CN1302065C - New type polyolefin thermoplastic elastomer - Google Patents
New type polyolefin thermoplastic elastomer Download PDFInfo
- Publication number
- CN1302065C CN1302065C CNB2004100265723A CN200410026572A CN1302065C CN 1302065 C CN1302065 C CN 1302065C CN B2004100265723 A CNB2004100265723 A CN B2004100265723A CN 200410026572 A CN200410026572 A CN 200410026572A CN 1302065 C CN1302065 C CN 1302065C
- Authority
- CN
- China
- Prior art keywords
- thermoplastic elastomer
- styrene
- olefinic
- elastomer
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 18
- 229920000098 polyolefin Polymers 0.000 title abstract description 5
- 239000004743 Polypropylene Substances 0.000 claims abstract description 24
- 229920001155 polypropylene Polymers 0.000 claims abstract description 24
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 229920001971 elastomer Polymers 0.000 claims abstract description 15
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 polypropylene Polymers 0.000 claims abstract description 12
- 239000000806 elastomer Substances 0.000 claims abstract description 5
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920000642 polymer Polymers 0.000 claims abstract 4
- 239000004971 Cross linker Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 8
- 238000004073 vulcanization Methods 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical group CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims 1
- 229920005629 polypropylene homopolymer Polymers 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 229920002397 thermoplastic olefin Polymers 0.000 abstract 3
- 239000004135 Bone phosphate Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000013536 elastomeric material Substances 0.000 abstract 1
- 239000005060 rubber Substances 0.000 description 10
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 7
- 229920002943 EPDM rubber Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 229920013649 Paracril Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229920006258 high performance thermoplastic Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- IQVBOXXFTNNNDF-UHFFFAOYSA-N styrene 1,2,3-tris(ethenyl)benzene Chemical compound C(=C)C=1C(=C(C=CC1)C=C)C=C.C=CC1=CC=CC=C1 IQVBOXXFTNNNDF-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Abstract
Description
Tensile strength MPa | Elongation at break (%) | Melting index (g/10min) | Shore hardness | Stress at definite elongation | |||
A | D | 100% | 200% | 300% | |||
11.3 | 558 | 0.685 | 85 | 25 | 5.8 | 6.8 | 8.0 |
Tensile strength MPa | Elongation at break (%) | Melting index (g/10min) | Shore hardness | Stress at definite elongation | |||
A | D | 100% | 200% | 300% | |||
9.7 | 577 | 0.7 | 88 | 26 | 5.6 | 6.5 | 7.4 |
Tensile strength MPa | Elongation at break (%) | Melting index (g/10min) | Shore hardness | Stress at definite elongation | |||
A | D | 100% | 200% | 300% | |||
8.2 | 484 | 0.62 | 90 | 26.5 | 4.9 | 5.7 | 6.6 |
Tensile strength MPa | Elongation at break (%) | Melting index (g/10min) | Shore hardness | Stress at definite elongation | |||
A | D | 100% | 200% | 300% | |||
9.7 | 343 | 0.83 | 98 | 29 | 6.5 | 7.5 | 8.6 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100265723A CN1302065C (en) | 2004-03-23 | 2004-03-23 | New type polyolefin thermoplastic elastomer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100265723A CN1302065C (en) | 2004-03-23 | 2004-03-23 | New type polyolefin thermoplastic elastomer |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1563173A CN1563173A (en) | 2005-01-12 |
CN1302065C true CN1302065C (en) | 2007-02-28 |
Family
ID=34480649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100265723A Expired - Fee Related CN1302065C (en) | 2004-03-23 | 2004-03-23 | New type polyolefin thermoplastic elastomer |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1302065C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108003542A (en) * | 2017-12-15 | 2018-05-08 | 深圳恒方大高分子材料科技有限公司 | A kind of peristaltic pump polyolefin elastomer and preparation method thereof |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100443519C (en) * | 2006-09-06 | 2008-12-17 | 江苏创源科技新材料有限公司 | Fusion graft process for modified polypropylene/acrylic acid polyester ether |
CN101307219B (en) * | 2007-05-16 | 2013-09-25 | 南通江洲工程材料科技有限公司 | Multicomponent high molecular composite construction sealing materials and production process thereof |
US8604125B2 (en) | 2008-06-25 | 2013-12-10 | Lg Chem, Ltd. | Polypropylene-based resin composition and automobile parts using the same |
CN101486816B (en) * | 2008-12-08 | 2011-05-11 | 宁波工程学院 | High impact resistance polypropylene composite material and preparation thereof |
CN101880432B (en) * | 2010-07-02 | 2012-02-01 | 深圳市科聚新材料有限公司 | Polyhydric graft ethylene-octene copolymer and preparation method thereof |
CN102367311B (en) * | 2011-09-26 | 2013-06-12 | 广州市聚赛龙工程塑料有限公司 | Low specific gravity polypropylene composite material for automobile bumper use and its preparation method |
CN102443241B (en) * | 2011-10-26 | 2013-05-29 | 江苏恒峰线缆有限公司 | SBS sulfonate prepared by reactive extrusion and addition, and preparation method thereof |
CN102786763A (en) * | 2012-06-04 | 2012-11-21 | 上海日杰弹性体塑胶有限公司 | Flexible pipe material for temperature resistant and thermoplastic elastomer and preparation method thereof |
CN102816336B (en) * | 2012-09-07 | 2014-10-22 | 上海第二工业大学 | Method for preparing high filling plastic masterbatch for polypropylene woven bag |
JP6322651B2 (en) * | 2012-12-27 | 2018-05-09 | ダウ グローバル テクノロジーズ エルエルシー | Manufacture of TPO roof membrane by different direction rotational extrusion |
CN107974024B (en) * | 2017-12-20 | 2020-03-17 | 石家庄英利体育用品有限公司 | Thermoplastic elastomer composition, and preparation method and application thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1385466A (en) * | 2001-05-16 | 2002-12-18 | 中国石油化工股份有限公司洛阳分公司 | Novel thermoplastic elastomer and preparation process thereof |
CN1435442A (en) * | 2002-01-28 | 2003-08-13 | 四川大学 | Tertiary polypropylene/elastomer/inorganic filler composite material and preparing method thereof |
-
2004
- 2004-03-23 CN CNB2004100265723A patent/CN1302065C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1385466A (en) * | 2001-05-16 | 2002-12-18 | 中国石油化工股份有限公司洛阳分公司 | Novel thermoplastic elastomer and preparation process thereof |
CN1435442A (en) * | 2002-01-28 | 2003-08-13 | 四川大学 | Tertiary polypropylene/elastomer/inorganic filler composite material and preparing method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108003542A (en) * | 2017-12-15 | 2018-05-08 | 深圳恒方大高分子材料科技有限公司 | A kind of peristaltic pump polyolefin elastomer and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN1563173A (en) | 2005-01-12 |
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Date of cancellation: 20110118 Granted publication date: 20070228 Pledgee: China Merchants Bank, Limited by Share Ltd, Guangzhou surplus Plaza Branch Pledgor: Guangzhou Lushan chemical materials Co., Ltd.|Guangzhou Hepalink Mstar Technology Ltd Registration number: 2009440000632 |
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Denomination of invention: Polyolefin thermoplastic elastomer (TPE) composition and preparation method thereof Effective date of registration: 20110118 Granted publication date: 20070228 Pledgee: China Merchants Bank, Limited by Share Ltd, Guangzhou surplus Plaza Branch Pledgor: Guangzhou Lushan New Materials Co., Ltd. Registration number: 2011990000011 |
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Date of cancellation: 20120620 Granted publication date: 20070228 Pledgee: China Merchants Bank, Limited by Share Ltd, Guangzhou surplus Plaza Branch Pledgor: Guangzhou Lushan New Materials Co., Ltd. Registration number: 2011990000011 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Polyolefin thermoplastic elastomer (TPE) composition and preparation method thereof Effective date of registration: 20120620 Granted publication date: 20070228 Pledgee: China Merchants Bank, Limited by Share Ltd, Guangzhou branch Pledgor: Guangzhou Lushan New Materials Co., Ltd. Registration number: 2012990000312 |
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Date of cancellation: 20140620 Granted publication date: 20070228 Pledgee: China Merchants Bank, Limited by Share Ltd, Guangzhou branch Pledgor: Guangzhou Lushan New Materials Co., Ltd. Registration number: 2012990000312 |
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