Background technology:
In the use of battery or super capacitor, usually adopt series system to improve their output voltage.But since their monomer capacity and internal resistance make and use in produce inevitably inconsistent, thereby bring in the serial connection charge process, little or internal resistance is high is easy to generate and overcharges and reduce useful life for capacity, even the phenomenon of damaging and exploding; Often easy generation the big for capacity or that internal resistance is low owes to fill phenomenon, equally also influences its useful life.Series connected battery or super capacitor are many more, and it is many more to discharge and recharge number of times, and the lack of uniformity between each series-connected cell is just serious more, and the big more damage of charging current is also just serious more.In order to solve this type of problem, people have thought thousand and one way, but still exist such or such deficiency and defective.
For example, general equalizing circuit, its equalizing circuit consumes the energy that overcharges in the charging process by resistance, thereby produces a large amount of heat energy, consequently causes the service behaviour of the battery that is recharged or super capacitor and working life to descend.
Another kind of charge equalization method is that the energy that overcharges in the charging process is moved compensation by equalizing circuit between the monomer of series battery or series capacitance group.This method brings system's lead-in wire to intersect too much, thereby produces the system insulation security problems.
Embodiment:
The present invention further specifies as follows in conjunction with specific embodiments referring to accompanying drawing:
A kind of semiconductor refrigeration type balanced charging method, series battery or the serial connected super capacitance group be made up of a plurality of battery cells or super capacitor monomer connect charging with power supply, each cell or super capacitor two ends semiconductor refrigeration type charge balancing circuit in parallel, the current balance cell in the circuit or the charging of super capacitor, overcharging stream in the charge balancing circuit is by semiconductor cooler refrigeration, cool off this circuit battery or super capacitor in parallel.
Concrete grammar is referring to accompanying drawing 1,2, by n battery B
1, B
2B
nOr n super capacitor C
1, C
2C
nGroup or series battery or the charging of serial connected super capacitance group, wherein the voltage on cell or the super capacitor is respectively U
1, U
2U
nThe electric current that flows through single electric capacity or super capacitor corresponds to i respectively
1, i
2I
n, at cell that is recharged or super capacitor two ends and connect a monitor-type refrigerator [6], monitor-type refrigerator [6] comprises a semiconductor cooler, and the semiconductor cooler cold junction is arranged on this cell or super capacitor place.When the monitor-type refrigerator monitors the voltage at this cell or super capacitor place or temperature when being higher than safety value, the semiconductor cooler refrigeration is cooled off this battery or super capacitor.
The inventive method realizes by the semiconductor refrigeration type balanced charging device, the semiconductor refrigeration type balanced charging device is referring to accompanying drawing 3, it is a monitor-type refrigerator [6], it is electrically connected with voltage transformation driver [2] by temperature and voltage monitor [1], both are all in parallel with cell B or super capacitor C, and voltage transformation driver [2] electrically connects with semiconductor cooler [3] and electric fan [4] respectively again.
The operation principle of semiconductor refrigerating cooled battery or super capacitor charge equalization method and circuit is as follows:
On each monomer super capacitor or battery, be installed in parallel a monitor-type refrigerator and form equalizing circuit.This equalizing circuit has the voltage that detects automatically in each monomer super capacitor or the battery charge and discharge process and the function of temperature; If on the voltage of this monomeric unit or the safety value that temperature reaches it in limited time, the monitor-type refrigerator of parallel connection on it, just can automatically the energy that overcharges to this monomer in the serial connection charge process be shunted, it is put on the semiconductor cooling device of monitor-type refrigerator, thereby on the cold junction of semiconductor cooler, produce " cold energy "; This " cold energy " can improve the working temperature characteristic of monomer by two kinds of methods; (1) electrode column by cell or super capacitor imports in the pole plate of monomer, directly reduces the temperature rise that each pole plate is produced because of the charging heating; (2) should " cold energy " blow to this cell or super capacitor by fin and fan, reduce the temperature rise of battery or super capacitor indirectly; On the other hand; " heat energy " that is produced on the semiconductor cooler hot junction; then blow to the outside by fin and fan; thereby both reach the proportionality action of cell or super capacitor being carried out charging process; simultaneously can be used to improve cell and super capacitor pole plate and operating ambient temperature with overcharging energy again; the temperature of cell and super capacitor is controlled in certain scope, reaches the purpose of further protection battery and super capacitor.When low temperature environment uses, then can be by the energising pole reversal of circuit with semiconductor cooler, thereby the energy in hot junction is used for heating battery or super capacitor, the electrolyte temperature of battery or super capacitor is raise, thereby improve the cold-starting characteristic of battery type super capacitor.
Because the refrigerating efficiency of conductor refrigeration device reaches 40%~45%,, thereby improved the utilance of comprehensive energy so method can be about 40% with traditional energy recuperation of being close to road consuming type equalizing circuit.
Above-mentioned introduction be the principle that the present invention works alone, it can also combine with microprocessor carries out intelligent equalization control, referring to accompanying drawing 4, it is that voltage monitor [1] electrically connects by data output interface [5] and microprocessor, constitutes intellectual semiconductor refrigerating balanced charging device.Its operation principle is as follows:
In the serial connection charge process, the observation circuit of monitor-type refrigerator is monitored the terminal voltage of cell or super capacitor at any time, parameters such as temperature rise, and to the digital signal of converting, send to microprocessor system by communication bus, microprocessor system is handled it by certain algorithm and is judged, and send control signal according to judged result, this signal is sent to the work of semiconductor refrigeration type balance module optimal control semiconductor cooling device equally by communication bus, under the prerequisite that guarantees system safety and operating characteristic, improve the charge capacity of total body unit to greatest extent.
The advantage of the inventive method and device is:
Not only can solve the equalization problem in battery or the super capacitor charging process preferably, and can also in charging process, carry out temperature control pole plate; Pole plate heated to its cooling or when starting in the winter time when temperature is too high and increase its cold starting performance; Thereby effectively reduce pole plate because of discharge and recharge the overheated distortion that causes, active material comes off even short circuit phenomenon, prolongs the useful life of battery and super capacitor.Simultaneously, improve gross energy utilance in the charging process relatively.