CN1548288A

CN1548288A - Transparent composite material

Info

Publication number: CN1548288A
Application number: CNA031266126A
Authority: CN
Inventors: 杨震荣; 陈洋彬
Original assignee: Individual
Current assignee: Individual
Priority date: 2003-05-15
Filing date: 2003-05-15
Publication date: 2004-11-24

Abstract

The transparent composite material includes transparent inorganic body of glass or other inorganic material, polymer body and cured polymer adhesive. The adhesive is dispersed in one or two sides of the transparent inorganic body and adheres the transparent inorganic body and the polymer body together via grouting to form one new kind of composite material. The composite material is transparent, has high inegrality, high weather resistance, high hardness, high rigidity and other advantages, and may be used in building, advertisement, traffic and other fields.

Description

A kind of printing opacity, transparent composite material

One, technical field

The present invention relates to the material that a kind of macromolecular material and glass, inorganic material are composited, printing opacity, transparent composite material that particularly a kind of printing opacity, transparent macromolecular material and glass, inorganic light transmissive material are composited.

Two, background technology

Along with the development of every profession and trade and the demand in market, building, ad decoration, lamp decoration and communications are badly in need of weather-proof, practical, safe, high-intensity printing opacity or material transparent; And the chemical industry aspect is used to observe and monitor the pipeline of whole chemical reaction process, also presses for high temperature resistant, corrosion resistant printing opacity or material transparent.Yet the printing opacity that these industries adopted, transparent material all are difficult to satisfy above-mentioned requirement because of the defective that its performance structure itself exists at present.Existing printing opacity, transparent material are: the doubling glass of glass, therebetween last layer film, glass, stone material thin slice and other printing opacity flaky material, the plastic material of surface through covering with paint, lacquer, colour wash, etc.If the above wherein a kind of material of single use all has certain limitation, for example: the glass of using glass or surface process covering with paint merely is as transparent structural material, the fragmentation easily because of its impact resistance difference is spilt the accident of falling and hurting sb.'s feelings so partition is disappeared simultaneously and the high-altitude may occur when fragmentation takes place its contingency; The doubling glass of therebetween last layer film is too just like the weakness of the equally easy fragmentation of glass, when in a single day its two sides is subjected to the impact of external force and when broken, soft phenomenon of falling can takes place inevitably; The impact resistance of stone material thin slice and other printing opacity flaky material is also poor, and fractures easily, is subject to many limitations in the use; Plastic material is because its rigidity deficiency, temperature become poor performance, and easily aging, problem such as hardness is little and can't adapt to the demand in market.

Three, summary of the invention

The objective of the invention is to provide a kind of globality strong, good weatherability, the hardness height, rigidity is excellent, safety is secure, and it is shock-resistant, high temperature resistant and corrosion-resistant, has good printing opacity, the advanced composite material (ACM) of properties of transparency, particularly a kind of macromolecular material and glass or the printing opacity that other inorganic light transmissive material was composited, transparent composite material, to solve existing printing opacity, transparent material is glass for example, the doubling glass of therebetween last layer film, the glass of surface through covering with paint, lacquer, colour wash, etc., stone material thin slice and other printing opacity flaky material, existing impact resistance is poor when using separately, the rigidity deficiency, easily broken and can stay the drawback of hidden danger in use, also overcome the plastic material temperature and become poor performance, easily aging, little and the indifferent shortcoming of rigidity of hardness, thus satisfy the needs of the advanced composite material (ACM) of a kind of high safety of every profession and trade demand and good decorative property.

The object of the present invention is achieved like this: a kind of printing opacity of the present invention, transparent composite material comprise: 1, glass basis or other inorganic light transmissive material matrix; 2, the matrix that is made of macromolecule polymer material for example is PMMA, PC, ABS, polyester, unsaturated resin, polyamide, polyurethane, epoxy resin, and one or more of above material can homopolymerization, copolymerization, the material that mixes; 3, bind into as a whole mutually with the matrix that constitutes by macromolecule polymer material glass basis or other inorganic light transmissive material matrix and the adhesive between both matrixes at this, described adhesive is a kind of acrylate copolymer that comprises, acrylate polymer, epoxy polymer, the acrylic acid epoxy polymer, PUR, polyurethane, polyester, unsaturated resin, acrylic acid---epoxy---polyurethane copolymer is interior, and be host or be that pigment is added or do not added to host by above mixture of substances by above material, the binding material that filler is made, this adhesive is through grouting process, can be respectively by heating, normal temperature, UV, ray, modes such as electron beam irradiation are solidified, thereby make glass basis or other inorganic light transmissive material matrix and the matrix that is made of macromolecule polymer material compound as a whole and form a kind of advanced composite material (ACM).

The present invention is a kind of advanced composite material (ACM), its globality is strong, with good weatherability, hardness height, good rigidly, secure safely, and pliable and tough feature set such as shock-resistant, high temperature resistant and corrosion-resistant, and have good printing opacity, properties of transparency, can be widely used in industries such as building, ad decoration, lamp decoration, traffic and chemical industry.For on chemical industry, in high temperature resistant and corrosion resistant pipeline, observe and monitor the process of whole chemical reaction easily and intuitively because of its transparent safety again.

Four, description of drawings

Below in conjunction with drawings and Examples structural behaviour of the present invention, principle technology are further described:

Fig. 1, be the structural representation of one of embodiment of the invention;

Fig. 2, be two structural representation of the embodiment of the invention;

Fig. 3, be three structural representation of the embodiment of the invention.

Five, the specific embodiment

A kind of printing opacity of the present invention, transparent composite material cited embodiment in Fig. 1 to Fig. 3 all adopts glass basis or other inorganic light transmissive material matrix 1 to form with the matrix 2 and the adhesive 3 that are made of macromolecule polymer material.The described matrix that constitutes by macromolecule polymer material 2 for the wherein a kind of of PMMA, PC, ABS, polyester, unsaturated resin, polyamide, polyurethane, these materials of epoxy resin or in them more than one can homopolymerization, copolymerization, the material that mixes, it can be modulated into pattern in advance, color or other photochromic effects have been arranged, and makes made composite have photoelectric properties such as fluorescence, luminous, refraction, colour developing, electrified light emitting, adjusting light power.Described adhesive 3 is formed by macromolecular material curing, it is between glass basis or other inorganic light transmissive material matrix 1 and the matrix 2 that is made of macromolecule polymer material, it is a kind of acrylate copolymer that comprises, acrylate polymer, epoxy polymer, the acrylic acid epoxy polymer, PUR, polyurethane, polyester, unsaturated resin, acrylic acid---epoxy---polyurethane copolymer is interior, and be host or be that pigment is added or do not added to host by above mixture of substances by above material, the binding material that filler is made, in grouting, it can be modulated into pattern, color or other photochromic effects are arranged, also can add LED and lead, small electric bulb etc., when the matrix 2 that makes and be made of macromolecule polymer material binds, give made composite and have fluorescence, luminous, refraction, colour developing, electrified light emitting, regulate photoelectric properties such as light power.This adhesive 3 is between glass basis or other inorganic light transmissive material matrix 1 and the matrix 2 that is made of macromolecule polymer material, with some thickness evenly or non-uniform Distribution on the single or double of glass basis or other inorganic light transmissive material matrix 1, through grouting process, can solidify by modes such as heating, normal temperature, UV, ray, electron beam irradiations respectively, thereby bind as a whole with the matrix 2 that constitutes by macromolecule polymer material glass basis or other inorganic light transmissive material matrix 1.Because the present invention is by the variation of physics such as multiple different material institute itself intrinsic refractive index, warm sex change, hardness and rigidity and chemical characteristic, can realize the physics and the chemical characteristic of this material monolithic are adjusted, thereby form a kind of advanced composite material (ACM) with multiple physics and chemical characteristic.

The present invention finishes like this:

At first keep at a distance and form the gap with glass basis or other inorganic light transmissive material matrix 1 with by matrix 2 these two kinds of matrixes that macromolecule polymer material constitutes, the adhesive 3 of selecting thermal coefficient of expansion with it to be complementary again, desired value according to composite, assess physics between this three, the complementarity of chemical property, then, in this gap, pour into and above-mentioned two kinds of matrixes 1 by instillation process, 2 adhesive that adapt 3, pass through curing process, utilize its cohesive force, glass basis or other inorganic light transmissive material matrix 1 are binded with the matrix 2 that is made of macromolecule polymer material.

As can be seen, this material only is one of wherein simple compound mode from Fig. 1 to Fig. 3 in the present invention.In fact, can release multiple structure, to satisfy the requirement of different industries and applications according to principle technology of the present invention.Particularly, the described exactly matrix 2 that is made of macromolecule polymer material is distributed in can have only layer of substance on glass basis or other inorganic light transmissive material matrix 1 single face, and the combination of the above material of one deck also can be arranged; The matrix 2 that is made of macromolecule polymer material is distributed in the inorganic light transmissive material matrix of glass basis or other 1 can have only layer of substance on two-sided, and the combination of the above material of one deck also can be arranged.Described adhesive 3 is distributed in can have only layer of substance on glass basis or other inorganic light transmissive material matrix 1 single face, and the combination of the above material of one deck also can be arranged; Adhesive 3 is distributed in the inorganic light transmissive material matrix of glass basis or other 1 can have only layer of substance on two-sided, and the combination of the above material of one deck also can be arranged.And, in face compacting, the erosion system of glass basis or other inorganic light transmissive material matrix 1, or do not suppress, lose pattern; Also can print or not print chromatograph, pattern.In face compacting, the erosion system of the matrix 2 that constitutes by macromolecule polymer material, or do not suppress, lose pattern; Also can print or not print chromatograph, pattern.

The present invention is compound through above-mentioned material, thereby formed a kind of multiple refractive index substance coexist printing opacity, transparent composite material of a wall of containing, separately physics and chemical characteristic are integrated in one, shown performances such as good pliability, impact resistance and superior stiffness especially.And, the present invention is before compound, owing in matrix 2 that constitutes by macromolecule polymer material and adhesive 3, be modulated into pattern respectively in advance, color or other photochromic effects arranged, so make this new material allow people watch card-cut sensation through being composited, thereby, with its material of using as aspects such as building, ad decoration, lamp decoration and regulatory signses, not only have practicality and security, also have much ornamental and ornamental.

What the present invention was showed in Fig. 1 to Fig. 3 all is a kind of printing opacity, transparent composite material, its shape and structure is respectively square body, triangulo column and cylinder, and core is a hollow-core construction, to keep printing opacity of the present invention, transparent characteristic, this is the wherein specific well-regulated section bar of part of the present invention.Certainly, using principle technology of the present invention, can produce printing opacity, the transparent composite material of the irregular even shape and structure complexity of shape and structure equally, for example is printing opacity, transparent composite material of platy structure etc.

Above-described only is preferential embodiment of the present invention.Should be pointed out that to those skilled in the art under the prerequisite that does not break away from principle of the invention technology, can also make some modification and improvement, this also is considered as belonging to protection scope of the present invention.

Claims

1, a kind of printing opacity, transparent composite material, the matrix (2) that comprises glass basis or other inorganic light transmissive material matrix (1), constitutes by macromolecule polymer material and solidify the adhesive (3) that forms by macromolecular material, it is characterized in that: this adhesive (3) with some thickness evenly or non-uniform Distribution on the single or double of glass basis or other inorganic light transmissive material matrix (1), by grouting process, mutually bind as a whole with the matrix (2) that constitutes by macromolecule polymer material glass basis or other inorganic light transmissive material matrix (1).

2, a kind of printing opacity according to claim 1, transparent composite material is characterized in that: the described matrix that constitutes by macromolecule polymer material (2) be the wherein a kind of of PMMA, PC, ABS, polyester, unsaturated resin, polyamide, polyurethane, these materials of epoxy resin or in them more than one can homopolymerization, copolymerization, the material that mixes.

3, a kind of printing opacity according to claim 1, transparent composite material, it is characterized in that: described adhesive (3) is a kind of acrylate copolymer, acrylate polymer, epoxy polymer, acrylic acid epoxy polymer, PUR, polyurethane, polyester, unsaturated resin, acrylic acid---epoxy---polyurethane copolymer of comprising, and is host or is that the binding material that pigment, filler are made is added or do not added to host by above mixture of substances by above material.

4, according to claim 1,2 described a kind of printing opacities, transparent composite material, it is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in can have only layer of substance on glass basis or other inorganic light transmissive material matrix (1) single face, and the combination of the above material of one deck also can be arranged.

5, according to claim 1,2 described a kind of printing opacities, transparent composite material, it is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in glass basis or other inorganic light transmissive material matrix (1) can have only layer of substance on two-sided, and the combination of the above material of one deck also can be arranged.

6, according to claim 1,3 described a kind of printing opacities, transparent composite material, it is characterized in that: described adhesive (3) is distributed in can have only layer of substance on glass basis or other inorganic light transmissive material matrix (1) single face, and the combination of the above material of one deck also can be arranged.

7, according to claim 1,3 described a kind of printing opacities, transparent composite material, it is characterized in that: described adhesive (3) is distributed in glass basis or other inorganic light transmissive material matrix (1) can have only layer of substance on two-sided, and the combination of the above material of one deck also can be arranged.