CN1621393A - Minim calcium element chelated foliage fertilizer - Google Patents
Minim calcium element chelated foliage fertilizer Download PDFInfo
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- CN1621393A CN1621393A CN 200310106000 CN200310106000A CN1621393A CN 1621393 A CN1621393 A CN 1621393A CN 200310106000 CN200310106000 CN 200310106000 CN 200310106000 A CN200310106000 A CN 200310106000A CN 1621393 A CN1621393 A CN 1621393A
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Abstract
The present invention relates to foliage fertilizer, and is especially one kind of foliage fertilizer with medium amount of calcium element chelate. By means of three production processes of acidolysis, acid and alkali hydrolysis and comprehensive utilization, waste protein material is prepared into ion level organic component. The product has amino acid content of 5-20 wt% and calcium content of 12-17 wt%. The said foliage fertilizer is easy to hydrolyze, and has reasonable components, obvious fertilizer effect and high bioavailability.
Description
Affiliated technical field
The present invention relates to a kind of foliar nutrient, particularly relate to a kind of novel middle micro-calcium element chelating preparation foliage fertilizer.
Background technology
The agriculture at present calcareous fertilisers of going up use are broadly divided into two kinds: a kind of is the inorganic calcium salt crystal, because it is a molecular crystal, the calcium constituent composition of molecular level is difficult to by plant absorbing, and utilization ratio is very low.Second kind is complexing calcium crystal, though there is complexing calcium attitude calcium ion, is utilized by plant absorbing easily, and it is difficult for molten water, uses inconvenience, the cost height, and fertilizer efficiency can not be guaranteed.
Summary of the invention
The objective of the invention is: a kind of novel middle micro-calcium element chelating preparation foliage fertilizer is provided. its facile hydrolysis, inner nutritive ingredient reasonable ratio, fertilizer efficiency is fairly obvious, and plant absorbing rate utilization ratio height can satisfy the greatest requirements of plant absorbing.
The technical solution adopted in the present invention is: design a kind of novel micro calcium constituent chelating foliage fertilizer, it adopts acid hydrolyzation, acid, alkali hydrolysis method, three kinds of different production technique of comprehensive use, with waste protein is raw material, become the calcic organic composition of ion level through the hydrolysis chelating, the aminoacids content of big this product of production cost is 15%～～20%, and the content of calcium is 12%～～17%.
The characteristics of described acid hydrolyzation are to make aminoacids complex behind the depleted proteolysis, and then through neutralization, chelating generates inner complex.
The invention has the beneficial effects as follows: the present invention compares advantage and is to adopt the protein calcium constituent, facile hydrolysis, inner nutritive ingredient reasonable ratio with traditional foliage fertilizer, utilized easilier by plant absorbing, improved the utilization ratio of plant to fertilizer efficiency, and stable performance, easily store easy to use.The raw material abundance that the present invention is used and cheap, production technique is simple, has very wide promotion prospect.Be raw materials for production owing to the present invention adopts depleted protein simultaneously, production cost reduces greatly.It is raw material with protein, chelating amino acids calcic foliage fertilizer through the generation of hydrolysis chelating, it compares biggest advantage with existing common blade face calcareous fertilisers: its facile hydrolysis, inner nutritive ingredient reasonable ratio, fertilizer efficiency is fairly obvious, plant absorbing rate, utilization ratio height can satisfy the greatest requirements of plant absorbing.
Description of drawings:
Fig. 1 is embodiment 1 an acid hydrolyzation process flow sheet.
Fig. 2 is embodiment 2 acid, the alkali hydrolysis method process flow sheet.
Fig. 3 is the chelating artwork of trace elements calcium in embodiment 3 aminoacids complexs.
Embodiment:
Embodiment 1:(acid hydrolyzation)
The characteristics of acid hydrolyzation are to make aminoacids complex behind the depleted proteolysis, then through neutralization, chelating generates inner complex, manufacture craft as shown in Figure 1, the entire making process of acid hydrolyzation adopts a whole set of chemical technology, at first collect depleted protein water, the HCI of adding 30% is hydrolyzed in protein water, whole solion becomes acid after the hydrolysis, and then the NaOH that adds alkalescence neutralizes, and makes whole protein water soln become neutral, add the CaOH chelating then, concentrate, drying is made the calcium finished product at last.Thereby finish whole manufacture craft.The organic component content scope of this finished product exists: amino acid/11 5%-20%; Calcium 12%-17%.
Embodiment 2:(acid, alkali hydrolysis method)
Adopt acid, alkali hydrolysis method: earlier with two kinds of acid, alkaline solution hydrolysis respectively mixes two kinds of solution then, and neutralization has been saved the consumption of soda acid, thereby effectively reduced production cost.
Whole manufacture craft is illustrated in fig. 2 shown below.
Acid, the alkali hydrolysis method entire making process has embodied a concentrated reflection of the purpose of conservation, and it carries out acid hydrolysis and basic hydrolysis to protein respectively, mixes neutralization after hydrolysis, removes by filter residue wherein, and chelating adds CaCL in the process of chelating then
2Calcium ion is collected in reaction, carries out concentrate drying again, and last chelating becomes the calcium finished product.
The organic content of this finished product is: amino acid/11 5%-20% calcium 12%-17%
Embodiment 3:(comprehensive use)
This method is to be raw material with the keratoprotein, and substep extracts costly Gelucystine in the keratoprotein, tyrosine, and smart ammonia etc., the chelating technology of trace elements calcium is as shown in Figure 3 in the aminoacids complex.
The content range of the organic composition of this finished product is: amino acid/11 5%-20%; Calcium 12%-17% generally speaking the present invention has its distinctive feature, and it has not only solved traditional blade face plant to the low problem of organic composition absorption rate in the fertilizer, has also effectively solved the high problem of fertilising cost.Have good development and utilize prospect.
Claims (4)
1, novel micro calcium constituent chelating foliage fertilizer, it is characterized in that: it adopts acid hydrolyzation, acid, alkali hydrolysis method, three kinds of different production technique of comprehensive use, with waste protein is raw material, become the calcic organic composition of ion level through the hydrolysis chelating, the product aminoacids content that produces is 15%-20%, and the content of calcium is 12%-17%.
2, novel micro calcium constituent chelating foliage fertilizer according to claim 1 is characterized in that:
Described acid hydrolyzation manufacture craft is as follows: the HCI that will collect adding 30% in the depleted protein water is hydrolyzed, whole solion becomes acid after the hydrolysis, and then the NaOH that adds alkalescence neutralizes, make whole protein water soln become neutral, add the CaOH chelating then, concentrate, drying is made the calcium finished product at last.
3, novel micro calcium constituent chelating foliage fertilizer according to claim 1 is characterized in that: described acid, alkali hydrolysis method: earlier with two kinds of acid, alkaline solution hydrolysis respectively mixes two kinds of solution then, neutralization, saved the consumption of soda acid, whole manufacture craft is as follows; Respectively protein is carried out acid hydrolysis and basic hydrolysis, mix neutralization after hydrolysis, remove by filter residue wherein, chelating adds CaCL in the process of chelating then
2Calcium ion is collected in reaction, carries out concentrate drying again, and last chelating becomes the calcium finished product.
4, novel micro calcium constituent chelating foliage fertilizer according to claim 1, it is characterized in that: described comprehensive use is to be raw material with the keratoprotein, and substep extracts costly Gelucystine in the keratoprotein, tyrosine, smart ammonia etc., the chelating technology of trace elements calcium is as follows in the aminoacids complex; Add hydrochloric acid and be hydrolyzed with keratoprotein hair, pig hair, feather, hydrolysis time 8 hours, temperature is controlled at 105 degree-110 degree, adding a certain amount of ammoniacal liquor again neutralizes, about 4 to 6 hours of time, temperature is controlled at 40 degree, carries out crystallization at last and filters, the crude product that obtains is carried out decolorizing and refining one time, again the crude product of a decolorizing and refining is carried out secondary decolourization refining rough wing propylhomoserin.The mother liquor of a decolorizing and refining crude product is extracted tyrosine, extract leucine from tyrosine again.The filtering mother liquor of crystallization adds CaCL and carries out chelatropic reaction, concentrates, and drying is made chelating calcium finished product at last.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106000 CN1621393A (en) | 2003-11-28 | 2003-11-28 | Minim calcium element chelated foliage fertilizer |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106000 CN1621393A (en) | 2003-11-28 | 2003-11-28 | Minim calcium element chelated foliage fertilizer |
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| CN1621393A true CN1621393A (en) | 2005-06-01 |
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| CN 200310106000 Pending CN1621393A (en) | 2003-11-28 | 2003-11-28 | Minim calcium element chelated foliage fertilizer |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206109A (en) * | 2010-03-29 | 2011-10-05 | 史蒂芬·苏克 | Method of preparing keratin fertilizer with an additive of humic acids in colloid form and keratin fertilizer with humic acids additive |
| CN103086796A (en) * | 2013-01-24 | 2013-05-08 | 广西大学 | Amino acid micro element fertilizer for preventing and treating sugarcane yellow and white seedling, and production method thereof |
| CN103694044A (en) * | 2013-12-13 | 2014-04-02 | 天津泰达园林建设有限公司 | Calcium-containing growth regulator for out-of-season plant transplantation in seashore saline lands |
| CN103708898A (en) * | 2014-01-17 | 2014-04-09 | 云南福发生物科技有限公司 | Method for producing natural amino acid water-soluble fertilizer by utilizing tobacco liquid waste regenerated by paper-making process |
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN106747834A (en) * | 2017-02-16 | 2017-05-31 | 湖南润丰达生态环境科技有限公司 | Compound amino acid zinc fertilizer prepared by a kind of utilization animal hair and preparation method thereof |
| CN112679234A (en) * | 2020-12-28 | 2021-04-20 | 秦皇岛华恒生物工程有限公司 | Comprehensive utilization method of beta-alanine crystallization mother liquor |
-
2003
- 2003-11-28 CN CN 200310106000 patent/CN1621393A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206109A (en) * | 2010-03-29 | 2011-10-05 | 史蒂芬·苏克 | Method of preparing keratin fertilizer with an additive of humic acids in colloid form and keratin fertilizer with humic acids additive |
| CN102206109B (en) * | 2010-03-29 | 2015-01-28 | 史蒂芬·苏克 | Method of preparing keratin fertilizer with an additive of humic acids in colloid form and keratin fertilizer with humic acids additive |
| CN103086796A (en) * | 2013-01-24 | 2013-05-08 | 广西大学 | Amino acid micro element fertilizer for preventing and treating sugarcane yellow and white seedling, and production method thereof |
| CN103086796B (en) * | 2013-01-24 | 2014-10-22 | 广西大学 | Amino acid micro element fertilizer for preventing and treating sugarcane yellow and white seedling, and production method thereof |
| CN103694044A (en) * | 2013-12-13 | 2014-04-02 | 天津泰达园林建设有限公司 | Calcium-containing growth regulator for out-of-season plant transplantation in seashore saline lands |
| CN103694044B (en) * | 2013-12-13 | 2015-06-17 | 天津泰达绿化集团有限公司 | Calcium-containing growth regulator for out-of-season plant transplantation in seashore saline lands |
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN103708892B (en) * | 2013-12-27 | 2015-12-09 | 四川通丰科技有限公司 | A kind of method of producing amino acid secondary element fertilizer |
| CN103708898A (en) * | 2014-01-17 | 2014-04-09 | 云南福发生物科技有限公司 | Method for producing natural amino acid water-soluble fertilizer by utilizing tobacco liquid waste regenerated by paper-making process |
| CN103708898B (en) * | 2014-01-17 | 2015-10-14 | 云南福发生物科技有限公司 | Papermaking-method reconstituted tobaccos waste liquid is utilized to produce the method for natural amino acid Water soluble fertilizer |
| CN106747834A (en) * | 2017-02-16 | 2017-05-31 | 湖南润丰达生态环境科技有限公司 | Compound amino acid zinc fertilizer prepared by a kind of utilization animal hair and preparation method thereof |
| CN112679234A (en) * | 2020-12-28 | 2021-04-20 | 秦皇岛华恒生物工程有限公司 | Comprehensive utilization method of beta-alanine crystallization mother liquor |
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