CN1613945A - Water cement and use for substituted gasoline cement - Google Patents

Water cement and use for substituted gasoline cement Download PDF

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Publication number
CN1613945A
CN1613945A CN 200310103173 CN200310103173A CN1613945A CN 1613945 A CN1613945 A CN 1613945A CN 200310103173 CN200310103173 CN 200310103173 CN 200310103173 A CN200310103173 A CN 200310103173A CN 1613945 A CN1613945 A CN 1613945A
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China
Prior art keywords
agent
water
rubber cement
latex
based rubber
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CN 200310103173
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CN100357383C (en
Inventor
廖国榜
丁薇
吕净生
蔡波
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XINSHIYE INDUSTRIAL DEVELOPING Co Ltd JIANGXI PROV
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XINSHIYE INDUSTRIAL DEVELOPING Co Ltd JIANGXI PROV
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Priority to CNB2003101031738A priority Critical patent/CN100357383C/en
Publication of CN1613945A publication Critical patent/CN1613945A/en
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Publication of CN100357383C publication Critical patent/CN100357383C/en
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Abstract

An aqueous adhesive gel can replace the petrol adhesive gel to bind rubber hose and cone belt fabrics. It is composed of lactoprene, dispersant agent, tackifier, stabilizer, accelerator, activator, vulcanized agent, bulking agent, antiager, mating agent,water. The product is innocuous pollution-free, not easy to fire and has longer retention period of 60-120 days.

Description

The purposes of a kind of water-based rubber cement and alternative gasoline rubber cement thereof
One, technical field
The present invention relates to a kind of rubber cement and uses thereof, particularly relate to the purposes of a kind of water-based rubber cement and alternative gasoline rubber cement thereof.
Two, background technology
Gasoline rubber cement involved in the present invention is meant with the tackify material of gasoline as organic solvent, uses more usually in the sebific duct of braiding or winding arrangement.
At present; Between the infantees layer of between rubber hose rubber and the textile armature and wire belt and the bonding general employing between infantees and the rubber with the rubber cement as organic solvent such as gasoline, its cementability is good, bonding strength is high, but shortcoming has been certain toxicity, environment has been existed pollute, fire hazardous, and because organic solvent is volatile, so be difficult for storage and transport; General nontoxic, pollution-free, the easy preservation of water-based rubber cement, easily transportation, but because bonding back cementability is poor, bonding strength is low, the wire belt industry does not still have the precedent that the water-based rubber cement uses.
Three, summary of the invention
Technical problem to be solved by this invention just provides a kind of above-mentioned two kinds of rubber cement advantages that integrate, and does not have its shortcoming again, is applicable to the water-based rubber cement that rubber hose and wire belt infantees are bonding.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: this aqueous adhesive, be made up of latex, dispersion agent, tackifier, stablizer, promotor, promoting agent, vulcanizing agent, weighting agent, anti-aging agent, Synergist S-421 95, water, the formulation by weight of this water-based rubber cement is:
Latex 30-55 dispersion agent 0.45-0.58 tackifier 9-15
Stablizer 0-0.002 promotor 0.18-0.35 promoting agent 0.3-0.35
Vulcanizing agent 0.5-0.71 weighting agent 4.09-7.9 anti-aging agent 0.21-0.55
Synergist S-421 95 0.12-6 water 15.85-55.09.
Above-mentioned latex is natural gum, neoprene latex, butadiene-styrene rubber, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, Stockholm tar, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, CZ, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are carbon black, light calcium carbonate, anti-aging agent is D, RD, paraffin, 4010, and Synergist S-421 95 is machine oil, carboxyl methylcellulose, tinting material, and water is soft water.
The purposes that above-mentioned water-based rubber cement substitutes the gasoline rubber cement is used for bonding between rubber hose rubber and the textile armature for this water-based rubber cement substitutes the gasoline rubber cement, and the also alternative gasoline rubber cement of this water-based rubber cement is used for bonding between the soaking paste technology of wire belt infantees layer and infantees and the rubber.
Production technique of the present invention is conventional aqueous adhesive production technique.
Technical essential of the present invention is the selection of component prescription and each component content, adopts in which kind of raw material and the same component each material content to select those skilled in the art all can obtain by reference as for each component.
The present invention compared with prior art has following advantage:
1, nontoxic, pollution-free, no disaster hidden-trouble, easily transportation, easily storage help the sebific duct industry, wire belt industry infantees soaking paste is produced to specialized, mass-producing direction and developed;
What 2, be used for rubber hose and wire belt infantees does not bondingly need to change former gasoline rubber cement bonding technical process and processing parameter, substitutes not have technical problem, does not need to invest separately yet;
3, adhesive effect is good, uses in rubber hose, wire belt infantees are produced through units such as Shanghai rubber head factory, Nanjing 7425 factories, and quality product can reach and surpass national standard;
4, the shelf time is long; Gasoline rubber cement preservation period was generally 1-3 days, and product preservation period of the present invention can be more than 60-120 days.
Four, embodiment
The invention will be further described with embodiment below:
Embodiment 1: this water-based rubber cement is made up of latex, dispersion agent, tackifier, stablizer, promotor, promoting agent, vulcanizing agent, weighting agent, anti-aging agent, Synergist S-421 95, water, and its formulation by weight is:
Latex 38 dispersion agents 0.58 tackifier 14.5
Stablizer 0.001 promotor 0.25 promoting agent 0.3
Vulcanizing agent 0.69 weighting agent 6.9 anti-aging agent 0.55
Synergist S-421 95 4.8 water 33.35.
Above-mentioned latex is natural gum and neoprene latex, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, Stockholm tar, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, CZ, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are carbon black, light calcium carbonate, anti-aging agent is D, RD, paraffin, 4010, and Synergist S-421 95 is machine oil, carboxyl methylcellulose, tinting material, and water is soft water.
Embodiment 2: the formulation by weight of this water-based rubber cement is:
Latex 40 dispersion agents 0.58 tackifier 9
Stablizer 0.001 promotor 0.189 promoting agent 0.35
Vulcanizing agent 0.56 weighting agent 4.4 anti-aging agent 0.455
Synergist S-421 95 5.6 water 29.96.
Above-mentioned latex is natural gum and neoprene latex, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, anti-aging agent is D, RD, paraffin, 4010, and Synergist S-421 95 is a carboxyl methylcellulose, and water is soft water.
Embodiment 3: the formulation by weight of this water-based rubber cement is:
Latex 45 dispersion agents 0.58 tackifier 13.03
Stablizer 0.002 promotor 0.18 promoting agent 0.3
Vulcanizing agent 0.5 weighting agent 4.5 anti-aging agent 0.21
Synergist S-421 95 0.98 water 26.7.
Above-mentioned latex is natural gum and butadiene-styrene rubber, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, anti-aging agent is D, and Synergist S-421 95 is a carboxyl methylcellulose, and water is soft water.
Embodiment 4: the formulation by weight of this water-based rubber cement is:
Latex 55 dispersion agents 0.45 tackifier 12.5
Promotor 0.18 promoting agent 0.1 vulcanizing agent 0.6
Weighting agent 4.09 anti-aging agent 0.21 Synergist S-421 95 0.12
Water 26.7.
Above-mentioned latex is a neoprene latex, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, promotor is DM, M, promoting agent is a stearic acid, and vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, and anti-aging agent is D, Synergist S-421 95 is a carboxyl methylcellulose, and water is soft water.
Embodiment 5: the formulation by weight of this water-based rubber cement is:
Latex 54 dispersion agents 0.58 tackifier 9
Stablizer 0.002 promotor 0.32 promoting agent 0.35
Vulcanizing agent 0.56 weighting agent 5.8 anti-aging agent 0.312
Synergist S-421 95 3.3 water 52.78.
Above-mentioned latex is natural gum and butadiene-styrene rubber, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, anti-aging agent is D, RD, paraffin, and Synergist S-421 95 is a carboxyl methylcellulose, and water is soft water.
Embodiment 6: the formulation by weight of this water-based rubber cement is:
Latex 34 dispersion agents 0.6 tackifier 10.3
Promotor 0.32 promoting agent 0.3 vulcanizing agent 0.5
Weighting agent 4.5 anti-aging agent 0.45 Synergist S-421 95 4.7
Water 17.3.
Above-mentioned latex is a butadiene-styrene rubber, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, promotor is DM, M, promoting agent is a stearic acid, and vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, and anti-aging agent is D, Synergist S-421 95 is carboxyl methylcellulose, tinting material, and water is soft water.
Embodiment 7: the formulation by weight of this water-based rubber cement is:
Latex 36 dispersion agents 0.58 tackifier 11.3
Stablizer 0.001 promotor 0.35 promoting agent 0.3
Vulcanizing agent 0.66 weighting agent 7.8 anti-aging agent 0.21
Synergist S-421 95 4.9 water 39.3.
Above-mentioned latex is natural gum and butadiene-styrene rubber, dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are light calcium carbonate, anti-aging agent is D, and Synergist S-421 95 is a carboxyl methylcellulose, and water is soft water.
Production technique of the present invention is as follows:
A, water, tackifier, dispersion agent add reactor, be warming up to 73 ℃ after, add Synergist S-421 95, progressively be warming up to 93 ℃ of circulations, A, be cooled to 73 ℃;
B, with the grinding that is mixed of promotor, anti-aging agent, vulcanizing agent, weighting agent, B;
C, B added in the reactor among 73 ℃ the A, progressively is cooled to normal temperature (15 ℃-40 ℃), add latex and promoting agent, stablizer and be mixed, get final product aqueous binders of the present invention.

Claims (5)

1, a kind of water-based rubber cement, it is made up of latex, dispersion agent, tackifier, stablizer, promotor, promoting agent, vulcanizing agent, weighting agent, anti-aging agent, Synergist S-421 95, water, it is characterized in that: the formulation by weight of this water-based rubber cement is:
Latex 30-55 dispersion agent 0.45-0.58 tackifier 9-15
Stablizer 0-0.002 promotor 0.18-0.35 promoting agent 0.3-0.35
Vulcanizing agent 0.5-0.71 weighting agent 4.09-7.9 anti-aging agent 0.21-0.55
Synergist S-421 95 0.12-6 water 15.85-55.09.
2, water-based rubber cement according to claim 1 is characterized in that: latex is natural gum, neoprene latex, butadiene-styrene rubber.
3, water-based rubber cement according to claim 1, it is characterized in that: dispersion agent is hydrogen peroxide, alizarin assistant, ethylene glycol, tackifier are coumarone, Stockholm tar, rosin, 107 glue, stablizer is an ammoniacal liquor, and promotor is DM, M, CZ, and promoting agent is a stearic acid, vulcanizing agent is that SULPHUR POWDER, zinc oxide, weighting agent are carbon black, light calcium carbonate, anti-aging agent is D, RD, paraffin, 4010, and Synergist S-421 95 is machine oil, carboxyl methylcellulose, tinting material, and water is soft water.
4, the described water-based rubber cement of a kind of claim 1 substitutes the purposes of gasoline rubber cement, it is characterized in that: this water-based rubber cement substitutes the gasoline rubber cement and is used for bonding between rubber hose rubber and the textile armature.
5, the described water-based rubber cement of a kind of claim 1 substitutes the purposes of gasoline rubber cement, it is characterized in that: this water-based rubber cement substitutes the gasoline rubber cement and is used for bonding between the soaking paste technology of wire belt infantees layer and infantees and the rubber.
CNB2003101031738A 2003-11-06 2003-11-06 Water cement and use for substituted gasoline cement Expired - Fee Related CN100357383C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2003101031738A CN100357383C (en) 2003-11-06 2003-11-06 Water cement and use for substituted gasoline cement

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Application Number Priority Date Filing Date Title
CNB2003101031738A CN100357383C (en) 2003-11-06 2003-11-06 Water cement and use for substituted gasoline cement

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CN100357383C CN100357383C (en) 2007-12-26

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433085A (en) * 2011-11-18 2012-05-02 江西省新视野实业发展有限公司 Multifunctional water-soluble adhesive cement for replacing gasoline adhesive cement
CN104387641A (en) * 2014-12-17 2015-03-04 江西省万载橡塑有限公司 Modified rubber powder and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1165171A (en) * 1997-01-16 1997-11-19 乔宗捷 Low-temp. vulcanization tyre patching rubber material
JP2000053939A (en) * 1998-08-05 2000-02-22 Yokohama Rubber Co Ltd:The Aqueous adhesive composition
US6127476A (en) * 1999-01-25 2000-10-03 Omnova Solutions Inc. Aqueous rubber composition
JP2000303044A (en) * 1999-04-19 2000-10-31 Yokohama Rubber Co Ltd:The Adhesive for polyester fiber-rubber, and procedure for gluing between polyester fiber and rubber
CN1233764C (en) * 2001-03-27 2005-12-28 中国人民解放军总后勤部军需装备研究所士兵系统研究中心 Sulfurized colloidal adhesive

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433085A (en) * 2011-11-18 2012-05-02 江西省新视野实业发展有限公司 Multifunctional water-soluble adhesive cement for replacing gasoline adhesive cement
CN102433085B (en) * 2011-11-18 2014-05-28 江西省新视野实业发展有限公司 Multifunctional water-soluble adhesive cement for replacing gasoline adhesive cement
CN104387641A (en) * 2014-12-17 2015-03-04 江西省万载橡塑有限公司 Modified rubber powder and preparation method thereof
CN104387641B (en) * 2014-12-17 2016-06-01 江西省万载橡塑有限公司 A kind of modified rubber powder and its preparation method

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