CN1600720A - Crown glass in use for discharge lamp in low pressure - Google Patents

Crown glass in use for discharge lamp in low pressure Download PDF

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Publication number
CN1600720A
CN1600720A CN 200410067162 CN200410067162A CN1600720A CN 1600720 A CN1600720 A CN 1600720A CN 200410067162 CN200410067162 CN 200410067162 CN 200410067162 A CN200410067162 A CN 200410067162A CN 1600720 A CN1600720 A CN 1600720A
Authority
CN
China
Prior art keywords
glass
low pressure
discharge lamp
crown glass
discharging lamp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200410067162
Other languages
Chinese (zh)
Inventor
陈业昌
诸定昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Huabao Glass Industry Co Ltd
Fudan University
Original Assignee
Guangzhou Huabao Glass Industry Co Ltd
Fudan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Huabao Glass Industry Co Ltd, Fudan University filed Critical Guangzhou Huabao Glass Industry Co Ltd
Priority to CN 200410067162 priority Critical patent/CN1600720A/en
Publication of CN1600720A publication Critical patent/CN1600720A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/095Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention is a leadless glass used for low pressure discharging lamp, its basic component consists of inorgaric oxides of SiO2, K2O, Na2O, Al2O3, CaO, MgO, B2O3, CeO2, Fe2O3, BaO and SrO etc. on proper weight ratio, it can be produced by prior glass prodn, device and technology. The soften temp, of said leadless glass is similar to chadional lead glass used for low pressure discharging lamp. So the glass can not only be used as arc material of low pressure discharging lamp, but also stem material used for electrode sealing.

Description

Crown glass in use for discharge lamp in low pressure
Technical field
The invention belongs to the electric light source technology field, be specifically related to the low melting glass of the plumbous composition of a kind of non-oxidation.
Background technology
Low-pressure discharge lamp is widely used in interior lighting.Be generally used for making in the glass tube of low-pressure discharge lamp, all contain a certain proportion of plumbous oxide.The adding of plumbous oxide can reduce the softening temperature and the melting temperature of Glass tubing, thus but save energy and minimizing manufacturing cost.But the lead in the Glass tubing (poisonous) composition can cause very big environmental pollution, and human beings'health is brought threat.Therefore, using the Glass tubing of unleaded composition to make low-pressure discharge lamp, will be the inevitable development trend of such light source.
Summary of the invention
The object of the present invention is to provide a kind of Unlead low-smelting point glass that is used to make low-pressure discharge lamp, to avoid of the harm of deleterious lead to global environment.
Another object of the present invention is to need not to change original production unit and production technique, prepare low-pressure discharge lamp with regard to available crown glass provided by the invention.
Glass material provided by the invention, its softening temperature (Tsoft) and tradition have the close of lead glass as low-pressure discharge lamp.
Crown glass provided by the invention both can be used as the arctube material of low-pressure discharge lamp, can be used as electrode sealing-in core column material again.
According to the present invention, can achieve the above object with the inorganic oxide compositions (prescription) that contains following base stock.Its base stock is expressed as with weight percent:
SiO 2 62.0-68.0%
K 2O 5.0-7.0%
Na 2O 10.0-15.0%
Al 2O 3 0-4.3%
CaO 2.5-6.2%
MgO 1.5-4.0%
B 2O 3 2.0-3.2%
CeO 2 0.1-0.4%
Fe 2O 3 0-0.20%
BaO 0-10.4%
SrO 0-4.0%。
The each component total amount satisfies 100%.
The glass that the present invention proposes can utilize the production unit and the production technique of original glass.Need not to change, can produce.
The average coefficient of expansion α of above-mentioned glass between 25 ℃ and 300 ℃ 25: 300tBe 103 ± 3.Be to be noted that glass, there is no in the former relevant patent and reported with this characteristic.
Embodiment
The invention is further illustrated by the following examples, but be not limited to this embodiment.
Embodiment 1
1, component (by weight):
SiO 2 63.8
K 2O 6.0
Na 2O 11.0
CaO 2.7
MgO 1.8
B 2O 3 2.5
CeO 2 0.1
BaO 9.0
SrO 3.0
2, coefficient of expansion α 25: 300t(* 10 -7): be 102
3, softening temperature (℃): 640
4, density p (g/cm 3): 2.50
Embodiment 2
1, component (by weight):
SiO 2 65.12
K 2O 6.0
Na 2O 14.0
Al 2O 3 3.0
CaO 5.4
MgO 3.6
B 2O 3 2.5
CeO 2 0.28
Fe 2O 3 0.1
2, coefficient of expansion α 25: 300t(* 10 -7) be 102
3, softening temperature (℃): 660
4, density p (g/cm 3): 2.55
Embodiment 3
1, component (by weight:
SiO 2 63.8
K 2O 6.0
Na 2O 11.0
Al 2O 3 2.0
CaO 2.7
MgO 1.8
B 2O 3 2.5
CeO 2 0.15
Fe 2O 3 0.05
BaO 7.0
SrO 3.0
2, coefficient of expansion α 25: 300t(* 10 -7) be 102
3, softening temperature (℃): 650
4, density p (g/cm 3): 2.52

Claims (1)

1, a kind of crown glass in use for discharge lamp in low pressure is characterized in that by weight percentage, and the each component proportioning is as follows:
SiO 2 62.0-68.0%
K 2O 5.0-7.0%
Na 2O 10.0-15.0%
Al 2O 3 0-4.3%
CaO 2.5-6.2%
MgO 1.5-4.0%
B 2O 3 2.0-3.2%
CeO 2 0.1-0.4%
Fe 2O 3 0-0.20%
BaO 0-10.4%
SrO 0-4.0%
Total amount satisfies 100%.
CN 200410067162 2004-10-14 2004-10-14 Crown glass in use for discharge lamp in low pressure Pending CN1600720A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410067162 CN1600720A (en) 2004-10-14 2004-10-14 Crown glass in use for discharge lamp in low pressure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410067162 CN1600720A (en) 2004-10-14 2004-10-14 Crown glass in use for discharge lamp in low pressure

Publications (1)

Publication Number Publication Date
CN1600720A true CN1600720A (en) 2005-03-30

Family

ID=34666552

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410067162 Pending CN1600720A (en) 2004-10-14 2004-10-14 Crown glass in use for discharge lamp in low pressure

Country Status (1)

Country Link
CN (1) CN1600720A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107572779A (en) * 2017-09-18 2018-01-12 安徽鑫民玻璃股份有限公司 A kind of Unlead low-smelting point coloured glass and its preparation technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107572779A (en) * 2017-09-18 2018-01-12 安徽鑫民玻璃股份有限公司 A kind of Unlead low-smelting point coloured glass and its preparation technology

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Legal Events

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20050330