CN1635202A - Nano thermal storage warming all band infrared fibrous composition - Google Patents
Nano thermal storage warming all band infrared fibrous composition Download PDFInfo
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- CN1635202A CN1635202A CN 200310122001 CN200310122001A CN1635202A CN 1635202 A CN1635202 A CN 1635202A CN 200310122001 CN200310122001 CN 200310122001 CN 200310122001 A CN200310122001 A CN 200310122001A CN 1635202 A CN1635202 A CN 1635202A
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- band infrared
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Abstract
The invention discloses a nanometer heat accumulation temperature elevated all wave section bend infra-red fiber composition, comprising 0.5~2% zirconium carbide with particle diameter of 10~100nm, 1~4% porcelain clay with particle diameter of 10~100nm, 0.02~0.6% spinning auxiliary agent, and the residual resin all by weight. By adding inorganic material capable of absorbing visible light and near infrared ray in high efficiency to the resin, the fiber of the invention can absorb the energy of visible light and near infrared ray to full advantage, and increase the temperature of fiber or textiles; by adding material capable of absorbing far-infrared ray in high efficiency to the fiber, the invention can increase the temperature of the textile at the same time with sending near-infrared ray, and improve the energy of far-infrared ray sent by the textile; because the added inorganic material is of nanometer grade, it is of great advantages to spinning and knitting, at same time, the nanometer powder increases the surface area and increases the infrared absorption and sending function.
Description
Technical field
The present invention relates to a kind of photo-thermal conversion fiber.
Background technology
The photo-thermal conversion fiber is a kind of novel warmth retention property functional fibre, and it can optionally absorb sunray and be converted into heat energy, to improve heat insulation effect, it is applied to aspects such as insulation garment, and very big development prospect is arranged.
About far IR fibre, appear in the newspapers both at home and abroad, as in resin raw material, adding the little energy of far infrared powder, make synthetic fiber etc., they can absorb far infrared effectively, and are converted into heat, and have certain limitation for the transform light energy of visible light.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of nanometer accumulation of heat intensification all band infrared fibre composition is provided.
Technical scheme of the present invention is summarized as follows:
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises zirconium carbide 0.5～2%, kaolin 1～4% by weight percentage, spinning-aid agent 0.02～0.6%, surplus is a resin, and the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Described spinning-aid agent is titanate esters or aluminic acid ester or silane.
Described resin is polyester or polypropylene or polyamide or polyacrylonitrile or viscose glue.
Described titanate esters is three oleoyl isopropyl titanates or isopropyl stearyl-methylpropenyl titanate esters.
Described aluminic acid ester is DL-411A or DL-411AF.
Described silane is two-(γ-tri-ethoxy silylpropyl) four sulphur or γ-sulfydryl trimethoxy silane or γ-(methacryloxy) propyl trimethoxy silicane or gamma-aminopropyl-triethoxy-silane.
A kind of nanometer accumulation of heat intensification all band infrared fibre composition of the present invention after making fiber and being woven to textiles, can play accumulation of heat and increase warm and function of health care by heating the blood circulation effect that promotes the user.
Because the present invention has added energy efficient absorption visible light and near infrared inorganic material zirconium carbide in the resin that routine is used, make fiber can fully absorb visible light and near infrared energy, improve the temperature of fiber or textiles, and the material kaolin that in this fiber, also adds energy efficient absorption far infrared, obviously this fiber and far infrared fiber fabric are inequality, in the near infrared while of emission, the temperature of fabric is raise, the far-infrared ray power of fabric emission is improved greatly, the fabric that people use this fiber to be made into, can stimulate circulation, increase volume of blood flow, play the effect of disease-prevention health better.Because the inorganic material of adding is nano level material, therefore, help spinning and braiding again, simultaneously, nano level powder, its surface area significantly increases, and has further increased the INFRARED ABSORPTION and the emitting performance of material.
The specific embodiment
Nanometer accumulation of heat intensification all band infrared fibre preparation of compositions of the present invention becomes fiber, be the preparation method who adopts the functional fiber that discloses, for example: take a morsel earlier and serve as the resin of carrier, add a certain proportion of nano level zirconium carbide and nano level kaolin and fully be mixed and made into concentrated master batch, then, again under the effect of spinning-aid agent, will concentrate master batch and mixed with resin is even, carry out spinning production through fusion method or wet method.
The adding of spinning-aid agent improves the spinnability of fibre-forming polymer under the situation that adds inorganic material.
The basic principle of selecting for use of spinning-aid agent is nontoxic, non-stimulated to people's skin.
Spinning-aid agent can select titanate esters or aluminic acid ester or silane.Wherein DL-411A in the aluminic acid ester or DL-411AF are that Fujian Normal University's macromolecule pilot plant and Foochow Cang Shan chemical industry kerosene factory produce, and they have function admirable, characteristics with low cost.
Below by embodiment the present invention is further described.
Embodiment 1
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 5 kilograms of zirconium carbides, 1 kilogram of kaolin by weight percentage; 0.2 kilogram of three oleoyl isopropyl titanate; 984.8 kilograms of resins, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 2
A kind of nanometer accumulation of heat intensification all band infrared fibre composition; comprise 15 kilograms of zirconium carbides by weight percentage; 15 kilograms of kaolin; 0.5 kilogram of isopropyl stearyl monomethyl propenyl titanate esters; 969.5 kilograms of polyester; the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 3
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 10 kilograms of kaolin by weight percentage, the DL-411A1 kilogram, 969 kilograms of polypropylene, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 4
A kind of nanometer accumulation of heat intensification all band infrared fibre composition, comprise 10 kilograms of zirconium carbides by weight percentage, 40 kilograms of kaolin, two-5 kilograms of (γ-tri-ethoxy silylpropyl) four sulphur, 945 kilograms of viscose glues, the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 5
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 35 kilograms of kaolin by weight percentage, 2 kilograms of γ-sulfydryl trimethoxy silane, 943 kilograms of polyacrylonitrile, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 6
A kind of nanometer accumulation of heat intensification all band infrared fibre composition, comprise 10 kilograms of zirconium carbides by weight percentage, 30 kilograms of kaolin, 3 kilograms of γ-(methacryloxy) propyl trimethoxy silicane, 957 kilograms of polyamide, the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 7
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 10 kilograms of zirconium carbides, 20 kilograms of kaolin by weight percentage, 4 kilograms of gamma-aminopropyl-triethoxy-silanes, 966 kilograms of polyamide, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 8
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 20 kilograms of kaolin by weight percentage, the DL-411AF4 kilogram, 956 kilograms of polyamide, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Claims (6)
1. a nanometer accumulation of heat intensification all band infrared fibre composition is characterized in that comprising by weight percentage zirconium carbide 0.5～2%, kaolin 1～4%, spinning-aid agent 0.02～0.6%, surplus is a resin, and the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
2. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 1, the described spinning-aid agent of its feature is titanate esters or aluminic acid ester or silane.
3. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 1, the described resin of its feature is polyester or polypropylene or polyamide or polyacrylonitrile or viscose glue.
4. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described titanate esters of its feature is three oleoyl isopropyl titanates or isopropyl stearyl monomethyl propenyl titanate esters.
5. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described aluminic acid ester of its feature is DL-411A or DL-411AF.
6. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described silane of its feature are two-(γ-tri-ethoxy silylpropyl) four sulphur or γ-sulfydryl trimethoxy silane or γ-(methacryloxy) propyl trimethoxy silicane or gamma-aminopropyl-triethoxy-silane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310122001 CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310122001 CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
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| Publication Number | Publication Date |
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| CN1635202A true CN1635202A (en) | 2005-07-06 |
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| CN 200310122001 Pending CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101640953B (en) * | 2009-08-18 | 2012-02-01 | 中山市康益保健用品有限公司 | Far infrared heating shell fabric |
| CN103132177A (en) * | 2013-03-13 | 2013-06-05 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN105200546A (en) * | 2015-11-03 | 2015-12-30 | 安踏（中国）有限公司 | Light-absorption and heat-storage far-infrared fiber as well as preparation method and application thereof |
| CN109385688A (en) * | 2017-08-10 | 2019-02-26 | 中国石化仪征化纤有限责任公司 | A kind of abnormity thermal polyester fibers and preparation method thereof |
| CN113155776A (en) * | 2021-04-29 | 2021-07-23 | 华东交通大学 | Prediction method for optimal harvest time of oranges |
-
2003
- 2003-12-30 CN CN 200310122001 patent/CN1635202A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101640953B (en) * | 2009-08-18 | 2012-02-01 | 中山市康益保健用品有限公司 | Far infrared heating shell fabric |
| CN103132177A (en) * | 2013-03-13 | 2013-06-05 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN103132177B (en) * | 2013-03-13 | 2015-01-21 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN105200546A (en) * | 2015-11-03 | 2015-12-30 | 安踏（中国）有限公司 | Light-absorption and heat-storage far-infrared fiber as well as preparation method and application thereof |
| CN105200546B (en) * | 2015-11-03 | 2018-01-26 | 安踏（中国）有限公司 | A kind of extinction accumulation of heat far IR fibre, its preparation method and application |
| CN109385688A (en) * | 2017-08-10 | 2019-02-26 | 中国石化仪征化纤有限责任公司 | A kind of abnormity thermal polyester fibers and preparation method thereof |
| CN113155776A (en) * | 2021-04-29 | 2021-07-23 | 华东交通大学 | Prediction method for optimal harvest time of oranges |
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Owner name: TIANJIN CITY GUOKE ELECTRONICS TECHNOLOGY CO., LT Free format text: FORMER OWNER: YUAN BING; APPLICANT Effective date: 20070209 |
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Effective date of registration: 20070209 Address after: 300384 Tianjin Huayuan Industrial Zone Orchid Road No. 1 Huayuan technology annotation workshop 303 Applicant after: Tianjin Ke Ke Electronic Technology Co., Ltd. Address before: 300072 12-4-602, three village, Tianjin University, Tianjin, Nankai District Applicant before: Yuan Bing Co-applicant before: Wang Qia |
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