CN1569341A - Method for selecting iron ore from red mud - Google Patents

Method for selecting iron ore from red mud Download PDF

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Publication number
CN1569341A
CN1569341A CN 200410023997 CN200410023997A CN1569341A CN 1569341 A CN1569341 A CN 1569341A CN 200410023997 CN200410023997 CN 200410023997 CN 200410023997 A CN200410023997 A CN 200410023997A CN 1569341 A CN1569341 A CN 1569341A
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Prior art keywords
red mud
red
iron
controlled
background field
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CN 200410023997
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CN1246082C (en
Inventor
温金德
冯婕
张玉明
李卫东
张坤
聂雨滨
王利娟
姜波
李福强
刘志云
蒋涛
孟旭
潘明友
王明银
田朝波
徐春华
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Shandong Qianshun Mining And Metallurgy Technology Co.,Ltd.
Aluminum Corp of China Ltd
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SHANDONG QIANSHUN MINING AND METALLURGY TECHNOLOGY Co Ltd
SHANDONG ALUMINIUM INDUSTRY Co Ltd
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Priority to CN 200410023997 priority Critical patent/CN1246082C/en
Publication of CN1569341A publication Critical patent/CN1569341A/en
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Publication of CN1246082C publication Critical patent/CN1246082C/en
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Abstract

The invention is a method for selecting iron ore from red mud. It preprocesses the red mud to eliminate the tiny red mud and acquires the red mud sand, carries on grinding and classification to the red mud sand then eliminates the tail ore through raw selection and acquires the concentrate after choiceness. The picking process uses high background field density and small pulse frequency, the choiceness uses lower background field density and larger pulse frequency. The flow is simple, and the reclaim rate of iron is high, the reclaim rate of iron can reach to 90%. The invention has excellent economical efficiency and social efficiency.

Description

From red mud, select the method for iron ore
Technical field
The present invention relates to a kind of method of from red mud, selecting iron ore, belong to field of silicate technology, be used for the processing of alumina producing waste red mud residues.
Background technology
At present, the production method of aluminium oxide comprises sintering process, Bayer process and Baeyer sintering combination method in the world, no matter be which kind of alumina-producing method, the capital produces accessory substance---red mud, red mud is as the accessory substance of alumina producing, one ton of aluminium oxide of every production, by-product 1-1.5 ton red mud, general in the world way is that it is piled into the red mud heap.Domestic only have a small amount of red mud to be used to produce cement and red-sludge plastic goods.Red mud is an alkaline matter, and the sewage that the rain-out red mud produces all has pollution to water quality and soil.Contain multiple valuable composition in the red mud, bulk deposition, discharging not only exerts an influence to environment, also being a kind of waste of resource, is the work that economic benefit and many social benefits are arranged to the red mud comprehensive utilization and to the work that valuable element reclaims therefore.
Produce in the technology of aluminium oxide in Baeyer sintering combination method, Bayer red mud need enter sintering process and prepare burden and continue to utilize, reclaim wherein aluminium oxide and sodium oxide molybdena, but the iron oxide that contains in the Bayer process red mud is not used, thereby mix to join and reach alumina by sintering and produce needed ingredient requirement and quartz wherein needs to consume high grade ore, therefore, how rationally to utilize iron wherein simultaneously can alleviate of the influence of quartzy silicon again, become a difficult problem in the Bayer process aluminum oxide production process sintering process.
The composition of red mud is mainly: aluminium oxide 15-25%, and iron oxide 25-35%, silica 15-25%, sodium oxide molybdena 5-15% also contains some other composition.In the aluminium oxide mineral reserve, exist the ferro-aluminum attendant phenomenon, after having passed through alumina extraction technology, valuable element aluminium is extracted out, and valuable element iron is at the accessory substance of alumina producing---obtained enrichment to a certain degree in the red mud, for providing certain basis, so from red mud, recycle the main direction that iron is comprehensive utilization red mud technical research project in the alumina producing always to its comprehensive utilization.
Red mud is handled and comprehensive utilization, is one of difficult problem of puzzlement countries in the world alumina producing always, and the iron in the recovery red mud is an important ring of red mud comprehensive utilization especially, and the various countries scientific research personnel falls over each other to study this difficult problem.Done many work aspect the research of iron in reclaiming red mud such as the former Soviet Union, Japan, Germany, the U.S., main method is magnetic separation, flotation, gravity treatment and combined process flow thereof, and its effect is all undesirable.With red mud and reducing agent mix grinding and carry out reduction roasting, carry out magnetic separation again, can improve the rate of recovery of iron greatly, but production cost height, flow process complexity.Domestic Zhongnan Polytechnic Univ, Northeastern University etc. also reclaim iron to red mud and have carried out more deep research and discussion." adopting the iron in the pulsating high gradient magnetic separator recovery red mud " literary composition that " Jiangxi non-ferrous metal " published on the 4th phase in 2000 has been introduced and has been used pulsating high gradient magnetic separator recovery Pingguo, Guangxi aluminium company to be raw material with Guigang bauxite, the production aluminium oxide produces the iron in the red mud, the result is that TFe is 19% o'clock in raw material, concentrate grade is 54.7%, the rate of recovery is 35.36%, and the feasibility of commercial Application is not strong.
Summary of the invention
The object of the present invention is to provide a kind of method of from red mud, selecting iron ore, the yield height of iron, the iron ore of acquisition is of high grade.
The method of selecting iron ore from red mud of the present invention is at first carried out preliminary treatment to red mud and is removed thin red mud and obtain red muddy sand, and red muddy sand is carried out grind grading, removes mine tailing through roughly selecting respectively again, selected back obtains concentrate.
Grind grading: the one, remove the bur on iron mineral surface, the 2nd, make iron-bearing mineral reach monomer dissociation, preferably the fineness of controlling behind the red muddy sand grind grading was that 200 mesh sieves account for 60~70%.Classification makes material that reaches certain fineness and the feed separation that does not reach this fineness as yet.Roughly selecting operation is to adopt higher background field intensity and less ripple frequency, can reclaim mineral morely, improves the overall recovery of iron mineral; Selected operation is to adopt lower background field intensity and bigger ripple frequency, non-iron mineral and the intergrowth roughly selected in the mineral is removed, to improve the iron grade in the concentrate to greatest extent; Preferably be controlled to be: the background field intensity of roughly selecting operation is controlled to be 0.85~0.95T, and ripple frequency is controlled to be 100~150 times/minute; Selected background field intensity is controlled to be 0.68~0.85T, and ripple frequency is controlled to be 200~250 times/minute.The classifying cyclone of roughly selecting with selected control is preferably in operation under the condition that pressure is 0.20~0.25Mpa, and is effective.
The gained concentrate is handled through washing, removes impurity as far as possible, so that improve the grade of iron ore, the red muddy sand that thin red mud obtains is also better through washing processing meeting with removing.
In order to reduce cost, slurry can be recycled.
The present invention selects iron ore from red mud method flow is simple, is convenient to implement, and the yield height of iron reaches more than 77%, and the overall recovery of iron can reach more than 90%, and the iron ore ferrous grade height of acquisition reaches more than 56%.Enforcement of the present invention can be alleviated the pressure of Bayer process red mud piece-rate system, reduces the pressure of sintering process ore blending system, produces aluminium oxide for Baeyer sintering combination method and has reduced manufacturing cost, has improved the market competitiveness.Simultaneously the ferro element in the red mud is carried out ore dressing and reclaim, the iron ore of selecting can be used for smelting iron, and has reached the purpose of red mud comprehensive utilization, turns waste into wealth, and is beneficial to environmental protection, has good economic benefit and social benefit.
Description of drawings
Fig. 1, one embodiment of the invention process flow diagram.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
The weight percent of the used red mud composition of the present invention consists of:
SiO 220.55, Fe 2O 336.97, Al 2O 320.46, Na 2O 11.36, surplus are other.Wherein, A/S (Al/Si ratio) 1.00, N/S (Na/Si ratio) 0.55.
Through after the primary election, the weight percent of selected red muddy sand consists of:
SiO 214.83, T Fe (total amount of Fe) 46.87, Al 2O 36.54, CaO 0.43, MgO 0.16, surplus be other.Wherein the S element 0.028, P element 0.255.
Ore in sand form thing phase weight percent consists of: N 2OAl 2O 31.68 SiO 21.73H 2O (moisture sodium silicoaluminate) accounts for 22.4%; 3NaAlSiO 4NaOH accounts for 3.4%; Fe 2O 3Account for 68.6%; AlO (OH) (diaspore) accounts for 2.5%; CaCO 3Account for 1.42%.
Essential mineral is bloodstone, goethite, siderite, contains sodium aluminosilicate of water, diaspore, secondly is aragonite and calcite to also have a spot of trona, waterglass, caustic soda etc. in the ore in sand form.
Processing procedure is as follows:
The thin red mud that red mud is removed wherein gets red muddy sand, and red muddy sand by twice separating, washing, is obtained iron-holder at the 30%-40% red muddy sand; With the red muddy sand grind grading, fineness was controlled to be 200 mesh sieves and accounted for 70%, separated with classifying cyclone, operating pressure is controlled at 0.22Mpa, implements to roughly select and selected operation, roughly selects to remove mine tailing and obtain chats, the selected concentrate that obtains, the process conditions of pulsating high gradient magnetic separation control are as follows:
Roughly select part: background field intensity magnetic flux density 0.855T, pulse frequency 125 times/minute, flow 100L/H gives 3 minutes ore deposit time;
Selected part: background field intensity magnetic flux density 0.681T, pulse frequency 200 times/minute, flow 100L/H gives 3 minutes ore deposit time.
Can carry out carrying out washing treatment to concentrate.Each operation washings can be recycled.
The concentrate grade of Huo Deing is 55.56% at last, and productive rate is 77.79%, and the overall recovery of iron is 90.38%; The chats grade of selecting is 49.55%, and productive rate is 9.26%, and the overall recovery of iron is 9.6%; The tailings grade of selecting is 0.1%, and productive rate is 12.95%, and the overall recovery of iron is 0.02%.
Embodiment 2
The method of selecting iron ore from red mud of the present invention is as follows:
The thin red mud that red mud is removed wherein gets red muddy sand, and red muddy sand by twice separating, washing, is obtained red muddy sand; With the red muddy sand grind grading, fineness was controlled to be 200 mesh sieves and accounted for 60%, separated with classifying cyclone, operating pressure is controlled at 0.20Mpa, implements to roughly select and selected operation, roughly selects to remove mine tailing and obtain chats, the selected concentrate that obtains, the process conditions of pulsating high gradient magnetic separation control are as follows:
Roughly select part: background field intensity magnetic flux density 0.92T, pulse frequency 140 times/minute, flow 100L/H gives 3 minutes ore deposit time;
Selected part: background field intensity magnetic flux density 0.75T, pulse frequency 220 times/minute, flow 100L/H gives 3 minutes ore deposit time.
Can carry out carrying out washing treatment to concentrate.Each operation washings can be recycled.
Other is with embodiment 1.
Embodiment 3
The method of selecting iron ore from red mud of the present invention is as follows:
The thin red mud that red mud is removed wherein gets red muddy sand, and red muddy sand by twice separating, washing, is obtained red muddy sand; With the red muddy sand grind grading, fineness was controlled to be 200 mesh sieves and accounted for 65%, separated with classifying cyclone, operating pressure is controlled at 0.24Mpa, implements to roughly select and selected operation, roughly selects to remove mine tailing and obtain chats, the selected concentrate that obtains, the process conditions of pulsating high gradient magnetic separation control are as follows:
Roughly select part: background field intensity magnetic flux density 0.90T, pulse frequency 120 times/minute, flow 110L/H gives 3 minutes ore deposit time;
Selected part: background field intensity magnetic flux density 0.80T, pulse frequency 230 times/minute, flow 105L/H gives 3 minutes ore deposit time.
Can carry out carrying out washing treatment to concentrate.Each operation washings can be recycled.
Other is with embodiment 1.
Embodiment 4
The method of selecting iron ore from red mud of the present invention is as follows:
The thin red mud that red mud is removed wherein gets red muddy sand, and red muddy sand by twice separating, washing, is obtained red muddy sand; With the red muddy sand grind grading, fineness was controlled to be 200 mesh sieves and accounted for 62%, separated with classifying cyclone, operating pressure is controlled at 0.21Mpa, implements to roughly select and selected operation, roughly selects to remove mine tailing and obtain chats, the selected concentrate that obtains, the process conditions of pulsating high gradient magnetic separation control are as follows:
Roughly select part: background field intensity magnetic flux density 0.88T, pulse frequency 140 times/minute, flow 110L/H gives 3.5 minutes ore deposit time;
Selected part: background field intensity magnetic flux density 0.81T, pulse frequency 225 times/minute, flow 110L/H gives 3 minutes ore deposit time.
Other is with embodiment 1.

Claims (9)

1, a kind of method of selecting iron ore from red mud is characterized in that at first red mud is carried out preliminary treatment to be removed thin red mud and obtain red muddy sand, and red muddy sand is carried out grind grading, removes mine tailing through roughly selecting respectively again, selected back obtains concentrate.
2, method according to claim 1 is characterized in that fineness was controlled at 200 mesh sieves behind the red mud grind grading to account for 60~70%.
3, method according to claim 2, it is characterized in that roughly selecting operation is to adopt higher background field intensity and less ripple frequency to carry out.
4, method according to claim 3 is characterized in that the background field intensity of roughly selecting operation is controlled to be 0.85~0.95T, and ripple frequency is controlled to be 100~150 times/minute.
5, method according to claim 3 is characterized in that selected operation is to adopt lower background field intensity and bigger ripple frequency to carry out.
6, method according to claim 5 is characterized in that selected background field intensity is controlled to be 0.68~0.85T, and ripple frequency is controlled to be 200~250 times/minute.
7, according to the described method of the arbitrary claim of claim 1-6, the pressure that it is characterized in that roughly selecting with the classifying cyclone of selected control is 0.20~0.25MPa.
8, method according to claim 7 is characterized in that concentrate need be through the washing processing.
9, method according to claim 8 is characterized in that removing thin red mud and obtains red muddy sand and need handle through washing.
CN 200410023997 2004-05-14 2004-05-14 Method for selecting iron ore from red mud Expired - Lifetime CN1246082C (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865146B (en) * 2005-05-18 2010-07-28 贵阳铝镁设计研究院 Red mud desanding and coarse matter removing method in alumina production
CN101831560A (en) * 2010-06-10 2010-09-15 中国铝业股份有限公司 Method for producing iron ore concentrate by using Bayer process red muddy sand
CN101875499A (en) * 2010-06-10 2010-11-03 中国铝业股份有限公司 Non-waste-residue production process for bauxite
CN101153350B (en) * 2007-09-17 2011-05-25 济南钢铁股份有限公司 Technique for industrialized development and utilization of red mud
CN101417261B (en) * 2008-11-21 2011-10-26 中国铝业股份有限公司 Bayer process red mud processing method
CN102989581A (en) * 2012-09-29 2013-03-27 贵州绿水青山环保科技有限公司 Method for removing radioactivity of red mud
CN104368440A (en) * 2014-09-30 2015-02-25 中国铝业股份有限公司 Novel technology and device for Bayer process-based separation of iron in high-iron red mud
CN105478218A (en) * 2015-05-07 2016-04-13 王海超 Processing method of separating fine red mud
CN108686828A (en) * 2018-05-29 2018-10-23 湖南埃铝环保科技有限公司 A method of sorting carries iron and removes sodium from red mud
CN111589572A (en) * 2020-05-21 2020-08-28 金建工程设计有限公司 Process for recovering iron ore concentrate and ore sand from alumina red mud
WO2024098929A1 (en) * 2022-11-08 2024-05-16 中铝郑州有色金属研究院有限公司 Treatment method for red mud resulting from digestion of high-iron bauxite

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865146B (en) * 2005-05-18 2010-07-28 贵阳铝镁设计研究院 Red mud desanding and coarse matter removing method in alumina production
CN101153350B (en) * 2007-09-17 2011-05-25 济南钢铁股份有限公司 Technique for industrialized development and utilization of red mud
CN101417261B (en) * 2008-11-21 2011-10-26 中国铝业股份有限公司 Bayer process red mud processing method
CN101831560A (en) * 2010-06-10 2010-09-15 中国铝业股份有限公司 Method for producing iron ore concentrate by using Bayer process red muddy sand
CN101875499A (en) * 2010-06-10 2010-11-03 中国铝业股份有限公司 Non-waste-residue production process for bauxite
CN102989581A (en) * 2012-09-29 2013-03-27 贵州绿水青山环保科技有限公司 Method for removing radioactivity of red mud
CN104368440A (en) * 2014-09-30 2015-02-25 中国铝业股份有限公司 Novel technology and device for Bayer process-based separation of iron in high-iron red mud
CN105478218A (en) * 2015-05-07 2016-04-13 王海超 Processing method of separating fine red mud
CN108686828A (en) * 2018-05-29 2018-10-23 湖南埃铝环保科技有限公司 A method of sorting carries iron and removes sodium from red mud
CN111589572A (en) * 2020-05-21 2020-08-28 金建工程设计有限公司 Process for recovering iron ore concentrate and ore sand from alumina red mud
WO2024098929A1 (en) * 2022-11-08 2024-05-16 中铝郑州有色金属研究院有限公司 Treatment method for red mud resulting from digestion of high-iron bauxite

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