CN110373134A - A kind of corrugated board bonding modified epoxy acrylic ester glue and preparation method thereof - Google Patents
A kind of corrugated board bonding modified epoxy acrylic ester glue and preparation method thereof Download PDFInfo
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- CN110373134A CN110373134A CN201910737459.2A CN201910737459A CN110373134A CN 110373134 A CN110373134 A CN 110373134A CN 201910737459 A CN201910737459 A CN 201910737459A CN 110373134 A CN110373134 A CN 110373134A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/122—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to saturated polysiloxanes containing hydrolysable groups, e.g. alkoxy-, thio-, hydroxy-
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses a kind of corrugated board bonding modified epoxy acrylic ester glue and preparation method thereof, including following percent composition: cationic maize starch 5-10%, cationic microgel crystalline cellulose 5-10%, phenolate lignin 1-3%, Sodium Caseinate 1-5%, maleic anhydride modified rosin glycerides 2-5%, mould inhibitor 1-2%, tertiary ethylene carbonate copolymer emulsion 25-35%, fluosilicic are total to modified epoxy acrylic ester lotion 30-60%；The modified epoxy acrylic ester lotion the preparation method is as follows: (1) methacrylic monomer reacts fluosilicic obtained by (2) with organic silicon monomer, fluorine-containing alcohol jointly be total to modified acrylate emulsion and continue and aqueous bisphenol A type epoxy resin generation polymerization reaction.The present invention is total to modified epoxy acrylic ester lotion using two-step method synthesis fluosilicic, method is simple, operation is convenient, and reaction rate is high, the product degree of polymerization is high, corrugation paper-hanging wearability, weatherability, waterproofness, anti-fouling and self-cleaning performance, the antibacterial and mouldproof function admirable produced.
Description
Technical field
The invention belongs to corrugated paper glue material fields, and in particular to a kind of corrugated board bonding modified epoxy propylene
Acid esters glue and preparation method thereof.
Background technique
Epocryl is also known as vinyl ester resin, is epoxy resin and acrylic or methacrylic acid by ester
Change reaction and be made, is current most widely used, the maximum Photocurable oligomers of dosage, laser curing velocity is in each quasi-oligomer
In be most fast, and the film after solidifying has that hardness is high, glossiness is good, corrosion resistance, heat resistance and electrochemistry are excellent
The features such as.
- Si-O- bond energy in organosilicon polymer is introduced into epoxy acrylate much larger than-C-C- key and-C-O- key
In resin, its thermostability, weatherability, high and low temperature resistance can be effectively improved, moreover it is possible to reduce internal stress.Currently, using organosilicon
Being modified to epoxy acrylate is also a kind of more typical method of modifying, and such as application No. is the special of CN201010508740.8
Benefit discloses a kind of organic silicon modified epoxy acrylate aqueous dispersion and preparation method thereof；Such as application No. is
The patent of CN201610682930.9, open organic silicon modified epoxy acrylate super-thin steel structure fireproof coating and preparation side
Method；Such as application No. is the patents of CN201711249881.0, disclose a kind of photosensitive resin material of 3D printing, photosensitive with low viscosity
Resin oligomers, organic silicon modified epoxy acrylate, reactive diluent are main material, produce photosensitive resin.But about organic
Research in terms of fluorine richness epoxy acrylate is still less, and there has been no related patents reports, since fluorine atom is special chemically
Matter is introduced into epoxy acrylic ester structure, and epoxy acrylate film coated surface is enable to reduce, and improves waterproof, antifouling and resistance to
Corrosive nature.
Based on the above reasons, develop it is a kind of for corrugated paper bonding fluorine silicon be total to modified epoxy acrylic ester glue have extensively
Wealthy market prospects and economic value.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of corrugated board bonding modified epoxies
Acrylate glue and preparation method thereof.
Technical solution of the present invention is summarized as follows:
A kind of corrugated board bonding modified epoxy acrylic ester glue, including following percent composition: cationic corn
It is starch 5-10%, cationic microgel crystalline cellulose 5-10%, phenolate lignin 1-3%, Sodium Caseinate 1-5%, maleic anhydride modified
Rosin glycerides 2-5%, mould inhibitor 1-2%, tertiary ethylene carbonate copolymer emulsion 25-35%, fluosilicic are total to modified epoxy acrylic acid
Ester lotion 30-60%；
The modified epoxy acrylic ester lotion the preparation method is as follows:
(1) it disperses 30-40 parts of methacrylic acids, 20-25 parts of butyl methacrylates, 1-2 parts of sodium lignin sulfonates in
In 100 parts of deionized waters, 1-3 parts of initiators of addition, 0.1-0.5 parts of catalyst are warming up to 110-120 DEG C after mixing evenly, open
Begin to be added dropwise and be mixed by what 5-10 parts of hydroxy-terminated polysiloxanes, 1-3 parts of vinyl triethoxyl siloxanes, 5-10 parts of fluorine-containing alcohols formed
Liquid is closed, and is stirred continuously, subsequent continuous insulation reaction 3-4h is added dropwise, produces fluosilicic and is total to modified acrylate emulsion；
(2) it is total in modified acrylate emulsion to fluosilicic and 40-50 parts of aqueous bisphenol A type epoxy resins, 1-2 parts of polymerization inhibitors is added
Agent, 85-95 DEG C of reaction 3-6h are total to modified epoxy acrylic ester lotion to get fluosilicic.
Preferably, the mould inhibitor presses 10:0.5:2:3 by tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid
Weight ratio mix.
Preferably, the fluorine-containing alcohol includes perfluoroalkyl ethanol, one kind of fluorine-containing polyether glycol or two classes.
Preferably, the perfluoroalkyl ethanol include perfluoro butyl ethyl alcohol, perfluoro hexyl ethyl alcohol, perfluoro octyl ethanol,
Perfluoro decyl ethyl alcohol it is one or more.
Preferably, the fluorine-containing polyether glycol includes polyether diatomic alcohol containing fluorine, fluorochemical polyether trihydroxylic alcohol, fluorochemical polyether
Tetrahydroxylic alcohol it is one or more.
Preferably, the initiator includes potassium peroxydisulfate, ammonium persulfate, benzoyl peroxide, dicetyl peroxydicarbonate two
One of cyclohexyl is a variety of.
Preferably, the catalyst includes one of STANNOUS SULPHATE CRYSTALLINE, zirconium oxide, p-methyl benzenesulfonic acid or a variety of.
Preferably, the polymerization inhibitor includes one of hydroquinone, tert-butyl catechol, copper naphthenate or more
Kind.
A kind of corrugated board bonding preparation method of modified epoxy acrylic ester glue: mixing tertiary ethylene carbonate copolymerization
Lotion, fluosilicic are total to modified epoxy acrylic ester lotion, and after being heated to 110-130 DEG C, other components, insulated and stirred 0.5-1h is added
Afterwards to get the modified epoxy acrylic ester glue.
Beneficial effects of the present invention:
(1) two-step method synthesis fluosilicic of the present invention is total to modified epoxy acrylic ester lotion, and method is simple, and it is convenient to operate, and anti-
Answer rate high, the product degree of polymerization is high.
(2) present invention utilizes the esterification and ethylene between hydroxy-terminated polysiloxane, fluorine-containing alcohol and methacrylic acid
Addition reaction between ethyl triethoxy silicane oxygen alkane and methacrylic acid, butyl methacrylate is modified acrylic monomers,
The esterification by ring opening for recycling gained fluosilicic to be total between modified acrylate emulsion and aqueous bisphenol A type epoxy resin reacts synthesis and produces eventually
Object.
(3) present invention utilizes organic silicon monomer, the monomer modified epoxy acrylate of Organic fluoride, improves its comprehensive performance, assigns
Give the excellent heat resistance of epoxy acrylate, wearability, weatherability, waterproofness, anti-fouling and self-cleaning performance, flexibility, anti-high and low-temp
Property, and compatible, the comprehensive performance of raising corrugated paper adhesive glue can be stablized with other components.
(4) present invention is improved using mould inhibitor made of tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid compounding
Corrugated paper bonds the antibiotic and sterilizing performance of glue, prevents corrugated paper moldy metamorphism, prolongs its service life.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification
Text can be implemented accordingly.
Embodiment 1
A kind of corrugated board bonding modified epoxy acrylic ester glue, including following percent composition: cationic corn
Starch 10%, cationic microgel crystalline cellulose 10%, phenolate lignin 3%, Sodium Caseinate 5%, maleic anhydride modified rosin glycerol
Ester 5%, mould inhibitor 2%, tertiary ethylene carbonate copolymer emulsion 35%, fluosilicic are total to modified epoxy acrylic ester lotion 30%；
A kind of corrugated board bonding modified epoxy acrylic ester glue preparation method, comprising the following steps:
(1) by 30 parts of methacrylic acids, 20 parts of butyl methacrylates, 1 part of sodium lignin sulfonate be scattered in 100 parts go from
In sub- water, 1 part of potassium peroxydisulfate is added, 0.1 part of STANNOUS SULPHATE CRYSTALLINE is warming up to 110 DEG C after mixing evenly, start to be added dropwise and be sealed by 5 parts of hydroxyls
The mixed liquor for holding polysiloxanes, 1 part of vinyl triethoxyl siloxanes, 5 parts of perfluoro butyl ethyl alcohol to form, and be stirred continuously, it drips
It adds Bi Houji and continues insulation reaction 3h, produce fluosilicic and be total to modified acrylate emulsion；
(2) addition 40 parts of aqueous bisphenol A type epoxy resins, 1 part of hydroquinone in modified acrylate emulsion are total to fluosilicic,
85 DEG C of reaction 3h are total to modified epoxy acrylic ester lotion to get fluosilicic；
(3) tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid are mixed by the weight ratio of 10:0.5:2:3, obtained mould proof
Agent；
(4) mixing tertiary ethylene carbonate copolymer emulsion, fluosilicic are total to modified epoxy acrylic ester lotion, after being heated to 110 DEG C,
Other components are added, to get the modified epoxy acrylic ester glue after insulated and stirred 0.5h.
Embodiment 2
A kind of corrugated board bonding modified epoxy acrylic ester glue, including following percent composition: cationic corn
Starch 7.5%, cationic microgel crystalline cellulose 7.5%, phenolate lignin 2%, Sodium Caseinate 3%, maleic anhydride modified rosin are sweet
Grease 3.5%, mould inhibitor 1.5%, tertiary ethylene carbonate copolymer emulsion 30%, fluosilicic are total to modified epoxy acrylic ester lotion
45%；
A kind of corrugated board bonding modified epoxy acrylic ester glue preparation method, comprising the following steps:
(1) 100 parts are dispersed by 35 parts of methacrylic acids, 22.5 parts of butyl methacrylates, 1.5 parts of sodium lignin sulfonates
In deionized water, 1.5 parts of ammonium persulfates are added, 0.3 part of zirconium oxide is warming up to 115 DEG C after mixing evenly, start be added dropwise by 7.5
The mixed liquor that part hydroxy-terminated polysiloxane, 2 parts of vinyl triethoxyl siloxanes, 7.5 parts of perfluoro octyl ethanols form, not
Disconnected stirring, is added dropwise subsequent continuous insulation reaction 3.5h, produces fluosilicic and be total to modified acrylate emulsion；
(2) addition 45 parts of aqueous bisphenol A type epoxy resins, 1.5 parts of tert-butyls in modified acrylate emulsion are total to fluosilicic
Catechol, 90 DEG C of reaction 4.5h are total to modified epoxy acrylic ester lotion to get fluosilicic；
(3) tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid are mixed by the weight ratio of 10:0.5:2:3, obtained mould proof
Agent；
(4) mixing tertiary ethylene carbonate copolymer emulsion, fluosilicic are total to modified epoxy acrylic ester lotion, after being heated to 120 DEG C,
Other components are added, to get the modified epoxy acrylic ester glue after insulated and stirred 1h.
Embodiment 3
A kind of corrugated board bonding modified epoxy acrylic ester glue, including following percent composition: cationic corn
Starch 5%, cationic microgel crystalline cellulose 5%, phenolate lignin 1%, Sodium Caseinate 1%, maleic anhydride modified rosin glycerides
2%, mould inhibitor 1%, tertiary ethylene carbonate copolymer emulsion 25%, fluosilicic are total to modified epoxy acrylic ester lotion 60%；
A kind of corrugated board bonding modified epoxy acrylic ester glue preparation method, comprising the following steps:
(1) by 40 parts of methacrylic acids, 25 parts of butyl methacrylates, 2 parts of sodium lignin sulfonates be scattered in 100 parts go from
In sub- water, 3 parts of benzoyl peroxides are added, 0.5 part of p-methyl benzenesulfonic acid is warming up to 120 DEG C after mixing evenly, start to be added dropwise
The mixed liquor being made of 10 parts of hydroxy-terminated polysiloxanes, 3 parts of vinyl triethoxyl siloxanes, 10 parts of perfluoroalkyl polyether dihydric alcohols,
And be stirred continuously, subsequent continuous insulation reaction 4h is added dropwise, produces fluosilicic and is total to modified acrylate emulsion；
(2) addition 50 parts of aqueous bisphenol A type epoxy resins, 2 parts of copper naphthenates in modified acrylate emulsion are total to fluosilicic,
95 DEG C of reaction 6h are total to modified epoxy acrylic ester lotion to get fluosilicic；
(3) tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid are mixed by the weight ratio of 10:0.5:2:3, obtained mould proof
Agent；
(4) mixing tertiary ethylene carbonate copolymer emulsion, fluosilicic are total to modified epoxy acrylic ester lotion, after being heated to 130 DEG C,
Other components are added, to get the modified epoxy acrylic ester glue after insulated and stirred 1h.
Embodiment 1-3 is tested for the property, test result is as follows shown in table:
| Adhesion strength/N/m | Water absorption rate/% | Antibiotic rate/% | |
| Embodiment 1 | 764 | 1.5 | 87.6 |
| Embodiment 2 | 782 | 1.2 | 88.5 |
| Embodiment 3 | 775 | 1.1 | 89.2 |
As seen from the above table, modified epoxy acrylic ester glue adhesion strength produced by the invention is high, and resists with excellent
Aqueous and antibiotic property.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (9)
1. a kind of corrugated board bonding modified epoxy acrylic ester glue, which is characterized in that including following percent composition: sun
Ion cornstarch 5-10%, cationic microgel crystalline cellulose 5-10%, phenolate lignin 1-3%, Sodium Caseinate 1-5%, Malaysia
Anhydride modified rosin glycerides 2-5%, mould inhibitor 1-2%, tertiary ethylene carbonate copolymer emulsion 25-35%, fluosilicic are modified ring altogether
Oxypropylene acid esters lotion 30-60%；
The modified epoxy acrylic ester lotion the preparation method is as follows:
(1) 100 parts are dispersed by 30-40 parts of methacrylic acids, 20-25 parts of butyl methacrylates, 1-2 parts of sodium lignin sulfonates
In deionized water, 1-3 parts of initiators of addition, 0.1-0.5 parts of catalyst are warming up to 110-120 DEG C after mixing evenly, start to drip
Add the mixing being made of 5-10 parts of hydroxy-terminated polysiloxanes, 1-3 parts of vinyl triethoxyl siloxanes, 5-10 parts of fluorine-containing alcohols
Liquid, and be stirred continuously, subsequent continuous insulation reaction 3-4h is added dropwise, produces fluosilicic and is total to modified acrylate emulsion；
(2) addition 40-50 parts of aqueous bisphenol A type epoxy resins, 1-2 parts of polymerization inhibitors in modified acrylate emulsion are total to fluosilicic,
85-95 DEG C of reaction 3-6h is total to modified epoxy acrylic ester lotion to get fluosilicic.
2. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 1, which is characterized in that described
Mould inhibitor is mixed by tourmaline powder, tea polyphenols, dimethyl fumarate, bamboo acetic acid by the weight ratio of 10:0.5:2:3.
3. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 1, which is characterized in that described
Fluorine-containing alcohol includes perfluoroalkyl ethanol, one kind of fluorine-containing polyether glycol or two classes.
4. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 3, which is characterized in that described
Perfluoroalkyl ethanol includes one kind or more of perfluoro butyl ethyl alcohol, perfluoro hexyl ethyl alcohol, perfluoro octyl ethanol, perfluoro decyl ethyl alcohol
Kind.
5. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 3, which is characterized in that described
Fluorine-containing polyether glycol include polyether diatomic alcohol containing fluorine, fluorochemical polyether trihydroxylic alcohol, fluorochemical polyether tetrahydroxylic alcohol it is one or more.
6. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 1, which is characterized in that described
Initiator includes one of potassium peroxydisulfate, ammonium persulfate, benzoyl peroxide, di-cyclohexylperoxy di-carbonate or a variety of.
7. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 1, which is characterized in that described
Catalyst includes one of STANNOUS SULPHATE CRYSTALLINE, zirconium oxide, p-methyl benzenesulfonic acid or a variety of.
8. a kind of corrugated board bonding modified epoxy acrylic ester glue according to claim 1, which is characterized in that described
Polymerization inhibitor includes one of hydroquinone, tert-butyl catechol, copper naphthenate or a variety of.
9. the preparation method that modified epoxy acrylic ester glue is used in a kind of corrugated board bonding, it is characterised in that: mixing versatic acid
Vinyl acetate copolymer emulsion, fluosilicic are total to modified epoxy acrylic ester lotion, and after being heated to 110-130 DEG C, other components, heat preservation is added
To get the modified epoxy acrylic ester glue after stirring 0.5-1h.
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| CN201910737459.2A CN110373134A (en) | 2019-08-11 | 2019-08-11 | A kind of corrugated board bonding modified epoxy acrylic ester glue and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112708375A (en) * | 2020-12-05 | 2021-04-27 | 东莞顺诚纸品有限公司 | Glue and preparation method and corrugated paper prepared by applying glue |
| CN116289310A (en) * | 2022-12-23 | 2023-06-23 | 南昌市龙然实业有限公司 | Safe low-chlorine paper cationic rosin size for food contact and preparation method thereof |
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|---|---|---|---|---|
| CN101100494A (en) * | 2007-06-21 | 2008-01-09 | 湖北大学 | Method for preparing silicon-fluorine modified acrylic ester emulsion based on macromolecule organic silicon and fluorine-containing monomer |
| US20150284566A1 (en) * | 2014-04-02 | 2015-10-08 | Georgia-Pacific Chemicals Llc | Methods for making lignocellulose composite products with oxidative binders and encapsulated catalyst |
| CN105586804A (en) * | 2015-09-28 | 2016-05-18 | 浙江帝龙新材料股份有限公司 | Modified acrylic resin coating agent for decorating paper and preparation method of modified acrylic resin coating agent |
-
2019
- 2019-08-11 CN CN201910737459.2A patent/CN110373134A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100494A (en) * | 2007-06-21 | 2008-01-09 | 湖北大学 | Method for preparing silicon-fluorine modified acrylic ester emulsion based on macromolecule organic silicon and fluorine-containing monomer |
| US20150284566A1 (en) * | 2014-04-02 | 2015-10-08 | Georgia-Pacific Chemicals Llc | Methods for making lignocellulose composite products with oxidative binders and encapsulated catalyst |
| CN105586804A (en) * | 2015-09-28 | 2016-05-18 | 浙江帝龙新材料股份有限公司 | Modified acrylic resin coating agent for decorating paper and preparation method of modified acrylic resin coating agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112708375A (en) * | 2020-12-05 | 2021-04-27 | 东莞顺诚纸品有限公司 | Glue and preparation method and corrugated paper prepared by applying glue |
| CN116289310A (en) * | 2022-12-23 | 2023-06-23 | 南昌市龙然实业有限公司 | Safe low-chlorine paper cationic rosin size for food contact and preparation method thereof |
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Application publication date: 20191025 |