CN1597823A - Novel paper plastic adhesive - Google Patents
Novel paper plastic adhesive Download PDFInfo
- Publication number
- CN1597823A CN1597823A CN 03146828 CN03146828A CN1597823A CN 1597823 A CN1597823 A CN 1597823A CN 03146828 CN03146828 CN 03146828 CN 03146828 A CN03146828 A CN 03146828A CN 1597823 A CN1597823 A CN 1597823A
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- CN
- China
- Prior art keywords
- emulsion
- natural
- deionized water
- vinyl acetate
- butyl acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The invention is a new kind of paper plastic adhesive. Its synthetic process: mixing butyl acrylate 120 kg, vinyl acetate 199 kg, isooctyl acrylate 160 kg, compound emulsifier 25 kg, and deionized water 509 kg and then preemulsifying to reserve preemulsion; then taking 1/4 of the preemulsion to put in a reaction kettle, raising the temperature to 80 deg.C, and adding in ammonium peroxysulphate 2.5 g as an initiator; dripping the residual preemulsion in the reaction kettle within 3 hours and preserving the heat for 1 hour, then lowering the temperature to 45 deg.C and discharging; and compounding natural emulsion, natural resin and synthetic emulsion in the ratio of 3 to 1 to 7 in a high-speed disperser and obtaining it. And its ingredients include: butyl acrylate 120 kg, vinyl acetate 199 kg, isooctyl acrylate 160 kg, ammonium peroxysulphate 2.5 g, compound emulsifier 25 kg, natural emulsion 190 kg, natural resin 128 kg, and deionized water 509 kg. It has the characters of high glossiness, strong adhesion, heat resistance, low-temperature resistance and long opening time, and easy cleaning.
Description
Technical field
The present invention relates to adhesive field, exactly is novel paper glue.
Background technology
The general bounding force of paper glue of existing market is relatively poor, and particle diameter is difficult for brushing more greatly, and surplus glue is difficult for beating wiping clean, and it is bigger that glue is influenced by weather condition.
Summary of the invention
Goal of the invention:
Solve the deficiency of above-mentioned paper glue, long novel paper glue of a kind of glossiness height, strong, heat-resisting, the anti-low temperature of bounding force and open hour is provided.
The technical scheme of technical solution problem:
One, synthesis process:
Mix after the pre-emulsification butyl acrylate 120kg, vinyl acetate between to for plastic 199kg, Isooctyl acrylate monomer 160kg, compound emulsifying agent 25kg, deionized water 509kg stand-by.Take out 1/4 stand-by pre-emulsion then and putting into reactor, when being warming up to 80 ℃, add ammonium persulphate 2.5kg as initiator; In 3 hours, will remain pre-emulsion and splash in the reactor, be incubated after 1 hour, cool the temperature to 45 ℃ of dischargings.In high speed dispersor, carry out composite in 3: 1: 7 ratio natural emulsion, natural resin, synthetic good emulsion glue.
Two, product is mainly prepared burden and is:
Butyl acrylate 120kg, vinyl acetate between to for plastic 199kg, Isooctyl acrylate monomer 160kg, ammonium persulphate 2.5kg, compound emulsifying agent 25kg, natural emulsion 190kg, natural resin 128kg, deionized water 509kg.
Beneficial effect:
Product of the present invention has characteristics such as glossiness height, strong, heat-resisting, the anti-low temperature of bounding force and open hour length.Its feel exquisiteness very easily is coated with anti-ly, and surplus glue can wipe clean, and is not subjected to the influence of Changes in weather and phenomenon occurs splitting.
Embodiment
Below in conjunction with example specific embodiments is described:
One, the used main batching of product:
1, butyl acrylate: 120kg
2, vinyl acetate between to for plastic: 199kg
3, Isooctyl acrylate monomer: 160kg
4, ammonium persulphate: 2.5kg
5, compound emulsifying agent: 25kg
6, natural emulsion: 190kg
7, natural resin: 128kg
8, deionized water: 509kg
Two, synthesis process:
Mix after the pre-emulsification butyl acrylate 120kg, vinyl acetate between to for plastic 199kg, Isooctyl acrylate monomer 160kg, compound emulsifying agent 25kg, deionized water 509kg stand-by.Take out 1/4 stand-by pre-emulsion then and putting into reactor, when being warming up to 80 ℃, add ammonium persulphate 2.5kg as initiator; In 3 hours, will remain pre-emulsion and splash in the reactor, be incubated after 1 hour, cool the temperature to 45 ℃ of dischargings.In high speed dispersor, carry out composite in 3: 1: 7 ratio natural emulsion, natural resin, synthetic good emulsion glue.
Three, product index:
Outward appearance: white or faint yellow colloid
Viscosity: 10000 ± 1000mpa.s (25 ℃)
Solid content: 50 ± 2%
PH value: 〉=7
Four, use range:
BOPP and BOPP can be crossed the quick good bond of the face of moulding, BOPP face and paper, polished face and paper, leatherette paper and plastic box, leatheroid and plastic box are compound.
Claims (1)
1, novel paper glue is characterized in that: its synthesis technique is to mix after the pre-emulsification butyl acrylate, vinyl acetate between to for plastic, Isooctyl acrylate monomer, compound emulsifying agent, deionized water stand-by; Take out 1/4 stand-by pre-emulsion then and putting into reactor, when being warming up to 80 ℃, add ammonium persulphate as initiator; In 3 hours, will remain pre-emulsion and splash in the reactor, be incubated after 1 hour, cool the temperature to 45 ℃ of dischargings; In high speed dispersor, natural emulsion, natural resin, synthetic good emulsion glue are carried out composite forming in 3: 1: 7 ratio; The main batching that product is used is: butyl acrylate 120kg, vinyl acetate between to for plastic 199kg, Isooctyl acrylate monomer 160kg, ammonium persulphate 2.5kg, compound emulsifying agent 25kg, natural emulsion 190kg, natural resin: 128kg, deionized water 509kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03146828 CN1597823A (en) | 2003-09-15 | 2003-09-15 | Novel paper plastic adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03146828 CN1597823A (en) | 2003-09-15 | 2003-09-15 | Novel paper plastic adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1597823A true CN1597823A (en) | 2005-03-23 |
Family
ID=34659685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03146828 Pending CN1597823A (en) | 2003-09-15 | 2003-09-15 | Novel paper plastic adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1597823A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086857A (en) * | 2015-09-06 | 2015-11-25 | 南通宝加利新材料有限公司 | Environment-friendly water-based rubber protection film and preparation method thereof |
| CN105176421A (en) * | 2015-10-21 | 2015-12-23 | 胡治国 | Aqueous adhesive |
| CN110066605A (en) * | 2019-04-19 | 2019-07-30 | 中国热带农业科学院橡胶研究所 | A kind of low ammonia or the application without ammoniacal latex in high stability shoes-used glue |
-
2003
- 2003-09-15 CN CN 03146828 patent/CN1597823A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086857A (en) * | 2015-09-06 | 2015-11-25 | 南通宝加利新材料有限公司 | Environment-friendly water-based rubber protection film and preparation method thereof |
| CN105086857B (en) * | 2015-09-06 | 2018-02-16 | 南通宝加利新材料有限公司 | A kind of environment-friendly type aqueous rubber protective film and preparation method thereof |
| CN105176421A (en) * | 2015-10-21 | 2015-12-23 | 胡治国 | Aqueous adhesive |
| CN110066605A (en) * | 2019-04-19 | 2019-07-30 | 中国热带农业科学院橡胶研究所 | A kind of low ammonia or the application without ammoniacal latex in high stability shoes-used glue |
| CN110066605B (en) * | 2019-04-19 | 2021-06-22 | 中国热带农业科学院橡胶研究所 | Application of low-ammonia or ammonia-free latex in high-stability shoe glue |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |