CN1557160A - Mixed insecticide missible oil formulation with neem oil as synergist - Google Patents
Mixed insecticide missible oil formulation with neem oil as synergist Download PDFInfo
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- CN1557160A CN1557160A CNA2004100234640A CN200410023464A CN1557160A CN 1557160 A CN1557160 A CN 1557160A CN A2004100234640 A CNA2004100234640 A CN A2004100234640A CN 200410023464 A CN200410023464 A CN 200410023464A CN 1557160 A CN1557160 A CN 1557160A
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- neem oil
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Abstract
The re-compounded pesticide is compounded with plant originated neem oil as synergist, acetamiprid, imidacloprid, hexaflumuron and chlorfenapyr as effective pesticidal components, surfactant, stabilizer, organic solvent, etc. Neem oil contains nimbin, amaroid and other pesticidal components and has also the effect of blocking epidermal air hole; and all of acetamiprid, imidacloprid, hexaflumuron and chlorfenapyr are efficient and low-toxicity pesticides. The composition of Neem oil and other effective pesticidal components has obvious pesticidal synergistic effect and less resistance, and the re-compounded pesticide has high efficiency, low toxicity, low residue and no pollution to agricultural product and environment.
Description
Technical field the invention belongs to a kind of mixed insecticide, relates to formulation of pesticide and preparation technique.
Background technology is because the human long-term insecticide that relies on single type, insect is easy to generate pesticide resistance, causes the chemical insecticide consumption sharply to increase, and not only increases the weight of peasant's financial burden, and can cause environment and pollution of agricultural products, have a large amount of mixed insecticides in the market, but great majority are big to the person poultry toxicity for being mixed between the chemical pesticide, easily cause pollution, and after long-time the use, insect also is easy to generate pesticide resistance.
Acetamiprid (acetamiprid) is a pyridine compounds and their, is a kind of novel pesticide.It except have tag and stomach poison function, also have stronger osmosis, and show quick-acting insecticidal powers, the lasting period is long, can reach about 20 days.This product is to the people, animal low toxicity, and is little to natural enemy lethality, lower to fish toxicity, little to the honeybee influence, be applicable to the control fruit tree, the Semiptera insect makes soil treatment with granule on the vegetables, can prevent and treat soil insect, at present, be used to prevent and treat aphid on the various crops in China.Imidacloprid (imidacloprid) is the Nitromethylene compounds, is a kind of novel pesticide.It has tag, stomach toxicity and systemic action, little to the people, animal low toxicity to natural enemy lethality, lower to fish toxicity, little to the honeybee influence, be applicable to control Semiptera, coleoptera, diptera and lepidoptera pest.At present, be used to prevent and treat aphid on the various crops, Trialeurodes vaporariorum Westwood, rice fulgorid etc. in China.
Fluorine bell urea (hexaflumuron) is a process for preparation of benzoylurea compounds, is chitin synthesis inhibitor, has very high desinsection and ovicidal activity, can prevent and treat coleoptera, diptera, Homoptera and lepidoptera pest.This product belongs to the environmental type agricultural chemicals to the people, animal low toxicity.
Chlorfenapyr (chlorfenapyr) is a kind of new pyrrole class Insecticidal and acaricidal agent, various pests is had tag and stomach poison function, and is little to natural enemy lethality to the people, animal low toxicity to crop safety, belongs to the environmental type agricultural chemicals.
More than several agricultural chemicals because long-term single use, very fast generation resistance, the peasant has to increase working concentration and access times, having increased control cost and pest resistance to insecticide further increases.
Neem oil is the vegetable oil that seal chinaberry seed obtains by cold rolling lixiviate, itself removes to contain glyceride (80-95%), outside free fatty acid (4-20%) and small amounts of inorganic and the organic salt, also contains pesticide and miticide actility composition bitter principle nimbin (C
30H
36O
9Molecular weight 540), salannin (C
34H
44O
9Molecular weight 596), meliantriol (C
30H
50O
5Molecular weight 490) and a small amount of nimbandiol (C
26H
32O
7Molecular weight 456), desacetylsalannin (C
32H
42O
8Molecular weight 554), desacetylnimbin (C
28H
34O
8Molecular weight 498), 6-acetylnimbandiol (C
28H
34O
8Molecular weight 498) and nimbin A (C
32H
40O
11Molecular weight 600) etc., according to international latest report, these active ingredients can be prevented and treated 413 kinds of insects.Its mechanism of action is different from the chemical pesticide of conventional organic synthesis.Seal chinaberry compound is by food refusal, walks quickly and keeps away, stop the children (if) worm casts off a skin and grows, walks quickly and keeps away and reduces the adult egg laying amount, also there are certain tagging, stomach toxicity and ovicidal action the while.The same with mineral oil with other vegetable oil, neem oil also has the effect that insect and mite class pore make insect be choked to death of stopping up.Neem oil is as a vegetable oil, from nature, has good compatibility with natural environment, toxicity is low, be difficult for causing environment and pollution of agricultural products, insect is not easy again to develop immunity to drugs, and mixed pesticide such as itself and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr has significant synergies to insect, the objective of the invention is to develop a class with plant resource composition neem oil as synergist, be the insecticide of insecticidal active ingredient with Acetamiprid etc.
Summary of the invention the present invention be with plant resource composition neem oil as synergist, be the insecticide of insecticidal active ingredient with Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr.
The present invention utilizes neem oil to be synergist, is that main active ingredient is mixed with Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr respectively, and allocates appropriate amount of addition agent into and be prepared into the compounded pesticides cream preparation.
Each component content proportioning (weight) is in the compounded pesticides cream preparation: neem oil content is 10-60%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-20%; Surface-active contents is 10%; Stabiliser content is 0.5-5.0%; Remaining is organic solvent.
Wherein surface active agent composition is to be selected from: the polyethenoxy ether class of nonionic, as benzylphenol APEO, phenethyl cumenyl phenol polyethenoxy ether, the alkyl benzene sulfonate of anionic is as in alkyl benzene calcium sulfonate, the phenethyl phenolic ether sulfonate one or more; Stabilizer component is to be selected from: 2, and 6-di-t-butyl Pyrogentisinic Acid; The organic solvent component is to be selected from: one or more in dimethylbenzene, dimethyl formamide, the acetone.
Each composition optimal proportion (weight) is in the compounded pesticides cream preparation: neem oil content is 20-40%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-5%; Surface-active contents is 10%; Stabiliser content is 2.5%; Remaining is organic solvent.
The compounded pesticides cream preparation adopts conventional farm chemical emulsion preparation processing technology to get final product in preparation process.
Compare with prior art, the present invention has following advantage and good effect:
1, both are composite has significant synergies to insect.
2, efficient, low toxicity, low-residual do not pollute agricultural product and environment.
3, insecticidal spectrum is wide, and insect is not easy to produce resistance.
Embodiment compounded pesticides cream preparation is to be active insecticidal components by neem oil and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr.Be equipped with surfactant, stabilizing agent, organic solvent etc. again.Improve retention rate and the osmosis of medicament on crop and polypide, thereby improve control efficiency.The inventor uses the neem oil of different content allocation plan and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr and other auxiliary agent vegetable aphid etc. has been carried out Toxicity Determination test and field biological effect small plot experiment.
In order to understand essence of an invention better, describe the technology contents of invention below in detail with example, but content of the present invention is not limited thereto.
Embodiment one: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Acetamiprid 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment two: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Acetamiprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment three: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Acetamiprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment four: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Acetamiprid 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment five: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Acetamiprid 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment six: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Imidacloprid 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment seven: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Imidacloprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment eight: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Imidacloprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment nine: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Imidacloprid 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment ten: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Imidacloprid 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 11: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Fluorine bell urea 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 12: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Fluorine bell urea 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 13: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Fluorine bell urea 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 14: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Fluorine bell urea 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 15: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Fluorine bell urea 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 16: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Chlorfenapyr 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 17: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Chlorfenapyr 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 18: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Chlorfenapyr 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 19: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Chlorfenapyr 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 20: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Chlorfenapyr 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Preparation of the present invention (embodiment four) is to the control efficiency of vegetable aphid:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment four | 2000 times | ????96.8 | ????100 | ????100 |
| Embodiment four | 2500 times | ????93.5 | ????98.2 | ????97.4 |
| Embodiment four | 3000 times | ????90.5 | ????97.3 | ????95.6 |
More than handle crop safety.
Preparation of the present invention (embodiment eight) is to the control efficiency of Bemisia tabaci:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment eight | 2000 times | ????95.8 | ????96.8 | ????97.0 |
| Embodiment eight | 2500 times | ????93.5 | ????94.2 | ????95.4 |
| Embodiment eight | 3000 times | ????90.5 | ????91.3 | ????92.5 |
More than handle crop safety.
Preparation of the present invention (embodiment 14) is to the control efficiency of diamond-back moth:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment 14 | 1000 times | ????73.8 | ????85.5 | ????93.5 |
| Embodiment 14 | 1500 times | ????65.5 | ????82.5 | ????90.4 |
| Embodiment 14 | 2000 times | ????60.5 | ????77.3 | ????85.6 |
More than handle crop safety.
Preparation of the present invention (embodiment 18) is to the control efficiency of apple tetranychus:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment 18 | 2000 times | 85.8 | ????95.2 | ????98.5 |
| Embodiment 18 | 2500 times | 73.5 | ????90.2 | ????95.4 |
| Embodiment 18 | 3000 times | 65.5 | ????86.3 | ????88.6 |
More than handle crop safety.
Claims (4)
1. a class is the compounded pesticides cream preparation of synergist with the neem oil, and it is characterized in that each component content proportioning (weight) is in the compounded pesticides cream preparation: neem oil content is 10-60%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-20%; Surface-active contents is 10%; Stabiliser content is 0.5-5.0%; Remaining is organic solvent.
2. neem oil according to claim 1 is the vegetable oil that is obtained by cold rolling lixiviate by the seed that prints chinaberry, itself remove and contain glyceride (80-95%), outside free fatty acid (4-20%) and small amounts of inorganic and the organic salt, also contain pesticide and miticide actility composition bitter principle nimbin (C
30H
36O
9Molecular weight 540), salannin (C
34H
44O
9Molecular weight 596), meliantriol (C
30H
50O
5Molecular weight 490) and a small amount of nimbandiol (C
26H
32O
7Molecular weight 456), desacetylsalannin (C
32H
42O
8Molecular weight 554), desacetylnimbin (C
28H
34O
8Molecular weight 498), 6-acetylnimbandiol (C
28H
34O
8Molecular weight 498) and nimbin A (C
32H
40O
11Molecular weight 600) etc.
3. surface active agent composition according to claim 1 is to be selected from: the polyethenoxy ether class of nonionic, as benzylphenol APEO, phenethyl cumenyl phenol polyethenoxy ether, the alkyl benzene sulfonate of anionic is as in alkyl benzene calcium sulfonate, the phenethyl phenolic ether sulfonate one or more; Stabilizer component is to be selected from: 2, and 6-di-t-butyl Pyrogentisinic Acid; The organic solvent component is to be selected from: one or more in dimethylbenzene, dimethyl formamide, the acetone.
4. each composition optimal proportion (weight) is in the compounded pesticides cream preparation according to claim 1: neem oil content is 20-40%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-5%; Surface-active contents is 10%; Stabiliser content is 2.5%; Remaining is organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100234640A CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100234640A CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1557160A true CN1557160A (en) | 2004-12-29 |
Family
ID=34352147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2004100234640A Pending CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1557160A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101228878B (en) * | 2007-01-25 | 2010-09-22 | 青岛海利尔药业有限公司 | Desinsection composite containing chlorfenapyr and hexaflumuron |
| CN106332911A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing litchi geometrid moths and preparing method thereof |
| CN106332918A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing olethreutes leucaspis meyrick in litchi and preparing method thereof |
| CN106332919A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing Arbela dea and preparing method thereof |
| CN106342935A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating litchi spotted cerambycid and preparation method thereof |
| CN106342936A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating Oligonychus litchii and preparation method thereof |
| CN106417285A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for control of lichee lump gall mite and preparation method thereof |
| CN106417289A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for preventing and controlling litchi whiteflies and preparation method thereof |
| CN106417288A (en) * | 2016-08-27 | 2017-02-22 | 卢婷 | Conopomorpha litchielle bradly control pesticide and preparation method thereof |
| CN106465714A (en) * | 2016-08-27 | 2017-03-01 | 梁小萍 | A kind of pesticide of preventing and treating Sphecosesia litchivora and preparation method thereof |
| CN108094426A (en) * | 2017-12-01 | 2018-06-01 | 陕西日日新生物科技有限公司 | A kind of plant source type pesticide synergistic agent and preparation method thereof |
| CN113796374A (en) * | 2021-01-27 | 2021-12-17 | 仲恺农业工程学院 | Pesticide containing neem oil special for flight control and preparation method thereof |
| US11779022B2 (en) * | 2017-12-27 | 2023-10-10 | Mclaughlin Gormley King Company | Mixtures of sabadilla alkaloids and neem oil and uses thereof |
-
2004
- 2004-02-09 CN CNA2004100234640A patent/CN1557160A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101228878B (en) * | 2007-01-25 | 2010-09-22 | 青岛海利尔药业有限公司 | Desinsection composite containing chlorfenapyr and hexaflumuron |
| CN106417285A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for control of lichee lump gall mite and preparation method thereof |
| CN106332918A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing olethreutes leucaspis meyrick in litchi and preparing method thereof |
| CN106332919A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing Arbela dea and preparing method thereof |
| CN106342935A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating litchi spotted cerambycid and preparation method thereof |
| CN106342936A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating Oligonychus litchii and preparation method thereof |
| CN106332911A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing litchi geometrid moths and preparing method thereof |
| CN106417289A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for preventing and controlling litchi whiteflies and preparation method thereof |
| CN106417288A (en) * | 2016-08-27 | 2017-02-22 | 卢婷 | Conopomorpha litchielle bradly control pesticide and preparation method thereof |
| CN106465714A (en) * | 2016-08-27 | 2017-03-01 | 梁小萍 | A kind of pesticide of preventing and treating Sphecosesia litchivora and preparation method thereof |
| CN108094426A (en) * | 2017-12-01 | 2018-06-01 | 陕西日日新生物科技有限公司 | A kind of plant source type pesticide synergistic agent and preparation method thereof |
| US11779022B2 (en) * | 2017-12-27 | 2023-10-10 | Mclaughlin Gormley King Company | Mixtures of sabadilla alkaloids and neem oil and uses thereof |
| CN113796374A (en) * | 2021-01-27 | 2021-12-17 | 仲恺农业工程学院 | Pesticide containing neem oil special for flight control and preparation method thereof |
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