is greater than the thermal contraction strain of the cooling procedure of weld metal, and weld metal can obtain compressive residual stress.When 190 ℃ of left and right sides, the value maximum of compressive residual stress, this moment, the fatigue behaviour of welding point improved maximum, and the LW3 solid core welding wire weld metal among the embodiment can obtain maximum compressive residual stress, and its fatigue behaviour is best, and is described as claim 2.Phase transition temperature is in 250 ℃～350 ℃ scope, weld metal also can obtain bigger compressive residual stress, the fatigue behaviour of its welding point also is greatly improved, LW4, LW5, LW6, LW7 solid core welding wire are this type of solid core welding wire among the embodiment, because alloy content is lower, relatively also more cheap, described as claim 3.Phase transition temperature is in 100 ℃～190 ℃ scope, alloy content as LW1 and LW2 solid core welding wire deposited metal is the highest, cost is higher, starting temperature of transformation is lower, but the phase change expansion strain is less, under the bigger situation of penetration ratio, the phase transition temperature of its weld metal can be adjusted to the scope about 190 ℃, the fatigue behaviour of its welding point also is greatly improved, but uneconomical, can use under the bigger situation of penetration ratio.Comparative example 1, comparative example's 2 solid core welding wire deposited metal phase change expansion strains are not enough to offset the thermal contraction strain, do not improve the meaning of fatigue behaviour.Comparative example 1 is the austenitic stainless steel welding material, and comparative example 2 is the mild steel welding material.In a word, the phase transition temperature of weld metal is in 100～350 ℃ scope, and the fatigue properties of welded joints of above-mentioned several solid core welding wires can be greatly improved,
Yet phase transition temperature is low more, requires the alloy content in the weld metal high more, and cost is high more comparatively speaking.When the phase point temperature scope was 190～350 ℃ as shown in Figure 2, the compressive residual stress of weld metal compressive residual stress during with respect to 190 ℃ was low, but its alloy content can reduce significantly, and then the solid core welding wire cost also decreases.We optimize quality and satisfy as above requirement, the solid core welding wire that cost is relatively low from economic angle with improve effect and take all factors into consideration for this reason.LW4 among the embodiment, LW5, LW6 and LW7 solid core welding wire are this type of solid core welding wire.
Among embodiment LW1-LW7 and comparative example 1, the comparative example 2, the solid core welding wire diameter is 1.6, and its component and weight percent content (%) see the following form 1.(wherein the impurities trace is disregarded among each embodiment)
Table 1
| Solid core welding wire | ?C | ?Cr | ??Ni | ?Mn | ??Si | ?Mo | ??Ti | ?Nb | Fe | Ms/℃ |
| ????LW1 | ?0.054 | ?11.74 | ??10.90 | ?1.38 | ??0.19 | ?0.35 | ??0.39 | ?0.10 | Surplus | 101 |
| ????LW2 | ?0.045 | ?10.87 | ??10.23 | ?1.42 | ??0.23 | ?0.46 | ??0.51 | ?0.12 | Surplus | 133 |
| ????LW3 | ?0.053 | ?9.98 | ??9.25 | ?1.60 | ??0.18 | ?0.44 | ??0.54 | ?0.12 | Surplus | 190 |
| ????LW4 | ?0.049 | ?9.10 | ??8.16 | ?1.38 | ??0.24 | ?0.65 | ??0.64 | ?0.16 | Surplus | 226 |
| ????LW5 | ?0.047 | ?8.37 | ??7.25 | ?1.75 | ??0.18 | ?0.40 | ??0.72 | ?0.17 | Surplus | 271 |
| ????LW6 | ?0.048 | ?7.30 | ??6.15 | ?1.50 | ??0.21 | ?0.64 | ??0.63 | ?0.12 | Surplus | 308 |
| ????LW7 | ?0.051 | ?6.33 | ??5.29 | ?1.43 | ??0.41 | ?0.33 | ??0.43 | ?0.15 | Surplus | 390 |
| The comparative example 1 | ?0.047 | ?12.80 | ??12.25 | ?1.50 | ??0.32 | ?0.34 | ??0.11 | ?0.13 | | 20 |
| The comparative example 2 | ?0.073 | ?1.96 | ??1.45 | ?1.71 | ??0.81 | ?0.55 | ??0.47 | ?0.10 | Surplus | 780 |
The used test specimen of fatigue experiment as shown in Figure 4 and Figure 5.Test material thickness is the Q235A steel plate of 8mm, adopts the non-bearing cross welding joint geometry that has big residual stress and concentrate than big stress.Adopt electrogas process, weld respectively with high fatigue property solid core welding wire of the present invention and common solid core welding wire, welding one deck, about leg height 8mm, welding current I=230A.On 10 tons of HF fatigue testing machines, carry out fatigue test, frequency f=139Hz, Cyclic Stress compares r=0.1.
See Table 2 with the welding point fatigue test comparing result of common solid core welding wire H08Mn2SiA.
Table 2
| The solid core welding wire example | Fatigue strength improves (at 2*10 6Under the cycle-index) | Improve fatigue life (under different stress levels) |
| ????LW1 | ????21％ | 8～14 times |
| ????LW2 | ????27％ | 9～17 times |
| ????LW3 | ????38％ | 10～20 times |
| ????LW4 | ????32％ | 7～14 times |
| ????LW5 | ????26％ | 5～11 times |
| ????LW6 | ????18％ | 4～8 times |
| ????LW7 | ????12％ | 2～3 times |
| The comparative example 1 | ????5％ | 1～2 times |
| The comparative example 2 | ????0％ | 0 times (fiducial value) |
The present invention all components and content open and that disclose can be by using for reference content disclosed herein, although component of the present invention is described by preferred embodiment, but those skilled in the art obviously can change component described herein in not breaking away from content of the present invention, spirit and scope, more particularly, the replacement that all are similar and change apparent to those skilled in the artly, these all are regarded as being included among content of the present invention, the spirit and scope.
Claims (4)
1. the solid core welding wire of a high fatigue property, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.5～2.0, Cr=5.0～12.0, Ni=4.0～11.0, Mo=0.1～1.0, Nb=0.1～1.0, Ti=0.1～1.0, Si=0.1～1.0, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 100～350 ℃.
2. solid core welding wire according to claim 1, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.8～1.2, Cr=8.0～10.0, Ni=8.0～10.0, Mo=0.3～0.6, Nb=0.3～0.6, Ti=0.3～0.6, Si=0.5～0.8, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 150～250 ℃.
3. solid core welding wire according to claim 1, it is characterized in that, described welding wire component and weight percent content (%) are: C=0.03～0.07, Mn=0.8～1.2, Cr=5.0～8.0, Ni=5.0～8.0, Mo=0.3～0.6, Nb=0.3～0.6, Ti=0.3～0.6, Si=0.5～0.8, all the other are Fe; The solid-state phase changes point temperature range of its deposited metal is 250～350 ℃.
4. solid core welding wire according to claim 1, its tissue should be low-carbon (LC) lath martensite tissue and austenite structure, and content is respectively 60～95% and 40～5%, in the zone of the 12≤Creq+1.25Nieq of scheffler organization chart≤25.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102091884A (en) * | 2011-01-25 | 2011-06-15 | 天津大学 | Flux-cored wire capable of generating compressive stress at weld toe of stainless steel weld joint |
| CN102554507A (en) * | 2012-02-01 | 2012-07-11 | 天津大学 | Solid welding wire for generating residual compression stress and application of solid welding wire to stainless steel welding |
| CN102615399A (en) * | 2012-03-27 | 2012-08-01 | 天津大学 | Welding method for improving fatigue life of socket welding weld toe of branch pipe |
| CN104722949A (en) * | 2015-02-02 | 2015-06-24 | 温州大学 | Solid-core welding wire for reducing welding residual stress of high-strength steel |
| US20190232417A1 (en) * | 2016-06-20 | 2019-08-01 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Gas-shielded arc welding method and method for manufacturing welded structure |
| CN110076476A (en) * | 2019-04-19 | 2019-08-02 | 黄石市高潮工矿机械有限公司 | A kind of high-strength composite solder |
| CN112430786A (en) * | 2020-11-23 | 2021-03-02 | 山西太钢不锈钢股份有限公司 | Stainless steel wire for welding in hydropower industry and preparation method thereof |
| WO2021237843A1 (en) * | 2020-05-28 | 2021-12-02 | 南京钢铁股份有限公司 | Ni-saving low-temperature steel submerged-arc welding wire for cryogenic environment, and welding process |
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2005
- 2005-02-03 CN CN 200510013183 patent/CN1257790C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102091884A (en) * | 2011-01-25 | 2011-06-15 | 天津大学 | Flux-cored wire capable of generating compressive stress at weld toe of stainless steel weld joint |
| CN102554507A (en) * | 2012-02-01 | 2012-07-11 | 天津大学 | Solid welding wire for generating residual compression stress and application of solid welding wire to stainless steel welding |
| CN102615399A (en) * | 2012-03-27 | 2012-08-01 | 天津大学 | Welding method for improving fatigue life of socket welding weld toe of branch pipe |
| CN104722949A (en) * | 2015-02-02 | 2015-06-24 | 温州大学 | Solid-core welding wire for reducing welding residual stress of high-strength steel |
| US20190232417A1 (en) * | 2016-06-20 | 2019-08-01 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Gas-shielded arc welding method and method for manufacturing welded structure |
| CN110076476A (en) * | 2019-04-19 | 2019-08-02 | 黄石市高潮工矿机械有限公司 | A kind of high-strength composite solder |
| WO2021237843A1 (en) * | 2020-05-28 | 2021-12-02 | 南京钢铁股份有限公司 | Ni-saving low-temperature steel submerged-arc welding wire for cryogenic environment, and welding process |
| CN112430786A (en) * | 2020-11-23 | 2021-03-02 | 山西太钢不锈钢股份有限公司 | Stainless steel wire for welding in hydropower industry and preparation method thereof |
| CN112430786B (en) * | 2020-11-23 | 2022-02-18 | 山西太钢不锈钢股份有限公司 | Stainless steel wire for welding in hydropower industry and preparation method thereof |
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Assignee: SHENZHEN CHIWAN SEMBAWANG ENGINEERING CO., LTD. Assignor: Tianjin University Contract fulfillment period: 2008.10.15 to 2013.10.15 Contract record no.: 2008990001287 Denomination of invention: Solid welding wire for lifting welding joint fatigne performance Granted publication date: 20060531 License type: Exclusive license Record date: 20081127 |
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