CN1552572A - Transmitting, transparent or reflecting composite materials - Google Patents
Transmitting, transparent or reflecting composite materials Download PDFInfo
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- CN1552572A CN1552572A CNA031267939A CN03126793A CN1552572A CN 1552572 A CN1552572 A CN 1552572A CN A031267939 A CNA031267939 A CN A031267939A CN 03126793 A CN03126793 A CN 03126793A CN 1552572 A CN1552572 A CN 1552572A
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- reflecting metal
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Abstract
A light transmitting or reflecting composite material is composed of a substrate made of high-molecular polymer and a glass or reflecting metal or optical-transmission organic or inorganic layer. Its preparing process includes such steps as hot pressing of a concave-convex template on said substrate, covering it on said another layer, and solidifying by heating or radiation of UV, ray, or electronic beams. Its advantages are high integrity, hardness rigidity, weatherability, decorative effect and optical performance, and low cost.
Description
One, technical field
The present invention relates to the material that a kind of macromolecular material and glass or metal etc. are inorganic, organic material is composited, particularly a kind of printing opacity, transparent macromolecular material and glass or metal etc. are inorganic, the printing opacity that organic material is composited, transparent or reflective composite.
Two, background technology
Along with the development of all trades and professions and the demand in market, industries such as building, ad decoration, lamp decoration, fine arts photograph decoration, light industry commodity, traffic administration and highway construction are badly in need of effective, weather-proof, practical, safe, high-intensity printing opacity, transparent or reflectorized material.Yet the printing opacity that these industries adopted, transparent or reflectorized material all are difficult to satisfy above-mentioned requirement because of the defective that its performance structure itself exists at present.Existing printing opacity, transparent or reflective material are: the doubling glass of pattern glass, veneer glass, therebetween last layer film, glass, stone material thin slice and other printing opacity flaky material, the plastic material of surface through covering with paint, lacquer, colour wash, etc.If the above wherein a kind of material of single use all has certain limitation, for example: use glass (for example pattern glass, veneer glass) or surface glass merely through covering with paint, lacquer, colour wash, etc., the fragmentation easily because of its impact resistance difference is spilt the accident of falling and hurting sb.'s feelings so partition is disappeared simultaneously and the high-altitude may occur when fragmentation takes place its contingency; The doubling glass of therebetween last layer film is too just like the weakness of the equally easy fragmentation of glass, when in a single day its two sides is subjected to the impact of external force and when broken, soft phenomenon of falling can takes place inevitably; The impact resistance of stone material thin slice and other printing opacity flaky material is also poor, and fractures easily, is subject to many limitations in the use; Plastic material is because its rigidity deficiency, temperature become poor performance, and problem such as easily aging, hardness is little, corrosion-resistant and can't adapt to the demand in market.And the top layer of veneer glass is peeled off easily and is not durable, and veneer glass and doubling glass all are difficult to cut, and pattern glass is because of being subjected to the restriction of hot-working condition, thus can not produce more careful, complicated decorative pattern, and can't satisfy the needs of all trades and professions.
Three, summary of the invention
The objective of the invention is to provide a kind of globality strong, production cost is low, good in optical property, weatherability is good, the hardness height, not easy to wear, rigidity is excellent, decorative effect is obvious, safety is secure, and it is pliable and tough shock-resistant, high temperature resistant and chemical resistance of concrete, has good printing opacity, the advanced composite material (ACM) of transparent or reflective function, particularly a kind of macromolecular material and glass or metal etc. are inorganic, the printing opacity that organic material is composited, transparent or reflective composite, to solve existing printing opacity, transparent or reflectorized material is pattern glass for example, veneer glass, the doubling glass of therebetween last layer film, the glass of surface through covering with paint, lacquer, colour wash, etc., stone material thin slice and other printing opacity flaky material, existing impact resistance is poor when using separately, the rigidity deficiency, easily broken and can stay the drawback of hidden danger in use, also overcome the plastic material temperature and become poor performance, easily aging, little and the indifferent shortcoming of rigidity of hardness, and wear and tear easily in the top layer that solves veneer glass, veneer glass and doubling glass all are difficult to cut, it is more careful that pattern glass can not be produced, complicated problems such as decorative pattern, thereby can satisfy a kind of high safety of all trades and professions demand and good decorative property, the needs of durable advanced composite material (ACM).
The object of the present invention is achieved like this: a kind of printing opacity of the present invention, transparent or reflective composite comprise: but 1, have glass basis or reflecting metal matrix and other an organic and inorganic light transmissive material matrix of print surface; 2, the matrix that constitutes by macromolecule polymer material, described this matrix is PMMA, PC, PVC, ABS, polyester, unsaturated resin, polyamide, polyurethane, epoxy resin, acrylate copolymer, acrylate polymer, epoxy polymer, the acrylic acid epoxy polymer, PUR, acrylic acid---epoxy---polyurethane copolymer, and one or more of above material can homopolymerization, copolymerization, the material that mixes, and be that to be that host is an amount of add or do not add pigment for the mixture of host or above material by above-mentioned substance, filler, auxiliary agent and the material made.The matrix that will be made of macromolecule polymer material is through recessed, the typography of relief printing plate press back, respectively by heating, normal temperature, UV, ray, modes such as electron beam irradiation are solidified, the material of the matrix that will be made of macromolecule polymer material is recessed with what met design requirement, the punch version, it is organic that press back covers glass basis or reflecting metal matrix and other, on the surface of inorganic light transmissive material matrix, again respectively by heating, normal temperature, UV, ray, curings such as electron beam irradiation, make glass basis or reflecting metal matrix and other organic, it is as a whole that inorganic light transmissive material matrix and the matrix that is made of macromolecule polymer material link, thereby make a kind of printing opacity, transparent or reflective composite.
Globality of the present invention is strong, the collection good in optical property, weatherability is good, hardness is high, not easy to wear, rigidity is excellent, decorative effect is obvious, safe and reliable, and characteristics such as pliable and tough shock-resistant, high temperature resistant and chemical resistance of concrete, its technology is simple, production cost is low, can conveniently cut, organize and implement easily and the large-scale popularization application, can be widely used in industries such as building, ad decoration, lamp decoration, fine arts photograph decoration, light industry commodity, traffic administration and highway construction.
Four, description of drawings
Below in conjunction with drawings and Examples structural behaviour of the present invention, principle technology are further described:
Fig. 1, be structural representation of the present invention;
Fig. 2, be wherein a kind of partial enlarged drawing of surface structure of Fig. 1.
Five, the specific embodiment
A kind of printing opacity of the present invention, transparent or reflective composite are linked by following two kinds of matrix materials process.These two kinds of matrix materials are respectively: but comprise glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix 1 with print surface; The matrix 2 that constitutes by macromolecule polymer material, described this matrix 2 is PMMA, PC, PVC, ABS, polyester, unsaturated resin, polyamide, polyurethane, epoxy resin, acrylate copolymer, acrylate polymer, epoxy polymer, the acrylic acid epoxy polymer, PUR, acrylic acid---epoxy---polyurethane copolymer, and one or more of above material can homopolymerization, copolymerization, the material that mixes, and by above-mentioned substance is that to be that host is an amount of add or do not add pigment for the mixture of host or above material, filler, auxiliary agent and the material made, why this matrix 2 adds pigment in advance in right amount, filler (for example LED etc.), auxiliary agent, be that intention has been modulated into pattern, color or other photochromic effects are arranged, make to the composite of being produced have polarisation, fluorescence, luminous, refraction, colour developing, electrified light emitting, regulate photoelectric properties such as light power.
The present invention finishes like this:
At first, it is organic with other that but selection has the glass basis or the reflecting metal matrix of print surface, the material of the matrix 2 that constitutes by macromolecule polymer material that inorganic light transmissive material matrix 1 and thermal coefficient of expansion are complementary, then, assess physics between the two, the complementarity of chemical property, again according to the physics of the composite that will make, the desired value of chemical property, material uncured in the matrix 2 that will be made of macromolecule polymer material is recessed with what met design requirement, the punch version, through recessed, the typography of relief printing plate press back, it is organic to cover glass basis or reflecting metal matrix and other with the even or non-homogeneous press back of some thickness, on the single or double of inorganic light transmissive material matrix 1, by heating, normal temperature, UV, ray, curing means such as electron beam irradiation, glass basis or reflecting metal matrix is organic with other, inorganic light transmissive material matrix 1 links with the matrix 2 that is made of macromolecule polymer material, and the advanced composite material (ACM) that is combined into one.Wherein, if selecting for use the reflecting metal material to do matrix matches with the matrix 2 that is made of macromolecule polymer material and combine, can be made into a kind of reflective composite as the material of matrix 1; Material as matrix 1 is matrix and matrix 2 combinations of pairs that are made of macromolecule polymer material as if selecting glass or stone material thin slice, printing opacity flaky material, macromolecule polymer material for use, can form a kind of printing opacity, transparent composite material.For example, the matrix 2 that is made of macromolecule polymer material among the present invention is designed to curved bodies such as hemisphere, select for use the reflecting metal material as matrix 1, cooperate the matrix 2 that constitutes by macromolecule polymer material, then make the reflecting sign, the mark decorations board that are used for aspects such as road signs; In the matrix 2 that constitutes by macromolecule polymer material, mix up appropriate filler, and be designed to casual photosphere, select for use glass again as matrix 1, cooperation is just made the glare proof glass that is used for aspects such as windshield by the matrix 2 that macromolecule polymer material constitutes; To be designed to difference of height bigger solid geometry pattern straggly by the matrix 2 that macromolecule polymer material constitutes, can be made into the transparent material that is similar to pattern glass, acid etching glass, if in the matrix 2 that constitutes by macromolecule polymer material, bestow appropriate color again, the effect of " color crystal glass " just arranged; Printing opacity, the transparent composite material that to make by the present invention, cover on products propaganda placard, calligraphy and painting photo and the daily ornament, making these is that the thing that is capped on plane but produces stereoscopic vision to the people originally, and can make its long preservation and can not be subjected to illumination and climatic influences to cause fading.
As can be seen, this material manifestation mode here only is wherein one of a kind of simple form of various compound modes from Fig. 1, Fig. 2 in the present invention.In fact, can also release the structure of multiple combination level according to principle of the present invention, to satisfy the requirement of different industries and various applications.Particularly, the described exactly matrix 2 that is made of macromolecule polymer material is distributed in the layer of substance that can have only matrix 2 materials on glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix 1 single face, and the combination of the above material of one deck also can be arranged; The matrix 2 that is made of macromolecule polymer material is distributed in the organic and inorganic light transmissive material matrix of glass basis or reflecting metal matrix and other 1 layer of substance that can have only matrix 2 materials on two-sided, and the combination of the above material of one deck also can be arranged.And, can suppress, print, lose system at the face of glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix 1, or not suppress, print, lose system chromatograph, pattern; Face at the matrix 2 that is made of macromolecule polymer material can be suppressed, print, loses system, or does not suppress, prints, loses system chromatograph, pattern.
Simultaneously, what showed in Fig. 2 also is a kind of basic configuration structure of the present invention, the matrix 2 that is made of macromolecule polymer material as a kind of printing opacity, transparent or reflective composite layer is made into regular, uniform ripple glaze shape herein, is a special case in numerous application.In fact, typography by concave, convex version press back, it is regular, even or random, inhomogeneous and ridge orientation is mixed and disorderly and the top layer of various decorative patterns that the matrix 2 that is made of macromolecule polymer material also can be made into careful, complicated obform body with triangle body, cone and prismatoid and other arbitrary shape structures etc., even decorative pattern is very young thin top layer, it also can be pure flat top layer, can satisfy different needs, mould colourful stereoeffect.
Since the present invention utilize several different materials itself the variation of intrinsic optics, physics and chemical characteristics such as optical index, warm sex change, hardness and rigidity, can realize that optics, physics and chemical characteristic to this material monolithic integrate, thereby formed a kind of coexist advanced composite material (ACM) of the unique optics of having of a wall, physics and chemical characteristic of multiple refractive index substance that contains, it integrates separately optics, physics and chemical characteristic in one, has shown characteristic and excellent optical properties such as good pliability, impact resistance, corrosion resistance and rigidity especially.And, the present invention is before compound, owing in the matrix 2 that constitutes by macromolecule polymer material, be modulated into pattern in advance, color or other photochromic effects arranged,, had the sensation that solid, embossing pattern and vision are waved so make this material allow people watch through being composited.Thereby, with its material of using, not only have practicality, durability and security as aspects such as building, ad decoration, mirror drawing phase frame, lamp decoration and road signs, also have much attractive, decorative and sight.
Above-described only is preferential embodiment of the present invention.Should be pointed out that to those skilled in the art under the prerequisite that does not break away from the principle of the invention, can also make some modification and improvement, this also is considered as belonging to protection scope of the present invention.
Claims (5)
1, a kind of printing opacity, transparent or reflective composite, comprise that glass basis or reflecting metal matrix and other are organic, inorganic light transmissive material matrix (1), the matrix (2) that constitutes by macromolecule polymer material, it is characterized in that: the matrix (2) that is made of macromolecule polymer material is PMMA, PC, PVC, ABS, polyester, unsaturated resin, polyamide, polyurethane, epoxy resin, acrylate copolymer, acrylate polymer, epoxy polymer, the acrylic acid epoxy polymer, PUR, acrylic acid---epoxy---polyurethane copolymer, and one or more of above material can homopolymerization, copolymerization, the material that mixes, and by above-mentioned substance is that to be that host is an amount of add or do not add pigment for the mixture of host or above material, filler, auxiliary agent and the material made, through recessed, the typography of relief printing plate press back, it is organic with other evenly or anisotropically its press back to be covered glass basis or reflecting metal matrix with some thickness, on the single or double of inorganic light transmissive material matrix (1), respectively by heating, normal temperature, UV, ray, curings such as electron beam irradiation, glass basis or reflecting metal matrix is organic with other, inorganic light transmissive material matrix (1) connects to a composite material with the matrix (2) that is made of macromolecule polymer material.
2, a kind of printing opacity as claimed in claim 1, transparent or reflective composite is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in the layer of substance that can have only matrix (2) material on glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix (1) single face.
3, as claim 1,2 described a kind of printing opacities, transparent or reflective composite, it is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in the combination of the above material of one deck that matrix (2) material can be arranged on glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix (1) single face.
4, a kind of printing opacity as claimed in claim 1, transparent or reflective composite is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix (1) layer of substance that can have only matrix (2) material on two-sided.
5, as claim 1,4 described a kind of printing opacities, transparent or reflective composite, it is characterized in that: the described matrix that is made of macromolecule polymer material (2) is distributed in the combination of glass basis or reflecting metal matrix and other organic and inorganic light transmissive material matrix (1) the above material of one deck that matrix (2) material can be arranged on two-sided.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031267939A CN1552572A (en) | 2003-06-04 | 2003-06-04 | Transmitting, transparent or reflecting composite materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031267939A CN1552572A (en) | 2003-06-04 | 2003-06-04 | Transmitting, transparent or reflecting composite materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1552572A true CN1552572A (en) | 2004-12-08 |
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ID=34322006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031267939A Pending CN1552572A (en) | 2003-06-04 | 2003-06-04 | Transmitting, transparent or reflecting composite materials |
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| Country | Link |
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| CN (1) | CN1552572A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100376384C (en) * | 2005-06-02 | 2008-03-26 | 李一明 | Decorative board and its manufacturing method |
| CN102479870A (en) * | 2010-11-24 | 2012-05-30 | 吉富新能源科技(上海)有限公司 | Method for manufacturing luminous module in specific position of luminous solar battery |
| CN101814263B (en) * | 2009-02-24 | 2012-08-15 | 上海新思维反光材料有限公司 | Preparation method of reflecting material |
| CN101868351B (en) * | 2007-11-21 | 2014-08-20 | 帝斯曼知识产权资产管理有限公司 | Multilayer constructions |
-
2003
- 2003-06-04 CN CNA031267939A patent/CN1552572A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100376384C (en) * | 2005-06-02 | 2008-03-26 | 李一明 | Decorative board and its manufacturing method |
| CN101868351B (en) * | 2007-11-21 | 2014-08-20 | 帝斯曼知识产权资产管理有限公司 | Multilayer constructions |
| CN101814263B (en) * | 2009-02-24 | 2012-08-15 | 上海新思维反光材料有限公司 | Preparation method of reflecting material |
| CN102479870A (en) * | 2010-11-24 | 2012-05-30 | 吉富新能源科技(上海)有限公司 | Method for manufacturing luminous module in specific position of luminous solar battery |
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