CN1623681A - Process for coating aluminium oxide at surface of plastic floor tile - Google Patents
Process for coating aluminium oxide at surface of plastic floor tile Download PDFInfo
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- CN1623681A CN1623681A CN 200310117146 CN200310117146A CN1623681A CN 1623681 A CN1623681 A CN 1623681A CN 200310117146 CN200310117146 CN 200310117146 CN 200310117146 A CN200310117146 A CN 200310117146A CN 1623681 A CN1623681 A CN 1623681A
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Abstract
A process for coating alumina on the surface of plastic floor tile includes such steps as goating UV-sensitive resin, spraying alumina sand, using UV lamp to rdiate it for hardening unit, coating UV-sensitive resin again, and using UV lamp to radiate it again. Its advantages are high resistance to abrasion, scraping, corrosion and compression, and stereoscopic grains.
Description
Technical field
The present invention relates to a kind of in plastic floor tile surface coating method of alumina, more specifically, be meant a kind of spray-type coating aluminum oxide sand of utilizing especially, with alumina-coated among two-layer sensitization UV cold coating, through the process of twice coating sensitization UV resin operation at plastic floor tile surface coating aluminium oxide, can avoid aluminium oxide to produce sedimentation at wear resistant plastic floor tile finished surface, prevent that aluminum oxide sand from coming off, the plastic floor tile surface is formed have splendid tack, wearability, scratch resistance, corrosion resistance, crushing resistance and have the third dimension lines concurrently.
Background technology
Though the construction of tradition plastic floor tile easily, but atomized surface effect, wearability, scratch resistance, skid resistance, corrosion resistance and the crushing resistance of its tool chiltern sense are all not as good as traditional ceramics and stone material floor tile, in order to improve above-mentioned shortcoming, the product of market plastic floor tile in recent years, the aluminium oxide photosensitive resin that adopts in sensitization UV resin the mode with interior interpolation aluminium oxide to form is formed at the top layer of plastic floor tile more through coating.
See also Fig. 1, shown in Figure 2, it is respectively traditional plastic floor tile external coating process block diagram and traditional plastic floor tile external coating schematic flow sheet, as we know from the figure, this tradition plastic floor tile external coating flow process is coating aluminium oxide sensitization UV resin 11A on semi-finished product 10A, and described aluminium oxide sensitization UV resin 11A needs to form through UV light irradiation 200A generation chemical change the plastic floor tile finished product 1A of sclerosis again.
See also Fig. 2, shown in Figure 3, it is respectively traditional plastic floor tile external coating schematic flow sheet, tradition is added the generalized section of the plastic floor tile of aluminium oxide, as we know from the figure, can add metal oxide among this sensitization UV resin 111A, wherein said metal oxide belongs to the tool scratch resistance, the additive of wearability, and have in the metal oxide that is added splendid wearability and scratch resistance for aluminium oxide 110A, so in the conventional process, aluminium oxide 110A is added among the sensitization UV resin 111A with interior addition manner, and this aluminium oxide sensitization UV resin 11A utilizes the mode of roller coating 100A to coat on the semi-finished product 10A.But when coating, heavier and sinking speed is fast because of aluminium oxide 110A proportion, and cause it still to be not applied on the semi-finished product 10A, just sedimentation among the sensitization UV resin 111A on roller 101A, and coat the aluminium oxide sensitization UV resin 11A on semi-finished product 10A surface, because of causing the aluminium oxide 110A grain density on plastic floor tile finished product 1A surface, aluminium oxide 110A particles settling also descends, so the atomized surface effect of the surperficial chiltern sense of the plastic floor tile finished product 1A that forms of coating institute also just becomes undesirable, because of aluminium oxide 110A particle can't protrude sensitization UV resin 111A surface, cause the plastic floor tile finished product 1A that manufactures with this conventional method, its surface can't produce wear-resisting, scratch resistance and can not have the atomized surface effect of identical chiltern sense with ceramic stone and ground building materials.For aluminium oxide 110A is not fallen among the sensitization UV resin 111A, need make aluminium oxide sensitization UV resin 11A that coating contains the aluminium oxide 110A of high-load, otherwise be difficult to make plastic floor tile finished product 1A to reach the atomized surface effect of required chiltern sense.And after the increase of aluminium oxide 110A addition, has the atomized surface effect of identical chiltern sense though its plastic floor tile finished product 1A generation is wear-resisting, scratch resistance reaches with ceramic stone and ground building materials, but the viscosity of its aluminium oxide sensitization UV resin 11A can increase, and the lip-deep aluminium oxide sensitization of the semi-finished product 10A UV resin 11A thickness of coating also can increase, and causes the cost of making plastic floor tile finished product 1A also and then to improve.
See also Fig. 2, Fig. 4, shown in Figure 5, it is respectively traditional plastic floor tile manufacturing process schematic diagram, tradition is added silica (SiO
2) the generalized section, the schematic perspective view of traditional plastic floor tile of plastic floor tile, as we know from the figure, that the surface of this plastic floor tile finished product 1A has formed is wear-resisting, the atomized surface effect of scratch resistance and formation and ceramic stone and the similar chiltern sense of ground building material surface, it is in processing procedure, the additive that makes an addition in the sensitization UV resin 111A is light specific gravity and the slower nonmetal oxide of sinking speed, and the additive of this nonmetal oxide is silica (SiO here
2) 120A, at semi-finished product 10A surface upper roller coating 100A silica (SiO
2) behind the sensitization UV resin 12A, behind sensitization UV light irradiation sclerosis 200A, promptly form plastic floor tile finished product 1A, the plastic floor tile finished product 1A surface that this method is produced has formed the atomized surface effect that has with ceramic stone and the similar chiltern sense of ground building material surface, but because of silica (SiO
2) 120A is nonmetal oxide, proportion is lighter, when roller coating 100A, through roller 101A extruding and be attached on the semi-finished product 10A these silica (SiO
2) the 120A particle is squeezed and can't protrudes sensitization UV resin 111A surface uniformly, though so the surface formation of plastic floor tile finished product 1A and the atomized surface effect of ceramic stone and the similar chiltern sense of ground building material surface, but atomized surface effect is undesirable, be that the chiltern sense is poor, still can't make the plastic floor tile finished product form the surface of wear-resisting, scratch resistant property of tool and skid resistance.
From the above, traditional plastic floor tile and manufacturing method thereof have following shortcoming:
1, in the sensitization UV resin, adds aluminium oxide easily because of aluminium oxide proportion is heavier with interior addition manner, and cause aluminium oxide to fall in the sensitization UV resin;
2, in the said method, be coated with aluminium oxide sensitization UV resin, make the plastic floor tile finished surface can't formation and the atomized surface effect of ceramic stone and the similar chiltern sense of ground building material surface in the roller mode;
3, the aluminium oxide sensitization UV resin of plastic floor tile finished surface is because of aluminium oxide sedimentation, so the plastic floor tile finished surface can't form the effect of wear-resisting, the scratch resistant and skid resistance of tool;
4, in the said method, after the aluminium oxide addition increases, its plastic floor tile finished product generation is wear-resisting, scratch resistance reaches and the atomized surface effect of ceramic stone and the similar chiltern sense of ground building material surface, but the viscosity of aluminium oxide sensitization UV resin can increase, and the aluminium oxide sensitization UV resin thickness of being coated on the surface of semi-finished also can increase, and causes the cost of making plastic floor tile also and then to improve;
5, in the said method, be coated with silica (SiO in the roller mode
2) sensitization UV resin, make the silica (SiO that is added
2) particle can't evenly protrude from the sensitization UV resin, and silica (SiO
2) the wear-resisting scratch-resisting difference comes off easily, causes the plastic floor tile finished surface to form the atomized surface effect of extremely undesirable chiltern sense, promptly wear-resisting, scratch resistance, skid resistance extreme difference.
The inventor is engaged in the plastic floor tile exploitation and studies for many years, for the constructional pluses and minuses of plastic floor tile, being familiar with and understanding on the certain degree arranged, because in aforesaid traditional plastic floor tile processing procedure, because of aluminium oxide being made an addition in the sensitization UV resin, can cause in aluminium oxide sedimentation and this plastic floor tile processing procedure with addition manner silica (SiO with interior addition manner
2) make an addition in the sensitization UV resin and can't produce preferable shortcomings such as harsh feeling, the inventor of this case studies improvement at above-mentioned disappearance, wish to create a kind of practical plastic floor tile, the inventor is in line with excelsior spirit, and the present invention is finished in constantly research idea finally.
Summary of the invention
The object of the present invention is to provide a kind ofly, the plastic floor tile surface is formed have splendid tack, wearability, scratch resistance, corrosion resistance, crushing resistance and third dimension lines in plastic floor tile surface coating method of alumina.
For achieving the above object, plastic floor tile of the present invention surface coating method of alumina, mainly be on not surface treated floor tile semi-finished product, the even for the first time coating of sensitization UV resin is attached on the floor tile semi-finished product, and in be coated with and still unhardened sensitization UV resin on, mode with spray coating is sprayed aluminum oxide sand equably, and aluminum oxide sand adopts the mode that adds spraying, can make aluminium oxide can be attached to the situation that does not produce sedimentation on the floor tile semi-finished product more equably, make the sensitization UV hardening of resin of spray coating aluminum oxide sand again through the UV light irradiation, sclerosis rear oxidation aloxite then can adhere to fully and is incorporated on the sensitization UV resin, again sensitization UV resin is coated for the second time the surface of aluminum oxide sand this moment, make aluminum oxide sand to be coated by sensitization UV resin fully, and utilize the still unhardened sensitization UV of UV light irradiation resin once more, promptly form the finished product of tool wear resistant plastic floor tile after making its sclerosis.
Particularly, coating method of alumina in plastic floor tile of the present invention surface mainly is to utilize to add formula spray pattern coating aluminium oxide, and aluminum oxide sand is coated among the two-layer sensitization UV cold coating, and its step is as follows:
A. the plastic floor tile semi-finished product being positioned over gets the raw materials ready on the loading bay prepares reprocessing;
B. be coated with for the first time sensitization UV resin equably on the half-finished surface of plastic floor tile with one group of coating apparatus;
C. be not coated with the other aluminum oxide sand of spraying on the sensitization UV resin surface fully the first time of sclerosis with spraying equipment;
D. shining sclerosis for the first time with a group or more UV lamp has finished the spraying of sensitization UV resin surface and has adhered to the plastic floor tile semi-finished product of aluminum oxide sand;
E. be attached with on the surface of aluminum oxide sand at the plastic floor tile semi-finished product that shone for the first time the UV lamp, be coated with sensitization UV resin for the second time with one group of coating apparatus;
F. the UV lamp with a group or more shines the surface that sclerosis is coated with sensitization UV resin for the second time for the second time;
G. utilize heat abstractor to cool off and be coated with sensitization UV resin the second time of having hardened;
H. surperficial tool is wear-resisting plastic floor tile finished product is delivered to material receiving desk and is placed and deposit.
In said method, aluminum oxide sand can make the plastic floor tile finished product have good wear-resisting, skid resistance.Described twice coating sensitization UV resin is coated on aluminum oxide sand wherein, makes the plastic floor tile finished product have good wearability.Wherein, described coating apparatus for example can be the roller coating apparatus for coating being attached to the equipment on plastic floor tile surface; And described spraying equipment can be can spray coating sand-blasting machine; Described heat abstractor can be radiator fan; The described type of cooling can be for but natural air cooled.
So, plastic floor tile of the present invention surface coating method of alumina, utilize the mode of spray coating to be coated with aluminium oxide, and the mode of utilizing roller coating with alumina-coated among two-layer sensitization UV cold coating, the plastic floor tile that utilizes this method to produce, can promote atomized surface effect that the floor tile finished surface forms the chiltern sense, wear-resisting, scratch resistance and skid resistance significantly, can prevent that also the situation that aluminum oxide sand comes off from producing.
Description of drawings
Fig. 1 is traditional plastic floor tile external coating process block diagram.
Fig. 2 is traditional plastic floor tile external coating schematic flow sheet.
Fig. 3 is the generalized section that tradition is added the plastic floor tile of aluminium oxide.
Fig. 4 is that tradition is added silica (SiO
2) the generalized section of plastic floor tile.
Fig. 5 is the schematic perspective view of traditional plastic floor tile.
Fig. 6 is a process block diagram of the present invention.
Fig. 7 is a manufacturing process schematic diagram of the present invention.
Fig. 7 A, Fig. 7 B, Fig. 7 C are respectively the local enlarged diagram of A among Fig. 7, B, C.
Fig. 8 is a generalized section of utilizing the plastic floor tile of specific embodiment of the invention production.
Fig. 9 is the schematic perspective view that utilizes the plastic floor tile of specific embodiment of the invention production.
The figure number explanation:
Plastic floor tile finished product 1A semi-finished product 10A roller coating 100A roller 101A
Aluminium oxide sensitization UV resin 11A aluminium oxide 110A sensitization UV resin 111A
Silica (SiO
2) sensitization UV resin 12A silica (SiO
2) 120A
UV light irradiation sclerosis 200A
The 1 plastic floor tile semi-finished product 10 roller coating for the first time 100 of wear resistant plastic floor tile finished product
Roller is coated with 101 sensitization UV resins, 11 aluminum oxide sand, 12 sensitization UV resins 13
Sand-blasting machine spray coating 200 sand-blasting machines 201 UV lamps shine 300 for the first time
For the second time roller is coated with 400 rollers and is coated with 401 UV lamps and shines 500 for the second time
The electric fan 600 material receiving desks 700 roller coating for the first time situation A that dispel the heat
Sand-blasting machine sprays situation B roller coating for the second time situation C
The specific embodiment
For making the reader more detailed clear and definite understanding can be arranged, now enumerate preferred embodiment and conjunction with figs. is described in detail as follows to purpose of the present invention, effect and structural feature:
Please cooperate and consult Fig. 6, Fig. 7, Fig. 7 A, Fig. 7 B, Fig. 7 C, Fig. 8 and shown in Figure 9, its be respectively A, B, C among process block diagram of the present invention, manufacturing flow chart of the present invention, Fig. 7 of the present invention local enlarged diagram, utilize the generalized section and the schematic perspective view of the product that method of the present invention produces, by diagram as can be known, plastic floor tile of the present invention surface coating method of alumina, include following steps: plastic floor tile semi-finished product 10 loading bays are got the raw materials ready; Sensitization UV resin 11 roller coating for the first time 100; Spray aluminum oxide sand 12; UV light irradiation sclerosis for the first time 300; Sensitization UV resin 13 roller coating for the second time 400; UV light irradiation sclerosis for the second time 500; Radiator fan cooling 600; Wear resistant plastic floor tile finished product 1 material receiving desk 700 places etc.Each step embodiment is described in detail as follows respectively:
Initial in plastic floor tile of the present invention surface coating method of alumina, plastic floor tile semi-finished product 10 are positioned over the preparation reprocessing of getting the raw materials ready on the loading bay, be coated with sensitization UV resin 11 with the one group of coating apparatus mode of roller coating 101 (in the present embodiment with) equably on the surface of plastic floor tile semi-finished product 10, then with spraying equipment on the surface of the sensitization UV resin 11 of the unhardened first time of roller coating 100 still equably to add spray pattern spray coating aluminum oxide sand 12.Wherein employed spraying equipment can be sand-blasting machine 201.Because of the present invention is the mode of utilizing sand-blasting machine spray coating 200, so can make aluminum oxide sand 12 can be attached to the surface of sensitization UV resin 11 fully, and make aluminum oxide sand 12 can protrude the surface that is distributed in sensitization UV resin 11 equably, and formation and ceramic stone and ground building material surface have the atomized surface effect of identical chiltern sense; And this spray pattern can be not heavier because of the proportion of aluminum oxide sand 12, and the situation that causes aluminum oxide sand 12 to fall in the sensitization UV resin 11 takes place.
Afterwards, UV lamp 300 with a group or more shines on the plastic floor tile semi-finished product 10 of the sensitization UV resin 11 that is attached with aluminum oxide sand 12 for the first time again, after making that sensitization UV resin 11 hardens because of the UV lamp shines 300 generation chemical changes for the first time, aluminum oxide sand 12 can be adhered to fully with sensitization UV resin 11 and combined, and aluminum oxide sand 12 can not come off because of external force easily.Sensitization UV resin 11 on these plastic floor tile semi-finished product 10 is attached with aluminum oxide sand 12; after the UV lamp shines 300 for the first time; with one group of coating apparatus sensitization UV resin roller 13 second time is coated with 400 on aluminum oxide sand 12 again; wherein utilize the mode of roller coating 401; can make sensitization UV resin 13 be attached to the surface of aluminum oxide sand 12 equably; the roller coating second time 400 described here can make aluminum oxide sand 12 be coated in the sensitization UV resin 13; and then shine not the sensitization UV resin 13 of sclerosis fully in a group or more UV lamp 500 the mode of shining for the second time; make this sensitization UV resin 13 produce chemical changes and harden; cause aluminum oxide sand 12 more to be coated on two-layer sensitization UV resin 11 fully in consolidation ground; in 13; and then aluminum oxide sand 12 more can not come off because of external force easily; and more increase the wear-resisting of aluminum oxide sand 12; the effect of scratch resistant property and skid resistance; 13 coatings of this sensitization UV resin are covered on the aluminum oxide sand 12; can make aluminum oxide sand 12 skins as covering the protective layer that one deck has the protection effect; except aluminum oxide sand 12 is not come off because of external force; also formation and ceramic stone and ground building material surface have the atomized surface effect of identical chiltern sense, more can make aluminum oxide sand 12 surfaces be formed with one and have splendid tack; wearability; scratch resistance; corrosion resistance; crushing resistance; and the protective layer of third dimension lines.At last, utilize heat abstractor (being electric fan heat radiation 600 in the present embodiment) to cool off and be coated with sensitization UV resin bed the second time of having hardened, the wear resistant plastic floor tile finished product 1 of surperficial tool wearability is delivered to material receiving desk 700 deposit, promptly finish the overall process of plastic floor tile surface coating aluminium oxide.
Please cooperate and consult shown in Fig. 7 A, Fig. 7 B, Fig. 7 C, it is the local enlarged diagram of A, B, C among Fig. 7, as shown in the figure as can be known, in plastic floor tile of the present invention surface coating method of alumina, the situation of roller coating for the first time A is the situation for sensitization UV resin 11 roller coating for the first time 100; Sand-blasting machine sprays situation B and utilizes sand-blasting machine equably aluminum oxide sand to be sprayed on situation on the sensitization UV resin 11 of roller coating for the first time 100, aluminum oxide sand 12 can be attached to fully on the sensitization UV resin 11 of the roller coating first time 100, and aluminum oxide sand 12 can not come off because of external force easily; The situation of roller coating for the second time C is the situation for sensitization UV resin 13 roller coating for the second time 400; because of sensitization UV resin 13 roller coating for the second time 400 can make the protective layers that cover one deck tool protection effect on the aluminum oxide sand 12 more; make that aluminum oxide sand 12 is more difficult to come off because of external force causes; and because of sensitization UV resin 13 roller coating for the second time 400; make plastic floor tile finished product 1 not only because of aluminum oxide sand 12 has anti-skidding effect, have more the effect of wear-resisting, scratch resistance and third dimension lines.
In sum, the method for plastic cement floor tile surface-coated aluminium oxide of the present invention has following advantages:
1, sprays the mode of oxidation aloxite with external-added, can make the oxidation aloxite coat equably tool Have on the plastic cement floor tile surface of semi-finished of sensitization UV resin;
2, spray the mode of oxidation aloxite with external-added, make the unlikely generation of oxidation aloxite fall to sensitization UV Situation in the resin;
3, can promote wearability and the scratch resistance of finished surface through twice coating operation of sensitization UV resin;
4, through twice coating operation of sensitization UV resin, the more difficult generation of oxidation aloxite is come off;
5, utilize the processing procedure of external-added spray pattern coating oxidation aloxite, the oxidation aloxite is coated on two Among the layer sensitization UV cold coating, can form with ceramic stone material and floor building material has identical chiltern sense The cloudy surface effect;
6, plastic cement floor tile finished surface can form tool third dimension lines and anti-skidding effect.
In a word, the processing procedure of plastic cement floor tile surface-coated aluminium oxide of the present invention has above-mentioned many excellent Point is the practicality invention with innovation, and the spy proposes the application in accordance with the law.
Claims (8)
1, a kind of plastic floor tile surface coating method of alumina mainly is to utilize to add formula spray pattern coating aluminium oxide, and aluminum oxide sand is coated among the two-layer sensitization UV cold coating, and its step is as follows:
A. the plastic floor tile semi-finished product being positioned over gets the raw materials ready on the loading bay prepares reprocessing;
B. be coated with for the first time sensitization UV resin equably on the half-finished surface of plastic floor tile with one group of coating apparatus;
C. be coated with on the sensitization UV resin surface in the first time of not hardening fully with spraying equipment and spray aluminum oxide sand;
D. shining sclerosis for the first time with a group or more UV lamp has finished the spraying of sensitization UV resin surface and has adhered to the plastic floor tile semi-finished product of aluminum oxide sand;
E. be attached with on the surface of aluminum oxide sand at the plastic floor tile semi-finished product that shone for the first time the UV lamp, be coated with sensitization UV resin for the second time with one group of coating apparatus;
F. the UV lamp with a group or more shines the surface that sclerosis is coated with sensitization UV resin for the second time for the second time;
G. utilize heat abstractor to cool off and be coated with sensitization UV resin the second time of having hardened;
H. surperficial tool is wear-resisting plastic floor tile finished product is delivered to material receiving desk and is placed and deposit.
2, plastic floor tile surface coating method of alumina according to claim 1, wherein, described coating apparatus is the roller coating apparatus.
3, plastic floor tile surface coating method of alumina according to claim 1, wherein, described coating apparatus is for being attached to coating the equipment on plastic floor tile surface.
4, plastic floor tile surface coating method of alumina according to claim 1, wherein, described spraying equipment is for realizing the sand-blasting machine of spray coating.
5, plastic floor tile surface coating method of alumina according to claim 1, wherein, described twice coating sensitization UV resin is coated on aluminum oxide sand wherein, makes the plastic floor tile finished product have good wearability.
6, plastic floor tile surface coating method of alumina according to claim 1, wherein, described aluminum oxide sand makes the plastic floor tile finished product have good wear-resisting, skid resistance.
7, plastic floor tile surface coating method of alumina according to claim 1, wherein, described heat abstractor is a radiator fan.
8, plastic floor tile surface coating method of alumina according to claim 1, wherein, the described type of cooling is the natural wind cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310117146 CN1273225C (en) | 2003-12-02 | 2003-12-02 | Process for coating aluminium oxide at surface of plastic floor tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310117146 CN1273225C (en) | 2003-12-02 | 2003-12-02 | Process for coating aluminium oxide at surface of plastic floor tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1623681A true CN1623681A (en) | 2005-06-08 |
| CN1273225C CN1273225C (en) | 2006-09-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310117146 Expired - Fee Related CN1273225C (en) | 2003-12-02 | 2003-12-02 | Process for coating aluminium oxide at surface of plastic floor tile |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100439059C (en) * | 2003-12-12 | 2008-12-03 | 美喆国际企业股份有限公司 | Plastic floor tile in features of ceramic tile, and manufacturing method |
| CN101589927A (en) * | 2008-03-17 | 2009-12-02 | 约瑟芬·莫雷蒂 | Exfoliating shower mat |
| CN102635220A (en) * | 2012-04-17 | 2012-08-15 | 郑祯勋 | Anti-scalding structure of plastic floor and preparation process thereof |
| CN104069977A (en) * | 2013-03-28 | 2014-10-01 | 三星显示有限公司 | Deposition apparatus, method for forming thin film using the same, organic light emitting display apparatus and method for manufacturing the same |
-
2003
- 2003-12-02 CN CN 200310117146 patent/CN1273225C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100439059C (en) * | 2003-12-12 | 2008-12-03 | 美喆国际企业股份有限公司 | Plastic floor tile in features of ceramic tile, and manufacturing method |
| CN101589927A (en) * | 2008-03-17 | 2009-12-02 | 约瑟芬·莫雷蒂 | Exfoliating shower mat |
| CN102635220A (en) * | 2012-04-17 | 2012-08-15 | 郑祯勋 | Anti-scalding structure of plastic floor and preparation process thereof |
| CN104069977A (en) * | 2013-03-28 | 2014-10-01 | 三星显示有限公司 | Deposition apparatus, method for forming thin film using the same, organic light emitting display apparatus and method for manufacturing the same |
| CN104069977B (en) * | 2013-03-28 | 2018-10-09 | 三星显示有限公司 | Depositing device, film forming method, oganic light-emitting display device and manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1273225C (en) | 2006-09-06 |
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