CN1635172A - Nano SnO2/Fe2O3 blending doped silver base electric contact alloy and preparing process thereof - Google Patents

Nano SnO2/Fe2O3 blending doped silver base electric contact alloy and preparing process thereof Download PDF

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Publication number
CN1635172A
CN1635172A CN 200310122263 CN200310122263A CN1635172A CN 1635172 A CN1635172 A CN 1635172A CN 200310122263 CN200310122263 CN 200310122263 CN 200310122263 A CN200310122263 A CN 200310122263A CN 1635172 A CN1635172 A CN 1635172A
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nano
sno
powder
electric contact
ball milling
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CN1302134C (en
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王俊勃
杨敏鸽
李英民
王鹏飞
陈立成
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XIAN ENGINEERING SCI-TECH COLLEGE
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XIAN ENGINEERING SCI-TECH COLLEGE
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Abstract

The invention belongs to a nanometer confounded additive composite silver based electric contact alloy and preparation technique thereof, especially to a component of nanometer SnO2/Fe3O3 blended silver doped based electric contact alloy electrical contacts material and preparation technique thereof, wherein, co-precipitating and roasting the SnO2 and Fe2O3 chemically for preparing confounded nanometer powder with different granularity, high-energy ball milling the mixed powder of Ag, SnO2 and Fe2O3 in air or nitrogen gas environment, and shaping them. The invention can improve the moldability and electrical property of silver-based electrical contacts material and reduce the contact point burning loss rate and improve its service life.

Description

Nano SnO 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof
Affiliated technical field:
The invention belongs to a kind of nano hybrid additive composite silver base alloy as electric contact material and preparation technology thereof, particularly relate to nano SnO 2/ Fe 2O 3Composition and the preparation technology thereof of the doped silver based alloy as electric contact material electrical contact material of blend.
Background technology:
Present known Ag-based electrical contact material has: 1. adopt high-energy ball milling to prepare nano SnO 2Money base alloy as electric contact material (number of patent application 00135475.2); 2. sol-gel method prepares nano SnO 2, ZnO, TiO 2And rare earth composition prepares nm-class Ag-base alloy as electric contact material (number of patent application 02146696.3); 3. adopt blended metal oxide (to contain SnO 2, ZrO, ZnO, TiO, MnO, WO etc.) money base alloy as electric contact material (number of patent application 03100430.X), and work in-process carries out the routine techniques of the ternary co-osmosized Ag-based electrical contact material of boron or carbon, nitrogen, boron.Above technology is in the formability of electrical contact material, electrical property, pitting of contacts speed and work-ing life the aspect certain limitation is arranged.
Summary of the invention
For overcoming the above problems, the invention provides a kind of nano SnO 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof, it can improve mouldability, the electrical property of Ag-based electrical contact material, and significantly reduces pitting of contacts speed, improves the service life of Ag-based electrical contact.
Solution of the present invention is: the design nano SnO 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: earlier with SnO 2, Fe 2O 3Chemical coprecipitation, roast prepare the nano powder that mixes of different nano particle sizes, then with Ag powder and SnO 2/ Fe 2O 3The mixed powder of hybrid-powder high-energy ball milling in air or nitrogen environment, the SnO for preparing 2, Fe 2O 3The nano particle disperse is distributed in the even mixed powder in the silver matrix, and the nano composite powder behind the ball milling is through conventional technological forming.
Described chemical coprecipitation is at 300 ℃-750 ℃, contains 50-99.5%SnO with the preparation of 1h-3h roast 2And 0.5-50%Fe 2O 3Nano particle size at 5-100nm nanometer blending oxide, Fe 2O 3Evenly distribution or solid solution are in SnO 2In the crystal grain; Then weight ratio is respectively the Ag powder of 80-95% and the SnO of 5-20% 2/ Fe 2O 3The mixed powder of mixed powder high-energy ball milling in air or nitrogen environment.
Described high-energy ball milling technology is: ratio of grinding media to material 10-100: 1, and the corresponding ball milling time is 15 minutes-3 hours, and ratio of grinding media to material is big more, and the ball milling time is short more.
Nano composite powder behind the described ball milling through 50MPa-600MPa cold pressing, Thermocompressed sintering and forming under 300-750 ℃, 50-400MPa.
Nano composite powder behind the described ball milling through pre-annealing, is colded pressing, is sintered base at 300-750 ℃ through 20-200MPa again, through hot extrusion, hot pull, rolling or multiple compression technology moulding.
Described chemical coprecipitation is to utilize SnCl 4And FeCl 3Mixed liquor dropping ammonia chemical coprecipitation prepares SnO 2And Fe 2O 3The nano hybrid oxide.
Characteristics of the present invention are: it utilizes SnCl 4And FeCl 3Mixed aqueous solution dropping ammonia chemical coprecipitation, preparation SnO 2And Fe 2O 3The nano hybrid oxide, the mixed powder preparation of high-energy ball milling contains Ag, the SnO of nano-oxide 2, Fe 2O 3Composite powder.With hot pressed sintering or cold-rolled sintered technological forming, obtain containing the silver-based electric contact alloy of nano-oxide, under the effect of nano-oxide, electrical conductivity, the contact resistance of material significantly improve, and can improve anti-melting welding ability and the anti electric arc corrosion ability of contact.
Be on the electrical contact material composition it is nano SnO with the difference of similar technology 2And Fe 2O 3Blend mix, in nano SnO 2And Fe 2O 3Preparation in adopted the mixed powder preparation of chemical coprecipitation and high-energy ball milling to contain Ag, the SnO of nano-oxide 2, Fe 2O 3The technology of composite powder.The AgSnO for preparing by above technology 2/ Fe 2O 3The series contact alloy is nano SnO 2/ Fe 2O 3Uniform particles is distributed in the Ag matrix.Because Fe 2O 3Dispersiveness and the mixed powder of high-energy ball milling, make nano SnO 2/ Fe 2O 3Particle dispersion is distributed in the Ag matrix rather than is distributed on the crystal boundary, so the electrical conductivity of contact significantly improves, can significantly reduce contact resistance.And nano SnO 2/ Fe 2O 3Particle has bigger invigoration effect, can improve anti-melting welding ability and the anti electric arc corrosion ability of contact, makes AgSnO 2/ Fe 2O 3The performance generation qualitative leap of series contact.
The present invention will be further described below in conjunction with the embodiment picture.
Fig. 1 is conventional commercial AgSnO 2In 2O 3Contact low power SEM pattern.
Fig. 2 is nano combined AgSnO 2/ Fe 2O 3Contact low power SEM pattern.
Fig. 3 is conventional commercial AgSnO 2In 2O 3Contact SEM pattern.
The nano combined AgSnO of Fig. 4 2/ Fe 2O 3Contact SEM pattern
Description of drawings: accompanying drawing is AgSnO 2Tradition contact and the contrast of nano combined contact arc erosion pattern.
As shown in the figure, compare with traditional contact, nano combined contact shows good dispersion electric arc Effect, the surface does not have obvious molten bath and liquid splash.
The density of hot pressing contact material is 9.2-9.9g/cm3, hardness HV:850-1550MPa.
Specific embodiment of the present invention is:
At first use chemical coprecipitation, under 300-750 ℃ of condition, the preparation of 1-3h roast contains 50-99.5%SnO2And 0.5-50%Fe2O 3Nano particle size at 5-100nm nanometer blending oxide, Fe2O 3Evenly distribution or solid solution are in SnO2In the crystal grain. Then weight ratio is respectively 80-95 The Ag powder of % and the SnO of 5-20%2/Fe 2O 3Mixed powder is high-energy ball milling in air or nitrogen environment Mixed powder. High-energy-milling is: ratio of grinding media to material 10-100: 1, and corresponding Ball-milling Time is 15 minutes Clock-3 hour (ratio of grinding media to material is more big, and Ball-milling Time is more short). Nano SnO behind the ball milling2And Fe2O 3Disperse is distributed in the silver matrix, SnO2And Fe2O 3Weight ratio be 5-20%. Nano combined behind the ball milling Powder (can through in advance annealing) through 50-600MPa cold pressing, at 300-750 ℃, 50-400MPa Lower Thermocompressed sintering and forming. Or the nano composite powder behind ball milling (can through in advance annealing) is through 20-200MPa colds pressing, sinters base at 300-750 ℃, through hot extrusion, hot pull, rolling or Multiple pressure waits the common process moulding.
Specific implementation method
Embodiment 1:
At 400 ℃, it is that 10: 2 nano particle size is at the SnO of 5-20nm that the 1h roast prepares weight ratio 2/ Fe 2O 3Chemical coprecipitation mixes oxidate powder.Weight ratio is respectively 88% Ag powder and 12% SnO 2/ Fe 2O 3Mix powder high-energy ball milling in air compression ring border.Adopt the oscillatory type ball mill, ratio of grinding media to material 20: 1, half an hour ball milling time, vibrational frequency 200s-1.Powder behind the ball milling cold pressing through 200-600MPa, Thermocompressed sintering and forming under 550 ℃, 200MPa.The AgSnO for preparing 2/ Fe 2O 3Contact alloy is nano SnO 2/ Fe 2O 3Particle is evenly distributed in the Ag matrix.
Embodiment 2:
At 550 ℃, it is that 7: 5 nano particle size is at the SnO of 20-40nm that the 1h roast prepares weight ratio 2/ Fe 2O 3Chemical coprecipitation mixes oxidate powder.Weight ratio is respectively 88% Ag powder and 12% SnO 2/ Fe 2O 3Mix powder high-energy ball milling in nitrogen environment.Adopt the stirring-type high energy ball mill, ratio of grinding media to material is 40: 1,300 rev/mins of rotating speeds.The ball milling time is 1 hour.Powder behind the ball milling is being colded pressing through 100MPa, is being sintered base at 650 ℃, then through multiple molded.The AgSnO for preparing 2/ Fe 2O 3Contact alloy is nano SnO 2/ Fe 2O 3Particle is evenly distributed in the Ag matrix.
Embodiment 3:
At 750 ℃, it is that 12: 5 nano particle size is at the SnO of 40-70nm that the 1h roast prepares weight ratio 2/ Fe 2O 3Chemical coprecipitation mixes oxidate powder.Weight ratio is respectively 88% Ag powder and 12% SnO 2/ Fe 2O 3Mix powder high-energy ball milling in air ambient.Adopt the oscillatory type ball mill, ratio of grinding media to material 20: 1,1 hour ball milling time, vibrational frequency 200s-1.Powder behind the ball milling cold pressing through 200-600MPa, Thermocompressed sintering and forming under 650 ℃, 200MPa.The AgSnO for preparing 2/ Fe 2O 3Contact alloy is nano SnO 2/ Fe 2O 3Particle is evenly distributed in the Ag matrix.

Claims (6)

1, nano SnO 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: earlier with SnO 2, Fe 2O 3Chemical coprecipitation, roast prepare the nano powder that mixes of different nano particle sizes, then with Ag powder and SnO 2/ Fe 2O 3The mixed powder of hybrid-powder high-energy ball milling in air or nitrogen environment, the SnO for preparing 2, Fe 2O 3The nano particle disperse is distributed in the even mixed powder in the silver matrix, and the nano composite powder behind the ball milling is through conventional technological forming.
2, nano SnO according to claim 1 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: described chemical coprecipitation is at 300 ℃-750 ℃, contains 50-99.5%SnO with the preparation of 1h-3h roast 2And 0.5-50%Fe 2O 3Nano particle size at 5-100nm nanometer blending oxide, Fe 2O 3Evenly distribution or solid solution are in SnO 2In the crystal grain; Then weight ratio is respectively the Ag powder of 80-95% and the SnO of 5-20% 2/ Fe 2O 3The mixed powder of mixed powder high-energy ball milling in air or nitrogen environment.
3, nano SnO according to claim 1 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: described high-energy-milling is: ratio of grinding media to material 10-100: 1, and corresponding Ball-milling Time is 15 minutes-3 hours, and ratio of grinding media to material is more big, and Ball-milling Time is more short.
4, nano SnO according to claim 1 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: the nano composite powder behind the described ball milling through 50MPa-600MPa cold pressing, Thermocompressed sintering and forming under 300-750 ℃, 50-400MPa.
5, nano SnO according to claim 1 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof, it is characterized in that: the nano composite powder behind the described ball milling, through pre-annealing, cold pressing, sinter base at 300-750 ℃ through 20-200MPa again, through hot extrusion, hot pull, rolling or multiple compression technology moulding.
6, nano SnO according to claim 1 2/ Fe 2O 3The doped silver based alloy as electric contact material of blend and preparation technology thereof is characterized in that: described chemical coprecipitation is to utilize SnCl 4And FeCl 3Mixed aqueous solution dropping ammonia chemical coprecipitation prepares SnO 2And Fe 2O 3The nano hybrid oxide.
CNB2003101222631A 2003-12-28 2003-12-28 Nano SnO2/Fe2O3 blending doped silver base electric contact alloy and preparing process thereof Expired - Fee Related CN1302134C (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101794636B (en) * 2010-02-02 2011-08-10 福达合金材料股份有限公司 Preparation method of silver ferric oxide electrical contact material
CN101964260B (en) * 2008-12-15 2012-08-29 中国船舶重工集团公司第七二五研究所 Ag/SnO2 electrical contact material and preparation method thereof
CN103290349A (en) * 2013-06-08 2013-09-11 西安工程大学 Preparation method of silver-based metal oxide/copper composite contact alloy
CN107868880A (en) * 2016-09-23 2018-04-03 霍尼韦尔国际公司 Siluer metal oxide alloy and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56133440A (en) * 1980-03-24 1981-10-19 Tanaka Kikinzoku Kogyo Kk Composite electrical contact material
JPS6021303A (en) * 1983-07-15 1985-02-02 Fuji Electric Corp Res & Dev Ltd Manufacture of electrical contact material
JPS6021304A (en) * 1983-07-15 1985-02-02 Fuji Electric Corp Res & Dev Ltd Manufacture of electrical contact material
DE59405126D1 (en) * 1993-08-23 1998-02-26 Siemens Ag SILVER-BASED CONTACT MATERIAL, USE OF SUCH A CONTACT MATERIAL IN A SWITCHGEAR OF ENERGY TECHNOLOGY AND METHOD FOR THE PRODUCTION OF THE CONTACT MATERIAL
CN1320711A (en) * 2000-12-28 2001-11-07 西安交通大学 Nm-class Ag-base alloy as electric contact material and its preparing process

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101964260B (en) * 2008-12-15 2012-08-29 中国船舶重工集团公司第七二五研究所 Ag/SnO2 electrical contact material and preparation method thereof
CN101794636B (en) * 2010-02-02 2011-08-10 福达合金材料股份有限公司 Preparation method of silver ferric oxide electrical contact material
CN103290349A (en) * 2013-06-08 2013-09-11 西安工程大学 Preparation method of silver-based metal oxide/copper composite contact alloy
CN103290349B (en) * 2013-06-08 2015-11-18 西安工程大学 A kind of preparation method of silver-base metal oxide/copper composite contact alloy
CN107868880A (en) * 2016-09-23 2018-04-03 霍尼韦尔国际公司 Siluer metal oxide alloy and preparation method thereof
US10290434B2 (en) 2016-09-23 2019-05-14 Honeywell International Inc. Silver metal oxide alloy and method of making
US10727006B2 (en) 2016-09-23 2020-07-28 Honeywell International Inc. Silver metal oxide alloy and method of making

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