CN1569961A - Bra cushion material and its making method - Google Patents

Bra cushion material and its making method Download PDF

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Publication number
CN1569961A
CN1569961A CN 200410027046 CN200410027046A CN1569961A CN 1569961 A CN1569961 A CN 1569961A CN 200410027046 CN200410027046 CN 200410027046 CN 200410027046 A CN200410027046 A CN 200410027046A CN 1569961 A CN1569961 A CN 1569961A
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thermoplastic elastomer
bra liner
mixing
liner material
screw rod
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CN 200410027046
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CN1279118C (en
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陈耀祥
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Abstract

The invention discloses a bra cushioning material by using thermoplastic rubber as the base, which is prepared from thermoplastic rubber, talcum powder, calcium carbonate or zinc oxide, petroleum series plasticizing agent, and amine antioxidants through the steps of mixing, thermal plasticizing, squeezing and granulating.

Description

A kind of bra liner material and preparation method thereof
Technical field
The present invention relates to the composition of macromolecular compound, specifically, relating to a kind of is the bra liner material and preparation method thereof of base-material with the thermoplastic elastomer.
Background technology
Brassiere is the fashionable dress of chest, is used for protecting women's health, and makes the chest lines graceful more.Existing with the brassiere of moulding sponge as liner, after dressing, the women can increase its graceful bearing to a certain extent.But, this is that the brassiere of liner exists many deficiencies with the sponge, mainly show: the foam mat ventilation property is poor, have feeling of oppression and heat or cause the skin discomfort after dressing this brassiere, this situation is even more serious in summer, punching is to strengthen ventilation property on foam mat though some are also arranged, and the foam mat easy deformation after the punching is damaged; Because sponge elasticity is relatively poor, easy deformation is damaged, and therefore this brassiere can not be rubbed and wash, and this has influenced the sanitation and hygiene of brassiere; After the washing, contain in the foam mat, be difficult for drying than juicy; Sponge is easily aging, after this brassiere is changed clothes several times, foam mat aged problem can occur.
Summary of the invention
For remedying the deficiencies in the prior art, a kind of material that is suitable for making bra liner more is provided, it is the bra liner material and preparation method thereof of base-material with the thermoplastic elastomer that the present invention proposes a kind of, its technical scheme is as follows:
Each component and the content thereof of this bra liner material are:
Thermoplastic elastomer;
Weight is 5~10% talcum powder, lime carbonate or zinc oxide of above-mentioned thermoplastic elastomer;
Weight is that 12~25% oil of above-mentioned thermoplastic elastomer is a softening agent;
Weight is 1~3% ketoamine class anti-aging agent of above-mentioned thermoplastic elastomer.
Above-mentioned thermoplastic elastomer can be polyurethanes thermoplastic elastomer (thermoplastic elastomer TPE), thermoplastic natural rubber, melt processible thermoplastic elastomer or silicon rubber.
Above-mentioned talcum powder, lime carbonate or zinc oxide are as weighting agent.Weighting agent has reinforcement and increment dual-use function, is divided into by function: strengthening agent, and it is a main purpose with physical and mechanical propertiess such as the tensile strength that improves described thermoplastic elastomer, tear strength, stress at definite elongation, wear resistance, hardness; Extender, it is to increase the volume or weight of thermoplastic elastomer, and reducing cost is main purpose.Talcum powder can be used as strengthening agent or extender with the grade difference, and the talcum powder price is lower.Lime carbonate comprises water-ground limestone, light calcium carbonate and treated carbonates, price is suitable and can fill in a large number, its strengthening action and its particle diameter, structure, surface properties are relevant, and water-ground limestone and light calcium carbonate are mainly as extender, and treated carbonates is as strengthening agent.Zinc oxide also has the function of vulcanizing agent, promoting agent and tinting material concurrently when being used as weighting agent, have certain reinforcing property, and can improve the stickiness of thermoplastic elastomer, strengthens the thermoplastic elastomer thermal conductivity.When selecting for use, can select suitable weighting agent and consumption thereof, the performance of thermoplastic elastomer is met the requirements according to the purpose that will reach.
Above-mentioned oil is that softening agent can be paraffin oils, naphthenic oil or fragrant hydrocarbon ils.Paraffin oils is paraffin oil again, and fragrant hydrocarbon ils is aromatic hydrocarbon oil or No. 4 rubber oil again, after paraffin oils, naphthenic oil and aromatic hydrocarbon wet goods softening agent enter in the thermoplastic elastomer, has increased the flexibility of thermoplastic elastomer; Increase plasticity-, be convenient to processing; Other Synergist S-421 95 (as weighting agent) there is humidification, makes it to be easy to disperse, shorten mixing time, improve melting efficiency; Increase the flowability, tackyness of thermoplastic elastomer and, be convenient to moulding from stickiness; Increase the winter hardiness of thermoplastic elastomer.In paraffin oils, naphthenic oil and the fragrant hydrocarbon ils, the consistency of paraffin oils and thermoplastic elastomer is relatively poor, and processing characteristics is relatively poor; The consistency of fragrance hydrocarbon ils and thermoplastic elastomer is good, good processability; The consistency of naphthenic oil and thermoplastic elastomer and processing characteristics are all between paraffin oils and fragrant hydrocarbon ils.This plasticizer consumption is many more, and it is soft more that thermoplastic elastomer becomes.When selecting for use, answer bonded products to require to select suitable manufacturing methods and definite its consumption.
The preferred anti-aging agent RD of above-mentioned ketoamine class anti-aging agent, antioxidant A W or antioxidant BLE.These three kinds of ketoamine class anti-aging agent can both protect deterioration by oxidation, thermal ageing and Weather effectively.In addition, anti-aging agent RD has stronger restraining effect to metal catalytic oxidation, and the protective effect hold-time is long; Antioxidant A W energy ozone ageing and flex crack; Antioxidant BLE can protect ozone ageing and flexing fatigue.
The preparation method of this bra liner material may further comprise the steps:
Step 1: with powdery or granulous thermoplastic elastomer and weight is that 5~10% talcum powder of above-mentioned thermoplastic elastomer or lime carbonate or zinc oxide add in the container and kneads, and the time is 4~6 minutes, makes these two kinds of mixing of materials even;
Step 2: 12~25% the oil that adds weight and be above-mentioned thermoplastic elastomer is a softening agent, and it is even to each mixing of materials to knead, and making oil is that softening agent infiltrates in the thermoplastic elastomer;
Step 3: add weight and be 1~3% ketoamine class anti-aging agent of above-mentioned thermoplastic elastomer, make each mixing of materials even;
Step 4:, extrude then and, promptly make the granulous bra liner material in head pelletizing moulding by the forcing machine thermoplastication.
Forcing machine can adopt single screw extrusion machine, and the feed section temperature of its screw rod is 165~180 ℃, and the compression section temperature of screw rod is 180 ℃~200 ℃, and the melt zone temperature of screw rod is 185 ℃~205 ℃.The temperature of screw rod feed section, compression section and melt zone increases successively.
The present invention is base-material with the thermoplastic elastomer, after adding an amount of weighting agent, softening agent, anti-aging agent successively and mixing, again through thermoplastication, the material that obtains has snappiness, thermoplasticity, good anti ageing property and higher flexibility (its shore hardness can hang down and reach-0025 degree).Make bra liner with this material, can a plurality of breather holes be set easily by Shooting Technique on liner, improve the permeability of liner, because this material has snappiness, so the setting of breather hole can not cause the yielding damage of liner; With the soft and high resilience of bra liner that this material is made, comfortable especially when brassiere is worn; Because this material has good anti ageing property, therefore adopt the brassiere long service life of the liner of making by this material; Because the bra liner made from this material is soft and high resilience, so brassiere cleans conveniently, can be at will rubs with hand and washes or washing machine cleaning and can not cause the deformed damaged of liner, and the brassiere water content after the cleaning is few, dries easily; This material does not contain harmful material, and is safe in utilization; The bra liner thermal adaptation scope made from this material is big, is-50 ℃~80 ℃.
Embodiment
Embodiment 1
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram granulous polyurethanes thermoplastic elastomers and the 50 gram lime carbonate adding containers, the time is 4 minutes, makes these two kinds of mixing of materials even;
Step 2: add 120 gram paraffin oils, it is even to each mixing of materials to knead, and paraffin oils is infiltrated in the polyurethanes thermoplastic elastomer;
Step 3: add 30 gram anti-aging agent RDs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1200 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 165 ℃, and the compression section temperature of screw rod is 180 ℃, and the melt zone temperature of screw rod is 185 ℃.
Each component and the content thereof of prepared 1200 gram bra liner materials are: polyurethanes thermoplastic elastomer 1000 grams, lime carbonate 50 grams, paraffin oils 120 grams and anti-aging agent RD 30 grams.
Embodiment 2
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram granulous thermoplastic natural rubbers and the 80 gram lime carbonate adding containers, the time is 5 minutes, makes these two kinds of mixing of materials even;
Step 2: add 180 gram naphthenic oil, it is even to each mixing of materials to knead, and naphthenic oil is infiltrated in the thermoplastic natural rubber;
Step 3: add 20 gram antioxidant A W, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1280 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 180 ℃, and the compression section temperature of screw rod is 200 ℃, and the melt zone temperature of screw rod is 205 ℃.
Each component and the content thereof of prepared 1280 gram bra liner materials are: thermoplastic natural rubber 1000 grams, lime carbonate 80 grams, naphthenic oil 180 grams and antioxidant A W20 gram.
Embodiment 3
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered melt processible thermoplastic elastomers and the 100 gram lime carbonate adding containers, the time is 6 minutes, makes these two kinds of mixing of materials even;
Step 2: add the fragrant hydrocarbon ils of 250 grams, it is even to each mixing of materials to knead, and fragrant hydrocarbon ils is infiltrated in the melt processible thermoplastic elastomer;
Step 3: add 10 gram antioxidant BLEs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1360 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 170 ℃, and the compression section temperature of screw rod is 185 ℃, and the melt zone temperature of screw rod is 190 ℃.
Each component and the content thereof of prepared 1360 gram bra liner materials are: melt processible thermoplastic elastomer 1000 grams, lime carbonate 100 grams, fragrant hydrocarbon ils 250 grams and antioxidant BLE 10 grams.
Embodiment 4
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered melt processible thermoplastic elastomers and the 50 gram talcum powder adding containers, the time is 4 minutes, makes these two kinds of mixing of materials even;
Step 2: add 190 gram paraffin oils, it is even to each mixing of materials to knead, and paraffin oils is infiltrated in the melt processible thermoplastic elastomer;
Step 3: add 20 gram anti-aging agent RDs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1260 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 175 ℃, and the compression section temperature of screw rod is 190 ℃, and the melt zone temperature of screw rod is 200 ℃.
Each component and the content thereof of prepared 1260 gram bra liner materials are: melt processible thermoplastic elastomer 1000 grams, talcum powder 50 grams, paraffin oils 190 grams and anti-aging agent RD 20 grams.
Embodiment 5
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered polyurethanes thermoplastic elastomers and the 70 gram talcum powder adding containers, the time is 5 minutes, makes these two kinds of mixing of materials even;
Step 2: add 250 gram naphthenic oil, it is even to each mixing of materials to knead, and naphthenic oil is infiltrated in the polyurethanes thermoplastic elastomer;
Step 3: add 10 gram antioxidant A W, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1330 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 168 ℃, and the compression section temperature of screw rod is 188 ℃, and the melt zone temperature of screw rod is 198 ℃.
Each component and the content thereof of prepared 1330 gram bra liner materials are: polyurethanes thermoplastic elastomer 1000 grams, talcum powder 70 grams, naphthenic oil 250 grams and antioxidant A W10 gram.
Embodiment 6
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram granulous thermoplastic natural rubbers and the 100 gram talcum powder adding containers, the time is 6 minutes, makes these two kinds of mixing of materials even;
Step 2: add the fragrant hydrocarbon ils of 120 grams, it is even to each mixing of materials to knead, and fragrant hydrocarbon ils is infiltrated in the thermoplastic natural rubber;
Step 3: add 30 gram antioxidant BLEs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1250 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 170 ℃, and the compression section temperature of screw rod is 190 ℃, and the melt zone temperature of screw rod is 195 ℃.
Each component and the content thereof of prepared 1250 gram bra liner materials are: thermoplastic natural rubber 1000 grams, talcum powder 100 grams, fragrant hydrocarbon ils 120 grams and antioxidant BLE 30 grams.
Embodiment 7
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram granulous melt processible thermoplastic elastomers and the 50 gram zinc oxide adding containers, the time is 6 minutes, makes these two kinds of mixing of materials even;
Step 2: add 250 gram paraffin oils, it is even to each mixing of materials to knead, and paraffin oils is infiltrated in the melt processible thermoplastic elastomer;
Step 3: add 20 gram antioxidant BLEs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1320 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 175 ℃, and the compression section temperature of screw rod is 200 ℃, and the melt zone temperature of screw rod is 205 ℃.
Each component and the content thereof of prepared 1320 gram bra liner materials are: melt processible thermoplastic elastomer 1000 grams, zinc oxide 50 grams, paraffin oils 250 grams and antioxidant BLE 20 grams.
Embodiment 8
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered thermoplastic natural rubbers and the 60 gram zinc oxide adding containers, the time is 5 minutes, makes these two kinds of mixing of materials even;
Step 2: add 120 gram naphthenic oil, it is even to each mixing of materials to knead, and naphthenic oil is infiltrated in the thermoplastic natural rubber;
Step 3: add 10 gram anti-aging agent RDs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1190 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 180 ℃, and the compression section temperature of screw rod is 195 ℃, and the melt zone temperature of screw rod is 200 ℃.
Each component and the content thereof of prepared 1190 gram bra liner materials are: thermoplastic natural rubber 1000 grams, zinc oxide 60 grams, naphthenic oil 120 grams and anti-aging agent RD 10 grams.
Embodiment 9
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered polyurethanes thermoplastic elastomers and the 100 gram zinc oxide adding containers, the time is 4 minutes, makes these two kinds of mixing of materials even;
Step 2: add the fragrant hydrocarbon ils of 200 grams, it is even to each mixing of materials to knead, and fragrant hydrocarbon ils is infiltrated in the polyurethanes thermoplastic elastomer;
Step 3: add 30 gram antioxidant A W, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1330 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 180 ℃, and the compression section temperature of screw rod is 190 ℃, and the melt zone temperature of screw rod is 200 ℃.
Each component and the content thereof of prepared 1330 gram bra liner materials are: polyurethanes thermoplastic elastomer 1000 grams, zinc oxide 100 grams, fragrant hydrocarbon ils 200 grams and antioxidant A W30 gram.
Embodiment 10
Prepare a kind of bra liner material by following operation successively:
Step 1: will knead in 1000 gram powdered silicon rubber and the 100 gram lime carbonate adding containers, the time is 6 minutes, makes these two kinds of mixing of materials even;
Step 2: add the fragrant hydrocarbon ils of 200 grams, it is even to each mixing of materials to knead, and fragrant hydrocarbon ils is infiltrated in the silicon rubber;
Step 3: add 20 gram anti-aging agent RDs, make each mixing of materials even;
Step 4:, extrude then and, promptly make 1320 and restrain the granulous bra liner materials in head pelletizing moulding by the forcing machine thermoplastication, forcing machine adopts single screw extrusion machine, the feed section temperature of its screw rod is 165 ℃, and the compression section temperature of screw rod is 180 ℃, and the melt zone temperature of screw rod is 185 ℃.
Each component and the content thereof of prepared 1320 gram bra liner materials are: silicon rubber 1000 grams, lime carbonate 100 grams, fragrant hydrocarbon ils 200 grams and anti-aging agent RD 20 grams.
Among the present invention, used thermoplastic elastomer can have substitute, used weighting agent, softening agent and anti-aging agent also can have substitute, as long as the material that makes can not produce harmful material and have satisfactory flexibility, elasticity, thermoplasticity, anti ageing property.

Claims (6)

1. a bra liner material is characterized in that each component and content thereof are: thermoplastic elastomer; Weight is 5~10% talcum powder, lime carbonate or zinc oxide of above-mentioned thermoplastic elastomer; Weight is that 12~25% oil of above-mentioned thermoplastic elastomer is a softening agent; Weight is 1~3% ketoamine class anti-aging agent of above-mentioned thermoplastic elastomer.
2. a kind of bra liner material according to claim 1 is characterized in that: described thermoplastic elastomer is polyurethanes thermoplastic elastomer, thermoplastic natural rubber, melt processible thermoplastic elastomer or silicon rubber.
3. a kind of bra liner material according to claim 1 is characterized in that: described oil is that softening agent is paraffin oils, naphthenic oil or fragrant hydrocarbon ils.
4. a kind of bra liner material according to claim 1 is characterized in that: described ketoamine class anti-aging agent is anti-aging agent RD, antioxidant A W or antioxidant BLE.
5. the preparation method of a kind of bra liner material according to claim 1 is characterized in that may further comprise the steps:
Step 1: with powdery or granulous thermoplastic elastomer and weight is that 5~10% talcum powder of above-mentioned thermoplastic elastomer or lime carbonate or zinc oxide add in the container and kneads, and the time is 4~6 minutes, makes these two kinds of mixing of materials even;
Step 2: 12~25% the oil that adds weight and be above-mentioned thermoplastic elastomer is a softening agent, and it is even to each mixing of materials to knead, and making oil is that softening agent infiltrates in the thermoplastic elastomer;
Step 3: add weight and be 1~3% ketoamine class anti-aging agent of above-mentioned thermoplastic elastomer, make each mixing of materials even;
Step 4:, extrude then and, promptly make the granulous bra liner material in head pelletizing moulding by the forcing machine thermoplastication.
6. the preparation method of a kind of bra liner material according to claim 5, it is characterized in that: described forcing machine is a single screw extrusion machine, the feed section temperature of its screw rod is 165 ℃~180 ℃, and the compression section temperature of screw rod is 180 ℃~200 ℃, and the melt zone temperature of screw rod is 185 ℃~205 ℃.
CN 200410027046 2004-04-24 2004-04-24 Bra cushion material and its making method Expired - Lifetime CN1279118C (en)

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Application Number Priority Date Filing Date Title
CN 200410027046 CN1279118C (en) 2004-04-24 2004-04-24 Bra cushion material and its making method

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CN1279118C CN1279118C (en) 2006-10-11

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756330A (en) * 2013-12-26 2014-04-30 惠州市永卓科技有限公司 Special silica gel for nubra and preparation method thereof
CN105838296A (en) * 2016-04-26 2016-08-10 东莞市魔丽身段服装有限公司 Non-stick hot melt adhesive and preparation process thereof
CN105860891A (en) * 2016-04-26 2016-08-17 东莞市魔丽身段服装有限公司 Non-cohesive hot-melt gel and preparation technique thereof
CN106496673A (en) * 2016-11-01 2017-03-15 王欣 A kind of latex brassiere mold cup
CN107286679A (en) * 2016-04-05 2017-10-24 王建伟 A kind of brassiere chest cup making material and its manufacture craft
CN107474334A (en) * 2016-06-08 2017-12-15 宋伟 Underwear mold cup and preparation method
CN109575378A (en) * 2018-11-16 2019-04-05 祝文艳 A kind of insert of brassiere material and preparation method thereof
CN110885471A (en) * 2019-11-28 2020-03-17 广东祥雄科学器材实业有限公司 Production process of SEBS rubber bra pad foaming material
CN111763430A (en) * 2020-07-01 2020-10-13 佛山市南方橡塑有限公司 Bra lining material
CN112300559A (en) * 2020-11-02 2021-02-02 深圳市夏娃之秀服饰有限公司 Improved bra lining material and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756330B (en) * 2013-12-26 2016-08-17 惠州市永卓科技有限公司 A kind of breast patch silicon special gel and preparation method thereof
CN103756330A (en) * 2013-12-26 2014-04-30 惠州市永卓科技有限公司 Special silica gel for nubra and preparation method thereof
CN107286679A (en) * 2016-04-05 2017-10-24 王建伟 A kind of brassiere chest cup making material and its manufacture craft
CN105838296A (en) * 2016-04-26 2016-08-10 东莞市魔丽身段服装有限公司 Non-stick hot melt adhesive and preparation process thereof
CN105860891A (en) * 2016-04-26 2016-08-17 东莞市魔丽身段服装有限公司 Non-cohesive hot-melt gel and preparation technique thereof
CN107474334A (en) * 2016-06-08 2017-12-15 宋伟 Underwear mold cup and preparation method
CN106496673A (en) * 2016-11-01 2017-03-15 王欣 A kind of latex brassiere mold cup
CN106496673B (en) * 2016-11-01 2018-07-03 王欣 A kind of latex brassiere mold cup
CN109575378A (en) * 2018-11-16 2019-04-05 祝文艳 A kind of insert of brassiere material and preparation method thereof
CN110885471A (en) * 2019-11-28 2020-03-17 广东祥雄科学器材实业有限公司 Production process of SEBS rubber bra pad foaming material
CN110885471B (en) * 2019-11-28 2022-05-10 广东祥雄科学器材实业有限公司 Production process of SEBS rubber bra pad foaming material
CN111763430A (en) * 2020-07-01 2020-10-13 佛山市南方橡塑有限公司 Bra lining material
CN112300559A (en) * 2020-11-02 2021-02-02 深圳市夏娃之秀服饰有限公司 Improved bra lining material and preparation method thereof

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