CN1565289A - Black tourmaline containing tobacco product and its making method and uses - Google Patents

Black tourmaline containing tobacco product and its making method and uses Download PDF

Info

Publication number
CN1565289A
CN1565289A CN 03129331 CN03129331A CN1565289A CN 1565289 A CN1565289 A CN 1565289A CN 03129331 CN03129331 CN 03129331 CN 03129331 A CN03129331 A CN 03129331A CN 1565289 A CN1565289 A CN 1565289A
Authority
CN
China
Prior art keywords
cigarette
aphrizite
smoking article
weight
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 03129331
Other languages
Chinese (zh)
Other versions
CN100341441C (en
Inventor
周秋华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNB03129331XA priority Critical patent/CN100341441C/en
Publication of CN1565289A publication Critical patent/CN1565289A/en
Application granted granted Critical
Publication of CN100341441C publication Critical patent/CN100341441C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

The invention discloses a cigarette product, which comprises 0.1-20 wt% of black tourmaline whose particle size is between 0.1-100 micrometer, the invention also discloses a process for preparing the cigarette product, which comprises the steps of disintegrating the tourmaline and mixing cigarette product raw materials.

Description

The smoking article and method for making and the purposes that contain aphrizite
Technical field
The present invention relates to smoking article, particularly contain the smoking article of aphrizite.Also relate to its preparation method and be used to reduce smoking nicotine, reduce tar content and improve the purposes of mouthfeel.
Background technology
As everyone knows, smoking is sizable for the threat of human health.The Nicotine that tobacco discharged in smoking process, carbon monoxide, smoking nicotine etc. not only to smoker itself, are very large to environment on every side and involuntary smoker's harm.Effectively reduce these pollutions and harm along with improving constantly of social civilization degree more and more seems most important.
For the aerial release of tar content, CO, smoking nicotine that reduces cigarette, country has formulated certain standard.Tar is to measure by YC/T29, the regulation tar content is low<and 12.0mg, in<16.0mg, height<23.0mg.For human beings'health,, require in the world tar content to be dropped to below the 12.0mg in the end of this century in order to reduce pollution.The atmospheric environment of GB/T16447-1996 tobacco and tobacco product, adjusting and test, GB/T16450-1996 routine analysis smoking machine, definition and standard conditions.The standard-required carbon monoxide is reduced to<15.0mg, and the smoking nicotine sense organ is made moderate progress just can illustrate that oneself reduces 0.1mg.
In recent years, there are many researchists to explore for the objectionable impurities that how to reduce cigarette.For example, CN1252245, Guo Cancheng, on November 23rd, 1999 submitted to, disclosed the method that a kind of biological tobacco reduces tar.This method is to use the metal porphyrins spray solution on pipe tobacco, and the tar of tobacco and obnoxious flavour CO, NO content are descended.Metal porphyrins is the analogue of human-body biological enzyme, can promote benzopyrene and CO, NO to reduce.
Aphrizite contains tens kinds of trace elements of abundant needed by human: magnesium, sulphur, iron, potassium, calcium, sodium, copper, zinc, cobalt, phosphorus, titanium, selenium or the like.Because of the content of magnesium and iron is the highest tourmalinite that becomes black.Its chemical structure more complicated, its chemical general formula are WX 8Y (BO 3) 3Si 6O 18(OH, F) 4, W=Na wherein, K, Ca; X=Mn, Mg, Li, Fe, Al; Y=V, Fe, Cr, Al.Tourmaline capable is used for various fields, for example water activation, sewage disposal, washing, preparation soil and fertilizer etc.At present, the data record is not arranged as yet, tourmalinite is used for the tobacco detoxifcation.
Summary of the invention
The objective of the invention is to use aphrizite as raw material, cigarette is carried out the negative ion detoxifcation, the tar in releasing and the reduction cigarette and the method for smoking nicotine, and the product of this method preparation.
One aspect of the present invention provides a kind of smoking article, and these goods contain the particle diameter of 0.1-20% weight at the 0.1-100 micron, and 0.5-50 micron preferably is more preferably the aphrizite of 4-25 micron.
In one embodiment of the invention, smoking article is selected from cigarette tissue, filter tip, cigarette with filter tip, cigarette package, Cigarette container, cigarette tin, cigarette package Jie sheet.
In another embodiment of the present invention, smoking article preferably contains the aphrizite of 0.5-10% weight, more preferably contains the aphrizite of 1-5% weight.
Aspect second of the present invention, a kind of method for preparing smoking article is provided, comprise step:
(a) the classified processing of aphrizite being crushed to particle diameter is the 0.1-100 micron;
(b) tourmalinite that will account for total goods raw material 0.1-20% weight mixes the smoking article raw material;
(c) make smoking article.
In one embodiment of the invention, will account for overall package material 0.5-10% weight, the aphrizite of preferred 1-5% weight mixes the smoking article raw material.
In another embodiment of the present invention, the particle diameter of this aphrizite is the 0.5-50 micron preferably, is more preferably the 4-25 micron.
Also have among the embodiment of the present invention, the product that this method makes is selected from cigarette tissue, filter tip, cigarette with filter tip, cigarette package, Cigarette container, cigarette tin, cigarette package Jie sheet.
The purposes of smoking article of the present invention is provided aspect the 3rd of the present invention, and this product is used to reduce smoking nicotine, reduces tar content and improves mouthfeel.
Description of drawings
Fig. 1 has shown the size distribution with the aphrizite powder of method preparation of the present invention.
Embodiment
The inventor finds that under study for action after aphrizite carried out the nanotechnology superfine grinding, along with diminishing of particle diameter, the ir radiation and the anion-generating capacity that are sent changed.When particle diameter reached the 4.85um left and right sides, its ir radiation was up to 0.95, and anion-generating capacity is 1600/cm 3, ir radiation and negative ion can effectively decompose harmful poisonous substance and reach 70%.
Through the aphrizite powder of the ultra-fine technical finesse of nanometer, its negative ion usefulness can be removed carcinogenic substance benzopyrene, smoking nicotine, carbon monoxide and the ammonia in the cigarette.Also can improve simultaneously the intravital oxygen metabolism of people, improve the lung sharpness.
Aphrizite is an inorganics, and its stability is good, and is nontoxic, and detoxifying effect is good, and the industrialization cost is low.Tobacco is being removed smoking nicotine and detoxifying de-odorised simultaneously, this product can also replenish essential various trace elements in the human body, plays to reduce and pollutes, protects environment, wholesome social benefit and economic benefit.
Smoking article among the present invention is meant Jie's sheet of the cigarette tissue, cigarette package, Cigarette container, cigarette tin and the insertion cigarette case that are used for containers of cigarettes etc., under these situations aphrizite is mixed in the paper pulp, uses the ordinary method dry forming.This term also comprises the cigarette filter that aphrizite and sponge blending in of fibers are made, and this filter tip and pipe tobacco one are reinstated the cigarette that the cigarette tissue parcel forms.
The used concrete consumption of aphrizite of the present invention is the 0.1-20% weight of total goods raw material.With this ratio, the aphrizite consumption that is converted to every cigarette is a 0.005%-1% weight.
Embodiment 1
The preparation of micron order aphrizite
Under the normal temperature and pressure state, carry out stage treatment, aphrizite is crushed to the 0.1-100 micron with micronizer mill.
Fig. 1 is seen in the distribution of aphrizite powder.
According to ir radiation as a result diameter of particle reach as high as 0.93 when the 4.85um, then get powder particle diameter mean value 3.96um, use the LS particle size analyzer to carry out the test of granularity and distribution thereof.See table 1 for details.
Table 1: sample powder particle size principal dimension parameter
Particle diameter/um Volume cumulative distribution % Account for total distributed %
????1.459 ????10 ????10
????2.000 ????17.07 ????7.07
????2.494 ????25 ????7.94
????3.960 ????50 ????25
????5.00 ????65.58 ????15.58
????5.781 ????75 ????9.92
????7.60 ????90 ????15
????8.00 ????92.16 ????2.16
????10.00 ????98.34 ????6.18
????14.00 ????100 ????10.66
Embodiment 2
The negative ion incidence of aphrizite powder
Testing tool: ITC-201A atmospheric ion concentration tester
Entrust Shanghai City environmentfriendly products quality supervision and test master station with this tester, measured every cubic metre negative ion concentration according to standard method.
Table 2: sample anion-generating capacity and grain size parameter
Sample Particle diameter/um Anion-generating capacity/cm 3(static state) Anion-generating capacity/cm 3(dynamically)
????A ????0.1 ????300 ????1200
????B ????10.00 ????395 ????1580
????C ????25.00 ????400 ????1600
????D ????100.00 ????350 ????1400
This shows: the particle diameter of sample powder is not thin more good more.Size distribution can reach maximum negative ion incidence in the time of 25 microns.Particle between the 0.1-100 micron all has obvious effect.
Following examples adopt the prepared aphrizite powder of embodiment 1.
Embodiment 3
Prepare cigarette tissue with aphrizite
With 5% weight 10 aphrizites are mixed in the 200g cigarette tissue paper pulp, stir, pave normal temperature and dry and make cigarette tissue.Roll 0.75 a gram/commercially available pipe tobacco (seven wolves) with it, make cigarette.
Embodiment 4
Prepare cigarette filter with aphrizite
With 5% weight the aphrizite powder is mixed in the 200g sponge fiber, be compacted into cigarette filter.Itself and 0.75 a gram/commercially available pipe tobacco (seven wolves) are reinstated the commercial cigarettes paper roll and risen, make cigarette with filter tip.
Embodiment 5
Prepare cigarette package with aphrizite
The aphrizite powder is mixed with 200 gram vinyon powder or 200g paper pulp with 5% weight, pour mould or oven dry compacting and the folding cigarette package of making into.
Embodiment 6
Prepare cigarette package Jie sheet with aphrizite
The aphrizite powder is mixed with 200g plastic powders or paper pulp with 5% weight, be pressed into Jie's sheet of 5cm * 5cm in the cigarette package.The every heavy 1g of Jie's sheet.
Embodiment 7
Prepare cigarette tin with aphrizite
50g aphrizite powder is mixed in 1 kilogram of plastic pellet, pour press molding in the mould into, make 5 cylindrical cigarette tins.Each cigarette tin can be adorned 100 cigarettes, heavy 200g.
Embodiment 8
The tobacco detoxifcation test of aphrizite goods
Tested the smoke panel test contrast of human body according to the method for standard GB 5606.4-1996 for various cigarette.
10 people are divided into 2 groups, before the cigarette divisional processing of each plate and after handling, respectively exhaust 1.
A. embodiment 3 and 4 cigarette of making is made suction immediately behind the cigarette.
B. cigarette is placed on embodiment 5,6,7 made cigarette package, cigarette bucket, puts into Jie's sheet that makes, place and began suction in 30 minutes later on, check.
Table 3 provides the result.Wherein A and B are the cigarette that the application's method is made, and A1 and B1 are original commercially available cigarette.Shown in the table is the result that tobacco product obtained with the aphrizite manufacturing of 5% weight.In cigarette, during suction to experience harmony good more, assorted gas is few more, pungency is low more, illustrates that the tar content of this cigarette is low more, the nicotine flue gas is few more.And pleasant impression is not pungent, does not have niff, illustrates that the mouthfeel of cigarette is good more.
The suction report of the cigarette that table 3-A embodiment 3 prepared cigarette tissue wrap up
Project Gloss 6 Fragrance 36 Harmony 6 Assorted gas 16 Pungency 16 Pleasant impression 20 Add up to
The mark section A B C A B C A B C A B C A B C A B C
Sample Board is other 6 4 2 36 28 18 6 4 2 16 12 9 16 13 11 20 14 8 100
A Double Happiness ?√ ?√ ?√ ?√ ?√ 90
A 1 Double Happiness ?√ ?√ ?√ 62
B Seven wolves ?√ ?√ 86
B 1 Seven wolves ?√ ?√ ?√ ?√ ?√ 52
The suction parcel of the cigarette with filter tip that table 3-B embodiment 4 is prepared
Project Gloss 6 Fragrance 36 Harmony 6 Assorted gas 16 Pungency 16 Pleasant impression 20 Add up to
The mark section A B C A B C A B C A B C A B C A B C
Sample Board is other 6 4 2 36 28 18 6 4 2 16 12 9 16 13 11 20 14 8 100
A Double Happiness ?√ ?√ ?√ 90
A 1 Double Happiness ?√ ?√ 66
B Seven wolves ?√ ?√ ?√ ?√ ?√ 86
B 1 Seven wolves ?√ ?√ ?√ 52
The cigarette that table 3-C packs with the cigarette package of embodiment 5 preparations
Project Gloss 6 Fragrance 36 Harmony 6 Assorted gas 16 Pungency 16 Pleasant impression 20 Add up to
The mark section A B C A B C A B C A B C A B C A B C
Sample Board is other 6 4 2 36 28 18 6 4 2 16 12 9 16 13 11 20 14 8 100
A Double Happiness ?√ ?√ 80
A 1 Double Happiness ?√ ?√ ?√ ?√ ?√ 66
B Seven wolves ?√ ?√ ?√ ?√ ?√ 76
B 1 Seven wolves ?√ ?√ ?√ ?√ ?√ 52
The cigarette that table 3-D packs with cigarette package Jie sheet of embodiment 6 preparations.
Project Gloss 6 Fragrance 36 Harmony 6 Assorted gas 16 Pungency 16 Pleasant impression 20 Add up to
The mark section A B C A B C A B C A B C A B C A B C
Sample Board is other 6 4 2 36 28 18 6 4 2 16 12 9 16 13 11 20 14 8 100
A Double Happiness ?√ ?√ ?√ 74
A 1 Double Happiness ?√ ?√ ?√ 66
B Seven wolves ?√ 70
B 1 Seven wolves 52
The cigarette that table 3-E packs with the cigarette tin of embodiment 7 preparations
Project Gloss 6 Fragrance 36 Harmony 6 Assorted gas 16 Pungency 16 Pleasant impression 20 Add up to
The mark section A B C A B C A B C A B C A B C A B C
Sample Board is other 6 4 2 36 28 18 6 4 2 16 12 9 16 13 11 20 14 B 100
A Double Happiness 82
A 1 Double Happiness 66
B Seven wolves 75
B 1 Seven wolves 52
This shows that with the cigarette that the aphrizite goods were handled, smoking nicotine and tar content all have obvious decline, mouthfeel is improved.
Embodiment 9
Repeat the process of embodiment 6 and made cigarette package Jie sheet, difference is with 0.5%, 1%, the aphrizite of 1096 and 20% weight is replaced the aphrizite of original 5% weight, test with embodiment 8 same methods, the result can reduce the nicotine flue gas and the tar content of cigarette equally, improves the mouthfeel of cigarette.Only along with the minimizing of content, the time that needs to place than long just can reach same effect.When content was higher, the time of placement can reach same effect than weak point.
Though illustrate and described preference of the present invention, should understand those skilled in the art and can make various changes according to the instruction of this paper, these change without prejudice to scope of the present invention.

Claims (9)

1. a smoking article is characterized in that, these goods contain the aphrizite of the particle diameter of 0.1-20% weight at the 0.1-100 micron.
2. smoking article as claimed in claim 1 is characterized in that, described goods are selected from cigarette tissue, filter tip, cigarette with filter tip, cigarette package, Cigarette container, cigarette tin, cigarette package Jie sheet.
3. smoking article as claimed in claim 1 is characterized in that described goods contain the aphrizite of 0.5-10% weight.
4. the method for claim 1 is characterized in that, described goods contain the aphrizite of 1-5% weight.
5. method for preparing smoking article is characterized in that the method comprising the steps of:
(a) the classified processing of aphrizite being crushed to particle diameter is the 0.1-100 micron;
(b) tourmalinite that will account for total goods raw material 0.1-20% weight mixes the smoking article raw material;
(c) make smoking article.
6. method as claimed in claim 5 is characterized in that, the aphrizite that accounts for total goods raw material 0.5-10% weight is mixed the smoking article raw material.
7. method as claimed in claim 5 is characterized in that, the aphrizite that accounts for total goods raw material 1-5% weight is mixed smoking article.
8. method as claimed in claim 5 is characterized in that, described goods are selected from cigarette tissue, filter tip, cigarette with filter tip, cigarette package, Cigarette container, cigarette tin, cigarette package Jie sheet.
9. the purposes of the described smoking article of claim 1 is characterized in that, this product is used for: reduce smoking nicotine, reduce tar content or improve mouthfeel.
CNB03129331XA 2003-06-18 2003-06-18 Black tourmaline containing tobacco product and its making method and uses Expired - Fee Related CN100341441C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB03129331XA CN100341441C (en) 2003-06-18 2003-06-18 Black tourmaline containing tobacco product and its making method and uses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB03129331XA CN100341441C (en) 2003-06-18 2003-06-18 Black tourmaline containing tobacco product and its making method and uses

Publications (2)

Publication Number Publication Date
CN1565289A true CN1565289A (en) 2005-01-19
CN100341441C CN100341441C (en) 2007-10-10

Family

ID=34469286

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB03129331XA Expired - Fee Related CN100341441C (en) 2003-06-18 2003-06-18 Black tourmaline containing tobacco product and its making method and uses

Country Status (1)

Country Link
CN (1) CN100341441C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101637307B (en) * 2009-06-16 2011-01-26 成进学 Cigarette fiber filter tip powerfully filtering off toxic matters and releasing microelement anions
CN103082412A (en) * 2013-02-05 2013-05-08 大亚科技股份有限公司 Ternary composite filter stick with tourmaline added
CN103222683A (en) * 2012-06-28 2013-07-31 湖北中烟工业有限责任公司 Cigarette filter rod provided with natural mineral and plant fiber composite additive
CN112155248A (en) * 2020-11-02 2021-01-01 桂林市鲍姑红艾医药科技有限公司 Preparation method of wormwood health cigarette

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1002781A (en) * 1964-08-07 1965-08-25 George Milton Jacobson Cigarette filter
JPH09299073A (en) * 1996-05-11 1997-11-25 Takashi Sato Healthy cigarette

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101637307B (en) * 2009-06-16 2011-01-26 成进学 Cigarette fiber filter tip powerfully filtering off toxic matters and releasing microelement anions
CN103222683A (en) * 2012-06-28 2013-07-31 湖北中烟工业有限责任公司 Cigarette filter rod provided with natural mineral and plant fiber composite additive
CN103082412A (en) * 2013-02-05 2013-05-08 大亚科技股份有限公司 Ternary composite filter stick with tourmaline added
CN112155248A (en) * 2020-11-02 2021-01-01 桂林市鲍姑红艾医药科技有限公司 Preparation method of wormwood health cigarette

Also Published As

Publication number Publication date
CN100341441C (en) 2007-10-10

Similar Documents

Publication Publication Date Title
Miao et al. Removal of cephalexin from effluent by activated carbon prepared from alligator weed: Kinetics, isotherms, and thermodynamic analyses
Havlin et al. Mathematical models for potassium release kinetics in calcareous soils
Lisha et al. Towards a practical solution for removing inorganic mercury from drinking water using gold nanoparticles
Siswoyo et al. Determination of key components and adsorption capacity of a low cost adsorbent based on sludge of drinking water treatment plant to adsorb cadmium ion in water
CN110652963A (en) Lanthanum carbonate modified co-pyrolysis sludge biochar and preparation method and application thereof
CN106365141A (en) Porous carbon material composites and their production process, adsorbents, cosmetics, purification agents, and composite photocatalyst materials
Karimi et al. Using industrial sewage sludge-derived biochar to immobilize selected heavy metals in a contaminated calcareous soil
She et al. Effects of nano bamboo charcoal on PAHs-degrading strain Sphingomonas sp. GY2B
CN106967435A (en) A kind of preparation method of multifunction soil improver
CN109850893A (en) A kind of preparation method and application of ox bone active carbon
CN111039658A (en) Phosphorus removal ceramsite and preparation method thereof
CN100341441C (en) Black tourmaline containing tobacco product and its making method and uses
Kede et al. Adsorption of Mercury (II) onto activated carbons derived from Theobroma cacao pod husk
Bouchemal et al. Adsorption modeling of Orange G dye on mesoporous activated carbon prepared from Algerian date pits using experimental designs
N’diaye et al. Valorization of Balanites aegyptiaca seeds from Mauritania: Modeling of adsorption isotherms of caffeine from aqueous solution
Liu et al. Simultaneous removal of ammonium and phosphate in aqueous solution using Chinese herbal medicine residues: Mechanism and practical performance
Helard et al. The adsorption and regeneration of natural pumice as low-cost adsorbent for nitrate removal from water
CN109529086A (en) A kind of multifunctional nano deodorizing sterilizing anionic additive and preparation method thereof
CN115785958B (en) Biochar-loaded micro-powder soil conditioner, preparation method and application
CN108766772A (en) A kind of carbon coating titanium phosphate sodium and its preparation and application
Shiel Variation in amounts of carbon and nitrogen associated with particle size fractions of soils from the Palace Leas meadow hay plots
KR101055661B1 (en) Heavy metal adsorption removal agent containing yulpi and heavy metal adsorption removal method using the same
Sivakumar et al. FILM AND PORE DIFFUSION MODELING FOR THE ADSORPTION OF DIRECT RED 81 ON ACTIVATED CARBON PREPARED FROM BALSAMODENDRON CAUDATUM WOOD WASTE.
CN108499546A (en) A kind of preparation method of heavy metal absorbent
Aziz et al. Treatment of fluoride contaminated water using mango (Mangifera indica) leaves powder as an adsorbent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20071010

Termination date: 20120618