CN202573206U - Explosion-proof glass film capable of blocking infrared and ultraviolet - Google Patents

Explosion-proof glass film capable of blocking infrared and ultraviolet Download PDF

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Publication number
CN202573206U
CN202573206U CN 201220152761 CN201220152761U CN202573206U CN 202573206 U CN202573206 U CN 202573206U CN 201220152761 CN201220152761 CN 201220152761 CN 201220152761 U CN201220152761 U CN 201220152761U CN 202573206 U CN202573206 U CN 202573206U
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Prior art keywords
film
ultraviolet
optical grade
layer
distance
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Expired - Fee Related
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CN 201220152761
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Chinese (zh)
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金国华
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SUZHOU XILIN OPTOELECTRONICS TECHNOLOGY INDUSTRY CO., LTD.
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SUZHOU KINGHIGH MEMBRANE TECHNOLOGY DEVELOPMENT Co Ltd
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Abstract

The utility model discloses an explosion-proof glass film capable of blocking infrared and ultraviolet. The explosion-proof glass film comprises anti-scrape glue solution, a first layer of optical thin film, a composite glue solution layer, an ultraviolet and infrared blocking reinforced layer, a metal or metal oxide layer, a second layer of optical high transparent PET (Polyethylene Terephthalate) thin film, a mounting glue layer and a release film. The explosion-proof glass film has the advantages that the heat insulation and the ultraviolet and infrared blocking performances are good; and the transparency and the explosion-proof function are favorable.

Description

A kind of at a distance from the separated ultraviolet implosion guard film of infrared ray
Technical field
The utility model relates to a kind of rupture pressure disc, particularly relates to a kind of septum pellucidum infrared ray and ultraviolet implosion guard film.
Background technology
In the prior art, the heat insulation common employing Heat insulation type adhering film of glass or the method for coating film on glass solve, and general Heat insulation type adhering film has explosion prevention function, use thereby have widely.
External product generally all is employed in polyester film surface splash-proofing sputtering metal film and inorganic oxide film and makes on automobile or building glass Heat insulation type adhering film; This method complex equipments and equipment and product cost are all very high, and be serious with the product light pollution that adopts metal sputtering to obtain.
Patent CN1951985A discloses a kind of nano transparent heat-insulating of preparation earlier functional paint, is coated in the transparent membrane substrate surface to coating through the mode that sprays and brush then, behind the dry solidification, obtains transparent heat-insulating film.Its preparation method is comparatively easy; Transparent heat-insulating film with low cost, as to make has the good transparency and excellent effect of heat insulation simultaneously; But product coating technology controllable thickness property is poor in actual production; The brilliant point of impurity and resin is many, and it is short to be prone to the xanthochromia life-span, final products poor adhesive force and do not possess explosion prevention function.
Patent CN102259448A has announced a kind of nano ceramics coating that on polyester base material, prepares, and coating resists the product that preparation technologies such as scraping the quick glue of lamination produces then.This preparation method can make transparent thermal isolation film, but the product that obtains at a distance from ultraviolet ability, be prone to xanthochromia and do not possess explosion prevention function.。
The utility model content
The utility model purpose: the purpose of the utility model is in order to solve the deficiency of prior art, provides a kind of thermal insulation good, good at a distance from ultraviolet ray, infrared ray performance, and has the good transparency and the adhering film to glass of explosion prevention function.
Technical scheme: in order to realize above purpose; The utility model is described a kind of at a distance from the separated ultraviolet implosion guard film of infrared ray, and said glass-film comprises from left to right successively: anti-glue, ground floor optical grade film, compound adhesive liquid layer, the separated infrared enhancement Layer of ultraviolet, metal or metal oxide layer, the high clear PET film of second layer optical grade, installation glue-line and the mould release membrance scraped.
A kind of at a distance from the preparation method of infrared ray at a distance from ultraviolet implosion guard film, said preparation method's concrete steps are following:
(A1) adopt the optical grade film as ground floor optical grade film; Adopt the high clear PET film of optical grade as the high clear PET film of second layer optical grade;
(A2) form metal or the metal oxide layer of 0.2~3um to the high clear PET film of second layer optical grade with metal or metallic compound sputter or chemical vapor deposition;
(A3) at metal or the separated infrared enhancement Layer of ultraviolet of metal oxide layer outer surface coating 4~6um;
(A4) be coated with on the corona surface of ground floor optical grade film 4~8um composite glue solution, oven dry and and at a distance from the coated face of the infrared enhancement Layer of ultraviolet compound obtain compound heat insulation at a distance from ultraviolet function film;
The compound function film that (A5) will obtain advances the curing chamber maintenance and takes out after 20~26 hours at the anti-glue of scraping of the outer surface coating of ground floor optical grade film;
(A6) the compound separated ultraviolet implosion guard film of said separated infrared ray that obtains of glue-line and mould release membrance is being installed at a distance from the infrared enhancement Layer one side coating of ultraviolet.
Be provided with one deck thermosetting functional paint between the utility model said ground floor optical grade film and the compound adhesive liquid layer; The separated infrared ray that is provided with the thermosetting functional paint at a distance from ultraviolet implosion guard film order from left to right is successively: anti-glue, ground floor optical grade film, thermosetting functional paint, compound adhesive liquid layer, the separated infrared enhancement Layer of ultraviolet, metal or metal oxide layer, the high clear PET film of second layer optical grade, installation glue-line and the mould release membrance scraped.
The above-mentioned preparation method who has the separated infrared ray of thermosetting functional paint at a distance from ultraviolet implosion guard film, said preparation method's concrete steps are following:
(B1) adopt the optical grade film as ground floor optical grade film; Adopt the high clear PET film of optical grade as the high clear PET film of second layer optical grade;
(B2) corona one side at ground floor optical grade film is coated with 4-10um thermosetting functional paint and places curing chamber to carry out maintenance;
(B3) form metal or the metal oxide layer of 0.2~3um to the high clear PET film of second layer optical grade with metal or metallic compound sputter or chemical vapor deposition;
(B4) at metal or the separated infrared enhancement Layer of ultraviolet of metal oxide layer outer surface coating 4~6um;
(B5) be coated with on the corona surface of ground floor optical grade film 4~8um composite glue solution, oven dry and and at a distance from the coated face of the infrared enhancement Layer of ultraviolet compound obtain compound heat insulation at a distance from ultraviolet function film;
The compound function film that (B6) will obtain advances the curing chamber maintenance and takes out after 20~26 hours at the anti-glue of scraping of the outer surface coating of ground floor optical grade film;
(B7) the compound separated ultraviolet implosion guard film of said separated infrared ray that obtains of glue-line and mould release membrance is being installed at a distance from the infrared enhancement Layer one side coating of ultraviolet.
The optical grade of ground floor described in the utility model film is the high transparent membrane of optical grade.
The functional paint of thermosetting described in the utility model comprises: the acrylic acid of anti-xanthochromia, warp grind nano material and the mylar that disperses; Perhaps acrylic acid and warp grind the nano material of disperseing; Above-mentioned material is evenly stirred preparation and obtains said thermosetting functional paint, and can be through in the thermosetting functional paint, adding the color of transparent nano dyestuff or pigment adjustment thermosetting functional paint.Said nano material is: nano metal or nano-oxide or nano-carbide or nanometer sulfide.This thermosetting functional paint coating is coated on the ground floor optical grade film and is obtained fine definition, the heat insulation separated ultraviolet function film of high adhesion force; This coating can be adjusted the transmitance that transmitance that visible region reaches 5-90 %, infrared light district can 0.0001-90 %, the transmitance of ultraviolet light 0.0001-90 %.
Comprise at a distance from the infrared enhancement Layer of ultraviolet described in the utility model: the acrylic acid of anti-xanthochromia, mylar and the nano material of disperseing through grinding; Said nano material is: nano metal or nano-oxide or nano-carbide or nanometer sulfide; Saidly in the acrylic resin of anti-xanthochromia or the mylar of anti-xanthochromia, add the nano material of disperseing through grinding at a distance from the infrared enhancement Layer of ultraviolet, the glue that mixes carries out gluing again and has just formed the infrared enhancement Layer of separated ultraviolet.
Metal described in the utility model or metal oxide layer be with volume to volume vacuum sputtering equipment or chemical vapor deposition machine through with metal or metallic compound sputter or chemical vapor deposition to the high transparent membrane of PET optical grade.
The described composite glue solution of the utility model can adopt dry-type composite glue liquid such as polyurethane, polyester, acrylic acid, organosilicon; And preferably have anti-xanthochromia ability strong, have better flexible composite glue solution, so preferentially adopt aliphatic polyurethane, polyester dry-type composite glue liquid.
Installation glue-line described in the utility model adopts acrylate glue, the organic silica gel of the strong pressure-sensitive of anti-xanthochromia ability; The acrylate glue of the moisture-curable that perhaps anti-xanthochromia ability is strong, organic silica gel, aliphatic poly ester gum; The acrylic acid of the automatic vent absorbent-type that perhaps anti-xanthochromia ability is strong, organosilicon presser sensor glue.
The mould release membrance that mould release membrance described in the utility model adopts the silicone release agent to be coated with is exclusively used in the compound usefulness of acrylate glue, organic silica gel with pressure-sensitive; Perhaps adopt the common high transparent membrane of PET optical grade to be exclusively used in and peel off back noresidue, the acrylic acid of automatic vent absorbent-type, the compound usefulness of organosilicon presser sensor glue; Perhaps adopt a kind of mould release membrance with surface micro chondritic that makes through coating in silicone release agent or other coating cured resins that is dispersed in of glass microballoon, fine silica powder, transparent resin microballoon, any kind that can be used for the utility model is installed the compound of glue-line.The preferred mould release membrance that adopts the surface micro chondritic in the utility model adopts this mould release membrance can make the installation glue-line have the microspheroidal scattering function, and it is said at a distance from the heat-insulating capability of infrared ray at a distance from ultraviolet implosion guard film to have increased the utility model.
The described anti-glue of scraping of the utility model adopts acrylic acid or organosilicon light-cured resin, or in above-mentioned material, adds through grinding the nano material of disperseing and stir preparation and obtain, and can be through adding transparent nano dyestuff or pigment adjustment color.
Beneficial effect: the utility model compared with prior art has the following advantages:
1, the utility model described at a distance from infrared ray at a distance from ultraviolet implosion guard film realized simultaneously heat insulation good, at a distance from ultraviolet ray, the infrared ray performance is good, has the good transparency, explosion-proof function.
2, in the utility model through using nano material, can regulate visible light as required, the transmitance of infrared light, ultraviolet light is produced the product of customer requirement and long product lifecycle.
3, the utility model is described need not to adopt complicated production equipment at a distance from the separated ultraviolet preparation method of infrared ray, and the preparation method is simple, and process controllability is high, the long product lifecycle of producing.
Description of drawings
Fig. 1 is the structural representation of embodiment 1 in the utility model.
Fig. 2 is the structural representation of embodiment 2 in the utility model.
Fig. 3 is the structural representation of embodiment 3 in the utility model.
The specific embodiment:
Below in conjunction with accompanying drawing and specific embodiment; Further illustrate the utility model; Should understand these embodiment only be used to the utility model is described and be not used in the restriction the utility model scope; After reading the utility model, those skilled in the art all fall within the application's accompanying claims institute restricted portion to the modification of the various equivalent form of values of the utility model.
Embodiment 1
As shown in Figure 1 a kind of at a distance from infrared ray at a distance from ultraviolet implosion guard film, comprise successively from left to right: anti-ly scrape glue 1, ground floor optical grade film 2, thermosetting functional paint 3, compound adhesive liquid layer 4, at a distance from the high clear PET film of the infrared enhancement Layer of ultraviolet 5, metal or metal oxide layer 6, second layer optical grade 7, glue-line 8 and mould release membrance 9 are installed; Wherein said ground floor optical grade film 2 adopts the colorless and transparent film of optical grade.
Present embodiment also discloses the preparation method of above-mentioned implosion guard film, and concrete steps are following:
(B1) adopt the optical grade film as ground floor optical grade film 2; Adopt the high clear PET film of optical grade as the high clear PET film 7 of second layer optical grade;
(B2) corona one side at ground floor optical grade film 2 is coated with 4um thermosetting functional paint 3 and places curing chamber to carry out maintenance 72 hours; The nano silver dispersion stirring that the mylar of the anti-xanthochromia of said thermosetting functional paint 3 employings and warp grind dispersion is prepared and is obtained;
(B3) be splashed to metal or the metal oxide layer 6 that forms 0.5um on the high clear PET film 7 of second layer optical grade with nanometer tungsten oxide;
(B4) at metal or the separated infrared enhancement Layer 5 of ultraviolet of metal oxide layer 6 outer surfaces coating 5um; Should stir formulated at a distance from acrylic acid and the nano vanadium dioxide dispersion liquid that the infrared enhancement Layer 5 of ultraviolet is anti-xanthochromia;
(B5) coating 6um composite glue solution on the corona surface of ground floor optical grade film 2, oven dry and and at a distance from the coated face of the infrared enhancement Layer 5 of ultraviolet compound obtain compound heat insulation at a distance from ultraviolet function film; This composite glue solution adopt anti-xanthochromia ability strong, have a better flexible aliphatic polyurethane composite glue solution;
The compound function film that (B6) will obtain advances the curing chamber maintenance and takes out after 24 hours at the anti-glue 1 of scraping of the outer surface coating of ground floor optical grade film 2; This is transparent anti-scrape acrylate glue, light trigger and nano silicon dispersion liquid that glue adopts anti-xanthochromia and together stirs and form;
(B7) in the infrared enhancement Layer 5 one sides coating of separated ultraviolet glue-line 8 and the mould release membrance 9 compound separated ultraviolet implosion guard films of said separated infrared ray that obtain are installed.
Embodiment 2
As shown in Figure 2 a kind of at a distance from infrared ray at a distance from ultraviolet implosion guard film, comprise successively from left to right: anti-ly scrape glue 1, ground floor optical grade film 2, thermosetting functional paint 3, compound adhesive liquid layer 4, at a distance from the high clear PET film of the infrared enhancement Layer of ultraviolet 5, metal or metal oxide layer 6, second layer optical grade 7, glue-line 8 and mould release membrance 9 are installed; Wherein said ground floor optical grade film 2 adopts the coloured film of optical grade; Its preparation method is with embodiment 1.
Embodiment 3
As shown in Figure 3 a kind of at a distance from infrared ray at a distance from ultraviolet implosion guard film, comprise successively from left to right: anti-ly scrape glue 1, ground floor optical grade film 2, compound adhesive liquid layer 4, at a distance from the high clear PET film of the infrared enhancement Layer of ultraviolet 5, metal or metal oxide layer 6, second layer optical grade 7, glue-line 8 and mould release membrance 9 are installed; Wherein said ground floor optical grade film 2 adopts the coloured film of optical grade.
Present embodiment is said following at a distance from the preparation method of ultraviolet implosion guard film at a distance from infrared ray:
(A1) adopt the optical grade film as ground floor optical grade film 2; Adopt the high clear PET film of optical grade as the high clear PET film 7 of second layer optical grade;
(A2) tungsten oxide and the nano-mixture of molybdenum oxide that mix with halogens are through metal or the metal oxide layer 6 of chemical vapor deposition formation 2um to the high clear PET film 7 of second layer optical grade;
(A3) at metal or the separated infrared enhancement Layer 5 of ultraviolet of metal oxide layer 6 outer surfaces coating 6um; Should stir formulated at a distance from acrylic acid and the nano vanadium dioxide dispersion liquid that the infrared enhancement Layer 5 of ultraviolet is anti-xanthochromia;
(A4) coating 4um composite glue solution on the corona surface of ground floor optical grade film 2, oven dry and and at a distance from the coated face of the infrared enhancement Layer 5 of ultraviolet compound obtain compound heat insulation at a distance from ultraviolet function film; This composite glue solution can adopt anti-xanthochromia ability strong, have a better flexible aliphatic polyurethane composite glue solution;
The compound function film that (A5) will obtain advances the curing chamber maintenance and takes out after 26 hours at the anti-glue 1 of scraping of the outer surface coating of ground floor optical grade film 2; This is transparent anti-scrape acrylate glue, light trigger and nano silicon dispersion liquid that glue adopts anti-xanthochromia and together stirs and form;
(A6) in the infrared enhancement Layer 5 one sides coating of separated ultraviolet glue-line 8 and the mould release membrance 9 compound separated ultraviolet implosion guard films of said separated infrared ray that obtain are installed.

Claims (3)

1. a separated infrared ray is at a distance from ultraviolet implosion guard film, and it is characterized in that: said glass-film comprises from left to right successively: anti-glue (1), ground floor optical grade film (2), compound adhesive liquid layer (4), the separated infrared enhancement Layer of ultraviolet (5), metal or metal oxide layer (6), the high clear PET film of second layer optical grade (7), installation glue-line (8) and the mould release membrance (9) scraped.
2. according to claim 1 a kind of at a distance from the separated ultraviolet implosion guard film of infrared ray, it is characterized in that: be provided with one deck thermosetting functional paint (3) between said ground floor optical grade film (2) and the compound adhesive liquid layer (4).
3. according to claim 1 a kind of at a distance from the separated ultraviolet implosion guard film of infrared ray, it is characterized in that: said ground floor optical grade film (2) is the high transparent membrane of optical grade.
CN 201220152761 2012-04-12 2012-04-12 Explosion-proof glass film capable of blocking infrared and ultraviolet Expired - Fee Related CN202573206U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725218A (en) * 2013-12-31 2014-04-16 浙江世窗光学薄膜制造有限公司 Total ultraviolet-proof automobile film and manufacturing method thereof
CN108977110A (en) * 2018-08-24 2018-12-11 宁波瑞凌辐射制冷科技有限公司 A kind of radiation refrigeration automobile window films
CN109254340A (en) * 2017-07-12 2019-01-22 张家港康得新光电材料有限公司 Infrared and ultraviolet ends composition, infrared and ultraviolet cut film and infrared and ultraviolet cut film application

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725218A (en) * 2013-12-31 2014-04-16 浙江世窗光学薄膜制造有限公司 Total ultraviolet-proof automobile film and manufacturing method thereof
CN103725218B (en) * 2013-12-31 2015-09-16 浙江世窗光学薄膜制造有限公司 Total ultraviolet-proof automobile film and manufacture method thereof
CN109254340A (en) * 2017-07-12 2019-01-22 张家港康得新光电材料有限公司 Infrared and ultraviolet ends composition, infrared and ultraviolet cut film and infrared and ultraviolet cut film application
CN109254340B (en) * 2017-07-12 2021-08-10 张家港康得新光电材料有限公司 Infrared and ultraviolet cut-off composition, infrared and ultraviolet cut-off film and application of infrared and ultraviolet cut-off film
CN108977110A (en) * 2018-08-24 2018-12-11 宁波瑞凌辐射制冷科技有限公司 A kind of radiation refrigeration automobile window films

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C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: SUZHOU XILIN OPTOELECTRONIC TECHNOLOGY INDUSTRY CO

Free format text: FORMER NAME: SUZHOU KINGHIGH FILM TECHNOLOGY DEVELOPMENT CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: 215400, 8, Kai Xing Road, old gate area, pontoon bridge, Suzhou, Jiangsu, Taicang

Patentee after: SUZHOU XILIN OPTOELECTRONICS TECHNOLOGY INDUSTRY CO., LTD.

Address before: 215400, 8, Kai Xing Road, old gate area, pontoon bridge, Suzhou, Jiangsu, Taicang

Patentee before: Suzhou Kinghigh Membrane Technology Development Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121205

Termination date: 20180412