CN1414198A - Curlable resin like construction wall surface decorative material and its preparation method - Google Patents

Curlable resin like construction wall surface decorative material and its preparation method Download PDF

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Publication number
CN1414198A
CN1414198A CN 02119647 CN02119647A CN1414198A CN 1414198 A CN1414198 A CN 1414198A CN 02119647 CN02119647 CN 02119647 CN 02119647 A CN02119647 A CN 02119647A CN 1414198 A CN1414198 A CN 1414198A
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Prior art keywords
resin
polyurethane
emulsion
kilogram
screen cloth
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CN 02119647
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Chinese (zh)
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CN1186510C (en
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巢启
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Abstract

The present invention discloses a coilable resin building wall facing decorative material and its preparation method. The present invention mainly uses resin as raw material, and forms into shape in a mould. It possesses the advantages of thin, coilable, strong weatherability, fastness to water, not sticky in high temperature, not brittle under low temperature, apparent stone imitation effect, easy to construct, low cost, etc..

Description

A kind of resin building metope face decoration material and preparation method of curling
What the present invention relates to is a kind of building wall face decoration material, particularly a kind of resin building metope face decoration material that curls, and this preparation methods.
At present, building wall face decoration material commonly used is marble, Hua Gangyan, ceramic tile, mosaic, coating etc., marble, spend the weight of firm rock self, make difficulty of construction very big, be difficult to it is sticked on surface of wall securely, be not suitable for highrise building, along with the technological progress of constructional materials, the use of ceramic tile, mosaic also is restricted, the substitute is coating, but coating there is its shortcoming that is difficult to overcome equally, mainly shows: easily be full of cracks, poor water resistance, easily peeling easily after-tacks constructional difficulties, material texture is not remarkable, and the cost height.Application number by inventor's invention is called for the 01114257.X name: the Chinese invention patent application of " a kind of building faced decorative material made from coating ", though overcome the defective of the said goods, but this invention also still has some deficiency, the place of its deficiency mainly is when environment temperature is higher, product surface easily after-tacks, thereby influenced attractive in appearance and life-span of surface of wall, and can be crisp hard when environment temperature is lower than 15 ℃ Celsius, easily jackknifing.In addition, yet there are no the report of other more advanced exterior wall face decoration material, do not see that particularly useful resin is prepared into the report of the building wall face decoration material that can curl.
One object of the present invention just provides a kind of resin building metope face decoration material that curls, thereby overcomes the existing deficiency of above-mentioned building faced decorative material.Another object of the present invention just provides a kind of preparation method of the resin building metope face decoration material that curls.
For achieving the above object, the present invention has taked such measure: a kind of resin building metope face decoration material that curls, mainly form by following raw material, and when the present invention was one square metre, raw material and amount thereof were:
Surface resin 0.3-1.5 kilogram
1 square of intensity is supported screen cloth 1-2 layer
Base resin 0.2-1.0 kilogram
Colored sheet material 0.2-3.0 kilogram;
Described surface resin is meant the resin of product surface layer, specifically refers to the reaction-curable resin, as unsaturated polyester resin, and epoxy resin, aliphatic polyurethane resin, acrylic acid-polyurethane etc.; Hot-melt resin is as polymethyl methacrylate, polystyrene, polyester, polyamide, polyethylene, polyurethane, polypropylene etc.; Solvent type resin is as polyester, Merlon, acrylic resin and emulsion, organosilicon-acrylic acid-grafted resin and emulsion, aliphatic polyurethane and emulsion, fluorocarbon resin;
Described base resin is meant the resin of product bottom surface layer, specifically refers to the reaction-curable resin, as unsaturated polyester resin, and epoxy resin, polyurethane resin etc.; Hot-melt resin, as polymethyl methacrylate, polystyrene, polyester, polyamide, polyethylene, polypropylene, various rubber, modified bitumen, polyurethane, polyvinyl chloride or reclaim again old plastics of usefulness etc., soluble resin is as acrylic resin and emulsion, organic-silicon-modified propylene and emulsion, polyurethane and emulsion, polyester, Merlon;
Described intensity supports screen cloth to be meant that the gauge is glass fiber screen cloth or the 10-200 purpose wire gauze or the resin screen cloth of 4 * 4-12 * 12;
Described colored sheet material refers to the sheet flag of 2-30 mm dia or the artificial colour coating and the resin flake of 2.0-120 mm dia, and thickness is at the 0.5-4 millimeter.
Colour stone grains is meant the natural of 0.5-4 millimeter or artificial colour stone grain.
The invention described above is prepared from by following step:
(1) surface resin is evenly coated on the mould, made its curing according to the condition of cure of different resins;
(2) on the surface resin that solidifies, lay one deck intensity and support screen cloth;
(3) evenly be coated with the upper surface resin again;
(4) take advantage of the surface resin that is coated with and evenly spill cloth enamel sheet material and 40-120 purpose stone flour when not dried, under the condition of cure that institute's coating resin needs, solidify, and the demoulding;
(5) the colored sheet surface sand milling after the surface resin curing is smooth, lay intensity then and support that screen cloth is coated with base resin more equably, and under the required condition of cure of resin, solidify.Also can use and paste the resin base resin plate stickup shaping of curing molding in the smooth colored sheet surface of sand milling.
Taking the present invention of above-mentioned measure, is the ideal substitute of building wall face decoration material, and its anti-aging time ratio coating prolongs greatly, water resistance is strong, in water, soak do not whiten for a long time arbitrarily, swelling, indeformable not, high temperature to 70 ℃ does not after-tack, low temperature to-10 ℃ not crisp hard.In addition, the present invention also has following characteristics:
(1) the present invention does the surface with stripping surface, and it is stronger ornamental that its surface is had, and the surface can be finer and close, more regular, overcome ceramic tile, spent the shortcoming of firm rock surface reflection and the easy loss of gloss of buffed surface, the surface of hommization simultaneously can make decorated surface effect more graceful.
(2) case hardness of the present invention is big, and high-intensity surface resin makes surface of the present invention produce anti-ruled area, and the use of the thin structure and the end, veil cloth, make the present invention have very strong fold resistance, can curl, the effect of tempering toughness with gentleness occur, sticking can buckling deformation behind the metope.
(3) the present invention is block, thickness is the 1.5-5 millimeter, in light weight is another characteristics of the present invention, thereby can overcome big, the difficult construction of weight of surface linings such as Hua Gangyan, marble, ceramic tile, the shortcoming that cost is high, and has the surface effect that is better than these materials.
Below in conjunction with embodiment the present invention is done further to describe in detail:
Embodiment 1
Composition of raw materials: 0.3 kilogram of epoxy resin
2 layers of 1 square of 4 * 4 glass fiber meshs
0.2 kilogram of acrylic resin (solvent borne)
8-15 mm dia and 2-5 mm dia, thickness 1-2.5 millimeter artificial colour
0.8 kilogram and 0.4 kilogram of paint flakes
3.0 kilograms of 40-120 order stone flours
Preparation method: on 1 square metre mould, be coated with 0.15 kilogram of epoxy resin equably, spontaneous curing at normal temperatures, apply 1 square metre of specification then and be 6 * 6 glass fiber mesh, evenly be coated with last 0.15 kilogram of epoxy resin again, take advantage of its uncured artificial colour paint flakes that evenly to sprinkle 0.8 kilogram of diameter be the 8-15 millimeter, the thin slice of 0.4 kilogram of 3-5 mm dia will be sprinkled after the unnecessary thin slice of bonding is not removed again, evenly sprinkle 1.5 kilograms of 40-120 purpose stone flours then, be allowed to condition at spontaneous curing under the normal temperature condition, the demoulding.The glass fiber mesh that applies 1 square metre 6 * 6 on the epoxy resin that solidifies evenly is coated with 0.2 kilogram solvent-type acrylic resin again, evenly sprinkles 1.5 kilograms of 40-120 purpose stone flours then, and air dry is solidified under normal temperature condition.Its stripping surface is the forming surface of product, the present invention that can obtain 1 square metre of thickness this moment is the 1.5-2 millimeter.
Embodiment 2
Composition of raw materials: 1.5 kilograms of epoxy resin
2 layers of 1 square of 12 * 12 glass fiber meshs
1.0 kilograms of elastomeric propylene yogurt liquid
3.0 kilograms of the colored sheet carpolites of 10-80 mm dia
4.0 kilograms of 40-120 order stone flours
Preparation method: on 1 square metre mould, be coated with 0.15 kilogram of epoxy resin equably, spontaneous curing at normal temperatures, apply 1 square metre of specification then and be 12 * 12 glass fiber mesh, evenly be coated with last 1.35 kilograms of epoxy resin again, take advantage of its uncured colored sheet carpolite that evenly sprinkles 3.0 kilograms of 1-80 mm dias, evenly sprinkle 1.5 kilograms of the stone flours of 40-120 then, be allowed to condition at spontaneous curing under the normal temperature condition, the demoulding.On the epoxy resin that solidifies, apply 1 square metre 12 * 12 glass fiber mesh, evenly be coated with 1.0 kilograms of elastomeric propylene yogurt liquid again, be mixed with 2.0 kilograms of 40-120 purpose stone flours in the emulsion, air dry is solidified under normal temperature condition. and its stripping surface is the forming surface of product, the present invention that can obtain 1 square metre of thickness this moment is the 4-5 millimeter.
Embodiment 3
Composition of raw materials: 1.0 kilograms of unsaturated polyester resins (import auxiliary agent)
2 layers of 1 square of 100 order nylon screen cloths
1.0 kilograms of aromatic series (70% solid content) polyurethane resins
The 30-120 mm dia is thick to be 1.5 kilograms of the artificial colour resin flakes of 1-3 millimeter
3.0 kilograms of 40-120 order stone flours
Preparation method: press the preparation method of above-mentioned raw materials prescription, the present invention that can to obtain 1 square metre of thickness be the 2.5-4 millimeter with reference to embodiment 1.
Embodiment 4
Composition of raw materials: 0.5 kilogram of polymethyl methacrylate
0.5 kilogram of unsaturated polyester resin
1 layer of 1 square of 200 order wire gauze
1 layer of 1 square of 6 * 6 glass fiber screen cloth
1.0 kilograms of polyurethane modified bitumens
8-15 mm dia and 2-5 mm dia, thickness be the 1-2.5 millimeter the artificial colour thin slice each 0.8 kilogram and 0.4 kilogram
3.0 kilograms of 40-120 order stone flours
The preparation method: 0.5 kilogram of polymethyl methacrylate behind the hot melt after film forming on the mould is solidified, apply 200 order wire gauzes, evenly be coated with last 0.5 kilogram of unsaturated polyester resin again, carry out the present invention that can to obtain 1 square metre of thickness be the 2-3.5 millimeter then by the preparation method of above-mentioned raw materials prescription with reference to embodiment 1.
Embodiment 5
Composition of raw materials: 0.2 kilogram of aliphatic polyurethane resin (no-solvent type)
1.5 kilograms of unsaturated polyester resins
1 layer of 1 square of 40 order nylon screen cloth
1 layer of 1 square of 6 * 6 glass fiber screen cloth
8-15 mm dia and 2-5 mm dia, thickness be the 1-2.5 millimeter the artificial colour thin slice each 0.8 kilogram and 0.4 kilogram
3.0 kilograms of 40-120 order stone flours
The preparation method: polyurethane resin applies 40 order nylon screen cloths after film forming on the mould is solidified, undertaken by the preparation method of above-mentioned raw materials prescription with reference to embodiment 1 then, the present invention that can to obtain 1 square metre of thickness be the 1.5-3 millimeter.
Embodiment 6
Composition of raw materials: 0.6 kilogram of polyester
1.2 kilograms of unsaturated polyester resins
1 layer of 1 square of 8 * 8 glass fiber mesh
8-15 mm dia and 2-5 mm dia, thickness be the 1-2.5 millimeter the artificial colour thin slice each 0.8 kilogram and 0.4 kilogram
0.6 kilogram of polyethylene
2.0 kilograms of 40-120 order stone flours
The preparation method: polyester applies the glass fiber screen cloth in film forming curing on mould behind the hot melt, coats 0.5 kilogram of unsaturated polyester resin, sprinkles artificial colour thin slice and stone flour, treats its curing, the demoulding.Artificial colour thin slice sand milling after will solidifying then is smooth, coat 0.7 kilogram of unsaturated polyester resin, press the polyethylene board that under the hot melt state, is prepared into 0.6 kilogram of/square metre consumption in advance, exhaust air, the present invention that can to obtain 1 square metre of thickness be the 2.5-4 millimeter with the embossing plate mould.

Claims (4)

1, a kind of resin building metope face decoration material that curls is characterized in that described ornament materials mainly is made up of following raw material, and when the present invention was one square metre, raw material and amount thereof were:
Surface resin 0.3-1.5 kilogram
1 square of intensity is supported screen cloth 1-2 layer
Base resin 0.2-1.0 kilogram;
Described surface resin is meant the resin of product surface layer, specifically refers to the reaction-curable resin, as unsaturated polyester resin, and epoxy resin, aliphatic polyurethane resin, acrylic acid-polyurethane etc.; Hot-melt resin is as polymethyl methacrylate, polystyrene, polyester, polyamide, polyethylene, polyurethane, polypropylene etc.; Solvent type resin is as polyester, Merlon, acrylic resin and emulsion, organosilicon-acrylic acid-grafted resin and emulsion, aliphatic polyurethane and emulsion, fluorocarbon resin;
Described base resin is meant the resin of product bottom surface layer, specifically refers to the reaction-curable resin, as unsaturated polyester resin, and epoxy resin, polyurethane resin etc.; Hot-melt resin, as polymethyl methacrylate, polystyrene, polyester, polyamide, polyethylene, polypropylene, various rubber, modified bitumen, polyurethane, polyvinyl chloride or reclaim again old plastics of usefulness etc., soluble resin is as acrylic resin and emulsion, organic-silicon-modified propylene and emulsion, polyurethane and emulsion, polyester, Merlon;
Described intensity supports screen cloth to be meant that the gauge is glass fiber screen cloth or the 10-200 purpose wire gauze or the resin screen cloth of 4 * 4-12 * 12.
2, ornament materials according to claim 1 is characterized in that also comprising in the described raw material colored sheet material 0.2-3.0 kilogram;
Described colored sheet material refers to the colored sheet carpolite of 2-30 mm dia or the artificial colour paint flakes of 2.0-120 mm dia, and its thickness is at the 0.5-4 millimeter.
3, want 1 or 2 described ornament materials according to right, it is characterized in that described ornament materials thickness is the 1.5-5 millimeter, can curl.
4, a kind of preparation method of the resin building metope face decoration material that curls is characterized in that described ornament materials is prepared from by following step:
(1) surface resin is evenly coated on the mould, made its curing according to the condition of cure of different resins;
(2) on the surface resin that solidifies, lay intensity and support screen cloth;
(3) evenly be coated with the upper surface resin again;
(4) take advantage of the surface resin that is coated with and evenly spill cloth enamel sheet material and stone flour when not dried, make its curing according to the condition of cure of different resins, and the demoulding;
(5) the colored sheet surface sand milling after the surface resin curing is smooth, lay intensity then and support that screen cloth is coated with base resin more equably, and under the required condition of cure of resin, solidify; Also can use and paste the resin base resin plate stickup shaping of curing molding in the smooth colored sheet surface of sand milling.
CN 02119647 2002-05-15 2002-05-15 Curlable resin like construction wall surface decorative material and its preparation method Expired - Fee Related CN1186510C (en)

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Application Number Priority Date Filing Date Title
CN 02119647 CN1186510C (en) 2002-05-15 2002-05-15 Curlable resin like construction wall surface decorative material and its preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02119647 CN1186510C (en) 2002-05-15 2002-05-15 Curlable resin like construction wall surface decorative material and its preparation method

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CN1414198A true CN1414198A (en) 2003-04-30
CN1186510C CN1186510C (en) 2005-01-26

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101563238A (en) * 2006-10-18 2009-10-21 新技术资源公司 Polymer or composite wall and surface veneering products, systems and methods of use thereof
CN102248850A (en) * 2011-04-23 2011-11-23 章文军 Production process of artificial jade with colored filament
CN101270240B (en) * 2007-12-02 2011-12-14 巢启 Color piece for building paint and preparing method
CN101100124B (en) * 2006-07-03 2012-06-06 崔勇 Fluorocarbon luminous wainscot and its manufacturing method
CN102733574A (en) * 2012-07-03 2012-10-17 福建省南安市荣达建材有限公司 Color change facing brick and manufacture method of color change facing brick
CN102876098A (en) * 2012-09-26 2013-01-16 苏州汾湖电梯有限公司 Tapestry-imitation decorative coating for aluminum alloy panel of elevator
CN104131677A (en) * 2014-08-19 2014-11-05 广西启利新材料科技股份有限公司 Method for preparing laminated boards by rock slices
CN107299740A (en) * 2017-08-03 2017-10-27 安徽真信涂料有限公司 A kind of metope building and ornament materials
CN110512812A (en) * 2019-08-28 2019-11-29 成都新柯力化工科技有限公司 A kind of building decoration flexibility imitation stone patch and preparation method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101100124B (en) * 2006-07-03 2012-06-06 崔勇 Fluorocarbon luminous wainscot and its manufacturing method
CN101563238A (en) * 2006-10-18 2009-10-21 新技术资源公司 Polymer or composite wall and surface veneering products, systems and methods of use thereof
CN101270240B (en) * 2007-12-02 2011-12-14 巢启 Color piece for building paint and preparing method
CN102248850A (en) * 2011-04-23 2011-11-23 章文军 Production process of artificial jade with colored filament
CN102248850B (en) * 2011-04-23 2013-05-15 章文军 Production process of artificial jade with colored filament
CN102733574A (en) * 2012-07-03 2012-10-17 福建省南安市荣达建材有限公司 Color change facing brick and manufacture method of color change facing brick
CN102876098A (en) * 2012-09-26 2013-01-16 苏州汾湖电梯有限公司 Tapestry-imitation decorative coating for aluminum alloy panel of elevator
CN104131677A (en) * 2014-08-19 2014-11-05 广西启利新材料科技股份有限公司 Method for preparing laminated boards by rock slices
CN107299740A (en) * 2017-08-03 2017-10-27 安徽真信涂料有限公司 A kind of metope building and ornament materials
CN110512812A (en) * 2019-08-28 2019-11-29 成都新柯力化工科技有限公司 A kind of building decoration flexibility imitation stone patch and preparation method

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